Morphology and Precipitation Kinetics of MnS in Low-Carbon Steel During Thin Slab Continuous Casting Process

The morphology of manganese sulfide formed during thin slab continuous casting process in low-carbon steel produced by compact strip production （CSP） technique was investigated. Using transmission electron microscopy analysis, it was seen that a majority of manganese sulfides precipitated at austenite grain boundaries, the morphologies of which were spherical or close to the spherical shape and the size of MnS precipitates ranged from 30 nm to 100 nm. A mathematical model of the manganese sulfide precipitation in this process was developed based on classical nucleation theory. Under the given conditions, the starting and finishing precipitation temperatures of MnS in the continuous casting thin slab of the studied low-carbon steel are 1 189 ℃ and 1 171 ℃, respectively, and the average diameter of MnS precipitates is about 48 nm within this precipitation temperature range. The influences of chemical components and thermo-mechanical processing conditions on the precipitation behavior of MnS in the same process were also discussed.

Effect of cooling structure on thermal behavior of copper plates of slab continuous casting mold

A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.

Flow and Temperature Fields in Slab Continuous Casting Molds

In order to develop super-board and super-thick slabs, the flow and temperatur fields were studied in slab continuous casting molds under different practical conditions, such as slab dimensions, with-drawing slab speed, design of nozzles, and superheat tempera-ture. The results showed that it is preferred to incline nozzle bores downwards and the submerged depth of the nozzles is best kept be-tween 250-300 mm. In addition, the solidified shell is thicker at the wide face than that at the narrow face, while the thin points alongthe wide face ekist both in the center and in the some area toward each respective end.

Modeling of unsteadiness of fluid flows and level fluctuations in thin slab continuous casting moulds

Unsteady fluid flows and level fluctuations in a thin slab continuous casting mould have significant influence on product quality. In this study, the phenomena concerning transient flow features and free surface motions were analyzed by means of the large eddy simulation （LES） software with the smagorinsky SGS model--VisualCast （VCast） II, where the Simpler algorithm on a body-fitted mesh was used to resolve governing equations. A series of water analog experiments on the fluid flow and the surface wave in the moulds of thin slab continuous casting were also performed. The results of fluid regions, middle of vortex and level fluctuation from digital simulations were identical with the results of the water analog experiments.

Numerical simulation of fluid flows in a slab continuous casting mold under electromagnetic stirring

This study established a three-dimensional mathematical model to determine the fluid flow in a slab continuous casting mold under an electromagnetic stirring force. The flow structure and distribution were studied with respect to different continuous casting parameters and stirring current. Based on the calculation results, the mold flux entrapment index in free surface and velocity uniformity index were used to evaluate the flow field in the mold. The theoretical basis for the optimization of the flow field structure was provided. The study also suggested an optimization method for electromagnetic stirring parameters.

Simulation of thermal behavior during peritectic steel solidification in slab continuous casting mold

Thermal behavior of the solidifying shell in continuous casting mold is very important to final steel products.In the present work,one two-dimension transient thermal-mechanical finite element model was developed to simulate the thermal behavior of peritectic steel solidifying in slab continuous casting mold by using the sequential coupling method.In this model,the steel physical properties at high temperature was gotten from the micro-segregation model withδ/γtransformation in mushy zone,and the heat flux was obtained according to the displacement between the surface of solidifying shell and the hot face of mold as solidification contraction,the liquid-solid structure and distribution of mold flux,and the temperature distribution of slab surface and mold hot face,in addition,the rate-dependent elastic-viscoplastic constitutive equation was applied to account for the evolution of shell stress in the mold.With this model,the variation characteristics of surface temperature,heat flux, and growth of the solidifying shell corner,as well as the thickness distribution of the liquid flux,solidified flux,air gap and the corresponding thermal resistance were described.

Physical modeling and numerical simulation of electromagnetic stirring in a slab continuous casting mold

Through physical modeling and numerical simulation,the flow field in a slab continuous casting mold with electromagnetic stirring is measured under different casting parameters and stirring currents. To qualitatively evaluate the flow field in the mold, two indexes,i, e., mold flux entrapment and velocity uniformity, are proposed. Based on these two indexes, some optimized stirring parameters under different casting conditions can be determined.

Generalized constructal optimization for the secondary cooling process of slab continuous casting based on entransy theory

Based on constructal theory and entransy theory,a generalized constructal optimization of a solidification heat transfer process of slab continuous casting for a specified total water flow rate in the secondary cooling zone was carried out.A complex function was taken as the optimization objective to perform the casting.The complex function was composed of the functions of the entransy dissipation and surface temperature gradient of the slab.The optimal water distribution at the sections of the secondary cooling zone were obtained.The effects of the total water flow rate in the secondary cooling zone,casting speed,superheat and water distribution on the generalized constructal optimizations of the secondary cooling process were analyzed.The results show that on comparing the optimization results obtained based on the optimal water distributions of the 8 sections in the secondary cooling zone with those based on the initial ones,the complex function and the functions of the entransy dissipation and surface temperature gradient after optimization decreased by 43.25%,5.90%and 80.60%,respectively.The quality and energy storage of the slab had obviously improved in this case.The complex function,composed of the functions of the entransy dissipation and surface temperature gradient of the slab,was a compromise between the internal and surface temperature gradients of the slab.Essentially,it is also the compromise between energy storage and quality of the slab.The"generalized constructal optimization"based on the minimum complex function can provide an optimal alternative scheme from the point of view of improving energy storage and quality for the parameter design and dynamic operation of the solidification heat transfer process of slab continuous casting.

