A flame retardant containing multiple antiflaming elements usually exhibits high-efficient flame retardancy. Here, a novel P/N/Si-containing ammonium polyphosphate derivative(APTES-APP) is synthesized from ammonium po...A flame retardant containing multiple antiflaming elements usually exhibits high-efficient flame retardancy. Here, a novel P/N/Si-containing ammonium polyphosphate derivative(APTES-APP) is synthesized from ammonium polyphosphate(APP) and silane coupling agent(3-aminopropyl)triethoxysilane(APTES)via cation exchange, which is quite different in the chemical structure from APTES-modified APP for retaining silicon hydroxyls. APTES-APP is highly efficient for the epoxy resin. 8%(mass) APTES-APP imparts excellent flame retardancy to the epoxy resin, with a V-0 rating at the UL-94 test(1.6 mm)and an LOI value of 26%(vol). The peak heat release rate and total smoke production of the flameretardant epoxy resin are decreased by 68.1% and 31.3%, respectively. The synergy of P/N/Si contributes to the well-expanded char residue with a strong and dense surface layer, which is a very good barrier against heat and mass transfer. Besides, there is no significant deterioration in the mechanical properties of flame-retardant epoxy resin thanks to silicon hydroxyls forming hydrogen bonds with epoxy molecules. Meanwhile, other molecules can be grafted onto APTES-APP via these silicon hydroxyls, if needed.Briefly, this work has developed a new strategy for amino silane as flame retardants. In conjunction with a low-cost and simple preparation method, APTES-APP has a promising prospect in the high-performance flame-retardant epoxy.展开更多
The chemical composition and high wear resistance of steel slag(SS)make it a potential alternative to traditional inorganic fillers.3-Aminopropyltriethoxysilane(KH550)modified steel slag(MSS)was successfully prepared,...The chemical composition and high wear resistance of steel slag(SS)make it a potential alternative to traditional inorganic fillers.3-Aminopropyltriethoxysilane(KH550)modified steel slag(MSS)was successfully prepared,and its application in epoxy(EP)anti-corrosion coating was introduced.Due to the grafting of silane coupling agent functional groups onto the surface of SS,MSS exhibited improved solubility in xylene organic solvent and reduced agglomeration.When the MSS content was 15 wt.%,the contact angle of the MSS/EP composite coating was 101°,and the abrasion was only 0.07 g,compared with 56.2°and 0.13 g,respectively,for the pure EP coating.The corrosion resistance of coatings was investigated by performing the electrochemical test(impedance)after immersion in a 3.5 wt.%NaCl solution.The electrochemical test results showed that the impedance modulus of the 15 wt.%MSS/EP composite coating at low frequency(Z_(f)=0.01 Hz)was approximately 1.08×10^(7)Ωcm^(2),which was two orders of magnitude higher than that of the pure EP coating.展开更多
Nano-silica treated with different kinds of coupling agent(KH550, A-143, A-151) was used to modify the surface condition of glass fiber, and then, the modified glass fiber/ unsaturated polyester resin(UPR) composites ...Nano-silica treated with different kinds of coupling agent(KH550, A-143, A-151) was used to modify the surface condition of glass fiber, and then, the modified glass fiber/ unsaturated polyester resin(UPR) composites materials were prepared. Scanning electron microscopy(SEM), dynamic mechanical analysis(DMA), and impact test were used to characterize the composite materials' structure and properties. The morphology of composite materials shows that the adhesion between nano-silica and glass fiber is improved when silane coupling agent is added in. The DMA and impact test results show that silane coupling agent(especially KH550 and A-151) could effectively improve the composite's mechanical properties. When the dose of KH550 was 0.1%(m ︰m), the storage modulus and impact strength reached the maximum.展开更多
Polyurethane/desulfurization ash(PU/DA)composites were synthesized using"one-pot method",with the incorporation of a silane coupling agent(KH550)as a"molecular bridge"to facilitate the integration ...Polyurethane/desulfurization ash(PU/DA)composites were synthesized using"one-pot method",with the incorporation of a silane coupling agent(KH550)as a"molecular bridge"to facilitate the integration of DA as hard segments into the PU molecular chain.The effects of DA content(φ)on the mechanical properties,thermal stability,and hydrophobicity of PU,both before and after the addition of KH550,were thoroughly examined.The results of microscopic mechanism analysis confirmed that KH550 chemically modified the surface of DA,facilitating its incorporation into the polyurethane molecular chain,thereby significantly enhancing the compatibility and dispersion of DA within the PU matrix.When the mass fraction of modified DA(MDA)reached 12%,the mechanical properties,thermal stability,and hydrophobicity of the composites were substantially improved,with the tensile strength reaching 14.9 MPa,and the contact angle measuring 100.6°.展开更多
