Discovery and inspiration of large-and medium-sized glutenite-rich oil and gas fields in the eastern South China Sea:An example from Paleogene Enping Formation in Huizhou 26 subsag,Pearl River Mouth Basin

Based on the practice of oil and gas exploration in the Huizhou Sag of the Pearl River Mouth Basin,the geochemical indexes of source rocks were measured,the reservoir development morphology was restored,the rocks and minerals were characterized microscopically,the measured trap sealing indexes were compared,the biomarker compounds of crude oil were extracted,the genesis of condensate gas was identified,and the reservoir-forming conditions were examined.On this basis,the Paleogene Enping Formation in the Huizhou 26 subsag was systematically analyzed for the potential of oil and gas resources,the development characteristics of large-scale high-quality conglomerate reservoirs,the trapping effectiveness of faults,the hydrocarbon migration and accumulation model,and the formation conditions and exploration targets of large-and medium-sized glutenite-rich oil and gas fields.The research results were obtained in four aspects.First,the Paleogene Wenchang Formation in the Huizhou 26 subsag develops extensive and thick high-quality source rocks of semi-deep to deep lacustrine subfacies,which have typical hydrocarbon expulsion characteristics of"great oil generation in the early stage and huge gas expulsion in the late stage",providing a sufficient material basis for hydrocarbon accumulation in the Enping Formation.Second,under the joint control of the steep slope zone and transition zone of the fault within the sag,the large-scale near-source glutenite reservoirs are highly heterogeneous,with the development scale dominated hierarchically by three factors(favorable facies zone,particle component,and microfracture).The(subaqueous)distributary channels near the fault system,with equal grains,a low mud content(<5%),and a high content of feldspar composition,are conducive to the development of sweet spot reservoirs.Third,the strike-slip pressurization trap covered by stable lake flooding mudstone is a necessary condition for oil and gas preservation,and the NE and nearly EW faults obliquely to the principal stress have the best control on traps.Fourth,the spatiotemporal configuration of high-quality source rocks,fault transport/sealing,and glutenite reservoirs controls the degree of hydrocarbon enrichment.From top to bottom,three hydrocarbon accumulation units,i.e.low-fill zone,transition zone,and high-fill zone,are recognized.The main area of the channel in the nearly pressurized source-connecting fault zone is favorable for large-scale hydrocarbon enrichment.The research results suggest a new direction for the exploration of large-scale glutenite-rich reservoirs in the Enping Formation of the Pearl River Mouth Basin,and present a major breakthrough in oil and gas exploration.

Stress corrosion cracking behavior of buried oil and gas pipeline steel under the coexistence of magnetic field and sulfate-reducing bacteria

Magnetic field and microorganisms are important factors influencing the stress corrosion cracking(SCC)of buried oil and gas pipelines. Once SCC occurs in buried pipelines, it will cause serious hazards to the soil environment. The SCC behavior of X80 pipeline steel under the magnetic field and sulfate-reducing bacteria(SRB) environment was investigated by immersion tests, electrochemical tests, and slow strain rate tensile(SSRT) tests. The results showed that the corrosion and SCC sensitivity of X80 steel decreased with increasing the magnetic field strength in the sterile environment. The SCC sensitivity was higher in the biotic environment inoculated with SRB, but it also decreased with increasing magnetic field strength, which was due to the magnetic field reduces microbial activity and promotes the formation of dense film layer. This work provided theoretical guidance on the prevention of SCC in pipeline steel under magnetic field and SRB coexistence.

