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热蒸镀-原位反应法制备的Mo-Si-X-C(X=Al,Ti)复相陶瓷涂层的微观结构和力学性能 被引量:1
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作者 徐永龙 郝安林 +5 位作者 孙威 熊翔 彭铮 陈耘田 陈招科 王雅雷 《中国有色金属学报》 EI CAS CSCD 北大核心 2016年第11期2326-2339,共14页
采用热蒸镀原位反应法制备Mo-Si-X-C(X=Al,Ti)碳基陶瓷涂层。利用X射线仪、扫描电子显微镜和纳米压痕测试仪对涂层的微观结构和力学性能进行表征,研究成分及热蒸镀工艺参数对涂层的物相组成、微观结构和力学性能的影响,并揭示涂层的形... 采用热蒸镀原位反应法制备Mo-Si-X-C(X=Al,Ti)碳基陶瓷涂层。利用X射线仪、扫描电子显微镜和纳米压痕测试仪对涂层的微观结构和力学性能进行表征,研究成分及热蒸镀工艺参数对涂层的物相组成、微观结构和力学性能的影响,并揭示涂层的形成机制。结果表明:不同组分蒸镀母料在1550℃、Ar气氛条件下,由于不同蒸气压诱发各异的扩散路径,从而使原位反应生成Mo-Si-X-C(X=Al,Ti)复相陶瓷涂层的形貌、相成分及分布明显不同。添加Ti和Al元素有利于分别生成(Ti_(0.8)Mo_(0.2)Si_2相和Mo(Si,Al)_2相,促进热蒸镀过程;随着温度的升高,基体表面Si黏性减弱,同时流动性增强,涂层中钼硅化物消失;1800℃真空环境下涂层中的SiC晶粒异常长大,破坏涂层结构,导致涂层失效。力学性能表明:同时添加Al、Ti元素,形成复杂多相界面结构的23Mo-63Si-7Ti-7Al陶瓷涂层的力学性能最优,其抗压强度达到19.584GPa,显微硬度达到1848HV及弹性模量达到255.124 GPa。 展开更多
关键词 热蒸镀法 原位反应法 SIC (ti0.8mo0.2)si2 涂层 碳基材料
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Characteristics of Faigue Crack Initiation in Ti-5Al-4Sn-2Zr-1Mo-0.7Nd-0.25Si Alloy
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作者 Jiafeng LEP Yuyin LIU +3 位作者 Shaoxuan GUAN Qingjiang WANG Zhongguang WANG Dong LI and Zhuangqi HU(State Key Lab. for Fatigue and Fracture of Materials, Institute of Metal Research, Chinese Academy of Sciences,Shenyan 110015, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1997年第3期238-240,共3页
The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue cr... The characteristics of fatigue crack initiation in Ti-5AI-4Sn-2Zr1Mo-O.7Nd-O.25Si alloy wereStudied. Two modes Of fatigue crack initiation were found. The Nd-rich phase particles displaybetter resistance to fatigue crack initiation than the matrix at lower stress. 展开更多
关键词 SN mo Characteristics of Faigue Crack Initiation in ti-5Al-4Sn-2Zr-1mo-0.7Nd-0.25Si Alloy ZR ti Al Nd Si
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Fabrication of Ti-Ni-Mo-Si composite coating by reactive braze coating process
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作者 裴新军 潘川 +1 位作者 黄继华 尹士科 《China Welding》 EI CAS 2012年第2期43-47,共5页
Ti-Ni-Mo-Si composite coating was fabricated on mild steel by reactive braze coating process with Ti61. 9Ni24. 6Si4. 411409.1 ( wt. % ) powders as the raw materials. Microstr^cture of the coating was characterized b... Ti-Ni-Mo-Si composite coating was fabricated on mild steel by reactive braze coating process with Ti61. 9Ni24. 6Si4. 411409.1 ( wt. % ) powders as the raw materials. Microstr^cture of the coating was characterized by optical microscopy, scanning electron microscopy, X-ray diffraction and energy dispersive spectroscopy and micro-hardness tester. Results indicate that the Ti-Ni-Mo-Si composite coating is metallurgically bonded to the mild steel substrate and has high hardness. The microstructure of the coating consists of the reinforcement of Ti5 Si3 and Mo9 Ti4 particles and the matrix of eutectic NiTi2. Due to the poor wettability of NiTi2 liquid at low temperature, TisSi3 and Mo9 Ti4 do not uniformly distribute in the NiTi2 matrix. 展开更多
关键词 reactive braze coating ti5 Si3 mo9ti4 Niti2 composite coating
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Separation and enrichment mechanism of C54–TiSi_(2) from hypoeutectic Ti–65 wt.%Si alloy during directional solidification via alternating electromagnetic fields
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作者 Kui‑song Zhu Jing‑fei Hu +2 位作者 Wen‑hui Ma Kui‑xian Wei Yong‑nian Dai 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2021年第1期29-37,共9页
The effects of directional solidification parameters and the coupling of directional solidification parameters and alternating electromagnetic fields on separation and enrichment of the C54–TiSi2 phase were investiga... The effects of directional solidification parameters and the coupling of directional solidification parameters and alternating electromagnetic fields on separation and enrichment of the C54–TiSi2 phase were investigated in a directionally solidified hypoeutectic Ti–65 wt.%Si alloy.The results indicated that by increasing the pull-down velocity at a given position within the ingot,the cooling rate,growth rate,and temperature gradient of ingot could be increased.At a pull-down velocity near 5μm/s,the temperature gradient,cooling rate,and growth rate decreased with increasing the thickness of the C54–TiSi2-rich layer.Electromagnetic fields enhanced mass transfer at pull-down velocities of 5,10,15,and 20μm/s,with resulting enriched layer thicknesses of 15,10,10,and 5 mm,respectively.By increasing the percentage of Ti in the Ti–Si alloy from 25 to 35 wt.%,the thickness of the C54–TiSi2-rich layer was increased from 2.5 to 3.3 cm.However,the maximum C54–TiSi2 content obtained experimentally in this layer decreased from 92.06 to 79.49 mass%. 展开更多
关键词 ti–Si alloy Directional solidification Electromagnetic field SEPARAtiON C54–tisi2
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