Based on the difference of the Y-terminal functional group of the silane coupling agent(Y-Si(X)_(3)),four different silane coupling agents were employed to pretreat the surface of the NdFeB powders.The effects of sila...Based on the difference of the Y-terminal functional group of the silane coupling agent(Y-Si(X)_(3)),four different silane coupling agents were employed to pretreat the surface of the NdFeB powders.The effects of silane coupling agents on the flowability and compressibility of compounds for preparing bonded NdFeB magnets were studied.It is indicated that compounds pretreated by silane coupling agents have weaker friction and meshing force.The apparent density is increased by 0.3 g/cm^(3 )compared with the compound without silane coupling agent,and the radial crushing strength is significantly increased by about 3-4 times.In addition,the epoxy resin is more evenly distributed on the surface of the compounds treated by silane coupling agents observed by scanning electron microscopy,and some agglomerated particles are produced.Also,the compressibility of compounds with silane coupling agents is significantly improved due to the fact that hardening exponents are reduced.However,the addition of silane coupling agents has almost no effect on the magnetic properties of bonded magnets.The special energy was used to manifest the flowability of magnetic powder particles representing the macroscopic performance of the force between powder particles,providing a new direction for the study of the interface compatibility of two-phase or multiphase composite materials.展开更多
To improve corrosion inhibition performance of copper foil with a novel two-step electrochemical modification processes,the surface of 35μm copper foils was coated with graphene oxide(GO)via electrochemical method at...To improve corrosion inhibition performance of copper foil with a novel two-step electrochemical modification processes,the surface of 35μm copper foils was coated with graphene oxide(GO)via electrochemical method at first step,then was further coated with 3-aminopropyltrimethoxysilane(APTS)at the second step.For the first step the copper foil acted as anode,and as cathode for the second one(we labeled it as E-GO).Optimum coating parameters for the preparation of E-GO coating are 5 V and 1 min with ratio of APTS/deionized water(DI)1.5/98.5(v/v).The physicochemical properties of modified coating were studied by X-ray diffraction(XRD),scanning electron microscopy(SEM)and hydrophilicity test.Electrochemical behavior of different samples were also investigated.The experimental results indicate that anti-corrosion performance is significantly improved with two-step modified coating.And E-GO coating shows more positive corrosion potential and the highest corrosion resistance rate than others according to the Tafel curve.It is also found that surface hydrophobicity of E-GO coating is significantly improved.展开更多
Ag_(3)PO_(4)exhibits a high photocatalytic activity if exposed to visible light,however,it displays bottlenecks such as poor cycle-stability and mediocre ability to degrade methyl orange(MO)because of limited adsorpti...Ag_(3)PO_(4)exhibits a high photocatalytic activity if exposed to visible light,however,it displays bottlenecks such as poor cycle-stability and mediocre ability to degrade methyl orange(MO)because of limited adsorption of MO molecules onto its surface.In this study,nano TiO_(2)prepared by a one-step method was combined with Ag_(3)PO_(4)to form a TiO_(2)@Ag_(3)PO_(4)heterojunction in order to improve this material both in terms of photocatalysis and photostability.After adding a KH-570 silane coupling agent,the photocatalytic performance of TiO_(2)@Ag_(3)PO_(4)could be improved even further,with the degradation rate of MO maintained at more than 90%after three cycles of visible in light.展开更多
In the current situation where the practical application of silicon anode materials encounters great challenges,silicon oxide(SiO_(x),0≤x≤2)has attracted the attention of researchers due to its relatively small volu...In the current situation where the practical application of silicon anode materials encounters great challenges,silicon oxide(SiO_(x),0≤x≤2)has attracted the attention of researchers due to its relatively small volume expansion,stable cycling performance,and low cost,which is possible to realize commercial applications earlier than silicon anode.However,it remains a challenge to prepare SiO_(x)materials with long-term stable cycling performance and high Coulombic efficiency using low-cost methods.In this work,SiO_(x)anode material with high Coulombic efficiency and good long-term cycling stability was prepared at a low cost by hydrolysis of siloxane and in situ polymerization of phenolic resin.The hydrolysis of siloxane was further regulated by different silane coupling agents to regulate the size and microstructure of prepared SiO_(x)materials,which displayed the substantially improved electrochemical performance.The excellent electrochemical performance of SiO_(x)prepared by regulated hydrolysis of siloxane with silane coupling agents is attributed to the effect of silane coupling agent on size and microstructure of SiO_(x),revealing that the strategy of modulating the hydrolysis of siloxane by silane coupling agent is a potential method to prepare high-performance SiO_(x)materials.展开更多
