A single step scheme with high accuracy for solving parabolic problem is proposed. It is shown that this scheme possesses good stability and fourth order accuracy with respect to both time and space variables, which a...A single step scheme with high accuracy for solving parabolic problem is proposed. It is shown that this scheme possesses good stability and fourth order accuracy with respect to both time and space variables, which are superconvergent.展开更多
Patents and previous research concerning the single-step synthesis of DME were reviewed. Rapid deactivation of the bifunctional catalyst is the main issue for the commercialization of the single-step synthesis process...Patents and previous research concerning the single-step synthesis of DME were reviewed. Rapid deactivation of the bifunctional catalyst is the main issue for the commercialization of the single-step synthesis process; in addition, the separation process and utilization of by-products have a larger impact on economic performance of the process. Recent progress involving the development of bifunctional catalysts and separation technology in the single-step process will most likely make the process commercially available in the near future.展开更多
Hepatocellular carcinoma (HCC) is a cancer with increasing incidence in the USA and high mortality rate. HCC is often difficult to treat due to underlying comorbidities such as cirrhosis. However, the application of l...Hepatocellular carcinoma (HCC) is a cancer with increasing incidence in the USA and high mortality rate. HCC is often difficult to treat due to underlying comorbidities such as cirrhosis. However, the application of loco-regional thermal ablation using radio frequency (RF) and trans-arterial embolization with chemotherapy (TACE) or without (TAE) has shown promising results in the treatment of patients not amenable to surgical resection or liver transplantation. Conventionally, RF and TAE are performed in two separated sessions or two steps and often RF ablation is performed percutaneously. However, no consensus has been reached regarding the ideal interval between the two treatments. In this article, we discuss the feasibility and benefits of a single-step TAE in combination with laparoscopic RF ablation in one operative session. We also present a case where this procedure has been successfully performed demonstrating its feasibility. We suggest that the use of laparoscopic RF ablation in the same surgical session as TAE is feasible and potentially offers several advantages over the two-step process that is usually performed with embolization followed by percutaneous RF with a long time interval. In this article we discuss such advantages.展开更多
Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film qualit...Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film quality, purity, and accurate composition control. However,the conventional physical vapor deposition process cannot meet the gap- filling requirement with the critical device dimension scaling down to 90 nm or below. In this study, we find that the deposit-etch-deposit process shows better gap-filling capability and scalability than the single-step deposition process, especially at the nano-scale critical dimension. The gap-filling mechanism of the deposit-etch-deposit process was briefly discussed. We also find that re-deposition of phase-change material from via the sidewall to via the bottom by argon ion bombardment during the etch step was a key ingredient for the final good gap filling. We achieve void-free gap filling of phase-change material on the 45-nm via the two-cycle deposit-etch-deposit process. We gain a rather comprehensive insight into the mechanism of deposit-etch-deposit process and propose a potential gap-filling solution for over 45-nm technology nodes for phase-change random access memory.展开更多
Simultaneous dyeing and durable press finishing of cotton fabrics with acid dyes bearing the different molecule structure and durable press finishing agent (DP agent abbr.) based on modified DMDHEU were investigated b...Simultaneous dyeing and durable press finishing of cotton fabrics with acid dyes bearing the different molecule structure and durable press finishing agent (DP agent abbr.) based on modified DMDHEU were investigated by using the pad-dry-cure process. Some factors affecting the process, such as structure of acid dyes, DP agent, catalysts and curing temperature were discussed. The dyed and finished fabrics were evaluated with respect to color strength, fixation, crease recovery angle, breaking strength and fastness properties. The results indicate that structure of acid dyes has a striking effect on the color strength of dyed and finished cotton fabric. The color strength and dry crease recovery angle of dyed and finished cotton fabric increases, whereas breaking strength decreases with increasing concentration of DP agent. It is necessary for ammonium nitrate to serve as catalyst. It is found that relatively satisfactory properties of dyed and finished cotton fabric can be obtained with appropriate adjustment of treating conditions.展开更多
This paper mainly proposes a new C-XSC (C- for eXtended Scientific Computing) software for the symmetric single step method and relaxation method for computing an enclosure for the solution set and compares the meth...This paper mainly proposes a new C-XSC (C- for eXtended Scientific Computing) software for the symmetric single step method and relaxation method for computing an enclosure for the solution set and compares the methods with others' and then makes some modifications and finally, examples illustrating the applicability of the proposed methods are given.展开更多
