A new zinc 1,3,5-benzenetricarboxylate Zn3(BTC)2(DMSO)4(BTC=1,3,5-benzenetricarboxylate) has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction.It crystallize...A new zinc 1,3,5-benzenetricarboxylate Zn3(BTC)2(DMSO)4(BTC=1,3,5-benzenetricarboxylate) has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction.It crystallizes in the monoclinic system,space group P21/c with a=10.0861(11),b=10.2527(11),c=16.4013(18),β=95.478(2)°,V=1688.3(3)3,Z=2,Zn3S4C26H30O16,Mr=922.85,Dc=1.815 g/cm3,F(000)=936,μ=2.434 mm-1,R=0.0319 and wR=0.0755.This compound consists of trimeric zinc clusters and BTC linkers.Alternate connection of these trimeric zinc clusters and BTC linkers results in a three-dimensional(3,6)-connected frame-work with rutile topology.展开更多
Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate(2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2...Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate(2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp)2(bpp)2(H2O)4](1) and [Mn3(stp)2(tpy)3(H2O)](H2O)5(2)(bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2':6',2''-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity(0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(Ⅱ) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional(1D) chain-like structure with three crystallographically independent Mn(Ⅱ) ions. The photoluminescent properties could be assigned to the π-π* transition of 2-sulfoterephthalate ligands.展开更多
Two novel complexes, namely {[Cd(AIP)(4,4'-bpy)]·1.3DMF}n(1) and [Cd(AIP)(2,2'- bpy)]n(2), have been synthesized through solvothermal reaction(H2AIP = 5-aminoisophthalic acid, 2,2'-bpy = 2,2'-bip...Two novel complexes, namely {[Cd(AIP)(4,4'-bpy)]·1.3DMF}n(1) and [Cd(AIP)(2,2'- bpy)]n(2), have been synthesized through solvothermal reaction(H2AIP = 5-aminoisophthalic acid, 2,2'-bpy = 2,2'-bipyridine, 4,4'-bpy = 4,4'-bipyridine, and DMF = N,N'-dimethylformamide) and structurally determined by single-crystal X-ray diffraction. Complex 1 shows a three-dimensional(3D) layer-pillar framework with rectangular channels, while complex 2 displays a two-dimensional(2D) wave net architecture. Furthermore, 1 and 2 were characterized by elemental analysis, infrared spectra(IR), thermal gravimetric analyses(TGA) and fluorescence measurements. The luminescent properties of 1 dispersed in various organic solvents have been investigated systematically, demonstrating high selectivity for acetone via the fluorescence quenching effect.展开更多
In recent years, considerable attention has been paid to supramolecular networks based on metal organic building blocks because of their potential applications in diverse fields, such as, catalysis, optics, sensors, m...In recent years, considerable attention has been paid to supramolecular networks based on metal organic building blocks because of their potential applications in diverse fields, such as, catalysis, optics, sensors, magnetism, and molecular recognition^[1-3]. On the ba- sis of the principles of crystal engineering and special synthesis strategies, several novel supramolecular frameworks have been assembled from various organic, inorganic and metal-organic moieties, which largely en- riches the structure chemistry of solid state materi-als^[4-9].展开更多
The organic-inorganic hybrid polymer [Mn(mbbimb)2(1,5-nds)]n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4,structure analysis indicates that 1 crys...The organic-inorganic hybrid polymer [Mn(mbbimb)2(1,5-nds)]n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4,structure analysis indicates that 1 crystallizes in monoclinic, space group C2/c with a=21.3546(17), b=11.8841(7), c=22.1588(16)A, β=108.058(3)°, C60H54MnN8O6S2, Mr=1102.17, Z=4, V=5346.5(7)A^3, Dc=1.369 g/cm^3, μ=0.386 mm^-1, F(000)=2300, S=1.091, R=0.0634 and wR=0.1559 for 4641 observed reflections (I 〉 2σ(I)). The Mn center is six-coordinated to furnish a distorted octahedral geometry, and the overall framework is a 6-connected 3D net.展开更多
