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Pesticide soil contamination mainly affects earthworm male reproductive parameters 被引量:6
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作者 Eduardo Bustos-Obregón RogerIziga Goicochea 《Asian Journal of Andrology》 SCIE CAS CSCD 2002年第3期195-199,共5页
Aim: To explore the effect of exposure to commercial Parathion~ (Pc) on the reproductive parameters (sperm and cocoon production and genotoxicity on male germ cells), the survival, the body weight and the gross anatom... Aim: To explore the effect of exposure to commercial Parathion~ (Pc) on the reproductive parameters (sperm and cocoon production and genotoxicity on male germ cells), the survival, the body weight and the gross anatomical changes in Eiseniafoetida. Methods: Three doses of Pc(1478, 739 and 444 mg/kg of soil) and three time intervals of exposure (5, 15 and 30 days) were used. Results: All treated animals were affected. An acute genotoxic effect, revealed by DNA fragmentation (comet assay), was seen by 5 days. Alterations in reproductive parameters were conspicuous in regard to the number of sperm, cocoons and worms born, and the histological observation of the gonads and seminal receptacles. In addition, the body weight and survival rate were decreased. Neuromuscular function was also affected. Conclusion: Earthworms are suitable bioindicators of chemical contamination of the soil, their advantage being their easy and economical handling 展开更多
关键词 EARTHWORM REPRODUCTION soil contamination organophosphoric agropesticide
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Land Parcel Land Use History as a Key to Site Selectionfor Documenting Soil Contamination Risk: a Case Study from Australian Suburbia
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作者 YU Jie Ursula Pietrzak Jim Peterson 《Geo-Spatial Information Science》 2005年第4期257-261,275,共6页
In that orcharding in early to mid twentieth century southeastern Australia involved use of certain heavy metal and As compounds in regular pest control spray procedures, some interest attaches to the possibility that... In that orcharding in early to mid twentieth century southeastern Australia involved use of certain heavy metal and As compounds in regular pest control spray procedures, some interest attaches to the possibility that these landparcels are underlain by soils with above background Cu, Pb and As levels. Interpretation of Land cover changes allowed land parcels previously occupied by orchards to be identified in the 1950s through time series air photos. A comparison of soil analysis results referring to soil samples from control sites, and from land parcels formerly occupied by orchardists, shows that contamination (above background) levels of cations in the pesticides can be found in the top 6 cm of former orchard soils. It is clear that digital spatial data handling and culturally informed air photo interpretation has a place in soil contamination studies, land use planning (with particular reference to re development) and in administration of public health. 展开更多
关键词 aerial photography digital orthophoto image soil contamination soil analysis land-use planning public health
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Comparison of a Soil Vulnerability Map for Tetracycline Soil Contamination at a Global and Local Scale
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作者 Ana De la Torre Irene Iglesias +2 位作者 Luis Miguel Camunas Maria Jesus Munoz Matilde Carballo 《Journal of Environmental Protection》 2013年第6期595-601,共7页
Recently, de la Torre[1] provided an approach for assessing the vulnerability of European soils for tetracyclines, fluoroquinolones and sulfamides contamination using a spatial risk assessment. It allowed identifying ... Recently, de la Torre[1] provided an approach for assessing the vulnerability of European soils for tetracyclines, fluoroquinolones and sulfamides contamination using a spatial risk assessment. It allowed identifying areas where vulnerable soil more occur, providing useful information for policies designed to reduce contamination. In the current study, this approach was applied to a local level, the autonomous region of Castile and León (C&L), located in the north-west part of Spain. High accurate and reliable source data were employed to generate a soil vulnerability map for tetracyclines in the study area, attempting to improve the release and consequence risk prediction. More specifically, pig density, temperature and soil use risk estimators were improved using data from national or local databases. Result comparison between the European and the present approach showed a good agreement demonstrating the utility of the European vulnerability map to be employed not only at global level but also for deciding how to allocate limited resources on national or subnational environmental surveillance programs of antibiotics. The model application at local level using more accurate data from national or local sources, afforded a better understanding of the spatial distribution of the risk, mainly associated with the higher accuracy of the national land use database SIOSE. It could offer a useful tool for local management of the risk, such as the management of animal manures fertilization on soil. 展开更多