Surface modification is a fascinating way to improve the compounding effect between inorganic fillers and polymers.In this study,zirconium tungsten phosphate(ZWP) with negative thermal expansion was surface modified b...Surface modification is a fascinating way to improve the compounding effect between inorganic fillers and polymers.In this study,zirconium tungsten phosphate(ZWP) with negative thermal expansion was surface modified by silane coupling agent 3-(Trimethoxysilyl)propyl methacrylate.The effects of surface modification and the modification mechanism were analyzed in detail by X-ray diffractometer,scanning electron microscopy,Fourier transform infrared spectroscopy and thermal mechanical analysis.The surface modification could effectively reduce the thermal expansion properties of the composite.When the added amount of 3-methacryloxypropyl trimethoxysilaneSilane(trade name:KH570) is 0.50 wt%,the thermal expansion coefficient of ZWP/Aromatic polyimide composite decreased by 9.76%.The surface modification also can effectively improve the dielectric performance of aromatic polyimides.The present work provides one new way to improve the thermal expansion behavior of composites.展开更多
Metakaolin(MK)is an important refractory raw material,which has been used as a cementitious material.In order to improve the bonding strength of MK,the composite cementitious materials were prepared by MK mixed with h...Metakaolin(MK)is an important refractory raw material,which has been used as a cementitious material.In order to improve the bonding strength of MK,the composite cementitious materials were prepared by MK mixed with hydrat-able alumina(HA)and microsilica(MS),respectively.The silane coupling agent(SCA)was introduced as a modifying agent.The rheological properties of MK-based composite cementitious slurries were investigated.The mechanical properties of corundum castables bonded with the composite cementitious materials and calcium aluminate cement(CAC)were comparatively studied.The results show that SCA improves the rheological properties of MK-based composite cementitious materials.The slurry of MK–MS mixture flows in a plastic manner,while the slurry of MK–HA mixture presents pseudoplastic flow.The addition of SCA reduces the yield stress value of the MK–HA slurry.The bonding strength of castables bonded with MK-based composite cementitious materials is lower than that of CAC bonding castables.The room temperature strength of MK–MS composite bonding castable remains the highest after being treated either at 1100 or 1550°C,and its high temperature modulus of rupture is higher than that of CAC bonding castables with microsilica added.展开更多
基金financially supported by the National Natural Science Foundation of China (22178242)。
文摘A flame retardant containing multiple antiflaming elements usually exhibits high-efficient flame retardancy. Here, a novel P/N/Si-containing ammonium polyphosphate derivative(APTES-APP) is synthesized from ammonium polyphosphate(APP) and silane coupling agent(3-aminopropyl)triethoxysilane(APTES)via cation exchange, which is quite different in the chemical structure from APTES-modified APP for retaining silicon hydroxyls. APTES-APP is highly efficient for the epoxy resin. 8%(mass) APTES-APP imparts excellent flame retardancy to the epoxy resin, with a V-0 rating at the UL-94 test(1.6 mm)and an LOI value of 26%(vol). The peak heat release rate and total smoke production of the flameretardant epoxy resin are decreased by 68.1% and 31.3%, respectively. The synergy of P/N/Si contributes to the well-expanded char residue with a strong and dense surface layer, which is a very good barrier against heat and mass transfer. Besides, there is no significant deterioration in the mechanical properties of flame-retardant epoxy resin thanks to silicon hydroxyls forming hydrogen bonds with epoxy molecules. Meanwhile, other molecules can be grafted onto APTES-APP via these silicon hydroxyls, if needed.Briefly, this work has developed a new strategy for amino silane as flame retardants. In conjunction with a low-cost and simple preparation method, APTES-APP has a promising prospect in the high-performance flame-retardant epoxy.
基金the University Synergy Innovation Program of Anhui Province(GXXT-2020-072).
文摘The chemical composition and high wear resistance of steel slag(SS)make it a potential alternative to traditional inorganic fillers.3-Aminopropyltriethoxysilane(KH550)modified steel slag(MSS)was successfully prepared,and its application in epoxy(EP)anti-corrosion coating was introduced.Due to the grafting of silane coupling agent functional groups onto the surface of SS,MSS exhibited improved solubility in xylene organic solvent and reduced agglomeration.When the MSS content was 15 wt.%,the contact angle of the MSS/EP composite coating was 101°,and the abrasion was only 0.07 g,compared with 56.2°and 0.13 g,respectively,for the pure EP coating.The corrosion resistance of coatings was investigated by performing the electrochemical test(impedance)after immersion in a 3.5 wt.%NaCl solution.The electrochemical test results showed that the impedance modulus of the 15 wt.%MSS/EP composite coating at low frequency(Z_(f)=0.01 Hz)was approximately 1.08×10^(7)Ωcm^(2),which was two orders of magnitude higher than that of the pure EP coating.
