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基于多特征融合的智能合约缺陷检测方法
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作者 王奕丰 曾诚 +2 位作者 全擎宇 王娇然 何鹏 《计算机工程》 CAS CSCD 北大核心 2024年第8期133-141,共9页
智能合约是区块链技术最成功的应用之一,随着其广泛应用,智能合约的安全问题也引起了研究人员的关注。尽管已有一些针对智能合约缺陷检测的研究,但对于智能合约代码特征的挖掘还不充分。提出一种采用多特征融合方式的智能合约缺陷检测... 智能合约是区块链技术最成功的应用之一,随着其广泛应用,智能合约的安全问题也引起了研究人员的关注。尽管已有一些针对智能合约缺陷检测的研究,但对于智能合约代码特征的挖掘还不充分。提出一种采用多特征融合方式的智能合约缺陷检测方法。首先,对智能合约代码进行预处理,其中包括颜色标记、词汇提取、ASCII字符转换以及合约之间继承关系的提取;然后,将颜色标记、词汇提取、ASCII字符转换得到的处理信息输入到由BERT、卷积神经网络(CNN)以及双向长短期记忆(BiLSTM)网络构建的融合模型中进行特征提取,同时将合约之间的继承关系信息输入node2vec随机游走算法,以获得合约关系的特征向量;最后,将所有特征向量连接并输入分类器进行缺陷分类。使用真实的Solidity智能合约数据集对该方法进行验证,实验结果表明,相比其他模型,所提多特征融合模型在F1值实现了6%~12%的改进,在准确度方面实现了4%~11%的提升,该方法能够更好地挖掘智能合约代码的深层特征,提高缺陷检测性能,对智能合约的安全性具有一定的应用价值。 展开更多
关键词 区块链 智能合约 Solidity语言 多特征 缺陷检测
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A defective iron-based perovskite cathode for high-performance IT-SOFCs:Tailoring the oxygen vacancies using Nb/Ta co-doping 被引量:2
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作者 Bayu Admasu Beshiwork Xinyu Wan +6 位作者 Min Xu Haoran Guo Birkneh Sirak Teketel Yu Chen Jun Song Chen Tingshuai Li Enrico Traversa 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期306-316,I0008,共12页
The sluggish kinetics of the electrochemical oxygen reduction reaction(ORR)in intermediatetemperature solid oxide fuel cells(IT-SOFCs)greatly limits the overall cell performance.In this study,an efficient and durable ... The sluggish kinetics of the electrochemical oxygen reduction reaction(ORR)in intermediatetemperature solid oxide fuel cells(IT-SOFCs)greatly limits the overall cell performance.In this study,an efficient and durable cathode material for IT-SOFCs is designed based on density functional theory(DFT)calculations by co-doping with Nb and Ta the B-site of the SrFeO_(3-δ)perovskite oxide.The DFT calculations suggest that Nb/Ta co-doping can regulate the energy band of the parent SrFeO_(3-δ)and help electron transfer.In symmetrical cells,such cathode with a SrFe_(0.8)Nb_(0.1)Ta_(0.1)O_(3-δ)(SFNT)detailed formula achieves a low cathode polarization resistance of 0.147Ωcm^(2) at 650℃.Electron spin resonance(ESR)and X-ray photoelectron spectroscopy(XPS)analysis confirm that the co-doping of Nb/Ta in SrFeO_(3-δ)B-site increases the balanced concentration of oxygen vacancies,enhancing the electrochemical performance when compared to 20 mol%Nb single-doped perovskite oxide.The cathode button cell with NiSDC|SDC|SFNT configuration achieves an outstanding peak power density of 1.3 W cm^(-2)at 650℃.Moreover,the button cell shows durability for 110 h under 0.65 V at 600℃ using wet H_(2) as fuel. 展开更多
关键词 Solid oxide fuel cell CATHODE Oxygen reduction reaction Power density DFT calculation
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Advancements,strategies,and prospects of solid oxide electrolysis cells(SOECs):Towards enhanced performance and large-scale sustainable hydrogen production 被引量:1
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作者 Amina Lahrichi Youness El Issmaeli +1 位作者 Shankara S.Kalanur Bruno G.Pollet 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期688-715,共28页
Solid oxide electrolysis cells(SOECs)represent a crucial stride toward sustainable hydrogen generation,and this review explores their current scientific challenges,significant advancements,and potential for large-scal... Solid oxide electrolysis cells(SOECs)represent a crucial stride toward sustainable hydrogen generation,and this review explores their current scientific challenges,significant advancements,and potential for large-scale hydrogen production.In SOEC technology,the application of innovative fabrication tech-niques,doping strategies,and advanced materials has enhanced the performance and durability of these systems,although degradation challenges persist,implicating the prime focus for future advancements.Here we provide in-depth analysis of the recent developments in SOEC technology,including Oxygen-SOECs,Proton-SOECs,and Hybrid-SOECs.Specifically,Hybrid-SOECs,with their mixed ionic conducting electrolytes,demonstrate superior efficiency and the concurrent production of hydrogen and oxygen.Coupled with the capacity to harness waste heat,these advancements in SOEC technology present signif-icant promise for pilot-scale applications in industries.The review also highlights remarkable achieve-ments and potential reductions in capital expenditure for future SOEC systems,while elaborating on the micro and macro aspects of sOECs with an emphasis on ongoing research for optimization and scal-ability.It concludes with the potential of SOEC technology to meet various industrial energy needs and its significant contribution considering the key research priorities to tackle the global energy demands,ful-fillment,and decarbonization efforts. 展开更多