The accumulation characteristics and exploration potential of oil and gas in the back-arc basin of Japan under the background of high heat flow

The Sea of Japan is located in the southeast margin of Eurasia, in the triangle area of the western Pacific Ocean. Due to the interaction of the Pacific plate, Eurasian plate and Philippine plate, its tectonic environment is complex, forming a typical trench-arc-basin system. At present, 148 oil and gas fields have been discovered in Japan, with an oil and gas resource of 255.78×10^(6) t, showing a good prospect for oil and gas exploration. Based on the previous research and the recently collected geological and geophysical data, the characteristics of tectonic-sedimentary evolution and geothermal field in the basins around the Sea of Japan are analyzed. The results show that the tectonic evolution of the basin is mainly controlled by plate subduction and back-arc oceanic crust expansion, and it mainly undergone four tectonic-sedimentary evolution stages: Subduction period, basin development period, subsidence period and compression deformation period. The overall heat flow value of Japan Sea is high, and it is distributed annularly along Yamato Ridge. The geothermal heat flow value is about 50–130 MW/m^(2), and the average heat flow is75.9±19.8 MW/m^(2), which has a typical “hot basin ”. The high heat flow background provides unique thermal evolution conditions for hydrocarbon generation, which leads to the high temperature and rapid evolution. The authors summarized as “early hydrocarbon generation, rapid maturity and shallow and narrow hydrocarbon generation window”. The type of oil and gas is mainly natural gas, and it mainly distributed in Neogene oil and gas reservoirs. The trap types are mainly structural traps, lithologic traps and composite traps. In addition, the pre-Neogene bedrock oil and gas reservoirs also show a good exploration prospect. The resource prospecting indicates that Niigata Basin, Ulleung Basin and kitakami Basin are the main target areas for future exploration and development.

Formation and distribution characteristics of Proterozoic–Lower Paleozoic marine giant oil and gas fields worldwide

There are rich oil and gas resources in marine carbonate strata worldwide.Although most of the oil and gas reserves discovered so far are mainly distributed in Mesozoic,Cenozoic,and upper Paleozoic strata,oil and gas exploration in the Proterozoic–Lower Paleozoic（PLP）strata—the oldest marine strata—has been very limited.To more clearly understand the oil and gas formation conditions and distributions in the PLP marine carbonate strata,we analyzed and characterized the petroleum geological conditions,oil and gas reservoir types,and their distributions in thirteen giant oil and gas fields worldwide.This study reveals the main factors controlling their formation and distribution.Our analyses show that the source rocks for these giant oil and gas fields are mainly shale with a great abundance of type I–II organic matter and a high thermal evolution extent.The reservoirs are mainly gas reservoirs,and the reservoir rocks are dominated by dolomite.The reservoir types are mainly karst and reef–shoal bodies with well-developed dissolved pores and cavities,intercrystalline pores,and fractures.These reservoirs arehighly heterogeneous.The burial depth of the reservoirs is highly variable and somewhat negatively correlated to the porosity.The cap rocks are mainly thick evaporites and shales,with the thickness of the cap rocks positively correlated to the oil and gas reserves.The development of high-quality evaporite cap rock is highly favorable for oil and gas preservation.We identified four hydrocarbon generation models,and that the major source rocks have undergone a long period of burial and thermal evolution and are characterized by early and long periods of hydrocarbon generation.These giant oil and gas fields have diverse types of reservoirs and are mainly distributed in paleo-uplifts,slope zones,and platform margin reef-shoal bodies.The main factors that control their formation and distribution were identified,enabling the prediction of new favorable areas for oil and gas exploration.

Effect of HCO_3^- concentration on CO_2 corrosion in oil and gas fields

The effect of HCO3^- concentration on CO2 corrosion was investigated by polarization measurement of potentiodynamic scans and weight-loss method, Under the conditions of high pressure and high temperature, the corrosion rate of steel X65 decreased with the increase of HCO3^- concentration, while pH of solution increased. SEM, EDS, and XRD results of the corrosion scales indir cated that the typical FeCO3 crystallite was found at low HCO3^- concentration but Ca（Fe,Mg）（CO3）2 was found at high HCO3^- con- centration. Ca^2＋ and Mg^2＋ are precipitated preferential to Fe^2＋ at high pH value. Potentiodynamic polarization curves showed that the cathodic current density decreases with the increase of HCO3^- concentration at low HCO3^- concentration. When the HCO3^- concentration reaches 0.126 mol/L, increasing HCO3^- concentration promotes cathodic reactions. Anodic behavior is an active process at low HCO3^- concentration and the anodic current density decreases with the increase of HCO3^- concentration. An evident active-passive behavior is exhibited in anodic process at 0.126 mol/L HCO3^-.

