The present study is designed to simulate and study the production of single crystals of semi-organic non-linear optical Glycine Sodium Nitrate (GSN) by using hyper6 software and experimentally by slow evaporation tec...The present study is designed to simulate and study the production of single crystals of semi-organic non-linear optical Glycine Sodium Nitrate (GSN) by using hyper6 software and experimentally by slow evaporation technique. This work has investigated the molecular properties of the crystals using the density functional theory to obtain the infrared spectrum of the crystal by simulation. The FTIR investigation of growing crystal has shown that the spectrum of the GSN crystal compared to simulation evaluation is similar;the only difference is in the range of 1.9% to 2.75% of wavelength peak values. The ultraviolet experimental measurement of the GSN molecule reveals the possibility of non-linear properties due to the spectrum cutoff in the wavelength peak of 301 nm. There was a significantly positive correlation between simulation and experimental assessment.展开更多
Cocoyl glycine was synthesized directly from coconut oil and sodium glycinate in yield of 87%. IR, ESI-MS and LC/MS analysis results showed that cocoyl glycine consists of a series of acyl glycines with different acyl...Cocoyl glycine was synthesized directly from coconut oil and sodium glycinate in yield of 87%. IR, ESI-MS and LC/MS analysis results showed that cocoyl glycine consists of a series of acyl glycines with different acyl chain lengths, and the proportion of each component was consistent with the composition of fatty acids derived from coconut oil. The surface tension and the Critical Micelle Concentration (CMC) of corresponding sodium salt were evaluated. The result showed that sodium cocoyl glycinate reduced the surface tension of water to a minimum value of approximately 33 mN·m-1 at CMC of 0.21 mmol·L-1.展开更多
The physicochemical properties,including the density,viscosity,and refractive index of aqueous solutions of sodium glycinate as a solvent for CO_2 absorption in the non-precipitation regime were measured under the wid...The physicochemical properties,including the density,viscosity,and refractive index of aqueous solutions of sodium glycinate as a solvent for CO_2 absorption in the non-precipitation regime were measured under the wide temperature range of 298.15 to 343.15 K.The concentration of the sodium glycinate in an aqueous form in the non-precipitation regime was identified up to 2.0 mol ? L^(-1).The coefficients of thermal expansion values were estimated from measured density data.It was found that,the densities,viscosities and refractive indices of the aqueous sodium glycinate decrease with an increase in temperature,whereas with increasing sodium glycinate concentration in the solution,all three properties increase.Thermal expansion coefficients slightly increase with rising temperature and concentration.The measured values of density,viscosity and refractive index were correlated as a function of temperature by using the least squares method.The predicted data obtained from correlation equations for all measured properties were in fairly good agreement with the experimental data.展开更多
文摘The present study is designed to simulate and study the production of single crystals of semi-organic non-linear optical Glycine Sodium Nitrate (GSN) by using hyper6 software and experimentally by slow evaporation technique. This work has investigated the molecular properties of the crystals using the density functional theory to obtain the infrared spectrum of the crystal by simulation. The FTIR investigation of growing crystal has shown that the spectrum of the GSN crystal compared to simulation evaluation is similar;the only difference is in the range of 1.9% to 2.75% of wavelength peak values. The ultraviolet experimental measurement of the GSN molecule reveals the possibility of non-linear properties due to the spectrum cutoff in the wavelength peak of 301 nm. There was a significantly positive correlation between simulation and experimental assessment.
文摘Cocoyl glycine was synthesized directly from coconut oil and sodium glycinate in yield of 87%. IR, ESI-MS and LC/MS analysis results showed that cocoyl glycine consists of a series of acyl glycines with different acyl chain lengths, and the proportion of each component was consistent with the composition of fatty acids derived from coconut oil. The surface tension and the Critical Micelle Concentration (CMC) of corresponding sodium salt were evaluated. The result showed that sodium cocoyl glycinate reduced the surface tension of water to a minimum value of approximately 33 mN·m-1 at CMC of 0.21 mmol·L-1.
基金Universiti Teknologi PETRONAS for providing financial support(Grant number YUTP-15-8209-005)RCCO_2C for technical support to complete the present research work
文摘The physicochemical properties,including the density,viscosity,and refractive index of aqueous solutions of sodium glycinate as a solvent for CO_2 absorption in the non-precipitation regime were measured under the wide temperature range of 298.15 to 343.15 K.The concentration of the sodium glycinate in an aqueous form in the non-precipitation regime was identified up to 2.0 mol ? L^(-1).The coefficients of thermal expansion values were estimated from measured density data.It was found that,the densities,viscosities and refractive indices of the aqueous sodium glycinate decrease with an increase in temperature,whereas with increasing sodium glycinate concentration in the solution,all three properties increase.Thermal expansion coefficients slightly increase with rising temperature and concentration.The measured values of density,viscosity and refractive index were correlated as a function of temperature by using the least squares method.The predicted data obtained from correlation equations for all measured properties were in fairly good agreement with the experimental data.