关键词 Solid oxide electrolysis cells Proton-SOECs Oxygen-SoECs Hybrid-SOECs Intermediate-high temperature electrolysers Hydrogenproduction
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Electrolyte Design for Low‑Temperature Li‑Metal Batteries:Challenges and Prospects 被引量:1
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作者 Siyu Sun Kehan Wang +3 位作者 Zhanglian Hong Mingjia Zhi Kai Zhang Jijian Xu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第2期365-382,共18页
Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements ... Electrolyte design holds the greatest opportunity for the development of batteries that are capable of sub-zero temperature operation.To get the most energy storage out of the battery at low temperatures,improvements in electrolyte chemistry need to be coupled with optimized electrode materials and tailored electrolyte/electrode interphases.Herein,this review critically outlines electrolytes’limiting factors,including reduced ionic conductivity,large de-solvation energy,sluggish charge transfer,and slow Li-ion transportation across the electrolyte/electrode interphases,which affect the low-temperature performance of Li-metal batteries.Detailed theoretical derivations that explain the explicit influence of temperature on battery performance are presented to deepen understanding.Emerging improvement strategies from the aspects of electrolyte design and electrolyte/electrode interphase engineering are summarized and rigorously compared.Perspectives on future research are proposed to guide the ongoing exploration for better low-temperature Li-metal batteries. 展开更多
关键词 Solid electrolyte interphase Li metal Low temperature Electrolyte design BATTERIES
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In-situ interfacial passivation and self-adaptability synergistically stabilizing all-solid-state lithium metal batteries 被引量:1
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作者 Huanhui Chen Xing Cao +6 位作者 Moujie Huang Xiangzhong Ren Yubin Zhao Liang Yu Ya Liu Liubiao Zhong Yejun Qiu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期282-292,I0007,共12页
The function of solid electrolytes and the composition of solid electrolyte interphase(SEI)are highly significant for inhibiting the growth of Li dendrites.Herein,we report an in-situ interfacial passivation combined ... The function of solid electrolytes and the composition of solid electrolyte interphase(SEI)are highly significant for inhibiting the growth of Li dendrites.Herein,we report an in-situ interfacial passivation combined with self-adaptability strategy to reinforce Li_(0.33)La_(0.557)TiO_(3)(LLTO)-based solid-state batteries.Specifically,a functional SEI enriched with LiF/Li_(3)PO_(4) is formed by in-situ electrochemical conversion,which is greatly beneficial to improving interface compatibility and enhancing ion transport.While the polarized dielectric BaTiO_(3)-polyamic acid(BTO-PAA,BP)film greatly improves the Li-ion transport kinetics and homogenizes the Li deposition.As expected,the resulting electrolyte offers considerable ionic conductivity at room temperature(4.3 x 10~(-4)S cm^(-1))and appreciable electrochemical decomposition voltage(5.23 V)after electrochemical passivation.For Li-LiFePO_(4) batteries,it shows a high specific capacity of 153 mA h g^(-1)at 0.2C after 100 cycles and a long-term durability of 115 mA h g^(-1)at 1.0 C after 800 cycles.Additionally,a stable Li plating/stripping can be achieved for more than 900 h at 0.5 mA cm^(-2).The stabilization mechanisms are elucidated by ex-situ XRD,ex-situ XPS,and ex-situ FTIR techniques,and the corresponding results reveal that the interfacial passivation combined with polarization effect is an effective strategy for improving the electrochemical performance.The present study provides a deeper insight into the dynamic adjustment of electrode-electrolyte interfacial for solid-state lithium batteries. 展开更多
关键词 Solid-state lithium batteries Composite solid electrolyte In-situ polymerization Interfacial passivation layer Self-adaptability
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Highly Efficient Aligned Ion‑Conducting Network and Interface Chemistries for Depolarized All‑Solid‑State Lithium Metal Batteries 被引量:1
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作者 Yongbiao Mu Shixiang Yu +12 位作者 Yuzhu Chen Youqi Chu Buke Wu Qing Zhang Binbin Guo Lingfeng Zou Ruijie Zhang Fenghua Yu Meisheng Han Meng Lin Jinglei Yang Jiaming Bai Lin Zeng 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第5期102-119,共18页
Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact l... Improving the long-term cycling stability and energy density of all-solid-state lithium(Li)-metal batteries(ASSLMBs)at room temperature is a severe challenge because of the notorious solid–solid interfacial contact loss and sluggish ion transport.Solid electrolytes are generally studied as two-dimensional(2D)structures with planar interfaces,showing limited interfacial contact and further resulting in unstable Li/electrolyte and cathode/electrolyte interfaces.Herein,three-dimensional(3D)architecturally designed composite solid electrolytes are developed with independently controlled structural factors using 3D printing processing and post-curing treatment.Multiple-type electrolyte films with vertical-aligned micro-pillar(p-3DSE)and spiral(s-3DSE)structures are rationally designed and developed,which can be employed for both Li metal anode and cathode in terms of accelerating the Li+transport within electrodes and reinforcing the interfacial adhesion.The printed p-3DSE delivers robust long-term cycle life of up to 2600 cycles and a high critical current density of 1.92 mA cm^(−2).The optimized electrolyte structure could lead to ASSLMBs with a superior full-cell areal capacity of 2.75 mAh cm^(−2)(LFP)and 3.92 mAh cm^(−2)(NCM811).This unique design provides enhancements for both anode and cathode electrodes,thereby alleviating interfacial degradation induced by dendrite growth and contact loss.The approach in this study opens a new design strategy for advanced composite solid polymer electrolytes in ASSLMBs operating under high rates/capacities and room temperature. 展开更多
关键词 All-solid-state lithium metal batteries Composite solid electrolyte 3D printing Areal capacity Interfacial degradation
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Boosting oxygen reduction activity and CO_(2) resistance on bismuth ferrite-based perovskite cathode for low-temperature solid oxide fuel cells below 600℃ 被引量:1
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作者 Juntao Gao Zhiyun Wei +5 位作者 Mengke Yuan Zhe Wang Zhe Lü Qiang Li Lingling Xu Bo Wei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第3期600-609,I0013,共11页
Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)... Developing efficient and stable cathodes for low-temperature solid oxide fuel cells(LT-SOFCs) is of great importance for the practical commercialization.Herein,we propose a series of Sm-modified Bi_(0.7-x)Sm_xSr_(0.3)FeO_(3-δ) perovskites as highly-active catalysts for LT-SOFCs.Sm doping can significantly enhance the electrocata lytic activity and chemical stability of cathode.At 600℃,Bi_(0.675)Sm_(0.025)Sr_(0.3)FeO_(3-δ)(BSSF25) cathode has been found to be the optimum composition with a polarization resistance of 0.098 Ω cm^2,which is only around 22.8% of Bi_(0.7)Sr_(0.3)FeO_(3-δ)(BSF).A full cell utilizing BSSF25 displays an exceptional output density of 790 mW cm^(-2),which can operate continuously over100 h without obvious degradation.The remarkable electrochemical performance observed can be attributed to the improved O_(2) transport kinetics,superior surface oxygen adsorption capacity,as well as O_(2)p band centers in close proximity to the Fermi level.Moreover,larger average bonding energy(ABE) and the presence of highly acidic Bi,Sm,and Fe ions restrict the adsorption of CO_(2) on the cathode surface,resulting in excellent CO_(2) resistivity.This work provides valuable guidance for systematic design of efficient and durable catalysts for LT-SOFCs. 展开更多
关键词 Low-temperature solid oxide fuel cell Perovskite cathode DFT calculations CO_(2) tolerance
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Unraveling the enigma:A comprehensive review of solid pseudopapillary tumor of the pancreas 被引量:1
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作者 Ye-Cheng Xu De-Liang Fu Feng Yang 《World Journal of Gastrointestinal Oncology》 SCIE 2024年第3期614-629,共16页