关键词 TETRACYCLINES soil contamination Vulnerability Map EUROPE GIS
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Spatial prediction of soil contamination based on machine learning: a review 被引量:3
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作者 Yang Zhang Mei Lei +1 位作者 Kai Li Tienan Ju 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2023年第8期13-29,共17页
Soil pollution levels can be quantified via sampling and experimental analysis;however,sampling is performed at discrete points with long distances owing to limited funding and human resources,and is insufficient to c... Soil pollution levels can be quantified via sampling and experimental analysis;however,sampling is performed at discrete points with long distances owing to limited funding and human resources,and is insufficient to characterize the entire study area.Spatial prediction is required to comprehensively investigate potentially contaminated areas.Consequently,machine learning models that can simulate complex nonlinear relationships between a variety of environmental conditions and soil contamination have recently become popular tools for predicting soil pollution.The characteristics,advantages,and applications of machine learning models used to predict soil pollution are reviewed in this study.Satisfactory model performance generally requires the following:1)selection of the most appropriate model with the required structure;2)selection of appropriate independent variables related to pollutant sources and pathways to improve model interpretability;3)improvement of model reliability through comprehensive model evaluation;and 4)integration of geostatistics with the machine learning model.With the enrichment of environmental data and development of algorithms,machine learning will become a powerful tool for predicting the spatial distribution and identifying sources of soil contamination in the future. 展开更多
关键词 soil contamination Machine learning PREDICTION Spatial distribution
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Multifaceted Insight into Sensitivity Analysis and Environmental Impact on Human Health of Soil Contamination Risk Assessment
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作者 Hao Zhang Ping Du +7 位作者 Bei Yuan Yunhui Zhang Juan Chen Hupeng Liu Aiyang Li Yuquan Wei Yanna Xiong Bin Zhao 《Environment & Health》 2023年第3期214-227,共14页
Sensitivity analysis is a valuable method for evaluating the impact of model parameters on health risk characterization,thereby supporting the prediction of critical uncertainty factors.However,limitations arise in te... Sensitivity analysis is a valuable method for evaluating the impact of model parameters on health risk characterization,thereby supporting the prediction of critical uncertainty factors.However,limitations arise in terms of cross-disciplinary discussions and in-depth analyses of previous research.To overcome these limitations,a systematic and multifaceted approach was introduced for analyzing the parameter sensitivities in soil contamination risk assessment.This approach specifically targeted the 12 main parameters associated with 65 soil contaminants for health risk assessment,employing detailed authoritative statistics for risk assessment.Screening analysis revealed that identified heavy metals and organics were influenced by key parameters,such as PM_(10),body weight of adults(BW_(a)),daily air inhalation rate of adults(DAIR_(a)),air exchange rate(ER),and typical soil parameters.PM_(10) showed a positive 100%correlation with inorganics and metals,but BW_(a) and DAIR_(a) exhibited different impacts on different chemicals,with an increase in potential risk observed with higher BW_(a) and lower DAIR_(a).Furthermore,incorporating soil parameters in the analysis showed that compact soil could improve the protection against vapor organic compounds for human health.This refined study presents a comprehensive strategy for sensitivity analysis in health risk assessment of soil contamination,thereby offering substantial support for the protection and preservation of human health.A logical framework also was provided for addressing the limitations of sensitivity analysis and facilitating an understanding of the complex relationships between model parameters and the health risk of soil contamination. 展开更多
关键词 soil contamination health risk assessment sensitivity analysis exposure parameter environmental implication
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Effects of Using Softwood Pellet Biochar Prepared at Different Temperatures with Grass Chippings on Retention of Heavy Metals in Contaminated Soils
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作者 Kyari Umar Dunoma Limin Ma +14 位作者 Xingquan Shu Haiyan Yu Weiwei Zhang Chengcheng Bu Yong-Sik Wang Jiahong Luo Guangyao Chen Jinpeng Yu Ru Zhang Yuchen Han Haoyu Zeng Matthew S. Wisseh Amina Grema Mustafa Mohammad Auwal Saidu Mufidat Mamman Khan 《Open Journal of Polymer Chemistry》 2024年第3期146-166,共21页
