ZrO2 was added into CaO-Al2O3-SiO2 glass-ceramics and the effect of ZrO2 on sintering and crystallization of CaO-Al2O3-SiO2 glass ceramics was investigated. The results show that the sintering shrinkage ratio of glass...ZrO2 was added into CaO-Al2O3-SiO2 glass-ceramics and the effect of ZrO2 on sintering and crystallization of CaO-Al2O3-SiO2 glass ceramics was investigated. The results show that the sintering shrinkage ratio of glass particles decreases with the increase of the content of ZrO2. ZrO2 has an unfavourable effect on sintering shrinkage ratio of glass particles. The sintering shrinkage ratio of glass particles increases with the increase of sintering temperature. The increase of sintering temperature favors the decrease of the liquid phase viscosity of glass particles. ZrO2 has little effect on crystallization of main crystalline phase （β-wollastonite）. However, it promotes the crystallization at relatively low temperature.展开更多
Sintering shrinkage, compressive strength, bending strength, chemical composition and their relationships with mi-crostructure of HA-Ti and HA-BG-Ti biomaterials were studied. The results show that sintering shrinkage...Sintering shrinkage, compressive strength, bending strength, chemical composition and their relationships with mi-crostructure of HA-Ti and HA-BG-Ti biomaterials were studied. The results show that sintering shrinkage curve of HA-BG-Ti composite changes just like S shape (23.1%-16.2%-21.8%-17.1%) with increase of Ti content, and sintering shrinkage of HA-BG-Ti composite is always higher than that of HA-Ti composite. The approach also indicates that compressive strength and bending strength of HA-BG-Ti composite are always higher than that of HA-Ti composite. Basically, with its compressive strength and bending strength equaling to 211.5 MPa and 132.1 MPa respectively, HA-10 vol. pct BG-60 vol. pct Ti composite can meet the mechanical properties requirements of the outer dense bulk. Furthermore, microstructure analysis shows that interfacial integration of HA-BG-Ti composite is better than that of HA-Ti composite. From X-ray diffraction (XRD) and SEM-EDAX analysis, brittle new phases including calcium titanate and calcium carbonate are detected in HA-Ti composite. New phases in HA-Ti composite and complex strong binding force accompanied by elemental diffusion of Si, Ti in HA-BG-Ti composite can explain theoretically the great difference of mechanical properties of HA-Ti and HA-BG-Ti composites.展开更多
文摘ZrO2 was added into CaO-Al2O3-SiO2 glass-ceramics and the effect of ZrO2 on sintering and crystallization of CaO-Al2O3-SiO2 glass ceramics was investigated. The results show that the sintering shrinkage ratio of glass particles decreases with the increase of the content of ZrO2. ZrO2 has an unfavourable effect on sintering shrinkage ratio of glass particles. The sintering shrinkage ratio of glass particles increases with the increase of sintering temperature. The increase of sintering temperature favors the decrease of the liquid phase viscosity of glass particles. ZrO2 has little effect on crystallization of main crystalline phase （β-wollastonite）. However, it promotes the crystallization at relatively low temperature.
基金The authors are grateful for the financial support from the National Natural Science Foundation of China(No.50174059).
文摘Sintering shrinkage, compressive strength, bending strength, chemical composition and their relationships with mi-crostructure of HA-Ti and HA-BG-Ti biomaterials were studied. The results show that sintering shrinkage curve of HA-BG-Ti composite changes just like S shape (23.1%-16.2%-21.8%-17.1%) with increase of Ti content, and sintering shrinkage of HA-BG-Ti composite is always higher than that of HA-Ti composite. The approach also indicates that compressive strength and bending strength of HA-BG-Ti composite are always higher than that of HA-Ti composite. Basically, with its compressive strength and bending strength equaling to 211.5 MPa and 132.1 MPa respectively, HA-10 vol. pct BG-60 vol. pct Ti composite can meet the mechanical properties requirements of the outer dense bulk. Furthermore, microstructure analysis shows that interfacial integration of HA-BG-Ti composite is better than that of HA-Ti composite. From X-ray diffraction (XRD) and SEM-EDAX analysis, brittle new phases including calcium titanate and calcium carbonate are detected in HA-Ti composite. New phases in HA-Ti composite and complex strong binding force accompanied by elemental diffusion of Si, Ti in HA-BG-Ti composite can explain theoretically the great difference of mechanical properties of HA-Ti and HA-BG-Ti composites.
