SmB_6 has been a well-known Kondo insulator for decades, but recently attracts extensive new attention as a candidate topological system. Studying SmB_6 under pressure provides an opportunity to acquire the much-neede...SmB_6 has been a well-known Kondo insulator for decades, but recently attracts extensive new attention as a candidate topological system. Studying SmB_6 under pressure provides an opportunity to acquire the much-needed understanding about the effect of electron correlations on both the metallic surface state and bulk insulating state. Here we do so by studying the evolution of two transport gaps(low temperature gap E_l and high temperature gap E_h) associated with the Kondo effect by measuring the electrical resistivity under high pressure and low temperature(0.3 K) conditions. We associate the gaps with the bulk Kondo hybridization, and from their evolution with pressure we demonstrate an insulator-tometal transition at ~4 GPa. At the transition pressure, a large change in the Hall number and a divergence tendency of the electron-electron scattering coefficient provide evidence for a destruction of the Kondo entanglement in the ground state. Our results raise the new prospect for studying topological electronic states in quantum critical materials settings.展开更多
A convenient fabrication technique for samarium hexaboride（SmB6） nanostructures（nanowires and nanopencils） is developed, combining magnetron-sputtering and chemical vapor deposition. Both nanostructures are proven...A convenient fabrication technique for samarium hexaboride（SmB6） nanostructures（nanowires and nanopencils） is developed, combining magnetron-sputtering and chemical vapor deposition. Both nanostructures are proven to be single crystals with cubic structure, and they both grow along the [001] direction. Formation of both nanostructures is attributed to the vapor-liquid-solid（VLS） mechanism, and the content of boron vapor is proposed to be the reason for their different morphologies at various evaporation distances. Field emission（FE） measurements show that the maximum current density of both the as-grown nanowires and nanopencils can be several hundred μA/cm^2, and their FN plots deviate only slightly from a straight line. Moreover, we prefer the generalized Schottky-Nordheim（SN） model to comprehend the difference in FE properties between the nanowires and nanopencils. The results reveal that the nonlinearity of FN plots is attributable to the effect of image potential on the FE process, which is almost independent of the morphology of the nanostructures.All the research results suggest that the SmB6 nanostructures would have a more promising future in the FE area if their surface oxide layer was eliminated in advance.展开更多
基金supported by the National Key Research and Development Program of China(2017YFA0302900,2016YFA0300300 and 2015CB921303)the National Natural Science Foundation of China(91321207,11427805,11404384,U1532267 and 11522435)+8 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(XDB07020300 and XDB07020200)supported by the National Natural Science Foundation of China(1374361)the National Key Research and Development Program of China(2016YFA0300300)the Fundamental Research Funds for the Central Universitiesthe Research Funds of Renmin University of China(14XNLF08)funded by the Los Alamos LDRD programthe FAPESP Grant 2013/2018-0supported by the ARO Grant No.W911NF-14-10525the Robert A.Welch Foundation Grant No.C-1411
文摘SmB_6 has been a well-known Kondo insulator for decades, but recently attracts extensive new attention as a candidate topological system. Studying SmB_6 under pressure provides an opportunity to acquire the much-needed understanding about the effect of electron correlations on both the metallic surface state and bulk insulating state. Here we do so by studying the evolution of two transport gaps(low temperature gap E_l and high temperature gap E_h) associated with the Kondo effect by measuring the electrical resistivity under high pressure and low temperature(0.3 K) conditions. We associate the gaps with the bulk Kondo hybridization, and from their evolution with pressure we demonstrate an insulator-tometal transition at ~4 GPa. At the transition pressure, a large change in the Hall number and a divergence tendency of the electron-electron scattering coefficient provide evidence for a destruction of the Kondo entanglement in the ground state. Our results raise the new prospect for studying topological electronic states in quantum critical materials settings.
基金Project supported by the National Key Basic Research Program of China(Grant No.2013CB933601)National Project for the Development of Key Scientific Apparatus of China(Grant No.2013YQ12034506)+3 种基金the Fundamental Research Funds for the Central Universities of Chinathe Science and Technology Department of Guangdong Province,Chinathe Education Department of Guangdong Province,Chinathe Natural Science Foundation of Guangdong Province,China(Grant No.2016A030313313)
文摘A convenient fabrication technique for samarium hexaboride（SmB6） nanostructures（nanowires and nanopencils） is developed, combining magnetron-sputtering and chemical vapor deposition. Both nanostructures are proven to be single crystals with cubic structure, and they both grow along the [001] direction. Formation of both nanostructures is attributed to the vapor-liquid-solid（VLS） mechanism, and the content of boron vapor is proposed to be the reason for their different morphologies at various evaporation distances. Field emission（FE） measurements show that the maximum current density of both the as-grown nanowires and nanopencils can be several hundred μA/cm^2, and their FN plots deviate only slightly from a straight line. Moreover, we prefer the generalized Schottky-Nordheim（SN） model to comprehend the difference in FE properties between the nanowires and nanopencils. The results reveal that the nonlinearity of FN plots is attributable to the effect of image potential on the FE process, which is almost independent of the morphology of the nanostructures.All the research results suggest that the SmB6 nanostructures would have a more promising future in the FE area if their surface oxide layer was eliminated in advance.