Heavy metals have been viewed as hazardous environmental pollutants, and anthropogenic activities due to their high toxicity and persistent nature in the environment. Anthropogenic activities such as artisanal mining,... Heavy metals have been viewed as hazardous environmental pollutants, and anthropogenic activities due to their high toxicity and persistent nature in the environment. Anthropogenic activities such as artisanal mining, industrial activities, improper usage of fertilizers and pesticides, and indiscriminate open waste disposal bring about an increase in the presence of heavy metals in the environment. In the Keffi Metropolis, different elements lead to land contamination which debilitates soil quality, plant survival, human well-being, and the environment as a result of extensive dispersion or quantity of heavy metals in the soil and water. In recent years, biochar has emerged as a promising soil amendment for mitigating heavy metal pollution due to its unique physicochemical properties. This paper provides the effects of softwood pellet biochar on the retention of heavy metals in contaminated soils. A microcosm experiment was carried out to investigate the effects of biochar on the retention of heavy metals in contaminated soils. This research aimed to give an overview of the effects of softwood biochar at different temperatures (550˚C and 700˚C) on the retention of heavy metals and metalloids released from the soil during water inundation. The results show that the addition of organic matter (grass chippings) minimizes heavy metal mobilization. Also, biochar at high temperatures is more effective than those at low temperatures. The expected outcome of the research analysis includes providing insights into the role of biochar in retaining heavy metal contamination and further understanding the use of biochar as a sorbent for the management of contaminated soil. 展开更多
关键词 Softwood Biochar Heavy Metal Contaminated soil Grass Chips Keffi Metropolis MICROCOSM
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Effect of Heavy Metal Contamination on Soil Enzymes Activities
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作者 Justice Ofori Yeboah Guangyu Shi Weilin Shi 《Journal of Geoscience and Environment Protection》 2021年第6期135-154,共20页
Several enzymes catalyze much of the processes that exist in the soil. Enzymes in polluted soils are usually less active due to their exposure to heavy metals. The main goal of this study was to see how bioavailable t... Several enzymes catalyze much of the processes that exist in the soil. Enzymes in polluted soils are usually less active due to their exposure to heavy metals. The main goal of this study was to see how bioavailable types of Cd affected the behavior of catalase, urease, and dehydrogenases, as well as to compare the findings from naturally and artificially polluted samples. An experiment was conducted on two types of farmland (garden) soil: natural soil and soil that had been chemically polluted with Cd. The total content of heavy metal graded these soils as very highly polluted with Cd. The experiment was repeated four times to test the effects of increasing concentration and days (time). Extracellular enzymes from farmland performed enzymatic activity tests that lasted 6 to 29 days after soil sampling. After 0, 5, 10, 20, 30, and 45 days of incubation, soil samples were taken for testing respectively. However, even though no nutrient was added, dehydrogenase and urease activity increased as Cd concentration increased from 0 to 5 mg/L as the days passed. This is a result of enzymes engaging in respiratory and other living activities because of the low cadmium concentration and respiratory soil properties. However, there were significant variations in enzyme activity between naturally polluted and artificially contaminated soils. Dehydrogenases, Urease, and Catalase all showed a common pattern of enzyme sensitivity, which could be ordered as Dehydrogenase > Urease > Catalase. Dehydrogenase enzyme activity has been discovered to be more Cd resistant. 展开更多
关键词 Enzyme Activity DEHYDROGENASES CATALASE UREASE soil contamination Heavy Metal
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Soil Explorations and Groundwater Monitoring to Evaluate Subsurface Contamination Due to Chromium in District Kasur, Pakistan
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作者 H. Rashid J. Takemura A.M. Farooqi 《Journal of Environmental Science and Engineering》 2011年第7期835-843,共9页
Due to improper tannery wastewater management in district Kasur Pakistan, groundwater has been reported to be highly contaminated. It was aimed to find out the extent up to which subsurface has contaminated due to chr... Due to improper tannery wastewater management in district Kasur Pakistan, groundwater has been reported to be highly contaminated. It was aimed to find out the extent up to which subsurface has contaminated due to chromium in areas adjacent to the tannery units. Eight (8) soil bores were conducted up to the depth of 30.5 meters and soil samples were tested for total and hexavalent chromium concentrations retained in soil by aqua regia digestion at the every depth of 1.5 meters. Afterwards monitoring wells were installed in these eight (8) bores so as to monitor chromium concentrations in the groundwater on monthly basis. The main source of contamination was considered to be the four (4) drains carrying tanneries effluent therefore samples were collected from these drains so as to observe seasonal variation in chromium concentration. 展开更多
关键词 Groundwater and soil contamination soil boring monitoring wells CHROMIUM tannery wastewater.