Characteristic Parameters for Dendritic Microstructure of Solidification During Slab Continuous Casting

The operating conditions during the continuous casting process have a great effect on the microstructure of slab solidification, including primary and secondary dendritic arm spacing. On the basis of the analysis of available work, a revised expression for describing secondary dendritic arm spacing during solidification of slab continuous casting was presented, and the relation between the ratio of primary dendritic arm spacing to secondary dendritic arm spacing and the cooling rate was obtained.

Numerical simulation of EMS position on flow, solidification and inclusion capture in slab continuous casting

Electromagnetic stirring(EMS)is a well-known and widely used technology for controlling the fluid flow in continuous casting mold,and therein the selection of stirrer position is closely related to final product.To investigate the effect of stirrer position on initial solidification and inclusion capturing,a mathematical model coupling with electromagnetic field,turbulence flow,solidification,and inclusion movement was constructed.Through comparing the magnetic flux density,flow field and solidified shell thickness with measured data,the reliability of the mathematical model was proved.The uniform index has been introduced to judge the uniformity of solidified shell,and the washing effects of EMS on the numbers and distribution of captured inclusions were discussed.The results show that a diagonal jet flow toward the mold wide face has generated when EMS is applied,and upper EMS position can effectively improve the uniformity of temperature and the solidified shell within the mold.Meanwhile,due to the washing effect of EMS,the number of inclusions inside the solidified shell decreases,and the distribution of captured inclusions along the mold width changes evenly.Decreasing the stirrer position,the uniform index decreases firstly and then increases,and the probability of inclusion capture by solidified shell increases.Thus,the upper stirrer position is suggested,with which the uniformity of solidified shell and cleanliness of slab are rational.

Large eddy simulation of transient transport and entrapment of particle during slab continuous casting

To investigate the transient transport and entrapment of argon bubbles and inclusions simultaneously during continuous casting,a 3D large eddy simulation model coupling molten steel flow,solidification and particle motion was constructed.In this model,momentum transfer between molten steel and argon bubbles was performed by two-way coupling.The predicted results indicate that argon bubble injection changed the flow pattern of molten steel and the inclusion motion in the liquid pool.Consequently,the inclusion capture near the solidifying front was changed.In addition,measurements of bubbles and inclusions in the obtained samples were performed by methods of optical microscope examination and galvanostatic electrolysis.The results show a favorable agreement between the model predictions and the measured results,which validate the mathematical model.Furthermore,the predicted results of the inclusion entrapment in the case with argon bubble injection are more compatible with the measurements than those in the case without argon bubble injection.

Longitudinal crack on slab surface at straightening stage during continuous casting using finite element method

Deformation behavior of slab at the straightening stage during continuous casting was simulated by the explicit dynamic finite element method,and the stress distribution along the width direction of the slab and its change regularity at slab center during continuous casting were obtained.The influence of distribution and change of stress on the propagation of longitudinal cracks on slab surface was discussed.The results show that the tensional stress appears on slab surface at the inner arc side and the compressive stress appears on slab surface at the outer arc side at stages 6-8 in straightening zone during continuous casting.Longitudinal cracks generally appear on slab top surface and do not appear on slab bottom surface,which are also observed in industry.

Strain in solidifying shell of continuous casting slabs

Two-dimension unsteady heat transfer model was applied to obtain the surfacetemperature and the shell thickness of continuous casting slabs during the process ofsolidification. On the basis of which, the mathematical model of strain at the interface of solidand liquid steel was set up. Through which, the strain in the solidifying shell under normal andabnormal operation conditions was gained. The results indicate that the strain is small under thenormal operation conditions and the internal crack never happens. However, when the variation of theroll gap is above 2 mm, the strain caused by which is greater than that caused by bulging.Furthermore, the total strain exceeds the critical one and the internal crack is the result. So itis of great importance to maintain the fine state of continuous casting machine to avoid theappearance of internal crack.

INVESTIGATION ON HOT DUCTILITY AND STRENGTH OF CONTINUOUS CASTING SLAB FOR AH32 STEEL

By means of Gleeble-1500 testing machine, the simulation of continuous casting process forAH32 steel was carried out and hot ductility and strength were determined. The cracking sensitivity was studied under the different temperatures and strain rates. The Precipitations of AIN at different temperatures and the fractures of high-temperature tensile samples were observed by using TEM （transmission electron microscope） and SEM （scanning electron microscope）. The factors affecting the brittle temperature zone were discussed.

