Sn/carbon-fibers(CFs) nanocomposite has been prepared by chemical vapor deposition with in-situ catalytic growth of CFs.The nanocomposite has been characterized by X-ray diffraction(XRD),field emission scanning el...Sn/carbon-fibers(CFs) nanocomposite has been prepared by chemical vapor deposition with in-situ catalytic growth of CFs.The nanocomposite has been characterized by X-ray diffraction(XRD),field emission scanning electron microscopy(FE-SEM),transmission electron microscopy(TEM) and Raman spectrum.The electrochemical performance of the nanocomposite has been investigated by galvanostatic cycling and cyclic voltammetry(CV).It has been found that a three-dimensional conductive network forms by the interconnected CFs,which offers conductive channels for the Sn nanoparticles.The nanocomposite gives a first charge capacity of 385 mAh.g-1 and exhibits an improved cycling stability than bare Sn.展开更多
基金supported by Zijin Program of Zhejiang University,Chinathe Fundamental Research Funds for the Central Universities (No. 2010QNA4003)+1 种基金the Ph.D.Programs Foundation of Ministry of Education of China(No. 20100101120024)the Foundation of Education Office of Zhejiang Province (No. Y201016484)
文摘Sn/carbon-fibers(CFs) nanocomposite has been prepared by chemical vapor deposition with in-situ catalytic growth of CFs.The nanocomposite has been characterized by X-ray diffraction(XRD),field emission scanning electron microscopy(FE-SEM),transmission electron microscopy(TEM) and Raman spectrum.The electrochemical performance of the nanocomposite has been investigated by galvanostatic cycling and cyclic voltammetry(CV).It has been found that a three-dimensional conductive network forms by the interconnected CFs,which offers conductive channels for the Sn nanoparticles.The nanocomposite gives a first charge capacity of 385 mAh.g-1 and exhibits an improved cycling stability than bare Sn.