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Investigation of Pollution Level of Traces Metals Elements in Agricultural Soil of Oubritenga Province of Burkina Faso 被引量:1
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作者 Salifou Laura Stéphanie Batchakoue Maïga-Yaleu Tambi Ramdé 《Open Journal of Soil Science》 2023年第3期187-198,共10页
The purpose of this study was to investigate the pollution level of trace metals As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Se and Zn in agricultural soil around the water reservoir. A total of 36 soil samples were colle... The purpose of this study was to investigate the pollution level of trace metals As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sb, Se and Zn in agricultural soil around the water reservoir. A total of 36 soil samples were collected both during off-season agriculture and pluvial agriculture from April to October 2022. The samples were analyzed for trace metals according to the standard methods of the US EPA 2007 with a microwave plasma atomic emission spectrometer (MP-AES), Agilent Model 4210. The pollution level was assessed using contamination factor (Cf) and modified contamination degree (mCd). During the off-season, the concentration of trace metals followed in descending order as Mn > Cr > Cu > Pb > Zn. As, Cd, Co, Hg, Ni, Sb and Se were below the detectable limits. In pluvial season, the concentration of traces of metal follows the order Mn > Cr > Zn > Cu > Ni > Pb > Hg > As. Cd, Co, Sb and Se remain below the detectable limits. The concentrations of Cr, Mn and Zn were lower in the off-season agriculture than in pluvial agriculture. For Cu and Pb, the concentrations were higher in the off-season than in pluvial agriculture. The Cf ranges from 0.24 to 11.70 depending on the considered trace metal. The Cf values of As, Ni, Pb, Zn and Mn indicated that the agricultural study soil was lowery contaminated by these trace metals. The agricultural study soil was moderately contaminated by Cr and Cu, and highly contaminated by Hg. Globally the agricultural study soil presents a moderate degree of contamination (mCd 2.25) by the eight trace metals studied. This result provides information on understanding the risks of trace metal contamination of agricultural soil. It is important to anticipate the control of soil contamination through regular monitoring of toxic metals in agricultural soils, control the quality of chemicals used in agriculture and regulate their use. 展开更多
关键词 Chemicals Products Trace Metals Pollution Index soil contamination OFF-SEASON Burkina Faso
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Remediation of Cu Contaminated Soil by Fe_(78)Si_(9)B_(13)^(AP)Permeability Reaction Barrier Combined with Electrokinetic Method
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作者 Liefei Pei Xiangyun Zhang Zizhou Yuan 《Journal of Renewable Materials》 SCIE EI 2023年第6期2969-2983,共15页
Iron-based amorphous crystalline powder Fe_(78)Si_(9)B_(13)^(AP)is used as a permeability reaction barrier(PRB)combined with an electrokinetic method(EK-PRB)to study the removal rate of Cu in contaminated soil.After t... Iron-based amorphous crystalline powder Fe_(78)Si_(9)B_(13)^(AP)is used as a permeability reaction barrier(PRB)combined with an electrokinetic method(EK-PRB)to study the removal rate of Cu in contaminated soil.After treating Cucontaminated soil for 5 days under different voltage gradients and soil water content,the soil pH is between 3.1 and 7.2.The increase of voltage gradient and soil water content can effectively promote the movement of Cu^(2+) to the cathode.The voltage gradient is 3 V/cm,and the water content of 40%is considered to be an optional experimental condition.Therefore,under this condition,the effects of Fe_(78)Si_(9)B_(13)^(AP)and zero-valent iron(ZVI)as PRB on the removal rate of total Cu in soil and the transformation of chemical forms of Cu are studied.Compared with ZVI,Fe_(78)Si_(9)B_(13)^(AP)as PRB has a better remediation effect.EK-Fe_(78)Si_(9)B_(13)^(AP)can remove 80.3%of total Cu in soil,and the biologically available Cu is reduced to 3.6%,which effectively reduces the environmental risk of contaminated soil. 展开更多
关键词 soil contamination amorphous alloy electrokinetic method IMMOBILIZATION
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Relationships among Environmental Lead in Playground Soils and Dust and Blood Lead of Children in Muncie, Indiana, USA
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作者 Abdulgadir Elnajdi Adam Berland +1 位作者 Carolyn Dowling Jessi Haeft 《Journal of Geoscience and Environment Protection》 2023年第10期21-31,共11页
The present study was designed to assess lead levels in playground soil and accumulated dust on playground equipment and then correlate those environmental lead measurements with children’s blood lead in the surround... The present study was designed to assess lead levels in playground soil and accumulated dust on playground equipment and then correlate those environmental lead measurements with children’s blood lead in the surrounding neighborhoods. Soil lead and surface dust were collected from 14 playgrounds in Muncie, Indiana, and blood lead levels were calculated for nearby children. Correlation analyses revealed a moderate positive association between dust Pb and soil Pb with a correlation coefficient r = 0.46 (p = 0.099). The relationship between settled dust on playground equipment and composite blood lead level also showed a medium positive correlation, indicated by r = 0.36 (p = 0.202). A positive correlation was also observed between soil Pb and composite blood