Single step and multi step CARE processes are optimized by computer simulations based on the mathematical model proposed previously. The product of purification factor and recovery yield is used as the objective fun...Single step and multi step CARE processes are optimized by computer simulations based on the mathematical model proposed previously. The product of purification factor and recovery yield is used as the objective function for optimizing a single step process. The objective function for the optimization of a multi step process is considered to obtain an anticipated product purity at a maximum recovery yield and a minimum number of CARE inividuals. Pairs of the operating conditions (eluant and affinity recycle flow rates) exist to give the maximums of above objective functions when membrane rejections to ligates and contaminants are equal in value. The optimum affinity recycle flow rate decreases with the increase of membrane rejections and equilibrium binding fractions of ligates. For a multi step process, when contaminants are rejected less than ligate, only one pair of the optimum eluant and affinity recycle flow rates exists.展开更多
Inertial piezoelectric actuators are widely applied in precision devices with simple structure and accurate movement.However,existing inertial piezoelectric actuators still face the challenges of rollback motion and b...Inertial piezoelectric actuators are widely applied in precision devices with simple structure and accurate movement.However,existing inertial piezoelectric actuators still face the challenges of rollback motion and bulky power supply.In this work,an alternate excitation strategy and a customized small power supply for a bimorph rotary piezoelectric actuator(BRPA)are proposed to solve the problems.The BRPA prototype is designed with a bipedal symmetrical structure,measuring 35 mm in height and 32 mm in diameter,which has a maximum rotation velocity of 0.247 rad/s and a resolution of 0.66μrad.Thanks to the bipedal symmetrical structure,the friction directions between the driving feet and the rotor can be coordinated to suppress the rollback.The rollback ratio is almost zero when the phase difference of the exciting signal is set as 180°.The customized power supply is designed and manufactured,whose size is 58 mm×56 mm×46 mm.It can output signals for the single step mode and the continuous mode,and they are adopted to excite BRPA to achieve a small stroke with one single step and a large stroke with continuous step,respectively.Then,an experimental system for optical fiber alignment is developed based on the BRPA and the customized small power supply,the experiment has verified the practicability of this work in the precision fields,especially in the miniaturized precision systems.展开更多
Biomass-derived porous carbons have been considered as the most potential candidate for effective CO_(2) adsorbent thanks to being widely-available precursor and having highly porous structure and stable chemical/phys...Biomass-derived porous carbons have been considered as the most potential candidate for effective CO_(2) adsorbent thanks to being widely-available precursor and having highly porous structure and stable chemical/physical features.However,the biomass-derived porous carbons still suffer from the poor optimization process in terms of the synthesis conditions.Herein,we have successfully fabricated coconut shell-derived porous carbon by a simple one-step synthesis process.The as-prepared carbon exhibits advanced textual activity together with well-designed micropore morphology and possesses oxygen-containing functional groups(reached 18.81 wt%)within the carbon matrix.Depending on the different activating temperatures(from 700 to 800℃)and KOH/biomass mass ratios(from 0.3 to 1),the 750℃ and 0.5 mass ratio were found to be enabling the highest CO_(2) capture performance.The optimal adsorbent was achieved a high CO_(2) uptake capacity of 5.92 and 4.15 mmol·g^(−1) at 0 and 25℃(1 bar),respectively.More importantly,as-prepared carbon adsorbent exhibited moderate isosteric heat of adsorption and high CO_(2)/N_(2) selectivity.The results were revealed not only the textural feature but also the surface functional groups critically determine the CO_(2) capture performance,indicating coconut shell-derived porous carbon has a considerable potential as a solid-state adsorbent for the CO_(2) capture.展开更多
ZnO-based n/p homojunctions were fabricated by sputtering from a single zinc nitride target at room temperature on metal or ITO-coated glass and Si substrates.A multi-target rf-sputtering system was used for the growt...ZnO-based n/p homojunctions were fabricated by sputtering from a single zinc nitride target at room temperature on metal or ITO-coated glass and Si substrates.A multi-target rf-sputtering system was used for the growth of all oxide films as multilayers in a single growth run without breaking the vacuum in the growth chamber.The nitrogen-containing films(less than 1.5 at.% of nitrogen)were n-type ZnO when deposited in oxygen-deficient Ar plasma(10%O_(2))and p-type ZnO when deposited in oxygen-rich Ar plasma(50%O_(2)).The all-oxide homojunction ITO/n-ZnO/p-ZnO/ITO/glass was fabricated in a single deposition run and exhibited visible transparency in the range of 75-85%.The n/p ZnO homojunctions,having metallic contacts,formed on conventionally processed substrates showed a fairly unstable behavior concerning the current-voltage characteristics.However,the same homojunctions formed on Si_(3)N_(4)-patterned substrates and stored in atmosphere for a period of five months were stable exhibiting a turn-on voltage of around 1.5 V.The realization of a room temperature sputtered transparent and stable ZnO homojunction paves the way to the realization of all-oxide transparent optoelectronic devices.展开更多
基金Supported by The National Natural Science Foundations of China (19871027)
文摘A single step scheme with high accuracy for solving parabolic problem is proposed. It is shown that this scheme possesses good stability and fourth order accuracy with respect to both time and space variables, which are superconvergent.
