The water quality grades of phosphate(PO4-P) and dissolved inorganic nitrogen(DIN) are integrated by spatial partitioning to fit the global and local semi-variograms of these nutrients. Leave-one-out cross validat...The water quality grades of phosphate(PO4-P) and dissolved inorganic nitrogen(DIN) are integrated by spatial partitioning to fit the global and local semi-variograms of these nutrients. Leave-one-out cross validation is used to determine the statistical inference method. To minimize absolute average errors and error mean squares,stratified Kriging(SK) interpolation is applied to DIN and ordinary Kriging(OK) interpolation is applied to PO4-P.Ten percent of the sites is adjusted by considering their impact on the change in deviations in DIN and PO4-P interpolation and the resultant effect on areas with different water quality grades. Thus, seven redundant historical sites are removed. Seven historical sites are distributed in areas with water quality poorer than Grade IV at the north and south branches of the Changjiang(Yangtze River) Estuary and at the coastal region north of the Hangzhou Bay. Numerous sites are installed in these regions. The contents of various elements in the waters are not remarkably changed, and the waters are mixed well. Seven sites that have been optimized and removed are set to water with quality Grades III and IV. Optimization and adjustment of unrestricted areas show that the optimized and adjusted sites are mainly distributed in regions where the water quality grade undergoes transition.Therefore, key sites for adjustment and optimization are located at the boundaries of areas with different water quality grades and seawater.展开更多
A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental samp...A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental sampling sites. According to its basis, an application in the optimization of sampling sites in the atmospheric environmental monitoring was discussed. The method was proven to be suitable and effective. The results were admitted and applied by the Environmental Protection Bureau (EPB) of many cities of China. A set of computer software of this approach was also completely compiled and used.展开更多
Recent estimates indicate that one-fifth of botanical species worldwide are considered at risk of becoming extinct in the wild. One available strategy for conserving many rare plant species is reintroduction, which ho...Recent estimates indicate that one-fifth of botanical species worldwide are considered at risk of becoming extinct in the wild. One available strategy for conserving many rare plant species is reintroduction, which holds much promise especially when carefully planned by following guidelines and when monitored long-term. We review the Center for Plant Conservation Best Reintroduction Practice Guidelines and highlight important components for planning plant reintroductions. Before attempting reintroductions practitioners should justify them, should consider alternative conservation strategies, understand threats, and ensure that these threats are absent from any recipient site. Planning a reintroduction requires considering legal and logistic parameters as well as target species and recipient site attributes.Carefully selecting the genetic composition of founders, founder population size, and recipient site will influence establishment and population growth. Whenever possible practitioners should conduct reintroductions as experiments and publish results. To document whether populations are sustainable will require long-term monitoring for decades, therefore planning an appropriate monitoring technique for the taxon must consider current and future needs. Botanical gardens can play a leading role in developing the science and practice of plant reintroduction.展开更多
Physical factors affecting the survival of Tachypleus tridentatus eggs were investigated by translocating their eggs between the high intertidal zone and the low intertidal zone of a known spawning site.The mean egg s...Physical factors affecting the survival of Tachypleus tridentatus eggs were investigated by translocating their eggs between the high intertidal zone and the low intertidal zone of a known spawning site.The mean egg survival rates per day were highest in the mid intertidal zone(45.1%±25.4%)and the lowest in the low intertidal zone(13.3%±27.6%).Differences in the elevation,air exposure time,and water content of the spawning ground were significant factors determining the egg survival rates.Excessive or insufficient air exposure time resulted in inadequate water content at higher and lower intertidal zones and could reduce egg survival.On the other hand,moderate saturation