lead values, as evidenced by r = 0.51 (p = 0.061). Furthermore, the assessment of spatial autocorrelation using Moran’s I index indicated no significant spatial clustering for the variables studied (dust Pb, soil Pb, and blood Pb). Correlation analysis showed a connection between lead levels in soil and dust, but no significant links were found between soil lead and blood lead and between dust lead and blood lead. These results suggest that environmental lead in parks has a limited impact on children’s blood lead levels nearby. Spatial autocorrelation analysis also revealed no significant spatial patterns among variables—dust, soil, and blood lead. Given these findings, it is recommended to seek expertise from qualified professionals and further perform comprehensive testing and analysis to investigate potential lead sources in children’s blood. The outcomes of this study offer valuable insights into assessing playground environmental lead contamination, contributing to future research priorities in this area. Specifically, future studies could focus on collecting larger sample sizes and characterizing blood lead in children who frequently use playgrounds rather than those who live nearby but may or may not use the playgrounds. 展开更多
关键词 Heavy Metals Public Health soil contamination Urban Parks Health Risk Assessment
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Temporal-spatial distribution and variability of cadmium contamination in soils in Shenyang Zhangshi irrigation area,China 被引量:8
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作者 SUN Li-na ZHANG Yao-hua +3 位作者 SUN Tie-heng GONG Zong-qiang LIN Xin LI Hai-bo 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第6期1241-1246,共6页
Heavy metal contamination in soils has been of wide concern in China in the last several decades. The heavy metal contamination was caused by sewage irrigation, mining and inappropriate utilization of various agrochem... Heavy metal contamination in soils has been of wide concern in China in the last several decades. The heavy metal contamination was caused by sewage irrigation, mining and inappropriate utilization of various agrochemicals and pesticides and so on. The Shenyang Zhangshi irrigation area (SZIA) in China is a representative area of heavy metal contamination of soils resulting from sewage irrigation for about 30 years duration. This study investigated the spatial distribution and temporal variation of soil cadmium contamination in the SZIA. The soil samples were collected from the SZIA in 1990 and 2004; Cd of soils was analyzed and then the spatial distribution and temporal variation of Cd in soils was modelled using kriging methods. The kriging map showed that long-term sewage irrigation had caused serious Cd contamination in topsoil and subsoil. In 2004, the Cd mean concentrations were 1.698 and 0.741 mg/kg, and the maxima 10.150 and 7.567 mg/kg in topsoils (0-20 cm) and subsoils (20-40 cm) respectively. These values are markedly more than the Cd levels in the second grade soil standard in China. In 1990, the Cd means were 1.023 and 0.331 mg/kg, and the maxima 9.400 and 3.156 mg/kg, in topsoils and subsoils respectively. The soil area in 1990 with Cd more than 1.5 mg/kg was 2701 and 206.4 hnl2 in topsoils and subsoils respectively; and in 2004, it was 7592 and 1583 hm^2, respectively. Compared with that in 1990, the mean and maximum concentration of Cd, as well as the soil area with Cd more than 1.5 mg/kg had all increased in 2004, both in topsoils and subsoils. 展开更多
关键词 temporal-spatial distribution cadmium contamination of soil Zhangshi sewage irrigation area (ZSIA) Shenyang
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Correlation between the Bearing Capacity of Crude Oil Contaminated Soil of Mgbede and the Percentage Contamination
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作者 Iloeje Amechi Francis 《Journal of Civil Engineering and Architecture》 2013年第12期1595-1600,共6页
This study was conducted in Mgbede, River State, Nigeria, hosting up to, or even more than 100 oil wells. It examined the relationship between the bearing capacity of crude oil contaminated soil and the percentage con... This study was conducted in Mgbede, River State, Nigeria, hosting up to, or even more than 100 oil wells. It examined the relationship between the bearing capacity of crude oil contaminated soil and the percentage contamination. Four uncontaminated soil samples were randomly collected at 1.5 m depth within the oil field with hand auger and analyzed for the load bearing properties limited to cohesion, angle of internal friction and bulk density. With these parameters, the bearing capacity was determined for each sample. Crude oil, collected from one of the oil wells with viscosity 0.02611 poises at 40~C and specific gravity 0.8227 g/cm3, was used as the contaminant. This was mixed with the soil sample at 5%, 10%, 15% and 20% concentrations. The mean values of the bearing capacity were 582.458 KN/m2, 495.35 KN/m2 for square and strip footings respectively at 0% contamination, 240.735 KN/m2 and 204.753 KN/m2 at 5%, 321.683 KN/m2 and 274.593 KN/m2 at 10%, 127.003 KN/m2 and 109.12 KN/m2 at 15%, 105.28 KN/m2 and 90.758 KN/m2 at 20% for square and strip footings, respectively. The results showed a consistent decrease in the load bearing values as the crude oil content increased. The result of the null hypothesis established a strong and significant relationship between the bearing capacity of crude oil contaminated soil and the percentage contamination. 展开更多
关键词 Bearing capacity contaminated soil crude oil percentage contamination.
