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La_(0.75)Sr_(0.25)Cr_(0.5)Mn_(0.5)O_(3)-δ−Ce_(0.8)Gd_(0.2)O_(1.9) composite electrodes as anodes in LaGaO_(3)-based direct carbon solid oxide fuel cells 被引量:2
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作者 CHEN Tian-yu XIE Yong-min +7 位作者 LU Zhi-bin WANG Liang CHEN Zhe-qin ZHONG Xiao-cong LIU Jia-ming WANG Rui-xiang XU Zhi-feng OUYANG Shao-bo 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第6期1788-1798,共11页
Direct carbon solid oxide fuel cells(DC-SOFCs)are promising,green,and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures.Developing suitable anode materials for... Direct carbon solid oxide fuel cells(DC-SOFCs)are promising,green,and efficient power-generating devices that are fueled by solid carbons and comprise all-solid-state structures.Developing suitable anode materials for DC-SOFCs is a substantial scientific challenge.Herein we investigated the use of La_(0.75)Sr_(0.25)Cr_(0.5)Mn_(0.5)O_(3)-δ−Ce_(0.8)Gd_(0.2)O_(1.9)(LSCM−GDC)composite electrodes as anodes for La_(0.9)Sr_(0.1)Ga_(0.8)Mg_(0.2)O_(3)-δelectrolyte-based DC-SOFCs,with Camellia oleifera shell char as the carbon fuel.The LSCM−GDC-anode DC-SOFC delivered a maximum power density of 221 mW/cm^(2) at 800℃ and it significantly improved to 425 mW/cm^(2) after Ni nanoparticles were introduced into the LSCM−GDC anode through wet impregnation.The microstructures of the prepared anodes were characterized,and the stability of the anode in a DC-SOFC and the influence of catalytic activity on open circuit voltage were studied.The above results indicate that LSCM–GDC anode is promising to be applied in DC-SOFCs. 展开更多
关键词 direct carbon solid oxide fuel cells anode material La_(0.75)Sr_(0.25)Cr_(0.5)Mn_(0.5)O_(3)-δ−Ce_(0.8)Gd_(0.2)O_(1.9) composite electrodes Ni nanoparticles
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一种测定定向凝固工艺参数的方法 被引量:4
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作者 陈健 郑启 +2 位作者 于洋 唐亚俊 胡壮麒 《材料工程》 EI CAS CSCD 北大核心 1994年第10期38-39,共2页
利用连续测定试样顶面温度的方法,方便地测定了定向凝固时的温度梯度以及固液界面位置,发现温度梯度受抽拉速度的影响不大,而固液界面的位置受抽拉速度影响较大,随着抽拉速度的增大,固液界面位置向下移动。
关键词 定向凝固 温度梯度 固液界面位置 抽拉速度
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铌硅化物基超高温合金整体定向凝固组织和固/液界面形态演化 被引量:6
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作者 何永胜 郭喜平 +1 位作者 郭海生 孙志平 《金属学报》 SCIE EI CAS CSCD 北大核心 2009年第9期1035-1041,共7页
采用有坩埚整体定向凝固技术研究了铌硅化物基超高温合金在不同过热温度下的定向凝固组织和固/液界面形态演化.研究结果表明:在抽拉速率均为15μm/s的条件下,当过热温度为1950℃时,定向凝固组织由初生铌基固溶体(Nb_(ss))枝晶和耦合生... 采用有坩埚整体定向凝固技术研究了铌硅化物基超高温合金在不同过热温度下的定向凝固组织和固/液界面形态演化.研究结果表明:在抽拉速率均为15μm/s的条件下,当过热温度为1950℃时,定向凝固组织由初生铌基固溶体(Nb_(ss))枝晶和耦合生长的花瓣状(Nb_(ss)+γ-(Nb,X)_5si_3)共晶组成;当过热温度为2000和2050℃时,凝固组织为耦合良好的花瓣状共晶;但随着过热温度进一步提高到2100和2150℃,凝固组织演变为粗大树枝状Nb_(ss)和细小共晶.随着过热温度的提高,固/液界面形态出现树枝状界面→胞状界面→树枝状界面的形貌变化. 展开更多
关键词 铌硅化物 超高温合金 熔体过热温度 定向凝固组织 固/液界面形貌
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用电子探针测定铝合金在定向凝固过程中的溶质分配系数 被引量:3
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作者 曹禄华 于家康 《分析测试技术与仪器》 1996年第3期44-47,共4页
用电子探针测定了铝合金中Al-1.35%Cu和Al-0.25%Cr在定向凝固过程中液固界面处的溶质分配系数。结果表明:液相区的Cu含量随离开界面的距离呈指数衰减,而固相区的则呈线性衰减。液固界面层厚度约在5~7μm范... 用电子探针测定了铝合金中Al-1.35%Cu和Al-0.25%Cr在定向凝固过程中液固界面处的溶质分配系数。结果表明:液相区的Cu含量随离开界面的距离呈指数衰减,而固相区的则呈线性衰减。液固界面层厚度约在5~7μm范围内。凝固速度越快,凝固初始过渡区就越短。对于平衡分配系数小于1的Al-1.35%Cu铝合金,非平衡分配系数大于平衡分配系数;而对于平衡分配系数大于1的Al-0.25%Cr铝合金,非平衡分配系数则小于平衡分配系数; 展开更多
关键词 铝合金 定向凝固 溶质分配系数 电子探针