Solid pseudopapillary tumor of the pancreas(SPTP)is a rare neoplasm predom-inantly observed in young females.Pathologically,CTNNB1 mutations,β-catenin nuclear accumulation,and subsequent Wnt-signaling pathway activat... Solid pseudopapillary tumor of the pancreas(SPTP)is a rare neoplasm predom-inantly observed in young females.Pathologically,CTNNB1 mutations,β-catenin nuclear accumulation,and subsequent Wnt-signaling pathway activation are the leading molecular features.Accurate preoperative diagnosis often relies on imaging techniques and endoscopic biopsies.Surgical resection remains the mainstay treatment.Risk models,such as the Fudan Prognostic Index,show promise as predictive tools for assessing the prognosis of SPTP.Establishing three types of metachronous liver metastasis can be beneficial in tailoring individu-alized treatment and follow-up strategies.Despite advancements,challenges persist in understanding its etiology,establishing standardized treatments for unresectable or metastatic diseases,and developing a widely recognized grading system.This comprehensive review aims to elucidate the enigma by consolidating current knowledge on the epidemiology,clinical presentation,pathology,molecular characteristics,diagnostic methods,treatment options,and prognostic factors. 展开更多
关键词 PANCREAS Solid pseudopapillary tumor Β-CATENIN Endoscopic ultrasound Surgery RECURRENCE Liver metastasis Prognostic prediction
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基于Solid Edge自动生成数控加工图的二次开发研究
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作者 吴事谱 陆祉好 阳开应 《锅炉技术》 北大核心 2024年第4期21-26,共6页
基于Solid Edge软件平台,利用C#进行二次开发,设计出一款利用三维设计模型和组件图生成数控加工工艺图纸的批量设计软件,并详细展示了软件的工作流程、原理和关键技术。经应用验证,该软件具有出图快、信息匹配度高、适用模型范围广、操... 基于Solid Edge软件平台,利用C#进行二次开发,设计出一款利用三维设计模型和组件图生成数控加工工艺图纸的批量设计软件,并详细展示了软件的工作流程、原理和关键技术。经应用验证,该软件具有出图快、信息匹配度高、适用模型范围广、操作灵活、界面友好等优点,以此实现了车间的无纸化高效数据传输和敏捷生产。 展开更多
关键词 Solid Edge 二次开发 数控加工图 轮廓图 C# 工程图 三维设计
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基于ADAMS的多关节机械手手抓部分的运动学仿真研究
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作者 毛龙所 李峰 +3 位作者 白东华 吕忠 华卫 张敏 《中国设备工程》 2024年第8期133-135,共3页
利用虚拟样机技术验证多关节机械手的机构设计是否正确,能否实现每分钟的抓取以及其载荷。运用Solid Edge ST5完成虚拟样机三维模型的建立,导入ADAMS中进行机械手机械系统的运动学分析。运用ADAMS对其中一个工作周期内的运动过程进行运... 利用虚拟样机技术验证多关节机械手的机构设计是否正确,能否实现每分钟的抓取以及其载荷。运用Solid Edge ST5完成虚拟样机三维模型的建立,导入ADAMS中进行机械手机械系统的运动学分析。运用ADAMS对其中一个工作周期内的运动过程进行运动学的仿真,得出其各个关节在一个工作周期的位移特性曲线以及速度加速度曲线。本文介绍了多关节机械手具体的虚拟样机几何模型的建立,以及利用ADAMA/View提供的Parasolid模型数据交换接口导入模型,在添加约束时需要关键注意的细节也有介绍。在计算机广泛普及的今天,利用三维设计以及ADAMS软件进行机械手手抓部分的运动学分析,可以大大缩短设计周期,提高设计精度,降低产品开发成本。 展开更多
关键词 虚拟样机技术 ADAMS 多关节机械手 运动学仿真 Solid Edge ST5
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Incombustible solid polymer electrolytes:A critical review and perspective
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作者 Kai Wu Jin Tan +4 位作者 Zhenfang Liu Chenguang Bao Ao Li Qi Liu Baohua Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期264-281,I0007,共19页
Since the advent of the solid-state batteries,employing solid polymer electrolytes(SPEs)to replace routine flammable liquid electrolytes is regarded to be one of the most promising solutions in pursing highenergy-dens... Since the advent of the solid-state batteries,employing solid polymer electrolytes(SPEs)to replace routine flammable liquid electrolytes is regarded to be one of the most promising solutions in pursing highenergy-density battery systems.SPEs with superior thermal stability,good processability,and high mechanical modulus obtain increasing attentions.However,SPE-based batteries are not impenetrable due to their decomposition and combustibility under extreme conditions.Researchers believe incorporating appropriate flame-retardant additives/solvents/fragments into SPEs can intrinsically reduce their flammability to solve the battery safety issues.In this review,the recent research progress of incombustible SPEs,with special emphasis on flame-retardant structural design,is summarized.Specifically,a brief introduction of flame-retardant mechanism,evaluation index for safety of SPEs,and a detailed overview of the latest advances on diverse-types SPEs in various battery systems are highlighted.The deep insight into thermal ru naway process,the free-standing incombustible GPEs,and the ratio nal design of pouch cell structures may be the main directions to motivate revolutionary next-generation for safety batteries. 展开更多
关键词 Non-flammable electrolyte Solid polymer electrolyte High safety electrolyte Solid state electrolyte Solid state battery
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Solid Bi_(2)O_(3)-derived nanostructured metallic bismuth with high formate selectivity for the electrocatalytic reduction of CO_(2)
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作者 Xiaoyan Wang Safeer Jan +1 位作者 Zhiyong Wang Xianbo Jin 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期803-811,共9页