Study on Flow in Mold With EMBr in Slab Continuous Casting

A mercury model has been developed to investigate the influences of Electromagnetic Mold Brake Ruler(EMBr-Ruler) and Flow Control Mold(FC Mold) on metal flow in slab continuous casting mold with the practical casting speed 1.0,1.3 and 2.0 m/min respectively.FC-Mold can efficiently repress the surface flow and its fluctuation.The expanding space of the jets is compressed by EMBr-Ruler and FC-Mold respectively,then the 'flow passage' where the vertical velocity of flow increases sharply is developed near the narrow wall with EMBr-Ruler and FC-Mold.It is bad for the development of the plug like flow.Only the nozzle ports are placed in the braking magnetic field region and the casting speed is suitable,EMBr can be beneficial to the formation of the plug like flow.The flow regime is improved with FC Mold when the casting speed is high(2.0 m/min),but EMBr can improve the flow field with medium casting speed(1.3 m/min),but when the casting speed is low(1.0 m/min),the effects of two types of EMBr are both unsatisfactory.

Study Segregation of Alloying Elements in Continuous Casting Slab with Valence Electron Structure

By calculating the electron structures of the phases that phosphor, sulfur and alloying elements dissolving inγ-Fe, the reason why alloying elements can bring centerline segregation in continuous casting slab (CCS) with nA, the number of electrons on the strongest covalent bonds, and the structure formation factor S were investigated, and an electron structural criterion to control and to eliminate the centerline segregation was advanced. Basing on this, the electron structures of a part of rare earth phosphides and sulfides are calculated, the physical mechanism that rare earth elements can control the segregation of phosphor and sulfur is analyzed, and the criterion is well verified.

Research on the trajectory of non-metal inclusions with the flow in the mold during the solidification of continuous casting slabs

By means of the numerical simulation method,the mathematical model of inclusions movement in the mold is established under the condition of austenitic and fen-itic stainless steel slab production. According to the simulation results, the main zones for inclusion particles accumulation were found and many factors that affected floating-up probability of inclusion particles were identified. These factors include the inclusion particle size, the casting speed and the slab width, etc. It is believed that the inclusion particle size is the key one among these factors.

Modeling and control of dynamic soft reduction in continuous slab casting

The centerline segregation in continuous casting steel is known to be formed by the interdendritic enriched liquid flow at the solidification end in strand.At present,several methods,such as thermal soft reduction, electromagnetic stirring and dynamic soft reduction,are available to reduce the center segregation and to improve the internal quality.Although some methods could alleviate center segregation to some extent,they can also give rise to new problems.For instance,thermal soft reduction can lead to surface cracking during casting of some steels and electromagnetic stirring can result in white band.Dynamic soft reduction is an effective technology for the improvement of strand quality in continuous slab casting.In this paper,the key parameters of dynamic soft reduction technology,such as soft reduction region,the total reduction amount,for low carbon steel have been studied based on experimental and theoretical analysis.The soft reduction region was related to the segregation of chemical composition,slab bulging of narrow side and avoiding internal crack of slab.The total reduction amount was composed of natural thermal shrinkage and actual reduction amount depending on critical strain.For low carbon steel with slab dimension of(950 - 1 950) mm×170 mm,the solid fraction range in soft reduction region was recommended from 0.4 to 0.8,the total reduction amount was 2.0 -2.8 mm,and the optimized reduction rate was 0.4 - 1.2 mm/min,respectively.Furthermore,a dynamic soft reduction system in continuous slab casting, Visual Cast-Dynamic,has been developed by multithreading method.It demonstrated that the dynamic soft reduction model in this study was correct with the ability of online control.

Technological Investigation on the Continuous Casting of Mid-Width Thin Slabs

Continuous casting of thin slabs is a key state project for 7th and sth five -year plans. On thebasis of foundamental works , CISRI condueted the tests of 102 heats in Lanzhou Steel Works in the periodof January 1991- June 1992. Three slab assortments of 50× 900 mm . 70 × 900 mm , 70 × 500 mm were ex-amined. In June of 1992, 412 t steel of 46 heats were cast with the efficiency of 91. 3 %. This. result meetsthe requiremeni of the state in this period. The mould, hedt transfer . casting technology and factors influ-encing slab’s qualities are investigated as well.

Numerical Simulation of Fluid Flow and Heat Transfer in Funnel Shaped Mold of Thin Slab Continuous Caster

Thin slab casting is used widely in the world. The control of molten steel flow and solidification in the mold is difficult due to the high casting speed and complicated configuration of the mold. Numerical simulation was carried out to study the fluid flow and heat transfer in the funnel shaped mold. The influence of nozzle design, casting speed and nozzle submersion depth on the flow and temperature fields in the mold was investigated, and guidance for selecting configurations of submerged nozzle was obtained.