基金Supported by the National Natural Science Foundation of of China(J1210061)
文摘Nano-silica treated with different kinds of coupling agent(KH550, A-143, A-151) was used to modify the surface condition of glass fiber, and then, the modified glass fiber/ unsaturated polyester resin(UPR) composites materials were prepared. Scanning electron microscopy(SEM), dynamic mechanical analysis(DMA), and impact test were used to characterize the composite materials' structure and properties. The morphology of composite materials shows that the adhesion between nano-silica and glass fiber is improved when silane coupling agent is added in. The DMA and impact test results show that silane coupling agent(especially KH550 and A-151) could effectively improve the composite's mechanical properties. When the dose of KH550 was 0.1%(m ︰m), the storage modulus and impact strength reached the maximum.
基金Funded by the National Key Research and Development Project(No.2019YFC1908204)the Guiding Projects in Fujian Province(No.2023H0023)the Fuzhou Science and Technology Plan Project(No.2022-P-012)。
文摘Polyurethane/desulfurization ash(PU/DA)composites were synthesized using"one-pot method",with the incorporation of a silane coupling agent(KH550)as a"molecular bridge"to facilitate the integration of DA as hard segments into the PU molecular chain.The effects of DA content(φ)on the mechanical properties,thermal stability,and hydrophobicity of PU,both before and after the addition of KH550,were thoroughly examined.The results of microscopic mechanism analysis confirmed that KH550 chemically modified the surface of DA,facilitating its incorporation into the polyurethane molecular chain,thereby significantly enhancing the compatibility and dispersion of DA within the PU matrix.When the mass fraction of modified DA(MDA)reached 12%,the mechanical properties,thermal stability,and hydrophobicity of the composites were substantially improved,with the tensile strength reaching 14.9 MPa,and the contact angle measuring 100.6°.
基金Project supported by Beijing Youth Top-notch Team Support Project of China(2018000021223TD10)Hebei Province Fund for Transformation of Major Science and Technology Achievements of China(19041029Z)Hebei Province International Science and Technology Cooperation Base Construction Project of China(20591002D)。
文摘Based on the difference of the Y-terminal functional group of the silane coupling agent(Y-Si(X)_(3)),four different silane coupling agents were employed to pretreat the surface of the NdFeB powders.The effects of silane coupling agents on the flowability and compressibility of compounds for preparing bonded NdFeB magnets were studied.It is indicated that compounds pretreated by silane coupling agents have weaker friction and meshing force.The apparent density is increased by 0.3 g/cm^(3 )compared with the compound without silane coupling agent,and the radial crushing strength is significantly increased by about 3-4 times.In addition,the epoxy resin is more evenly distributed on the surface of the compounds treated by silane coupling agents observed by scanning electron microscopy,and some agglomerated particles are produced.Also,the compressibility of compounds with silane coupling agents is significantly improved due to the fact that hardening exponents are reduced.However,the addition of silane coupling agents has almost no effect on the magnetic properties of bonded magnets.The special energy was used to manifest the flowability of magnetic powder particles representing the macroscopic performance of the force between powder particles,providing a new direction for the study of the interface compatibility of two-phase or multiphase composite materials.
基金Funded by the National Natural Science Foundation of China(Nos.21671086 and 21761013)the Ganzhou Key Research&Development Projects(Ganshikefa[2019]60)。
文摘To improve corrosion inhibition performance of copper foil with a novel two-step electrochemical modification processes,the surface of 35μm copper foils was coated with graphene oxide(GO)via electrochemical method at first step,then was further coated with 3-aminopropyltrimethoxysilane(APTS)at the second step.For the first step the copper foil acted as anode,and as cathode for the second one(we labeled it as E-GO).Optimum coating parameters for the preparation of E-GO coating are 5 V and 1 min with ratio of APTS/deionized water(DI)1.5/98.5(v/v).The physicochemical properties of modified coating were studied by X-ray diffraction(XRD),scanning electron microscopy(SEM)and hydrophilicity test.Electrochemical behavior of different samples were also investigated.The experimental results indicate that anti-corrosion performance is significantly improved with two-step modified coating.And E-GO coating shows more positive corrosion potential and the highest corrosion resistance rate than others according to the Tafel curve.It is also found that surface hydrophobicity of E-GO coating is significantly improved.