and dehydration were repeated with each tidal movement in the mid intertidal zone.This dynamic is considered as one of the crucial factors for the survival of eggs and is considered optimal for spawning.Therefore,the protection of the mid intertidal zone is imperative for maximizing the egg survival rate in Tsuyazaki Cove where almost all suitable nesting sites have disappeared due to coastal development.By protecting these optimal sites for spawning and recovering other optimal sites on suitable beaches,a positive contribution can be made to future management and conservation.The study also suggests that translocating eggs from marginal to optimal spawning sites might be a recovery strategy for this globally endangered species.展开更多
Fe-N-C electrocatalysts,comprising FeN_(4) single atom sites immobilized on N-doped carbon supports,offer excellent activity in the oxygen reduction reaction(ORR),especially in alkaline solution.Herein,we report a sim...Fe-N-C electrocatalysts,comprising FeN_(4) single atom sites immobilized on N-doped carbon supports,offer excellent activity in the oxygen reduction reaction(ORR),especially in alkaline solution.Herein,we report a simple synthetic strategy for improving the accessibility of FeN_(4) sites during ORR and simultaneously fine-tuning the microenvironment of FeN_(4) sites,thus enhancing the ORR activity.Our approach involved a simple one-step pyrolysis of a Fe-containing zeolitic imidazolate framework in the presence of NaCl,yielding a hierarchically porous Fe-N-C electrocatalyst containing tailored FeN_(4) sites with slightly elongated Fe-N bond distances and reduced Fe charge.The porous carbon structure improved mass transport during ORR,whilst the microenvironment optimized FeN_(4) sites benefitted the adsorption/desorption of ORR intermediates.Accordingly,the developed electrocatalyst,possessing a high FeN_(4) site density(9.9×10^(19) sites g^(-1))and turnover frequency(2.26 s^(-1)),delivered remarkable ORR performance with a low overpotential(a half-wave potential of 0.90 V vs.reversible hydrogen electrode)in 0.1 mol L^(-1) KOH.展开更多
基金The National Natural Science Fundation of China under contract Nos 41376190,41271404,41531179,41421001 and41601425the Open Funds of the Key Laboratory of Integrated Monitoring and Applied Technologies for Marin Harmful Algal Blooms,SOA under contract No.MATHA201120204+1 种基金the Scientific Research Project of Shanghai Marine Bureau under contract No.Hu Hai Ke2016-05the Ocean Public Welfare Scientific Research Project,State Oceanic Administration of the People's Republic of China under contract Nos 201305027 and 201505008
文摘The water quality grades of phosphate(PO4-P) and dissolved inorganic nitrogen(DIN) are integrated by spatial partitioning to fit the global and local semi-variograms of these nutrients. Leave-one-out cross validation is used to determine the statistical inference method. To minimize absolute average errors and error mean squares,stratified Kriging(SK) interpolation is applied to DIN and ordinary Kriging(OK) interpolation is applied to PO4-P.Ten percent of the sites is adjusted by considering their impact on the change in deviations in DIN and PO4-P interpolation and the resultant effect on areas with different water quality grades. Thus, seven redundant historical sites are removed. Seven historical sites are distributed in areas with water quality poorer than Grade IV at the north and south branches of the Changjiang(Yangtze River) Estuary and at the coastal region north of the Hangzhou Bay. Numerous sites are installed in these regions. The contents of various elements in the waters are not remarkably changed, and the waters are mixed well. Seven sites that have been optimized and removed are set to water with quality Grades III and IV. Optimization and adjustment of unrestricted areas show that the optimized and adjusted sites are mainly distributed in regions where the water quality grade undergoes transition.Therefore, key sites for adjustment and optimization are located at the boundaries of areas with different water quality grades and seawater.
文摘A new approach applying fuzzy mathematic theorems, including the Primary Matrix Element Theorem and the Fisher Classification Method, was established to solve the optimization problem of atmospheric environmental sampling sites. According to its basis, an application in the optimization of sampling sites in the atmospheric environmental monitoring was discussed. The method was proven to be suitable and effective. The results were admitted and applied by the Environmental Protection Bureau (EPB) of many cities of China. A set of computer software of this approach was also completely compiled and used.