文摘Patents and previous research concerning the single-step synthesis of DME were reviewed. Rapid deactivation of the bifunctional catalyst is the main issue for the commercialization of the single-step synthesis process; in addition, the separation process and utilization of by-products have a larger impact on economic performance of the process. Recent progress involving the development of bifunctional catalysts and separation technology in the single-step process will most likely make the process commercially available in the near future.
文摘Hepatocellular carcinoma (HCC) is a cancer with increasing incidence in the USA and high mortality rate. HCC is often difficult to treat due to underlying comorbidities such as cirrhosis. However, the application of loco-regional thermal ablation using radio frequency (RF) and trans-arterial embolization with chemotherapy (TACE) or without (TAE) has shown promising results in the treatment of patients not amenable to surgical resection or liver transplantation. Conventionally, RF and TAE are performed in two separated sessions or two steps and often RF ablation is performed percutaneously. However, no consensus has been reached regarding the ideal interval between the two treatments. In this article, we discuss the feasibility and benefits of a single-step TAE in combination with laparoscopic RF ablation in one operative session. We also present a case where this procedure has been successfully performed demonstrating its feasibility. We suggest that the use of laparoscopic RF ablation in the same surgical session as TAE is feasible and potentially offers several advantages over the two-step process that is usually performed with embolization followed by percutaneous RF with a long time interval. In this article we discuss such advantages.
基金Project supported by the National Basic Research Program of China (Grant Nos.2010CB934300,2011CBA00607,and 2011CB932800)the National Integrate Circuit Research Program of China (Grant No. 2009ZX02023-003)+1 种基金the National Natural Science Foundation of China (Grant Nos. 60906004,60906003,61006087,and 61076121)the Science and Technology Council of Shanghai,China (Grant No. 1052nm07000)
文摘Ge2Sb2Te5 gap filling is one of the key processes for phase-change random access memory manufacture. Physical vapor deposition is the mainstream method of Ge2Sb2Te5 film deposition due to its advantages of film quality, purity, and accurate composition control. However,the conventional physical vapor deposition process cannot meet the gap- filling requirement with the critical device dimension scaling down to 90 nm or below. In this study, we find that the deposit-etch-deposit process shows better gap-filling capability and scalability than the single-step deposition process, especially at the nano-scale critical dimension. The gap-filling mechanism of the deposit-etch-deposit process was briefly discussed. We also find that re-deposition of phase-change material from via the sidewall to via the bottom by argon ion bombardment during the etch step was a key ingredient for the final good gap filling. We achieve void-free gap filling of phase-change material on the 45-nm via the two-cycle deposit-etch-deposit process. We gain a rather comprehensive insight into the mechanism of deposit-etch-deposit process and propose a potential gap-filling solution for over 45-nm technology nodes for phase-change random access memory.
文摘Simultaneous dyeing and durable press finishing of cotton fabrics with acid dyes bearing the different molecule structure and durable press finishing agent (DP agent abbr.) based on modified DMDHEU were investigated by using the pad-dry-cure process. Some factors affecting the process, such as structure of acid dyes, DP agent, catalysts and curing temperature were discussed. The dyed and finished fabrics were evaluated with respect to color strength, fixation, crease recovery angle, breaking strength and fastness properties. The results indicate that structure of acid dyes has a striking effect on the color strength of dyed and finished cotton fabric. The color strength and dry crease recovery angle of dyed and finished cotton fabric increases, whereas breaking strength decreases with increasing concentration of DP agent. It is necessary for ammonium nitrate to serve as catalyst. It is found that relatively satisfactory properties of dyed and finished cotton fabric can be obtained with appropriate adjustment of treating conditions.
文摘This paper mainly proposes a new C-XSC (C- for eXtended Scientific Computing) software for the symmetric single step method and relaxation method for computing an enclosure for the solution set and compares the methods with others' and then makes some modifications and finally, examples illustrating the applicability of the proposed methods are given.
文摘Single step and multi step CARE processes are optimized by computer simulations based on the mathematical model proposed previously. The product of purification factor and recovery yield is used as the objective function for optimizing a single step process. The objective function for the optimization of a multi step process is considered to obtain an anticipated product purity at a maximum recovery yield and a minimum number of CARE inividuals. Pairs of the operating conditions (eluant and affinity recycle flow rates) exist to give the maximums of above objective functions when membrane rejections to ligates and contaminants are equal in value. The optimum affinity recycle flow rate decreases with the increase of membrane rejections and equilibrium binding fractions of ligates. For a multi step process, when contaminants are rejected less than ligate, only one pair of the optimum eluant and affinity recycle flow rates exists.
