In 1985,Bibby and Dale first reported the synthesis of silica-sodalite from organic solvent such as ethylene glycol or propanol.In 1987, Van Erp and his coworkers reported the formation of crystalline aluminosilicates...In 1985,Bibby and Dale first reported the synthesis of silica-sodalite from organic solvent such as ethylene glycol or propanol.In 1987, Van Erp and his coworkers reported the formation of crystalline aluminosilicates in organic solvents such as hexanol,glycol, glycerol, sulfolane and pyridine. Because the concepts effective in the aqueous synthesis cannot be simply applied to the nonaqueous media,the formation mechanism of zeolite in the nonaqueous system has not been investigated yet.展开更多
Aluminum-ion batteries(AIBs)are recognized as one of the promising candidates for future energy stor-age devices due to their merits of cost-effectiveness,high voltage,and high-power operation.Many efforts have been d...Aluminum-ion batteries(AIBs)are recognized as one of the promising candidates for future energy stor-age devices due to their merits of cost-effectiveness,high voltage,and high-power operation.Many efforts have been devoted to the development of cathode materials,and the progress has been well summarized in this review paper.Moreover,in addition to materials,the intercalation mechanism also plays a key role in determining cell per-formance.Here,the research progress of cathode materials and corresponding ion intercalation mechanism in AIBs are summarized,including intercalation of AlCl_(4)-,intercala-tion of Al^(3+),and coordination of AlCl_(2)^(+)/AlCl^(2+).This minireview provides comprehensive guidance on the design of cathode materials for the development of high-performance AIBs.展开更多
文摘In 1985,Bibby and Dale first reported the synthesis of silica-sodalite from organic solvent such as ethylene glycol or propanol.In 1987, Van Erp and his coworkers reported the formation of crystalline aluminosilicates in organic solvents such as hexanol,glycol, glycerol, sulfolane and pyridine. Because the concepts effective in the aqueous synthesis cannot be simply applied to the nonaqueous media,the formation mechanism of zeolite in the nonaqueous system has not been investigated yet.
基金financially supported by the National key R&D Program of China (No. 2018YFB0104001)。
文摘Aluminum-ion batteries(AIBs)are recognized as one of the promising candidates for future energy stor-age devices due to their merits of cost-effectiveness,high voltage,and high-power operation.Many efforts have been devoted to the development of cathode materials,and the progress has been well summarized in this review paper.Moreover,in addition to materials,the intercalation mechanism also plays a key role in determining cell per-formance.Here,the research progress of cathode materials and corresponding ion intercalation mechanism in AIBs are summarized,including intercalation of AlCl_(4)-,intercala-tion of Al^(3+),and coordination of AlCl_(2)^(+)/AlCl^(2+).This minireview provides comprehensive guidance on the design of cathode materials for the development of high-performance AIBs.