Petroleum Geology in the Tarim，Junggar and Turpan－Hami Basins Showing Favorable Conditions for the OccurrenceofLargeandMediumoilandGasFields

The frequent upwarping and subsidence,and folding and uplifting of the earth crust caused by the isostatic adjustments and tectonic movements change the types of sediments in the basins frequently,and often cause the occurrence of multi-source formations in the geologic profile.As in the Tarim basin,during the first transgression in the early paleozoic,the deepest location was the Ordovician sag,in which deep marine clastic and carbonate rocks were deposited and main source rocks were included.In the late Paleozoic,it was the second transgression cycle,the thickest sedi-ments of Carboniferous-Permian were deposited in thie Awati sag and southwest sag which would be another major petroleum source rocks(Fig.2).

Daily Variation of Natural Emission of Methane to the Atmosphere and Source Identification in the Luntai Fault Region of the Yakela Condensed Oil/Gas Field in the Tarim Basin,Xinjiang,China

The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern China. Using an online method, which couples together a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry （GC/C/MS）, 13^C/12^C ratios of methane in flux chambers were measured and showed that methane gases are liable to migrate from deep oil/gas reservoirs to the surface through fault regions and that a part of the migrated methane, which remains unoxidized can be emitted into the atmosphere. Methane emission rates were found to be highest in the mornings, lowest in the afternoons and then increase gradually in the evenings. Methane emission rates varied dramatically in different locations in the fault region. The highest methane emission rate was 10.96 mg/m^2·d, the lowest 4.38 mg/m^2, and the average 7.55 mg/ m^2·d. The 13^C/12^C ratios of the methane in the flux chambers became heavier as the enclosed methane concentrations increased gradually, which reveals that methane released from the fault region might come from thermogenic methane of the deep condensed oil/gas reservoir.

Practice and theoretical and technical progress in exploration and development of Shunbei ultra-deep carbonate oil and gas field,Tarim Basin,NW China

In this review on the exploration and development process of the Shunbei ultra-deep carbonate oil and gas field in the Tarim Basin, the progress of exploration and development technologies during the National 13th Five-Year Plan of China has been summarized systematically, giving important guidance for the exploration and development of ultra-deep marine carbonate reservoirs in China and abroad. Through analyzing the primary geological factors of “hydrocarbon generation-reservoir formation-hydrocarbon accumulation” of ancient and superposed basin comprehensively and dynamically, we point out that because the Lower Cambrian Yuertusi Formation high-quality source rocks have been located in a low-temperature environment for a long time, they were capable of generating hydrocarbon continuously in late stage, providing ideal geological conditions for massive liquid hydrocarbon accumulation in ultra-deep layers. In addition, strike-slip faults developed in tectonically stable areas have strong control on reservoir formation and hydrocarbon accumulation in this region. With these understandings, the exploration focus shifted from the two paleo-uplifts located in the north and the south to the Shuntuoguole lower uplift located in between and achieved major hydrocarbon discoveries. Through continuing improvement of seismic exploration technologies for ultra-deep carbonates in desert, integrated technologies including seismic acquisition in ultra-deep carbonates,seismic imaging of strike-slip faults and the associated cavity-fracture systems, detailed structural interpretation of strike-slip faults, characterization and quantitative description of fault-controlled cavities and fractures, description of fault-controlled traps and target optimization have been established. Geology-engineering integration including well trajectory optimization,high efficiency drilling, completion and reservoir reformation technologies has provided important support for exploration and development of the Shunbei oil and gas field.

