A novel process for separation of red (Y2O3:Eu^3+), blue(BaMgAl10O17:Eu^2+) and green (CeMgAl10O17:Tb^3) rare earth fluorescent powders was proposed. At first, the blue powder can be extracted selectively f...A novel process for separation of red (Y2O3:Eu^3+), blue(BaMgAl10O17:Eu^2+) and green (CeMgAl10O17:Tb^3) rare earth fluorescent powders was proposed. At first, the blue powder can be extracted selectively from an aqueous solution using a chelating collector 2-thenoyltrifluoroacetone (TTA) dissolved in heptane at alkaline pH condition, then, chloroform was used for extracting the green powder into organic phase. The red phosphor remains in aqueous phase with potassium sodium tartrate depressant (PST). Therefore, three phosphors can be separated successfully from their artificial mixtures by liquid/liquid extraction, and grades and recovery of separated products reach respectively as follows: red is 96.9% and 95.2%, blue is 82.7% and 98.8%, green is 94.6% and 82.6%.展开更多
A novel process for separation of red (Y2O3: Eu^3+), blue (Sr, Ca, Ba)10(PO4)6Cl2: Eu^2+ and green (LaPO4: Tb^3+, Ce^3+) fine tricolor phosphor powders was established. First, the green phosphor was ext...A novel process for separation of red (Y2O3: Eu^3+), blue (Sr, Ca, Ba)10(PO4)6Cl2: Eu^2+ and green (LaPO4: Tb^3+, Ce^3+) fine tricolor phosphor powders was established. First, the green phosphor was extracted and separated from three phosphor mixtures in heptane/DMF(N, N-Dimethylformamide) system using stearylamine or laurylamine (DDA) as the cationic surfactant. Then, after being treated with 99.5% ethanol, the blue and red phosphors could be separated in Heptane/DMF system in presence of 1-octanesulfonic acid sodium salt as the anionic surfactant. Satisfactory separation results have been achieved through two steps extractions with their artificial mixtures. The grades and recovery of separated products reached respectively as follows: red product was 95.3% and 90.9%, blue product was 90.0% and 95.2%, and green product was 92.2% and 91.8%.展开更多
The extraction behavior of rare earths was studied by using paraffin with ceresin as a diluent containing 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5.In solid phase,the composition of complexes is REP_3.The equilib- rium...The extraction behavior of rare earths was studied by using paraffin with ceresin as a diluent containing 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5.In solid phase,the composition of complexes is REP_3.The equilib- rium extraction constants and pH_(1/2) values of solid-liquid extraction are higher than those of normal liquid-liquid extraction.The extraction efficiency tends to maximum when the ratio of phases is 1:1.When the extraction temperature is higher than the melting point of paraffin and the extraction time is over 10 min,the extraction efficiency keeps constant.Moreover,the relationship among separation factor,equilibrium extrac- tion constant,pH_(1/2) value and atomic number was obtained.The mechanism of solid-liquid extraction is analogous to that of liquid-liquid extraction.展开更多
A novel bifunctional task-specific ionic liquid(TSIL),i.e.[trialkylmethylammonium][sec-nonylphenoxy acetate]([A336] [CA-100]) was impregnated on intermediate polarized XAD-7 resin,and the prepared solvent impreganated...A novel bifunctional task-specific ionic liquid(TSIL),i.e.[trialkylmethylammonium][sec-nonylphenoxy acetate]([A336] [CA-100]) was impregnated on intermediate polarized XAD-7 resin,and the prepared solvent impreganated resin(SIR) was studied for rare earth(RE) separation.Adsorption ability of the SIR was indicated to be obviously higher than that prepared by [A336][NO3] because of the functional anion of [A336][CA-100].Adsorption kinetics,adsorption isotherm,separation and desorption of the SIR were also stu...展开更多
Rare earths(REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovere...Rare earths(REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovered from the deposits and purified. As solvent extraction is the main technology for the recovery and purification of the metals, the review mainly presents our recent works on the extraction and separation of tetravalent cerium cation by neutral α-aminophosphonates, the individual rare earth separation by α-aminophosphonic acids, and the continuous preparation of high-purity thorium. The extraction and separation of some other metals are also discussed.展开更多
Extraction and separation of yttrium in chloride medium using tri-n-octylmethylammonium(2-sec-octylphenoxy) acetate([N(1888)][SOPAA]) as an extractant were studied in this article. Tri-n-butyl phosphate(TBP) w...Extraction and separation of yttrium in chloride medium using tri-n-octylmethylammonium(2-sec-octylphenoxy) acetate([N(1888)][SOPAA]) as an extractant were studied in this article. Tri-n-butyl phosphate(TBP) was used as a phase modifier to accelerate phase separation and improve the stability of organic phase. The addition of TBP contributed to shortening phase separation time, increasing extraction capacity of rare earth elements(REEs) and decreasing viscosity of organic phase. The slope analysis method and infrared spectroscopy were conducted to investigate the ion-association extraction mechanisms. Extraction and stripping performances of the different systems were also compared. The article showed that the extraction performance of mixed [N(1888)][SOPAA] and TBP is superior to that of [N(1888)][SOPAA] for heavy rare earth element(HREE).展开更多
diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone ...diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone 5), A new 4 acylpyrazol 5 one derivative (H 2BPMPP) was syntheszed, which contains a heterocyclic ring between two 1 phenyl 3 methyl 4 acylpyrazol 5 one rings. The new compound was characterized by element analyses, UV, IR and 1H NMR spectra. The equilibrium of the keto enol tautomerism was studied. The results show that a lower dielectric constant of solvent favors the enol form which has a higher λ max . Due to special merits of paraffin wax, the solid liquid extraction behavior of Ce(Ⅲ) with molten paraffin wax as a diluent was also investigated at higher temperature. The value of the pH 1/2 was 3.19 and the value of log K ex was 3.467. The chemical composition of the complex was obtained by the slope analysis method.展开更多
In the present work, a novel α-aminophosphonate extractant(Cextrant 230) was synthesized for the extraction and recovery of cerium and thorium from sulphate medium. The introduction of amine group into the phosphat...In the present work, a novel α-aminophosphonate extractant(Cextrant 230) was synthesized for the extraction and recovery of cerium and thorium from sulphate medium. The introduction of amine group into the phosphate molecule would enhance the extraction of Ce(Ⅳ) and Th(Ⅳ). The effects of extractant concentration, H2SO4 concentration and temperature on the metal extraction were investigated in detail. It was found that the extraction of Ce(Ⅳ), Th(Ⅳ) and REs(La, Gd, Yb) in sulphate medium decreased in the following order: Ce(Ⅳ)〉Th(Ⅳ)〉REs(Ⅲ). A solvent extraction process to extract and recover cerium and thorium from bastnasite leaching was proposed, in which the purities of cerium and thorium products reached 99.9% and 99% with yield of 92% and 98%, respectively.展开更多
基金Funded by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (ROCS, SEM [2005] No. 383)
文摘A novel process for separation of red (Y2O3:Eu^3+), blue(BaMgAl10O17:Eu^2+) and green (CeMgAl10O17:Tb^3) rare earth fluorescent powders was proposed. At first, the blue powder can be extracted selectively from an aqueous solution using a chelating collector 2-thenoyltrifluoroacetone (TTA) dissolved in heptane at alkaline pH condition, then, chloroform was used for extracting the green powder into organic phase. The red phosphor remains in aqueous phase with potassium sodium tartrate depressant (PST). Therefore, three phosphors can be separated successfully from their artificial mixtures by liquid/liquid extraction, and grades and recovery of separated products reach respectively as follows: red is 96.9% and 95.2%, blue is 82.7% and 98.8%, green is 94.6% and 82.6%.
基金Funded by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (ROCS, SEM [2005] No. 383)
文摘A novel process for separation of red (Y2O3: Eu^3+), blue (Sr, Ca, Ba)10(PO4)6Cl2: Eu^2+ and green (LaPO4: Tb^3+, Ce^3+) fine tricolor phosphor powders was established. First, the green phosphor was extracted and separated from three phosphor mixtures in heptane/DMF(N, N-Dimethylformamide) system using stearylamine or laurylamine (DDA) as the cationic surfactant. Then, after being treated with 99.5% ethanol, the blue and red phosphors could be separated in Heptane/DMF system in presence of 1-octanesulfonic acid sodium salt as the anionic surfactant. Satisfactory separation results have been achieved through two steps extractions with their artificial mixtures. The grades and recovery of separated products reached respectively as follows: red product was 95.3% and 90.9%, blue product was 90.0% and 95.2%, and green product was 92.2% and 91.8%.
文摘The extraction behavior of rare earths was studied by using paraffin with ceresin as a diluent containing 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5.In solid phase,the composition of complexes is REP_3.The equilib- rium extraction constants and pH_(1/2) values of solid-liquid extraction are higher than those of normal liquid-liquid extraction.The extraction efficiency tends to maximum when the ratio of phases is 1:1.When the extraction temperature is higher than the melting point of paraffin and the extraction time is over 10 min,the extraction efficiency keeps constant.Moreover,the relationship among separation factor,equilibrium extrac- tion constant,pH_(1/2) value and atomic number was obtained.The mechanism of solid-liquid extraction is analogous to that of liquid-liquid extraction.