CO_(2) electrochemical reduction(CO_(2)ER)is an important research area for carbon neutralization.However,available catalysts for CO_(2) reduction are still characterized by limited stability and activity.Recently,met... CO_(2) electrochemical reduction(CO_(2)ER)is an important research area for carbon neutralization.However,available catalysts for CO_(2) reduction are still characterized by limited stability and activity.Recently,metallic bismuth(Bi)has emerged as a promising catalyst for CO_(2) ER.Herein,we report the solid cathode electroreduction of commercial micronized Bi2O3as a straightforward approach for the preparation of nanostructured Bi.At-1.1 V versus reversible hydrogen electrode in a KHCO3aqueous electrolyte,the resulting nanostructure Bi delivers a formate current density of~40 mA·cm^(-2) with a current efficiency of~86%,and the formate selectivity reaches97.6% at-0.78 V.Using nanosized Bi2O3as the precursor can further reduce the primary particle sizes of the resulting Bi,leading to a significantly increased formate selectivity at relatively low overpotentials.The high catalytic activity of nanostructured Bi is attributable to the ultrafine and interconnected Bi nanoparticles in the nanoporous structure,which exposes abundant active sites for CO_(2) electrocatalytic reduction. 展开更多
关键词 BISMUTH carbon dioxide ELECTROCATALYSIS FORMATE solid electroreduction
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Integrating theory with the nanoreactor concept to synthesize hollow carbon sphere-encapsulated PtNi alloys for enhanced H_(2) generation
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作者 Yufeng Wu Minwei Song +3 位作者 Ziyi Zhao Guang-Hui Wang Changlong Wang Didier Astruc 《Carbon Energy》 SCIE EI CAS CSCD 2024年第7期150-162,共13页
The rational design of efficient bimetallic nanoparticle(NP)catalysts is challenging due to the lack of theoretical understanding of active components and insights into the mechanisms of a specific reaction.Here,we re... The rational design of efficient bimetallic nanoparticle(NP)catalysts is challenging due to the lack of theoretical understanding of active components and insights into the mechanisms of a specific reaction.Here,we report the rational design of nanoreactors comprising hollow carbon sphere-confined PtNi bimetallic NPs(PtNi@HCS)as highly efficient catalysts for hydrogen generation via ammonia borane hydrolysis in water.Using both density functional theory calculations and molecular dynamics simulations,the effects of an active PtNi combination and the critical synergistic role of a hollow carbon shell on the molecule diffusion adsorption behaviors are explored.Kinetic isotope effects and theoretical calculations allow the clarification of the mechanism,with oxidative addition of an O-H bond of water to the catalyst surface being the rate-determining step.The remarkable catalytic activity of the PtNi@HCS nanoreactor was also utilized for successful tandem catalytic hydrogenation reactions,using in situ-generated H_(2) from ammonia borane with high efficiency.The concerted design,theoretical calculations,and experimental work presented here shed light on the rational elaboration of efficient nanocatalysts and contribute to the establishment of a circular carbon economy using green hydrogen. 展开更多
关键词 ammonia borane hydrogen NANOALLOY NANOREACTOR solid catalyst
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Advanced Materials for NH_(3)Capture:Interaction Sites and Transport Pathways
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作者 Hai‑Yan Jiang Zao‑Ming Wang +5 位作者 Xue‑Qi Sun Shao‑Juan Zeng Yang‑Yang Guo Lu Bai Ming‑Shui Yao Xiang‑Ping Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第11期119-155,共37页
Ammonia(NH3)is a carbon-free,hydrogen-rich chemical related to global food safety,clean energy,and environmental protection.As an essential technology for meeting the requirements raised by such issues,NH3 capture has... Ammonia(NH3)is a carbon-free,hydrogen-rich chemical related to global food safety,clean energy,and environmental protection.As an essential technology for meeting the requirements raised by such issues,NH3 capture has been intensively explored by researchers in both fundamental and applied fields.The four typical methods used are(1)solvent absorption by ionic liquids and their derivatives,(2)adsorption by porous solids,(3)abadsorption by porous liquids,and(4)membrane separation.Rooted in the development of advanced materials for NH3 capture,we conducted a coherent review of the design of different materials,mainly in the past 5 years,their interactions with NH3 molecules and construction of transport pathways,as well as the structure–property relationship,with specific examples discussed.Finally,the challenges in current research and future worthwhile directions for NH3 capture materials are proposed. 展开更多
关键词 Ammonia capture Solvents Porous solids Porous liquids Membranes
