This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of con...This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of convolution—deconvolution cyclic voltammetry at 25℃ and I=0.10 mol· dm^(-3)(KNO_3).Stability constants were calculated from pH—metric data using the SUPERQUAD com- puter program and cyclic voltammograms were collected,stored and manipulated using the EG and G CONDECON 300 software.A considerably larger ligand:metal ratio(e,g.50:1)was possible using voltammetry.Evaluation of results from the two techniques suggests that stability constants for the species[CdL_2]and[CdL_3]are reliable when calculated fromvoltammetry while those for[CdL]are more reliable when determined by pH-metric titration.展开更多
(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvat...(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvated monomer with lanthanum(Ⅲ)in a trigonal bipyramidal coordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.展开更多
In this article, the modified simple equation method has been extended to celebrate the exact solutions of nonlinear partial time-space differential equations of fractional order. Firstly, the fractional complex trans...In this article, the modified simple equation method has been extended to celebrate the exact solutions of nonlinear partial time-space differential equations of fractional order. Firstly, the fractional complex transformation has been implemented to convert nonlinear partial fractional differential equations into nonlinear ordinary differential equations. Afterwards, modified simple equation method has been implemented, to find the exact solutions of these equations, in the sense of modified Riemann-Liouville derivative. For applications, the exact solutions of time-space fractional derivative Burgers’ equation and time-space fractional derivative foam drainage equation have been discussed. Moreover, it can also be concluded that the proposed method is easy, direct and concise as compared to other existing methods.展开更多
为提高密林地形激光雷达测量(Light Detection and Ranging,LiDAR)点云数据植被点和地面点精准分类精度,采用5大传统滤波方法对林区点云进行滤波精度评定,借助布料仿真滤波算法实施相应的初始滤波处理,经准确处理后得到地形特征相对完...为提高密林地形激光雷达测量(Light Detection and Ranging,LiDAR)点云数据植被点和地面点精准分类精度,采用5大传统滤波方法对林区点云进行滤波精度评定,借助布料仿真滤波算法实施相应的初始滤波处理,经准确处理后得到地形特征相对完备的初始地表点,再对具有突出植被点的初始地表点实施迭代开运算,由此得出新的地表点。并借助Ⅰ类误差、Ⅱ类误差等一系列的指标获得科学的评估精确度。布料仿真算法与简单形态学算法组合滤波较传统滤波算法Ⅱ类、总误差均明显下降,Kappa系数呈增长趋势。结果表明,该方法适用于林区点云分类,可以获得较好的滤波效果。展开更多
Let G be a finite group and Irr(G)the set of all irreducible complex characters of G.Let cd(G)be the set of all irreducible complex character degrees of G and denote byρ(G)the set of all primes which divide some char...Let G be a finite group and Irr(G)the set of all irreducible complex characters of G.Let cd(G)be the set of all irreducible complex character degrees of G and denote byρ(G)the set of all primes which divide some character degree of G.The character-prime graphΓ(G)associated to G is a simple undirected graph whose vertex set isρ(G)and there is an edge between two distinct primes p and q if and only if the product p q divides some character degree of G.We show that the finite nonabelian simple groups A_(7),J_(1),J_(3),J_(4),L_(3)(3)and U_(3)(4)are uniquely determined by their degree-patterns and orders.展开更多
文摘This paper reports the determination of stability constants for complexes of Cd(Ⅱ)with Gly, Ala,Val,Asp,Gly—Asp,Asp Gly,Gly—Gly and Gly—Gly—Gly using both micro—pH—metric titra- tions and the application of convolution—deconvolution cyclic voltammetry at 25℃ and I=0.10 mol· dm^(-3)(KNO_3).Stability constants were calculated from pH—metric data using the SUPERQUAD com- puter program and cyclic voltammograms were collected,stored and manipulated using the EG and G CONDECON 300 software.A considerably larger ligand:metal ratio(e,g.50:1)was possible using voltammetry.Evaluation of results from the two techniques suggests that stability constants for the species[CdL_2]and[CdL_3]are reliable when calculated fromvoltammetry while those for[CdL]are more reliable when determined by pH-metric titration.
文摘(CH_3OCH_2CH_2C_5H_4)_2LnI(Ln=La,Nd)complexes have been synthesized by the reaction between NaI and[(CH_3OCH_2CH_2C_5H_4)_2LnCl]2 in THF;A single crystal X-ray study has shown that the lanthanum complex is an unsolvated monomer with lanthanum(Ⅲ)in a trigonal bipyramidal coordination geometry if the cyclopentadienyl ring is regarded as occupying a single polyhedral vertex.
文摘In this article, the modified simple equation method has been extended to celebrate the exact solutions of nonlinear partial time-space differential equations of fractional order. Firstly, the fractional complex transformation has been implemented to convert nonlinear partial fractional differential equations into nonlinear ordinary differential equations. Afterwards, modified simple equation method has been implemented, to find the exact solutions of these equations, in the sense of modified Riemann-Liouville derivative. For applications, the exact solutions of time-space fractional derivative Burgers’ equation and time-space fractional derivative foam drainage equation have been discussed. Moreover, it can also be concluded that the proposed method is easy, direct and concise as compared to other existing methods.
文摘为提高密林地形激光雷达测量(Light Detection and Ranging,LiDAR)点云数据植被点和地面点精准分类精度,采用5大传统滤波方法对林区点云进行滤波精度评定,借助布料仿真滤波算法实施相应的初始滤波处理,经准确处理后得到地形特征相对完备的初始地表点,再对具有突出植被点的初始地表点实施迭代开运算,由此得出新的地表点。并借助Ⅰ类误差、Ⅱ类误差等一系列的指标获得科学的评估精确度。布料仿真算法与简单形态学算法组合滤波较传统滤波算法Ⅱ类、总误差均明显下降,Kappa系数呈增长趋势。结果表明,该方法适用于林区点云分类,可以获得较好的滤波效果。
基金supported by NSFC(12071484)Hunan Provincial Natural Science Foundation(2020JJ4675)Foundation of Guangdong University of Science and Technology.
文摘Let G be a finite group and Irr(G)the set of all irreducible complex characters of G.Let cd(G)be the set of all irreducible complex character degrees of G and denote byρ(G)the set of all primes which divide some character degree of G.The character-prime graphΓ(G)associated to G is a simple undirected graph whose vertex set isρ(G)and there is an edge between two distinct primes p and q if and only if the product p q divides some character degree of G.We show that the finite nonabelian simple groups A_(7),J_(1),J_(3),J_(4),L_(3)(3)and U_(3)(4)are uniquely determined by their degree-patterns and orders.