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固溶处理定向凝固高温合金DZ8的组织与力学性能
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作者 张帅奇 宗毳 +4 位作者 陈升平 赵文侠 张宏炜 张强 谭永宁 《航空材料学报》 EI CAS CSCD 北大核心 2016年第4期10-15,共6页
观察了1260℃与1240℃固溶温度热处理后DZ8合金的显微组织,比较了两者的拉伸与持久性能。结果表明:采用1260℃固溶温度热处理,DZ8合金存在少于1%的γ+γ'共晶相,但富Hf相发生初熔;采用1240℃固溶温度热处理,合金未发现初熔但仍存在... 观察了1260℃与1240℃固溶温度热处理后DZ8合金的显微组织,比较了两者的拉伸与持久性能。结果表明:采用1260℃固溶温度热处理,DZ8合金存在少于1%的γ+γ'共晶相,但富Hf相发生初熔;采用1240℃固溶温度热处理,合金未发现初熔但仍存在12%左右的γ+γ'共晶相。DZ8合金分别采用1260℃与1240℃固溶温度热处理后,室温、700℃与980℃拉伸性能以及980℃/205 MPa持久性能相当,但采用1260℃固溶温度热处理的D28合金其760℃/725 MPa持久性能较采用1240℃固溶温度热处理的有所下降。 展开更多
关键词 固溶温度 显微组织 力学性能 定向高温合金
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Direct wave and edge waves radiated into a solid medium by a circular thickness-mode transducer
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作者 ZHANG Hailan, LI Mingxuan and YING Chongfu(Institute of Acouslics, Academia Sinica) 《Chinese Journal of Acoustics》 1990年第1期1-10,共10页
The transient acoustic field radiated by a piezoelectric thickness-mode transducer into a solid medium is theoretically analysed. It is proved that the field consists of the direct wave, the longitudinal edge waves, t... The transient acoustic field radiated by a piezoelectric thickness-mode transducer into a solid medium is theoretically analysed. It is proved that the field consists of the direct wave, the longitudinal edge waves, the shear edge.waves, the head wave and the surface waves. The wavefront approximations of all these waves are given which result in a clear physical picture which is not only simple but also cotains the main features of the field. The theoretical result well describes the experiment. 展开更多
关键词 WAVE Direct wave and edge waves radiated into a solid medium by a circular thickness-mode transducer MODE
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一种高硼定向凝固合金的初熔行为及其对力学性能的影响 被引量:6
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作者 张洪伟 秦学智 +1 位作者 李小武 周兰章 《金属学报》 SCIE EI CAS CSCD 北大核心 2017年第6期684-694,共11页
系统研究了高硼DZ444定向凝固合金的初熔行为及其对力学性能的影响。结果表明,在铸态合金中,枝晶间包含大量g/g′共晶、MC碳化物和由硼化物、Ni5Hf及h相组成的"团聚相"。在固溶处理期间,团聚相周围受硼化物显著影响的g基体首... 系统研究了高硼DZ444定向凝固合金的初熔行为及其对力学性能的影响。结果表明,在铸态合金中,枝晶间包含大量g/g′共晶、MC碳化物和由硼化物、Ni5Hf及h相组成的"团聚相"。在固溶处理期间,团聚相周围受硼化物显著影响的g基体首先发生初熔。硼化物不是初熔的形核点,但是对初熔的形成具有关键作用。较高的B含量,使得合金具有较低的初熔温度,介于1160~1170℃之间,明显低于正常合金。提升温度或延长保温时间,初熔现象变得更加严重。采用水淬方式,初熔倾向于凝固为典型的g枝晶和大量细小的沉淀相颗粒;而采用空冷方式时,初熔依次凝固为团聚相、g基体和g/g′共晶相,团聚相形貌与铸态时没有明显差异。完整热处理时,固溶温度由1210℃提升到1230℃,初熔略微增加,而当温度达1250℃时,初熔区尺寸和面积分数剧烈增大,对合金造成严重破坏。由于温度较低,合金的高、低温时效对初熔组织影响不是很大。随着初熔区尺寸和面积分数增加,初熔区消耗了大量的固溶强化元素,同时初熔区内部易萌生大量微裂纹,从而使合金的拉伸性能稍有下降,持久性能显著降低。 展开更多
关键词 定向凝固高温合金 固溶处理 初熔 团聚相 力学性能
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Investigation on the application of reformed coke oven gas in direct reduction iron production with a mathematical model 被引量:1
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作者 Juan Wu Shu-Qiang Guo Wei-Zhong Ding 《Advances in Manufacturing》 SCIE CAS 2013年第3期276-283,共8页
