Porous oxide ceramics are widely used in extreme working conditions owing to their excellent resistance to high temperatures and corrosion.However,sintering is an inevitable process applied to ceramics,from the green ...Porous oxide ceramics are widely used in extreme working conditions owing to their excellent resistance to high temperatures and corrosion.However,sintering is an inevitable process applied to ceramics,from the green body to the final product.The highly complex structures exacerbate the shrinkage-induced ir-regular deformation and crack formation in the sintering process.A pioneering approach is developed in this study to achieve zero shrinkage for porous alumina ceramics during multistep sintering,using a combination of active fillers-ZrAl 3 and Al 75 Si 25.The response surface method is used to optimize the material compositions and sintering process,to achieve shrinkages of less than 0.05%for the entire pro-cess.The sintering expansion mechanism is investigated by analyzing the pyrolysis and microstructures of samples at different temperatures.The combination of ZrAl 3 and Al 75 Si 25 can attain the continuous expansion of the matrix in a wide temperature range of 600-1400°C.Furthermore,typical alumina com-ponents are fabricated and used to verify the effectiveness of the proposed approach.Owing to shrinkage suppression,the profile deviation of the samples is less than 0.1 mm,and the proportion of microcracks is reduced by 97.8%.The suggested approach shows potential applications in near-net,low-defect fabrica-tion of complex fine ceramic components.展开更多
基金the National Natural Science Foun-dation of China(No.52005392)the National Science and Tech-nology Major Project(No.J2019-Ⅶ−0013-0153)the Fundamental Research Funds for the Central Universities,and the Youth Innova-tion Team of Shaanxi Universities.
文摘Porous oxide ceramics are widely used in extreme working conditions owing to their excellent resistance to high temperatures and corrosion.However,sintering is an inevitable process applied to ceramics,from the green body to the final product.The highly complex structures exacerbate the shrinkage-induced ir-regular deformation and crack formation in the sintering process.A pioneering approach is developed in this study to achieve zero shrinkage for porous alumina ceramics during multistep sintering,using a combination of active fillers-ZrAl 3 and Al 75 Si 25.The response surface method is used to optimize the material compositions and sintering process,to achieve shrinkages of less than 0.05%for the entire pro-cess.The sintering expansion mechanism is investigated by analyzing the pyrolysis and microstructures of samples at different temperatures.The combination of ZrAl 3 and Al 75 Si 25 can attain the continuous expansion of the matrix in a wide temperature range of 600-1400°C.Furthermore,typical alumina com-ponents are fabricated and used to verify the effectiveness of the proposed approach.Owing to shrinkage suppression,the profile deviation of the samples is less than 0.1 mm,and the proportion of microcracks is reduced by 97.8%.The suggested approach shows potential applications in near-net,low-defect fabrica-tion of complex fine ceramic components.