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Remediation of in-situ Leach Mining Contaminated Soil by Amendment-plant Synergism 被引量:1
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作者 冯秀娟 朱易春 +4 位作者 阎思诺 鄱洋 马彩云 高咪 张素贞 《Agricultural Science & Technology》 CAS 2014年第1期63-70,78,共9页
This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitroge... This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitrogen; to be specific, the concentration of nitrate nitrogen in soil planted with wheat was reduced from 692.19 mg/kg to lower than 100 mg/kg; when the mass ratio of amendment to soil reached 3:50 and the amendment particle size was 1-2 mm, the concentration of nitrate ni-trogen in soil planted with wheat was reduced to 43 mg/kg. The amendment type exhibited extremely significant effects on the concentration of ammonium nitrogen; to be specific, when the mass ratio of amendment to soil reached 10:50, the concen-tration of ammonium nitrogen in soil added with 2-3 mm zeolite was reduced from 23 593.75 to 3 300 mg/kg on day 15. Amendments and plants mainly exhibited desorption performance for sulfate radical in soil, and the amendment type extreme-ly significantly affected the concentration of sulfate radical; to be specific, the con-centration of sulfate radical in soil added with limestone increased from 370 mg/kg to 900 mg/kg on day 7. 展开更多
关键词 In-situ leach mining of rare earth mine Leaching reagent ammonia sul-fate soil contamination Amendment-plant synergism REMEDIATION
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Effect of amendments on growth and metal uptake of giant reed(Arundo donax L.) grown on soil contaminated by arsenic,cadmium and lead 被引量:6
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作者 杨淼 肖细元 +2 位作者 苗旭峰 郭朝晖 王凤永 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第6期1462-1469,共8页
The effects of five amendments such as acetic acid(AA), citric acid (CA), ethylenediamine tetraacetic acid (EDTA), sepiolite and phosphogypsum on growth and metal uptake of giant reed (Arundo donax L.) grown o... The effects of five amendments such as acetic acid(AA), citric acid (CA), ethylenediamine tetraacetic acid (EDTA), sepiolite and phosphogypsum on growth and metal uptake of giant reed (Arundo donax L.) grown on soil contaminated by arsenic (As), cadmium (Cd) and lead (Pb) were studied. The results showed that the shoot biomass of giant reed was enhanced by 24.8% and 15.0%, while superoxide mutase and catalase activities slightly varied when adding 5.0 mmol/kg CA and 2.5 mol/kg EDTA to soil as compared to the control, respectively. The concentrations of As, Cd and Pb in shoots were remarkably increased by the addition of 2.5 mmol/kg AA and CA, 5.0 mmol/kg EDTA, and 4.0 g/kg sepiolite as compared to the control. The accumulations of As and Cd were also significantly enhanced in the above condition, while the shoot Pb accumulation was noticeably enhanced by amending with 4.0 g/kg sepiolite and 8.0 g/kg phosphogysum, respectively. The results suggested that AA, CA and sepiolite could be used as optimum soil amendments for giant reed remediation system. 展开更多
关键词 PHYTOREMEDIATION giant reed soil amendments heavy metal contaminated soil metal uptake
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In-situ Elimination Effect on Heavy Metals in Contaminated Soil from the Mining Area by Ramie 被引量:4
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作者 王冶 张兴 +3 位作者 揭雨成 佘玮 刑虎成 朱守晶 《Agricultural Science & Technology》 CAS 2012年第2期375-379,共5页
[Objective] The aim was to study on in-situ elimination effect on heavy metals in soil of the mining area by ramie (Boehmeria nivea (L.) Gaud.). [Methods] Based on Xiangzhu No.3 and Zhongzhu No.1, we conducted res... [Objective] The aim was to study on in-situ elimination effect on heavy metals in soil of the mining area by ramie (Boehmeria nivea (L.) Gaud.). [Methods] Based on Xiangzhu No.3 and Zhongzhu No.1, we conducted research on heavy metals contents of plants growing in soil of Qibao Mountain orefield in Liuyang, Hunan Province, and on characteristics of enrichment and transfer of heavy metals (Cu, Pb, Cd, Zn) under influence of the two ramie species. [Result] It was concluded that trend of Cu content in different parts of ramie was as follows: rootskinleafbone; trend of Pb was rootleafskinbone; trend of Cd was rootskinboneleaf; the