Two novel coordination compounds formulated as [Co2(EY)2(L1)]·2C2H5OH(1) and [Mn2(EY)2(L1)]·2C2H5OH(2)(EY = Eosin Y dianion, L1 = 4,4'-bipyridine) based on Eosin Y dye ligand have been prepare...Two novel coordination compounds formulated as [Co2(EY)2(L1)]·2C2H5OH(1) and [Mn2(EY)2(L1)]·2C2H5OH(2)(EY = Eosin Y dianion, L1 = 4,4'-bipyridine) based on Eosin Y dye ligand have been prepared by solvothermal reactions and structurally characterized. Single-crystal X-ray diffraction studies reveal that compounds 1 and 2 are isostructural. They show weak antiferromagnetic coupling between the adjacent Co^Ⅱ and Mn^Ⅱ ions, respectively.展开更多
A new cadmium(Ⅱ) nitrite complex Cd2(H2C3PIm)2(BDC)(NO2)2(1,H2C3PIm = 2,2'-(1,3-propanediyl)bis(1H-benzimidazole),H2BDC = 1,4-benzenedicarboxylic acid) has been synthesized by solvothermal reaction in ...A new cadmium(Ⅱ) nitrite complex Cd2(H2C3PIm)2(BDC)(NO2)2(1,H2C3PIm = 2,2'-(1,3-propanediyl)bis(1H-benzimidazole),H2BDC = 1,4-benzenedicarboxylic acid) has been synthesized by solvothermal reaction in formamide,and its structure(C42H36Cd2N10O8,Mr = 1033.61) was determined by single-crystal X-ray diffraction analysis.The crystal belongs to the monoclinic system,space group P21/n with a = 0.9859(5),b = 0.8936(5),c = 2.3188(5) nm,β = 97.576(5)°,V = 2.025(16) nm3,Z = 2,Dc = 1.695 g/cm3,μ(MoKα) = 1.118 mm-1,F(000) = 1036,S = 1.017,the final R = 0.0304 and wR = 0.0752 for 3761 reflections with I 〉 2σ(I).The centrosymmetric complex 1 contains a dimer in which two distorted octahedral Cd(II) centers are bridged by BDC ligand and chelated by H2C3PIm.The units of the complex are linked via weak N-H···O hydrogen bonds between the nitrito and the BDC ligands,leading to the formation of a 1D zigzag chain along the b axis.The π-π packing interactions contribute to the formation of a three-dimensional supramolecular architecture.The complex exhibits strong photoluminescence at room temperature.展开更多
The title compound, [Zn(4-pytpy)(NO3)2] (4-pytpy = 4′-(4-pyridyl)-2,2′:6′,2"- terpyridine) 1, has been synthesized by the solvothermal reaction of Zn(NO3)2·6H2O with 4-pytpy in CH3OH solution. It c...The title compound, [Zn(4-pytpy)(NO3)2] (4-pytpy = 4′-(4-pyridyl)-2,2′:6′,2"- terpyridine) 1, has been synthesized by the solvothermal reaction of Zn(NO3)2·6H2O with 4-pytpy in CH3OH solution. It crystallizes in the triclinic system, space group P1 with a = 8.358(6), b = 11.121(8), c = 11.374(8)A, α = 74.226(11), β = 74.532(11), γ = 83.085(12)°, Mr= 499.74, V= 979.3(12) A3, Z = 2, Dc = 1.695 g/cm3, F(000) = 508,μ = 1.309 mm^-1, the final R = 0.0547 and wR = 0.1588. X-ray crystal structure analysis revealed that the Znn is hexa-eoordinated by two oxygen atoms from two nitrate groups and four nitrogen atoms, three of which are from the tridentate domain of one 4-pytpy and the other from the monodentate domain of another 4-pytpy. 4-pytpy as a bridging ligand connects ZnⅡ into a one-dimensional coordination polymer.展开更多
Three-dimensional(3D) ultra-tiny Fe_(2)O_(3) nanoparticles/graphene hydrogels were prepared using a facile and efficient solvothermal reaction, by which the phase of iron oxide, particle size and the morphology of hyd...Three-dimensional(3D) ultra-tiny Fe_(2)O_(3) nanoparticles/graphene hydrogels were prepared using a facile and efficient solvothermal reaction, by which the phase of iron oxide, particle size and the morphology of hydrogels can be precisely controlled by simply adjusting the solvothermal reaction time. Accordingly, the effect of the microstructures of hydrogels on electrochemical performance was