基金This work was supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.18KJD430009)the Qing Lan Project of Jiangsu Province.
文摘Ag_(3)PO_(4)exhibits a high photocatalytic activity if exposed to visible light,however,it displays bottlenecks such as poor cycle-stability and mediocre ability to degrade methyl orange(MO)because of limited adsorption of MO molecules onto its surface.In this study,nano TiO_(2)prepared by a one-step method was combined with Ag_(3)PO_(4)to form a TiO_(2)@Ag_(3)PO_(4)heterojunction in order to improve this material both in terms of photocatalysis and photostability.After adding a KH-570 silane coupling agent,the photocatalytic performance of TiO_(2)@Ag_(3)PO_(4)could be improved even further,with the degradation rate of MO maintained at more than 90%after three cycles of visible in light.
基金This study was financially supported by the National Natural Science Foundation of China(No.22204159)the Instrument Developing Project of the Chinese Academy of Sciences(No.YJKYYQ20210003)Natural Science Foundation of Jilin Province(No.20210101402JC)。
文摘In the current situation where the practical application of silicon anode materials encounters great challenges,silicon oxide(SiO_(x),0≤x≤2)has attracted the attention of researchers due to its relatively small volume expansion,stable cycling performance,and low cost,which is possible to realize commercial applications earlier than silicon anode.However,it remains a challenge to prepare SiO_(x)materials with long-term stable cycling performance and high Coulombic efficiency using low-cost methods.In this work,SiO_(x)anode material with high Coulombic efficiency and good long-term cycling stability was prepared at a low cost by hydrolysis of siloxane and in situ polymerization of phenolic resin.The hydrolysis of siloxane was further regulated by different silane coupling agents to regulate the size and microstructure of prepared SiO_(x)materials,which displayed the substantially improved electrochemical performance.The excellent electrochemical performance of SiO_(x)prepared by regulated hydrolysis of siloxane with silane coupling agents is attributed to the effect of silane coupling agent on size and microstructure of SiO_(x),revealing that the strategy of modulating the hydrolysis of siloxane by silane coupling agent is a potential method to prepare high-performance SiO_(x)materials.
基金supported by the national science foundation of china (Nos. 22071221, 21905252)the natural science foundation of Henan province (Nos. 182300410192, 212300410086)。
文摘Surface modification is a fascinating way to improve the compounding effect between inorganic fillers and polymers.In this study,zirconium tungsten phosphate(ZWP) with negative thermal expansion was surface modified by silane coupling agent 3-(Trimethoxysilyl)propyl methacrylate.The effects of surface modification and the modification mechanism were analyzed in detail by X-ray diffractometer,scanning electron microscopy,Fourier transform infrared spectroscopy and thermal mechanical analysis.The surface modification could effectively reduce the thermal expansion properties of the composite.When the added amount of 3-methacryloxypropyl trimethoxysilaneSilane(trade name:KH570) is 0.50 wt%,the thermal expansion coefficient of ZWP/Aromatic polyimide composite decreased by 9.76%.The surface modification also can effectively improve the dielectric performance of aromatic polyimides.The present work provides one new way to improve the thermal expansion behavior of composites.
基金The present work was supported by National Natural Science Foundation of China(Grant Nos.U21A2057 and U20A20239)College Students'Innovative Entrepreneurial Training Plan Program of Hubei Province(Grant No.20181088100)。
文摘Metakaolin(MK)is an important refractory raw material,which has been used as a cementitious material.In order to improve the bonding strength of MK,the composite cementitious materials were prepared by MK mixed with hydrat-able alumina(HA)and microsilica(MS),respectively.The silane coupling agent(SCA)was introduced as a modifying agent.The rheological properties of MK-based composite cementitious slurries were investigated.The mechanical properties of corundum castables bonded with the composite cementitious materials and calcium aluminate cement(CAC)were comparatively studied.The results show that SCA improves the rheological properties of MK-based composite cementitious materials.The slurry of MK–MS mixture flows in a plastic manner,while the slurry of MK–HA mixture presents pseudoplastic flow.The addition of SCA reduces the yield stress value of the MK–HA slurry.The bonding strength of castables bonded with MK-based composite cementitious materials is lower than that of CAC bonding castables.The room temperature strength of MK–MS composite bonding castable remains the highest after being treated either at 1100 or 1550°C,and its high temperature modulus of rupture is higher than that of CAC bonding castables with microsilica added.