trend of Zn was rootskinboneleaf. In farmland A (with low content of heavy metal), for per square meter of plough horizon, effect of Zhong 1 on heavy metals transferring volume and the period for restoration of the soil into national standard one (Category Ⅲ of Environmental Quality Standard for Soil) have been concluded. Specifically, for Cu, the corresponding values were 3 404.44 mg and 8.59 y, respectively; for Pb, the values were 3 638.5 mg and 13.52 y; for Cd, the values were 720.48 mg and 1.49 y; for Zn, the values were 37 324.8 mg and 0.67 y. [Conclusion] Soil contaminated by Cu, Pb, Cd, and Zn in orefield can be rapidly restored by growing ramie. 展开更多
关键词 RAMIE Mining area Contaminated soil Heavy metal In-situ elimination
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Spatial Patterns of Soil Heavy Metals in Urban-Rural Transition Zone of Beijing 被引量:43
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作者 HU Ke-Lin ZHANG Feng-Rong +2 位作者 LI Hong HUANG Feng LI Bao-Guo 《Pedosphere》 SCIE CAS CSCD 2006年第6期690-698,共9页
To identify the main sources responsible for soil heavy metal contamination, 70 topsoils were sampled from the Daxing County in the urban-rural transition zone of Beijing. The concentrations of heavy metals Cu, Zn, Pb... To identify the main sources responsible for soil heavy metal contamination, 70 topsoils were sampled from the Daxing County in the urban-rural transition zone of Beijing. The concentrations of heavy metals Cu, Zn, Pb, Cr, Cd, Ni, As, Se, Hg, and Co; the soil texture; and the organic matter content were determined for each soil sample. Descriptive statistics and geostatistics were used to analyze the data, and Kriging analysis was used to estimate the unobserved points and to map the spatial patterns of soil heavy metals. The results showed that the concentrations of all the soil heavy metals exceeded their background levels with the exception of As and Se. However, only the Cd concentration in some areas exceeded the critical value of the national soil quality standard. The semivariance analysis showed that the spatial correlation distances for soil Cu, Zn, Cr, Cd, As, Ni, and Co ranged from 4.0 to 7.0 km, but soil Se, Pb, and Hg had a larger correlation distance. Soil Co, Se, Cd, Cu and Zn showed a strong spatial correlation, whereas the other soil heavy metals showed medium spatial correlation. Soil heavy metal concentrations were related to soil texture, organic matter content, and the accumulation of heavy metals in the soils, which was because of air deposition and use of water from the Liangshui, Xinfeng, and Fenghe rivers that are contaminated by wastewater and sewage for the purpose of irrigation of fields. Hence, a comprehensive treatment plan for these rivers should be formulated. 展开更多
关键词 GEOSTATISTICS heavy metal soil contamination soil texture spatial variability
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Soil enzymatic activities and microbial community structure with different application rates of Cd and Pb 被引量:29
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作者 KHAN Sardar CAO Qing +2 位作者 HESHAM Abd El-Latif XIA Yue HE Ji-zheng 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第7期834-840,共7页
This study focused on the changes of soil microbial diversity and potential inhibitory effects of heavy metals on soil enzymatic activities at different application rates of Cd and/or Pb. The soil used for experiments... This study focused on the changes of soil microbial diversity and potential inhibitory effects of heavy metals on soil enzymatic activities at different application rates of Cd and/or Pb. The soil used for experiments was collected from Beijing and classified as endoaquepts. Pots containing 500 g of the soil with different Cd and/or Pb application rates were incubated for a period of 0, 2, 9, 12 weeks in a glasshouse and the soil samples were analyzed for individual enzymes, including catalase, alkaline phosphatase and dehydrogenase, and the changes of microbial community structure. Results showed that heavy metals slightly inhibited the enzymatic activities in all the samples spiked with heavy metals. The extent of inhibition increased significantly with increasing level of heavy metals, and varied with the incubation periods. The soil bacterial community structure, as determined by polymerase chain reaction- denaturing gradient gel electrophoresis techniques, was different in the contaminated samples as compared to the control. The highest community change was observed in the samples amended with high level of Cd. Positive correlations were observed among the three enzymatic activities, but negative correlations were found between the amounts of the heavy metals and the enzymatic activities. 展开更多