systematically studied. It was found that Fe_(2)O_(3)/r GO-50 hydrogels(with a solvothermal reaction time of 50 min) possessed a desirable crystallinity, suitable particle size, decent porous structure, large specific surface area and high electrical conductivity, thus exhibiting a superior electrochemical performance as binder-free anode of supercapacitors: a large potential range of 1.15 V, an ultrahigh specific capacitance of 1090 F·g^(-1) at a current density of 2A·g^(-1) and excellent rate capability (531 F·g^(-1) at 10 A·g^(-1)). The rational design and systematic research of electrode materials will provide new lights for the preparation of advanced electrochemical energy storage devices.展开更多
As a potential substitute for LiFePO4, LiMnPO4 has attracted more and more attention due to its higher energy, showing potential application in electric vehicle(EV) or hybrid electric vehicle(HEV). In this work,so...As a potential substitute for LiFePO4, LiMnPO4 has attracted more and more attention due to its higher energy, showing potential application in electric vehicle(EV) or hybrid electric vehicle(HEV). In this work,solvothermal method was used to prepare nano-sized LiMnPO4, where ethylene glycol was used as solvent, and lithium acetate(LiAc), phosphoric acid(H3 PO4) and manganese chloride(MnCl2) were used as precursors. The crystal structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The electrochemical performance was evaluated by charge-discharge cycling, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the molar ratio of LiAc:H3 PO4:MnCl2 plays a critical role in directing the morphology of LiMnPO4. Large plates transform into irregular nanoparticles when the molar ratio changes from 2:1:1 to 6:1:1. After carbon coating, the product prepared from the 6:1:1 precursor could deliver discharge capacities of 156.9,122.8, and 89.7 mAhg-1 at 0.05 C, 1 C and 10 C, respectively.The capacity retention can be maintained at 85.1% after 200 cycles at 1 C rate for this product.展开更多
Novel mono-dispersed hollow polyhedral ceria nano powders with the average particle size of 250 nm were directly synthesized via a simple template-free mixed solvothermal method by using water-ethanol as the solvent. ...Novel mono-dispersed hollow polyhedral ceria nano powders with the average particle size of 250 nm were directly synthesized via a simple template-free mixed solvothermal method by using water-ethanol as the solvent. The formation of such hollow structure with the regular polyhedral particle shape was based on a solvent-controlled Ostwald ripening coupled self-templating process. The mixed solvent promoted the formation of the regular solid particles at the beginning of solvothermal reaction and drove the Ostwald ripening as the reaction went on. Owing to the Ostwald ripening and self-assembly of nano crystallites, ceria nano particles converted into the hollow structures with regular polyhedral shape during the solvothermal process just by increasing solvothermal reaction time. The as-synthesized hollow ceria nano powders exhibited strong absorptions in the UV-vis spectrum and the evaluated energy band gaps increased according to the shape evolution and size decrease of the nano particles, which demonstrated obvious blue shift effects.展开更多