To investigate the application of reformed coke oven gas (COG) in producing the direct reduction iron (DRI), we simulated a countercurrent gas solid moving bed reactor in which the iron ore pellet was reduced by r... To investigate the application of reformed coke oven gas (COG) in producing the direct reduction iron (DRI), we simulated a countercurrent gas solid moving bed reactor in which the iron ore pellet was reduced by reformed COG. An ordinary differential equation (ODE) was set based on the unreacted shrinking core model considering both mass and energy balances of the reactor. The concentration and temperature profiles of all species within the reactor were obtained by solving the ODE sys tem. The solid conversion and gas utilization were studied by changing gas flow rate, solid flow rate, reactor length, and the ratio of O/CHa to guide the practical application of COG in DRI production. Model results showed that COG was suitable for the DRI production. In order to meet the requirement of the industrial production, the minimum gas flow rate was set as 130,000 Nm3/h, and the maximum production was 90 t/h. The reactor length and the mole ratio x(O): x(CH4) were depended on the actual industrial situations. 展开更多
关键词 Mathematical simulation - Reformed cokeoven gas Gas solid reactor - Direct reduction
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Simulation of ChIP-Seq based on extra-sonication of IPed DNA fragments
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作者 WANG Wei SHI XiaoLong LU ZuHong 《Chinese Science Bulletin》 SCIE EI CAS 2010年第22期2380-2389,共10页
The combination of chromatin immunoprecipitation with sequencing (ChIP-Seq) is an effective method for obtaining an in vivo genome-wide profile of the interaction of a protein with DNA. With the dramatic development o... The combination of chromatin immunoprecipitation with sequencing (ChIP-Seq) is an effective method for obtaining an in vivo genome-wide profile of the interaction of a protein with DNA. With the dramatic development of high-throughput short sequencing technologies, several new algorithms have been developed to process ChIP-Seq. However, the reported analytical tools for ChIP-Seq based on size selection of immunoprecipitated (IPed) DNA fragments are mainly adopted on the Solexa system. As a sequencer with the highest throughput, few studies of ChIP-Seq based on SOLiD system have been reported. The main difference of the SOLiD and Solexa systems exists in the length of DNA fragments during preparing sequencing libraries. The SOLiD system has relatively short DNA fragments if it processes a further sonication of IPed DNA fragments in order to meet the length requirement of DNA fragments for emulsion-PCR (ePCR). This work aims to investigate the influences of DNA fragment length on data analysis from ChIP-Seq. Previous studies show that typical bimodal peaks can be observed in Solexa ChIP-Seq data, but based on the analysis of the real SOLiD ChIP-Seq data in this study, we found that there were no double peaks with apparent reads shift in a local enriched region and the local reads distribution of peaks were tested by normal distribution. Using real and simulated ChIP-Seq data, three main ChIP-Seq algorithms (CisGenome, SISSRs and MACS) have been investigated. We found that algorithms developed for processing ChIP-Seq data generated from Solexa library protocol, cannot efficiently capture the feature of the ChIP-Seq data from SOLiD library. Misuse of those analytical tools would be a possible reason for failure of ChIP-Seq on the SOLiD system. Therefore, a new ChIP-Seq analytical strategy for an extra-sonication of IPed DNA fragments needs to be developed. 展开更多
关键词 DNA片段 超声 模拟 染色质免疫沉淀 iD系统 芯片 片段长度 聚合酶链反应
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