关键词 soil contamination heavy metals application rate enzymatic activity microbial community
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Effects of Red Mud on the Remediation of Pb, Zn and Cd in Heavy Metal Contaminated Paddy Soil 被引量:3
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作者 范美蓉 罗琳 +3 位作者 廖育林 汤海涛 魏建宏 吴家梅 《Agricultural Science & Technology》 CAS 2012年第2期388-392,共5页
[Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contam... [Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contaminated soil. [Method] The soil incubation experiment was conducted to study the effect of red mud on the pH values and electrical conductivity (EC), and the remediation efficiency of red mud on lead (Pb), zinc (Zn) and cadmium (Cd) in heavy metal contaminated soil. [Result] Red mud addition reduced the content of exchangeable Pb, Zn and Cd in the soil significantly. Compared with the control, when incubated for 30, 60 and 90 d with the red mud dosage of 4% (W/W), the exchangeable Pb content was decreased by 39.25%, 41.38% and 50.19%; exchangeable Zn content was decreased by 49.26%, 57.32% and 47.16%; and exchangeable Cd content was decreased by 19.53%, 24.06% and 25.70%, respectively. The application of red mud had significant impact on the share of Pb, Zn and Cd contents in five forms, and different amounts of red mud application all reduced the proportion of exchangeable Pb, Zn and Cd to the total Pb, Zn and Cd. In addition, the proportion of exchangeable Pb, Zn and Cd to total Pb, Zn and Cd decreased with the increasing amount of red mud addition. [Conclusion] The study provided references for reasonable application of red mud and reduction of heavy metal pollution in paddy soil. 展开更多
关键词 Red mud LEAD zinc and cadmium Heavy metal contaminated soil Remediation efficiency
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Soil heavy metal(loid)s and risk assessment in vicinity of a coal mining area from southwest Guizhou, China 被引量:17
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作者 QIN Fan-xin WEI Chao-fu +3 位作者 ZHONG Shou-qin HUANG Xian-fei PANG Wen-pin JIANG Xin 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第9期2205-2213,共9页
Total concentrations of arsenic, lead, cadmium, mercury, nickel, chromium, and copper in the soils from near a coal mine area in southwest Guizhou, China, were measured to evaluate the level of contamination, and the ... Total concentrations of arsenic, lead, cadmium, mercury, nickel, chromium, and copper in the soils from near a coal mine area in southwest Guizhou, China, were measured to evaluate the level of contamination, and the potential ecological risks posed by the heavy metals were quantitatively estimated. Results reveal that all heavy metals/metalloid exceeded the background values for soil environmental quality of heavy metals in Guizhou area. Geo-accumulation index(I_(geo)) showed that arsenic had the highest contamination level(I_(geo)=4) among the seven heavy metals/metalloid, and the contamination levels of mercury and lead were also relatively high(I_(geo)=3). Pearson correlation and cluster analysis identified that mercury, copper and arsenic had a relationship, and their presence might be mainly related to mining activity, coal and oil combustion, and vehicle emissions. Improved Nemerow index indicated that the overall level of heavy metal contamination in the studied area ranged from moderately–heavily contaminated to heavily contaminated level. Potential ecological risk index(R_I) analysis manifested that the whole ecological risk level ranged from high degree to very high degree(325.30≤R_I≤801.02) in the studied soil samples, and the potential ecological risk factors (E_r^i) of heavy metals/metalloid were as follows: Hg > As > Cd > Pb > Cu > Ni > Cr, and the E_r^i of Hg and As reached very high risk grade. 展开更多
关键词 heavy metals soil contamination ecological risk coal mining area Xingren county
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