Influence of gas flow on thermal field and stress during growth of sapphire single crystal using Kyropoulos method

The professional modeling software package CrysVUn was employed to study the process of a large sapphire single crystal growth using Kyropoulos method.The influence of gas pressure on thermal field,solid-liquid interface shape,gas velocity field and von Mises stress were studied for the first time.It is found that the root of the seed melt when gas pressure equals to one atmosphere or more than one atmosphere,especially during the seeding period,this result is consistent with the experimental observation,and this paper presents three ways to solve this problem.The temperature gradient and stress decreases significantly as the gas pressure increases.The convexity of the solid-liquid interface slightly increases when the gas pressure increases.Numerical analysis was used to optimize the hot zone design.

Study on the Environmental Impact of Oil and Gas Field Development on the Ecological Red Line Area

To cooperate with the five ministries and commissions of the state to carry out joint investigation on the environmentally sensitive areas involved in oil and gas exploration and development,for the problems found in survey,containing complex type and numerous amount of ecologically sensitive space and ecological red line involved in oil and gas field enterprises,scientific nature of delimitation,lack of strong support of laws and regulations for forced withdrawal of oil and gas production facilities in these areas,some countermeasures and suggestions were proposed,such as further evaluating and combing scope and functional zoning of existing environmentally sensitive areas and ecological red lines,treating differently,enhancing pertinence of prohibition in ecologically sensitive regions,declining blindness of the withdrawal of oil and gas facilities in environmentally sensitive areas,strengthening seriousness of approval of exploration and mining rights of oil and gas resources,and establishing strategic reserve exploration and hierarchical development mechanism. Moreover,oil and gas field enterprises should integrate more efforts to ① accelerate to find out the current situation of environmental quality,② adhere to developing in protection,and protecting in development,③ increase attention and participation strengthen of providing technical support for national oil and gas exploration and development strategy evaluation,④ accelerate communication and docking with local governments on the ecological red line,⑤ actively strive to be included in the positive list management of local governments,⑥ accelerate to establish and perfect primary database of oil and gas production and facilities construction,and ⑦ document management information system of the ecological red line.

Exploration of Complicated Oil and Gas Fields

Complicated oil and gas fields occupy an important position in oil and gas exploration. In this paper, complicated oil and gas fields are grouped into four types: fault-block, lithologic, stratigraphic and fissure types. On the basis of the new theory of petroleum geological exploration in composite oil and gas accumulation areas within continental basins, a new exploration sequence suitable for complicated oil and gas fields has been established, which comprises four stages:(1) initial exploration;(2) preliminary exploration;(3) early step-by-step exploration and development: and(4) late step-by-step exploration and development. The idea of cybernetics has been taken to control various links of a systematic exploration project so as to fully, effectively and comprehensively utilize the new exploration techniques, eventually realizing the optimization of exploration with the aim of raising the efficiency of exploration of complicated oil and gas fields.

Technological progress and development directions of PetroChina overseas oil and gas field production

This study reviews the development history of PetroChina’s overseas oil and gas field development technologies, summarizes the characteristic technologies developed, and puts forward the development goals and technological development directions of overseas business to overcome the challenges met in overseas oil and gas production. In the course of PetroChina’s overseas oil and gas field production practice of more than 20 years, a series of characteristic technologies suitable for overseas oil and gas fields have been created by combining the domestic mature oil and gas field production technologies with the features of overseas oil and gas reservoirs, represented by the technology for high-speed development and stabilizing oil production and controlling water rise for overseas sandstone oilfields, high efficiency development technology for large carbonate oil and gas reservoirs and foamy oil depletion development technology in use of horizontal wells for extra-heavy oil reservoirs. Based on in-depth analysis of the challenges faced by overseas oil and gas development and technological requirements, combined with the development trends of oil and gas development technologies in China and abroad, overseas oil and gas development technologies in the future are put forward, including artificial intelligence reservoir prediction and 3 D geological modeling, secondary development and enhanced oil recovery(EOR) of overseas sandstone oilfields after high speed development, water and gas injection to improve oil recovery in overseas carbonate oil and gas reservoirs, economic and effective development of overseas unconventional oil and gas reservoirs, efficient development of marine deep-water oil and gas reservoirs. The following goals are expected to be achieved: keep the enhanced oil recovery(EOR) technology for high water-cut sandstone oilfield at international advanced level, and make the development technology for carbonate oil and gas reservoirs reach the international advanced level, and the development technologies for unconventional and marine deep-water oil and gas reservoirs catch up the level of international leading oil companies quickly.