基金Guangxi Chairman's Foundation grant #09203-04 to Hong Liu and colleagues supported JM attendance at the IABG conference possiblefunding from the U.S. Fish and Wildlife Service(1448-40181-99-G173)+4 种基金Florida Department of Agriculture and Consumer Services (#20161,021010,022647)Miami-Dade County Natural Areas Management and Environmentally Endangered Lands Program (R-80807)Arizona Department of TransportationU.S. Forest ServiceU.S. National Park Service
文摘Recent estimates indicate that one-fifth of botanical species worldwide are considered at risk of becoming extinct in the wild. One available strategy for conserving many rare plant species is reintroduction, which holds much promise especially when carefully planned by following guidelines and when monitored long-term. We review the Center for Plant Conservation Best Reintroduction Practice Guidelines and highlight important components for planning plant reintroductions. Before attempting reintroductions practitioners should justify them, should consider alternative conservation strategies, understand threats, and ensure that these threats are absent from any recipient site. Planning a reintroduction requires considering legal and logistic parameters as well as target species and recipient site attributes.Carefully selecting the genetic composition of founders, founder population size, and recipient site will influence establishment and population growth. Whenever possible practitioners should conduct reintroductions as experiments and publish results. To document whether populations are sustainable will require long-term monitoring for decades, therefore planning an appropriate monitoring technique for the taxon must consider current and future needs. Botanical gardens can play a leading role in developing the science and practice of plant reintroduction.
文摘Physical factors affecting the survival of Tachypleus tridentatus eggs were investigated by translocating their eggs between the high intertidal zone and the low intertidal zone of a known spawning site.The mean egg survival rates per day were highest in the mid intertidal zone(45.1%±25.4%)and the lowest in the low intertidal zone(13.3%±27.6%).Differences in the elevation,air exposure time,and water content of the spawning ground were significant factors determining the egg survival rates.Excessive or insufficient air exposure time resulted in inadequate water content at higher and lower intertidal zones and could reduce egg survival.On the other hand,moderate saturation and dehydration were repeated with each tidal movement in the mid intertidal zone.This dynamic is considered as one of the crucial factors for the survival of eggs and is considered optimal for spawning.Therefore,the protection of the mid intertidal zone is imperative for maximizing the egg survival rate in Tsuyazaki Cove where almost all suitable nesting sites have disappeared due to coastal development.By protecting these optimal sites for spawning and recovering other optimal sites on suitable beaches,a positive contribution can be made to future management and conservation.The study also suggests that translocating eggs from marginal to optimal spawning sites might be a recovery strategy for this globally endangered species.
基金supported by a James Cook Research Fellowship,administered by the Royal Society Te Apārangifunding support from Greg and Kathryn Trounson,the Energy Education Trust of New Zealand,the Mac Diarmid Institute for Advanced Materials and Nanotechnology,the National Key Projects for Fundamental Research and Development of China(2017YFA0206904 and 2017YFA0206900)+1 种基金the National Natural Science Foundation of China(51825205 and 21871279)the Beijing Natural Science Foundation(2191002)。
文摘Fe-N-C electrocatalysts,comprising FeN_(4) single atom sites immobilized on N-doped carbon supports,offer excellent activity in the oxygen reduction reaction(ORR),especially in alkaline solution.Herein,we report a simple synthetic strategy for improving the accessibility of FeN_(4) sites during ORR and simultaneously fine-tuning the microenvironment of FeN_(4) sites,thus enhancing the ORR activity.Our approach involved a simple one-step pyrolysis of a Fe-containing zeolitic imidazolate framework in the presence of NaCl,yielding a hierarchically porous Fe-N-C electrocatalyst containing tailored FeN_(4) sites with slightly elongated Fe-N bond distances and reduced Fe charge.The porous carbon structure improved mass transport during ORR,whilst the microenvironment optimized FeN_(4) sites benefitted the adsorption/desorption of ORR intermediates.Accordingly,the developed electrocatalyst,possessing a high FeN_(4) site density(9.9×10^(19) sites g^(-1))and turnover frequency(2.26 s^(-1)),delivered remarkable ORR performance with a low overpotential(a half-wave potential of 0.90 V vs.reversible hydrogen electrode)in 0.1 mol L^(-1) KOH.