基金supported by ‘Hundreds Talents Program’from Chinese Academy of Sciences, National Natural Science Foundation of China (50574080, 20901073)National Key Technology R&D Program of China (2006BAC02A10)Distinguished Young Scholar Foundation of Jilin Province (20060114)
文摘A novel bifunctional task-specific ionic liquid(TSIL),i.e.[trialkylmethylammonium][sec-nonylphenoxy acetate]([A336] [CA-100]) was impregnated on intermediate polarized XAD-7 resin,and the prepared solvent impreganated resin(SIR) was studied for rare earth(RE) separation.Adsorption ability of the SIR was indicated to be obviously higher than that prepared by [A336][NO3] because of the functional anion of [A336][CA-100].Adsorption kinetics,adsorption isotherm,separation and desorption of the SIR were also stu...
基金supported by the National Program on Key Basic Research Project(973 Program)(Grant No.2012CBA01206)the National Natural Science Foundation of China(Grant Nos.21521092,51222404)+1 种基金the Strategic Priority Research Program of CAS(Grant No.XDA02030100)the Open Project of State Key Laboratory of Rare Earth Resource Utilization(Grant No.RERU2017019)
文摘Rare earths(REs) play a key role in high-tech fields and the associated thorium is a vital element for nuclear energy. However, to be used in high-tech industry or nuclear energy, these elements must first be recovered from the deposits and purified. As solvent extraction is the main technology for the recovery and purification of the metals, the review mainly presents our recent works on the extraction and separation of tetravalent cerium cation by neutral α-aminophosphonates, the individual rare earth separation by α-aminophosphonic acids, and the continuous preparation of high-purity thorium. The extraction and separation of some other metals are also discussed.
基金Project supported by‘Hundreds Talents Program’from Chinese Academy of SciencesNational Natural Science Foundation of China(21571179)+1 种基金Science and Technology Major Project of the Fujian Province,China(2015HZ0101)Xiamen Universities,Research Institutions Jointing Enterprise Projects(3502Z20152009)
文摘Extraction and separation of yttrium in chloride medium using tri-n-octylmethylammonium(2-sec-octylphenoxy) acetate([N(1888)][SOPAA]) as an extractant were studied in this article. Tri-n-butyl phosphate(TBP) was used as a phase modifier to accelerate phase separation and improve the stability of organic phase. The addition of TBP contributed to shortening phase separation time, increasing extraction capacity of rare earth elements(REEs) and decreasing viscosity of organic phase. The slope analysis method and infrared spectroscopy were conducted to investigate the ion-association extraction mechanisms. Extraction and stripping performances of the different systems were also compared. The article showed that the extraction performance of mixed [N(1888)][SOPAA] and TBP is superior to that of [N(1888)][SOPAA] for heavy rare earth element(HREE).
文摘diketone type chelating ligands have high coordinative activity and selectivity, and are widely applied in analytical chemistry. In order to obtain profounder understanding to the properties of bis(4 acylpyrazolone 5), A new 4 acylpyrazol 5 one derivative (H 2BPMPP) was syntheszed, which contains a heterocyclic ring between two 1 phenyl 3 methyl 4 acylpyrazol 5 one rings. The new compound was characterized by element analyses, UV, IR and 1H NMR spectra. The equilibrium of the keto enol tautomerism was studied. The results show that a lower dielectric constant of solvent favors the enol form which has a higher λ max . Due to special merits of paraffin wax, the solid liquid extraction behavior of Ce(Ⅲ) with molten paraffin wax as a diluent was also investigated at higher temperature. The value of the pH 1/2 was 3.19 and the value of log K ex was 3.467. The chemical composition of the complex was obtained by the slope analysis method.
基金Project supported by National Basic Research Program of China(973 program,2012CBA01206)the National Natural Science Foundation of China(21521092,51222404)the Strategic Priority Research Program of CAS(XDA02030100)
文摘In the present work, a novel α-aminophosphonate extractant(Cextrant 230) was synthesized for the extraction and recovery of cerium and thorium from sulphate medium. The introduction of amine group into the phosphate molecule would enhance the extraction of Ce(Ⅳ) and Th(Ⅳ). The effects of extractant concentration, H2SO4 concentration and temperature on the metal extraction were investigated in detail. It was found that the extraction of Ce(Ⅳ), Th(Ⅳ) and REs(La, Gd, Yb) in sulphate medium decreased in the following order: Ce(Ⅳ)〉Th(Ⅳ)〉REs(Ⅲ). A solvent extraction process to extract and recover cerium and thorium from bastnasite leaching was proposed, in which the purities of cerium and thorium products reached 99.9% and 99% with yield of 92% and 98%, respectively.