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Mechanism of high Li-ion conductivity in poly(vinylene carbonate)-poly(ethylene oxide)cross-linked network based electrolyte revealed by solid-state NMR
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作者 Fan Li Tiantian Dong +5 位作者 Yi Ji Lixin Liang Kuizhi Chen Huanrui Zhang Guanglei Cui Guangjin Hou 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期377-383,I0010,共8页
Solid polymer electrolytes(SPEs)have become increasingly important in advanced lithium-ion batteries(LIBs)due to their improved safety and mechanical properties compared to organic liquid electrolytes.Cross-linked pol... Solid polymer electrolytes(SPEs)have become increasingly important in advanced lithium-ion batteries(LIBs)due to their improved safety and mechanical properties compared to organic liquid electrolytes.Cross-linked polymers have the potential to further improve the mechanical property without trading off Li-ion conductivity.In this study,focusing on a recently developed cross-linked SPE,i.e.,the one based on poly(vinylene carbonate)-poly(ethylene oxide)cross-linked network(PVCN),we used solid-state nuclear magnetic resonance(NMR)techniques to investigate the fundamental interaction between the chain segments and Li ions,as well as the lithium-ion motion.By utilizing homonuclear/heteronuclear correlation,CP(cross-polarization)kinetics,and spin-lattice relaxation experiments,etc.,we revealed the structural characteristics and their relations to lithium-ion mobilities.It is found that the network formation prevents poly(ethylene oxide)chains from crystallization,which could create sufficient space for segmental tumbling and Li-ion co nductio n.As such,the mechanical property is greatly improved with even higher Li-ion mobilities compared to the poly(vinylene carbonate)or poly(ethylene oxide)based SPE analogues. 展开更多
关键词 ssNMR Lithium-ion mobility CROSS-LINK Solid polymer electrolyte
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Neoantigen cancer vaccines:a new star on the horizon
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作者 Xiaoling Li Jian You +3 位作者 Liping Hong Weijiang Liu Peng Guo Xishan Hao 《Cancer Biology & Medicine》 SCIE CAS CSCD 2024年第4期274-311,共38页
Immunotherapy represents a promising strategy for cancer treatment that utilizes immune cells or drugs to activate the patient's own immune system and eliminate cancer cells.One of the most exciting advances withi... Immunotherapy represents a promising strategy for cancer treatment that utilizes immune cells or drugs to activate the patient's own immune system and eliminate cancer cells.One of the most exciting advances within this field is the targeting of neoantigens,which are peptides derived from non-synonymous somatic mutations that are found exclusively within cancer cells and absent in normal cells.Although neoantigen-based therapeutic vaccines have not received approval for standard cancer treatment,early clinical trials have yielded encouraging outcomes as standalone monotherapy or when combined with checkpoint inhibitors.Progress made in high-throughput sequencing and bioinformatics have greatly facilitated the precise and efficient identification of neoantigens.Consequently,personalized neoantigen-based vaccines tailored to each patient have been developed that are capable of eliciting a robust and long-lasting immune response which effectively eliminates tumors and prevents recurrences.This review provides a concise overview consolidating the latest clinical advances in neoantigen-based therapeutic vaccines,and also discusses challenges and future perspectives for this innovative approach,particularly emphasizing the potential of neoantigen-based therapeutic vaccines to enhance clinical efficacy against advanced solid tumors. 展开更多
关键词 IMMUNOTHERAPY neoantigen cancer vaccine solid tumors high-throughput sequencing BIOINFORMATICS PDOs AI HLA TCR
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Underestimated Methane Emissions from Solid Waste Disposal Sites Reveal Missed Greenhouse Gas Mitigation Opportunities
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作者 Yao Wang Chuanbin Zhou +6 位作者 Ziyang Lou Houhu Zhang Abid Hussain Liangtong Zhan Ke Yin Mingliang Fang Xunchang Fei 《Engineering》 SCIE EI CAS CSCD 2024年第5期12-15,共4页