基金supported by the National Natural Science Foundation of China(Grant Nos.52105015 and 52225501)the China Postdoctoral Science Foundation(Grant No.2021M690830)the Postdoctoral Science Foundation of Heilongjiang Province,China(Grant No.LBH-Z21018)。
文摘Inertial piezoelectric actuators are widely applied in precision devices with simple structure and accurate movement.However,existing inertial piezoelectric actuators still face the challenges of rollback motion and bulky power supply.In this work,an alternate excitation strategy and a customized small power supply for a bimorph rotary piezoelectric actuator(BRPA)are proposed to solve the problems.The BRPA prototype is designed with a bipedal symmetrical structure,measuring 35 mm in height and 32 mm in diameter,which has a maximum rotation velocity of 0.247 rad/s and a resolution of 0.66μrad.Thanks to the bipedal symmetrical structure,the friction directions between the driving feet and the rotor can be coordinated to suppress the rollback.The rollback ratio is almost zero when the phase difference of the exciting signal is set as 180°.The customized power supply is designed and manufactured,whose size is 58 mm×56 mm×46 mm.It can output signals for the single step mode and the continuous mode,and they are adopted to excite BRPA to achieve a small stroke with one single step and a large stroke with continuous step,respectively.Then,an experimental system for optical fiber alignment is developed based on the BRPA and the customized small power supply,the experiment has verified the practicability of this work in the precision fields,especially in the miniaturized precision systems.
基金Financial support was provided by Zhejiang Provincial Natural Science Foundation(Grant No.LY21B070005)National Undergraduate Training Program for Innovation and Entrepreneurship of China and Self designed scientific research project of Zhejiang Normal University(Grant No.2021ZS06)。
文摘Biomass-derived porous carbons have been considered as the most potential candidate for effective CO_(2) adsorbent thanks to being widely-available precursor and having highly porous structure and stable chemical/physical features.However,the biomass-derived porous carbons still suffer from the poor optimization process in terms of the synthesis conditions.Herein,we have successfully fabricated coconut shell-derived porous carbon by a simple one-step synthesis process.The as-prepared carbon exhibits advanced textual activity together with well-designed micropore morphology and possesses oxygen-containing functional groups(reached 18.81 wt%)within the carbon matrix.Depending on the different activating temperatures(from 700 to 800℃)and KOH/biomass mass ratios(from 0.3 to 1),the 750℃ and 0.5 mass ratio were found to be enabling the highest CO_(2) capture performance.The optimal adsorbent was achieved a high CO_(2) uptake capacity of 5.92 and 4.15 mmol·g^(−1) at 0 and 25℃(1 bar),respectively.More importantly,as-prepared carbon adsorbent exhibited moderate isosteric heat of adsorption and high CO_(2)/N_(2) selectivity.The results were revealed not only the textural feature but also the surface functional groups critically determine the CO_(2) capture performance,indicating coconut shell-derived porous carbon has a considerable potential as a solid-state adsorbent for the CO_(2) capture.
基金partially supported by the EU Horizon 2020‘ASCENT’project,grant agreement No 654384(project 046)the“Materials and Processes for Energy and Environment Applications-AENAO”(MIS 5002556)project co-financed by Greece and EU(European Regional Development Fund)+1 种基金the EU's FP7/2007-2013 project“Oxide Materials Towards a Matured Post-silicon Electronics Era-ORAMA”(contract no.NMP3-LA-2010-246334)the project“Electronics Beyond Silicon Era”(ELBESIER)Erasmus+KА2 programme.
文摘ZnO-based n/p homojunctions were fabricated by sputtering from a single zinc nitride target at room temperature on metal or ITO-coated glass and Si substrates.A multi-target rf-sputtering system was used for the growth of all oxide films as multilayers in a single growth run without breaking the vacuum in the growth chamber.The nitrogen-containing films(less than 1.5 at.% of nitrogen)were n-type ZnO when deposited in oxygen-deficient Ar plasma(10%O_(2))and p-type ZnO when deposited in oxygen-rich Ar plasma(50%O_(2)).The all-oxide homojunction ITO/n-ZnO/p-ZnO/ITO/glass was fabricated in a single deposition run and exhibited visible transparency in the range of 75-85%.The n/p ZnO homojunctions,having metallic contacts,formed on conventionally processed substrates showed a fairly unstable behavior concerning the current-voltage characteristics.However,the same homojunctions formed on Si_(3)N_(4)-patterned substrates and stored in atmosphere for a period of five months were stable exhibiting a turn-on voltage of around 1.5 V.The realization of a room temperature sputtered transparent and stable ZnO homojunction paves the way to the realization of all-oxide transparent optoelectronic devices.