Wet reclamation of waste sodium silicate-bonded sand produces much alkaline sewage and causes pollution. Recycling water glass from wet reclamation sewage of the waste sodium silicate-bonded sand can solve pollution i...Wet reclamation of waste sodium silicate-bonded sand produces much alkaline sewage and causes pollution. Recycling water glass from wet reclamation sewage of the waste sodium silicate-bonded sand can solve pollution issues and generate economic benefits. In this work, the wet reclamation sewage was filtered, and the filtrate was causticized with a quicklime powder to produce a lye. The effects of causticization temperature, causticization time, and the amount of quicklime powder on the causticization rate were studied. The lye was used to dissolve the silica in the filtration residue to prepare a sodium silicate solution. The effects of the mass of filtration residue, dissolution temperature, and dissolution time on sodium silicate modulus were studied. Finally, the recycled water glass was obtained by concentrating the sodium silicate solution, and the bonding strength of the recycled water glass was tested. The results showed that the causticization rate could be improved by increasing the amount of quicklime powder, causticization temperature, and causticization time, and the highest causticization rate was above 92%. Amorphous silica in the filtration residue dissolved in the lye. Increasing the amount of the filtration residue, dissolution temperature, and dissolution time could improve the sodium silicate modulus. The bonding strength of the recycled water glass was close to that of commercial water glass. The recycled water glass could be used as a substitute for the commercial water glass.展开更多
Na1＋xV3O8 nanoribbon thin film was successfully fabricated by annealing the V2O5 xerogel film on sodium sili-cate glass substrate at 450℃. It has been identified that the amount of sodium ions diffused into the V2O5...Na1＋xV3O8 nanoribbon thin film was successfully fabricated by annealing the V2O5 xerogel film on sodium sili-cate glass substrate at 450℃. It has been identified that the amount of sodium ions diffused into the V2O5 xerogel film increases with the high temperature of annealing treatment. The sodium glass substrate serves as a limited sodium source to induce the transformation from V2O5 to Na1＋xV3O8.展开更多
利用水玻璃作为浆液主剂,对复合浆液的胶凝时间、黏度、抗压强度、水质毒理、SEM、IR、29Si NMR分别进行了研究。试验结果表明:新型复合浆液能实现浆液的胶凝时间可调、黏度低、固砂体力学性能较高的特点;浆液的水质毒理性能表现较为良...利用水玻璃作为浆液主剂,对复合浆液的胶凝时间、黏度、抗压强度、水质毒理、SEM、IR、29Si NMR分别进行了研究。试验结果表明:新型复合浆液能实现浆液的胶凝时间可调、黏度低、固砂体力学性能较高的特点;浆液的水质毒理性能表现较为良好;SEM分析得知浆液胶结情况良好;IR及29 Si NMR分析证实,反应产生了硅酸盐的聚合产物。展开更多
基金financially supported by the National Natural Science Foundation of China(No.51775204)
文摘Wet reclamation of waste sodium silicate-bonded sand produces much alkaline sewage and causes pollution. Recycling water glass from wet reclamation sewage of the waste sodium silicate-bonded sand can solve pollution issues and generate economic benefits. In this work, the wet reclamation sewage was filtered, and the filtrate was causticized with a quicklime powder to produce a lye. The effects of causticization temperature, causticization time, and the amount of quicklime powder on the causticization rate were studied. The lye was used to dissolve the silica in the filtration residue to prepare a sodium silicate solution. The effects of the mass of filtration residue, dissolution temperature, and dissolution time on sodium silicate modulus were studied. Finally, the recycled water glass was obtained by concentrating the sodium silicate solution, and the bonding strength of the recycled water glass was tested. The results showed that the causticization rate could be improved by increasing the amount of quicklime powder, causticization temperature, and causticization time, and the highest causticization rate was above 92%. Amorphous silica in the filtration residue dissolved in the lye. Increasing the amount of the filtration residue, dissolution temperature, and dissolution time could improve the sodium silicate modulus. The bonding strength of the recycled water glass was close to that of commercial water glass. The recycled water glass could be used as a substitute for the commercial water glass.
基金Supported by the National Natural Science Foundation of China(No.50572031)the Key Project of Ministry of Education ofChina.
文摘Na1＋xV3O8 nanoribbon thin film was successfully fabricated by annealing the V2O5 xerogel film on sodium sili-cate glass substrate at 450℃. It has been identified that the amount of sodium ions diffused into the V2O5 xerogel film increases with the high temperature of annealing treatment. The sodium glass substrate serves as a limited sodium source to induce the transformation from V2O5 to Na1＋xV3O8.
文摘利用水玻璃作为浆液主剂,对复合浆液的胶凝时间、黏度、抗压强度、水质毒理、SEM、IR、29Si NMR分别进行了研究。试验结果表明:新型复合浆液能实现浆液的胶凝时间可调、黏度低、固砂体力学性能较高的特点;浆液的水质毒理性能表现较为良好;SEM分析得知浆液胶结情况良好;IR及29 Si NMR分析证实,反应产生了硅酸盐的聚合产物。