1.Introduction Cities are responsible for approximately 70%of all anthropogenic greenhouse gas(GHG)emissions and about 60%of all anthropogenic methane(CH4)emissions[1,2].Solid waste disposal sites(including landfills ... 1.Introduction Cities are responsible for approximately 70%of all anthropogenic greenhouse gas(GHG)emissions and about 60%of all anthropogenic methane(CH4)emissions[1,2].Solid waste disposal sites(including landfills and dumpsites),which are prevalent in global cities,emit CH4 generated from the anaerobic biodegradation of municipal solid waste(MSW).Notably,the proportions of CH4 emissions from disposal sites surpass 50%of the total CH4 emissions in some megalopolises[3].CH4 has a high global warming potential(GWP),being 28 times stronger than carbon dioxide(CO_(2))over a 100-year period and 80 times stronger over a 20-year period[4].Understanding and mitigating CH4 emissions from solid waste disposal sites is particularly pertinent and pressing,considering that the latest Synthesis Report from the Intergovernmental Panel on Climate Change(IPCC)emphasizes that the current pace of mitigation and adaptation policies and measures falls short of restraining global temperature rise to under 1.5℃ within the 21st century[4].More than 150 countries signed the Global Methane Pledge at the United Nations Climate Change Conference in Glasgow(COP26),which aims to reduce global annual CH4 emissions by 30%by 2030,compared with emissions in 2020[5]. 展开更多
关键词 LANDFILL SOLID restrain
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Enhancing layered perovskite ferrites with ultra-high-density nanoparticles via cobalt doping for ceramic fuel cell anode
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作者 Shuo Zhai Rubao Zhao +9 位作者 Hailong Liao Ling Fu Senran Hao Junyu Cai Yifan Wu Jian Wang Yunhong Jiang Jie Xiao Tao Liu Heping Xie 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期39-48,共10页
Nanoparticles anchored on the perovskite surface have gained considerable attention for their wide-ranging applications in heterogeneous catalysis and energy conversion due to their robust and integrated structural co... Nanoparticles anchored on the perovskite surface have gained considerable attention for their wide-ranging applications in heterogeneous catalysis and energy conversion due to their robust and integrated structural configuration.Herein,we employ controlled Co doping to effectively enhance the nanoparticle exsolution process in layered perovskite ferrites materials.CoFe alloy nanoparticles with ultra-high-density are exsolved on the(PrBa)_(0.95)(Fe_(0.8)Co_(0.1)Nb_(0.1))2O_(5+δ)(PBFCN_(0.1))surface under reducing atmosphere,providing significant amounts of reaction sites and good durability for hydrocarbon catalysis.Under a reducing atmosphere,cobalt facilitates the reduction of iron cations within PBFCN_(0.1),leading to the formation of CoFe alloy nanoparticles.This formation is accompanied by a cation exchange process,wherein,with the increase in temperature,partial cobalt ions are substituted by iron.Meanwhile,Co doping significantly enhance the electrical conductivity due to the stronger covalency of the Cosingle bondO bond compared with Fesingle bondO bond.A single cell with the configuration of PBFCN_(0.1)-Sm_(0.2)Ce_(0.8)O_(1.9)(SDC)|SDC|Ba_(0.5)Sr_(0.5)Co_(0.8)Fe_(0.2)O_(3−δ)(BSCF)-SDC achieves an extremely low polarization resistance of 0.0163Ωcm^(2)and a high peak power density of 740 mW cm^(−2)at 800℃.The cell also shows stable operation for 120 h in H_(2)with a constant current density of 285 mA cm^(−2).Furthermore,employing wet C_(2)H_(6)as fuel,the cell demonstrates remarkable performance,achieving peak power densities of 455 mW cm^(−2)at 800℃and 320 mW cm^(−2)at 750℃,marking improvements of 36%and 70%over the cell with(PrBa)_(0.95)(Fe_(0.9)Nb_(0.1))_(2)O_(5+δ)(PBFN)-SDC at these respective temperatures.This discovery emphasizes how temperature influences alloy nanoparticles exsolution within doped layered perovskite ferrites materials,paving the way for the development of high-performance ceramic fuel cell anodes. 展开更多
关键词 Solid oxide fuel cell ANODE Ethane fuel NANOPARTICLE EXSOLUTION Layered perovskite Ferrites
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An efficient recycling strategy to eliminate the residual“impurities”while heal the damaged structure of spent graphite anodes
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作者 Dan Yang Ying Yang +7 位作者 Haoran Du Yongsheng Ji Mingyuan Ma Yujun Pan Xiaoqun Qi Quan Sun Kaiyuan Shi Long Qie 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第6期1027-1034,共8页
