目的为了有效降低空间大功率微波器件铝合金镀银表面的电子发射系数,提高空间大功率微波器件的微放电阈值。方法研究了铝基体上电化学镀银平板试样表面的两种粗糙化处理方法——微图形光刻法和直接湿化学腐蚀法,利用扫描电子显微镜和激...目的为了有效降低空间大功率微波器件铝合金镀银表面的电子发射系数,提高空间大功率微波器件的微放电阈值。方法研究了铝基体上电化学镀银平板试样表面的两种粗糙化处理方法——微图形光刻法和直接湿化学腐蚀法,利用扫描电子显微镜和激光扫描显微镜对两类表面处理得到的多孔平板样品的粗糙形貌进行了表征,利用电流法对其表面二次电子发射(SEY)特性进行了测试分析。结果所获得的规则阵列圆孔表面和大深宽比及随机分布的粗糙表面均能够显著降低镀银表面SEY,并且工艺重复性好。与平滑银表面相比,抑制效果最好的圆孔阵列样品表面能将SEY的最大值从2.2降到1.3,E1值从50 e V增加到100e V;随机刻蚀结构能将平滑银表面SEY的最大值从2.2降至1.1,E1提升至300 e V。基于孔隙内二次电子轨迹追踪的蒙特卡洛理论模拟方法,对两种典型样品的表面二次电子陷阱效应进行了理论分析,表面SEY特性模拟规律与测试数据一致。结论光刻和湿化学刻蚀工艺制备的银表面微形貌均能有效降低镀银表面的SEY,镀银表面粗糙化处理方法能够提高卫星大功率微波部件的微放电可靠性,并不会显著增加其插损。展开更多
Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires（SiNWs） and silicon ...Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires（SiNWs） and silicon inverted pyramid arrays（SiIPs） were introduced on surface of Gr-Si solar cell through silver and copper-catalyzed chemical etching, respectively. The effects of SiNWs and SiIPs on carrier lifetime, optical properties and efficiency of Gr-SiNWs and Gr-SiIPs solar cells were systematically analyzed. The results show that the inverted pyramid arrays have more excellent ability for balancing antireflectance loss and surface area enlargement. The power conversion efficiency（PCE） and carrier lifetime of Gr-SiIPs devices respectively increase by 62% and 34% by comparing with that of Gr-SiNWs solar cells. Finally, the Gr-SiIPs cell with PCE of 5.63% was successfully achieved through nitric acid doping. This work proposes a new strategy to introduce the inverted pyramid arrays for improving the performance of Gr-Si solar cells.展开更多
Nanostructure-textured solar cell owns unique properties but has some shortages especially in its fabrication and passivation.In this paper,nanostructures for crystalline silicon solar cell have been synthesized by co...Nanostructure-textured solar cell owns unique properties but has some shortages especially in its fabrication and passivation.In this paper,nanostructures for crystalline silicon solar cell have been synthesized by controllable method based on silver catalyzed chemical etching.In this way,only the front surface of cell is etched and rear surface is protected.It was found that cells textured via the new method obtained equally excellent optical while superior electrical properties compared with those textured via traditional HF/AgNO3 etching.The V OC and I SC of the cell were improved by 6% and 11%,respectively.Then the cells were passivated via a bi-layer passivation(SiO2 & SiN x),in contrast to traditional SiN x passivation.It was also found that cells with new passivation exhibited improved V OC and I SC by 4% and 25%,respectively.The encouraging results can provide fundamental data for developing the nanostructure-textured crystalline silicon solar cell in following researches.展开更多
文摘目的为了有效降低空间大功率微波器件铝合金镀银表面的电子发射系数,提高空间大功率微波器件的微放电阈值。方法研究了铝基体上电化学镀银平板试样表面的两种粗糙化处理方法——微图形光刻法和直接湿化学腐蚀法,利用扫描电子显微镜和激光扫描显微镜对两类表面处理得到的多孔平板样品的粗糙形貌进行了表征,利用电流法对其表面二次电子发射(SEY)特性进行了测试分析。结果所获得的规则阵列圆孔表面和大深宽比及随机分布的粗糙表面均能够显著降低镀银表面SEY,并且工艺重复性好。与平滑银表面相比,抑制效果最好的圆孔阵列样品表面能将SEY的最大值从2.2降到1.3,E1值从50 e V增加到100e V;随机刻蚀结构能将平滑银表面SEY的最大值从2.2降至1.1,E1提升至300 e V。基于孔隙内二次电子轨迹追踪的蒙特卡洛理论模拟方法,对两种典型样品的表面二次电子陷阱效应进行了理论分析,表面SEY特性模拟规律与测试数据一致。结论光刻和湿化学刻蚀工艺制备的银表面微形貌均能有效降低镀银表面的SEY,镀银表面粗糙化处理方法能够提高卫星大功率微波部件的微放电可靠性,并不会显著增加其插损。
基金support of this work from the NSFC (Nos. 51504117, 61764009 and 51762043)Yunnan Applied Basic Research Project (No. Y0120150138)Research Fund of Yunnan Province Collaborative Innovation Center (No. 2014XTZS009)
文摘Nanostructures of silicon are gradually becoming hot candidate due to outstanding capability for trapping light and improving conversion efficiency of solar cell. In this paper, silicon nanowires（SiNWs） and silicon inverted pyramid arrays（SiIPs） were introduced on surface of Gr-Si solar cell through silver and copper-catalyzed chemical etching, respectively. The effects of SiNWs and SiIPs on carrier lifetime, optical properties and efficiency of Gr-SiNWs and Gr-SiIPs solar cells were systematically analyzed. The results show that the inverted pyramid arrays have more excellent ability for balancing antireflectance loss and surface area enlargement. The power conversion efficiency（PCE） and carrier lifetime of Gr-SiIPs devices respectively increase by 62% and 34% by comparing with that of Gr-SiNWs solar cells. Finally, the Gr-SiIPs cell with PCE of 5.63% was successfully achieved through nitric acid doping. This work proposes a new strategy to introduce the inverted pyramid arrays for improving the performance of Gr-Si solar cells.
基金supported by the National Basic Research Program of China ("973" Project)(Grant No. 2009CB939703)the National Natural Science Foundation of China (Grant Nos. 11104319,51172268)the Chinese Academy of Solar Energy Action Plan
文摘Nanostructure-textured solar cell owns unique properties but has some shortages especially in its fabrication and passivation.In this paper,nanostructures for crystalline silicon solar cell have been synthesized by controllable method based on silver catalyzed chemical etching.In this way,only the front surface of cell is etched and rear surface is protected.It was found that cells textured via the new method obtained equally excellent optical while superior electrical properties compared with those textured via traditional HF/AgNO3 etching.The V OC and I SC of the cell were improved by 6% and 11%,respectively.Then the cells were passivated via a bi-layer passivation(SiO2 & SiN x),in contrast to traditional SiN x passivation.It was also found that cells with new passivation exhibited improved V OC and I SC by 4% and 25%,respectively.The encouraging results can provide fundamental data for developing the nanostructure-textured crystalline silicon solar cell in following researches.