Composition and origin of molecular compounds in the condensate oils of the Dabei gas field, Tarim Basin, NW China

The Dabei gas field in the Kuqa Depression of the Tarim Basin is the most complex and deep continental condensate gas field in China. Comprehensive two-dimensional gas chromatography?time of flight mass spectrometer (GC×GC-TOFMS) analysis was conducted on five condensate oil samples from this field. The results show that the samples have n-alkane series in complete preservation and rich adamantanes. According to the methyladamantane index, the condensate oil is the product of the source rock with vitrinite reflectance (Ro) of 1.3%–1.6%. According to the gas maturity calculated through carbon isotope and vitrinite reflectance, the natural gas is corresponding to Ro of 1.3%–1.7%, reflecting that the natural gas and condensate oil are basically formed during the same period at the high maturity stage of source rock. The Dabei gas field has favorable geological conditions for hydrocarbon accumulation: thick salt rock in the Paleogene acts as a regional high-quality caprock directly overlying the high-quality sandstone reservoir of the Cretaceous, the coal source rocks have high hydrocarbon generation intensity and provide continuous oil and gas, and the subsalt thrust structures develop in rows with rich faults, providing migration pathways for oil and gas migration. These factors together controlled the formation of the Dabei gas field.

Status quo and countermeasures of energy audit in oil and gas field enterprises

To develop energy audits in oil and gas field enterprises has important and realistic significance. Chinese energy audit in oil and gas field enterprises is still in the exploratory stage, the paper puts forward some countermeasures and proposals through the analysis on status quo to identify the shortcomings.

Reservoir Characteristics and Guidance for Exploration in the Beach Area of Shengli Oilfields

The beach area of Shengli Oilfield lies 1n the east and north of Zhanhua sag which is located in the southern end of Bohai Bay Basin(Fig.1).Its geological situation is generally similar to that in Zhanhua sag.Several decades of exploration shows that this area is the most enriched petroleum area in Bo-hai Bay Basin.Oil and gas distributed there in a same way as in Bohai Bay Basin,but also distributed in its own unique way.

Development characteristics, models and strategies for overseas oil and gas fields

Based on about 20 years of accumulated experience and knowledge of oil and gas field development in overseas countries and regions for China's oil companies, the development features, ideas, models and plan designing strategies of overseas oil and gas fields were comprehensively summarized. Overseas oil and gas field development has ten major features, such as non-identity project resource, diversity of contract type, complexity of cooperation model, and so on. The overseas oil and gas field development aims at the maximization of production and benefit during the limited contract period, so the overseas oil and gas field development models are established as giving priority to production by natural energy, building large-scale production capacity, putting into production as soon as possible, realizing high oil production recovery rate, and achieving rapid payback period of investment. According to the overseas contract mode, a set of strategies for overseas oil and gas field development plans were made. For tax systems contracts, the strategy is to adopt the mode of "first fat and then thinner, easier in the first and then harder", that is, early investment pace, production increase rate, development workload and production were decided by the change of tax stipulated in the contract. For production share contracts, the strategy is to give priority to high production with a few wells at a high production recovery rate to increase the cost-oil and shorten the period of payback. For technical service contracts, the strategy is that the optimal production target and workload of the project were determined by the return on investment, so as to ensure that the peak production and stable production periods meet the contract requirements.

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