The recycling of graphite from spent lithium-ion batteries(LIBs)is overlooked due to its relatively low added value and the lack of efficient recovering methods.To reuse the spent graphite anodes,we need to eliminate ... The recycling of graphite from spent lithium-ion batteries(LIBs)is overlooked due to its relatively low added value and the lack of efficient recovering methods.To reuse the spent graphite anodes,we need to eliminate their useless components(mainly the degraded solid electrolyte interphase,SEI)and reconstruct their damaged structure.Herein,a facile and efficient strategy is proposed to recycle the spent graphite on the basis of the careful investigation of the composition of the cycled graphite anodes and the rational design of the regeneration processes.The regenerated graphite,which is revitalized by calcination treatment and acid leaching,delivers superb rate performance and a high specific capacity of 370 mAh g^(-1)(~99% of its theoretical capacity)after 100 cycles at 0.1 C,superior to the commercial graphite anodes.The improved electrochemical performance could be attributed to unchoked Li^(+) transport channels and enhanced charge transfer reaction due to the effective destruction of the degraded SEI and the full recovery of the damaged structure of the spent graphite.This work clarifies that the electrochemical performance of the regenerated graphite could be deteriorated by even a trace amount of the residual“impurity”and provides a facile method for the efficient regeneration of graphite anodes. 展开更多
关键词 GRAPHITE ANODE REGENERATION Solid electrolyte interphase Spent lithium-ion battery
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Simulation study on cuttings transport of the backreaming operation for long horizontal section wells
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作者 Yu-Fei Chen Hui Zhang +8 位作者 Wen-Xin Wu Jun Li Yong Ouyang Zong-Yu Lu De-Xin Ma Yong-Chuan Wu Jun-Bo Liu Ke-Rou Liu Zhuo-Xin Dong 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1149-1170,共22页
The backreaming operation plays a significant role in safe drilling for horizontal wellbores, while it may cause severe stuck pipe accidents. To lower the risk of the stuck pipe in backreaming operations, the mechanis... The backreaming operation plays a significant role in safe drilling for horizontal wellbores, while it may cause severe stuck pipe accidents. To lower the risk of the stuck pipe in backreaming operations, the mechanism of cuttings transport needs to be carefully investigated. In this research, a transient cuttings transport with multiple flow patterns model is developed to predict the evolution of cuttings transported in the annulus while backreaming. The established model can provide predictions of the distribution of cuttings bed along the wellbore considering the bulldozer effect caused by large-size drilling tools(LSDTs). The sensitivity analyses of the size of LSDTs, and backreaming operating parameters are conducted in Section 4. And a new theory is proposed to explain the mechanism of cuttings transport in the backreaming operation, in which both the bit and LSDTs have the “cleaning effect” and “plugging effect”.The results demonstrate that the cuttings bed in annuli is in a state of dynamic equilibrium, but the overall trend and the distribution pattern are obvious. First, larger diameters and longer drilling tools could lead to a higher risk of the stuck pipe. Second, we find that it is not the case that the higher flow rate is always better for hole cleaning, so three flow-rate intervals are discussed separately under the given conditions. When the “dangerous flow rate”(<33 L/s in Case 4) is employed, the cuttings bed completely blocks the borehole near the step surface and causes a stuck pipe directly. If the flow rate increases to the “low flow rate” interval(33-35 L/s in Case 4), a smaller flow rate instead facilitates borehole cleaning. If the flow rate is large enough to be in the “high flow rate” interval(>35 L/s in Case 4),the higher the flow rate, the better the cleaning effect of cuttings beds. Third, an interval of tripping velocity called “dangerous velocity” is proposed, in which the cuttings bed accumulation near the LSDTs is more serious than those of other tripping velocities. As long as the applied tripping velocity is not within the “dangerous velocity”(0.4-0.5 m/s in Case 5) interval in the backreaming operation, the risk of the stuck pipe can be controlled validly. Finally, through the factors analyses of the annular geometry,particle properties, and fluid properties in Section 5, it can be found that the “low flow rate”, “high flow rate” and “dangers flow rate” tend to decrease and the “dangerous velocity” tends to increase with the conditions more favorable for hole cleaning. This study has some guiding significance for risk prediction and parameter setting of the backreaming operation. 展开更多
关键词 Backreaming Stuck pipe Hole cleaning Transient solid transport Multiple flow patterns
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