To further investigate the influence of metal ions on the allylic rearrangement of 3,4,5,6-tetrahydrophthalic an- hydride during the hydrothermal reaction, metal ions such as manganese(Ⅱ), zinc(Ⅱ) and cadmium(...To further investigate the influence of metal ions on the allylic rearrangement of 3,4,5,6-tetrahydrophthalic an- hydride during the hydrothermal reaction, metal ions such as manganese(Ⅱ), zinc(Ⅱ) and cadmium(Ⅱ) have been employed in the synthesis, which leads to the formation of three new lamellar coordination polymers, [MnⅡs(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H20)] (3Mn), [ZnⅡs(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H20)] (4Zn), and [CdⅡ3(μ3-OH)2(1,2-chedc)2] (5Cd) (1-chec=cyclohexene-l-carboxylate, 1,2-chedc=cyclohexene-1,2- dicarboxylate, 2,3-chedc=cyclohexene-1,2-dicarboxylate). Interestingly, the allylic rearrangement reaction is metal-dependent, which occurs only in 3Mn and 4Zn, resulting in the formation of one chiral carbon atom of the corresponding dicarboxylate ligands in both compounds. In addition, the magnetic property of compound 3Mn was studied, which revealed strong antiferromagnetic interactions between the metal centers.展开更多
Low density and high porosity polyacrylonitrile(PAN)nanofibers prepared by electrospinning were used as brackets for photocatalyst W_(18)O_(49) to prepare a kind of light weight and easy recycling water purification m...Low density and high porosity polyacrylonitrile(PAN)nanofibers prepared by electrospinning were used as brackets for photocatalyst W_(18)O_(49) to prepare a kind of light weight and easy recycling water purification material for the first time.The influence of tungsten source concentration on the formation of W_(18)O_(49) during a solvothermal process was systematically investigated.The prepared PAN@W_(18)O_(49) nanofibers(NFs)utilize the outstanding visible light photocatalytic performance and the adsorption performance of W_(18)O_(49),and at the same time give the advantages of low density and easy recyclability.The pollutant removal performance of the composite nanofibers was investigated by using five contaminants including rhodamine B(RhB),methylene blue(MB),malachite green(MG),methyl orange(MO)and chlortetracycline(CTC)as substrates.Among them,the degradation process of rhodamine B has been studied in detail.After five cycles,the degradation efficiency did not decrease significantly,showing excellent reusability of PAN@W_(18)O_(49) NFs.Besides,the adsorption performance of PAN@W_(18)O_(49) NFs during the photocatalytic process was also studied in detail.Compared with recently reported literature,the degradation efficiency of organic pollutants by PAN@W_(18)O_(49) NFs showed better performance,and PAN@W_(18)O_(49) NFs felt had a promising prospect in the field of degradation of contaminants.展开更多
Cadmium sulfide (CdS) nanowires were synthesized on Cd foil via a simple solvothermal reaction at 180℃ using thiosemicarbazide as the sulfide source and ethylenediamine as the solvent. The CdS nanowires are hexagon...Cadmium sulfide (CdS) nanowires were synthesized on Cd foil via a simple solvothermal reaction at 180℃ using thiosemicarbazide as the sulfide source and ethylenediamine as the solvent. The CdS nanowires are hexagonal-phase single crystals with an average diameter of 50 nm and length of several microns. The as-prepared CdS nanowires show an absorption peak of around 483 nm in the absorption spectrum. The CdS nanowires exhibit bright photoluminescence (PL) with two distinct emission bands at 503 nm and 697 nm, which shows that the as-prepared CdS nanowires are high-quality nanocrystals.展开更多
基金supported by the National Natural Science Foundation of China (No 20871027)the Program for New Century Excellent Talents in University (NCET-07-0169)
文摘A new zinc 1,3,5-benzenetricarboxylate Zn3(BTC)2(DMSO)4(BTC=1,3,5-benzenetricarboxylate) has been solvothermally synthesized in DMSO and structurally determined by X-ray single-crystal diffraction.It crystallizes in the monoclinic system,space group P21/c with a=10.0861(11),b=10.2527(11),c=16.4013(18),β=95.478(2)°,V=1688.3(3)3,Z=2,Zn3S4C26H30O16,Mr=922.85,Dc=1.815 g/cm3,F(000)=936,μ=2.434 mm-1,R=0.0319 and wR=0.0755.This compound consists of trimeric zinc clusters and BTC linkers.Alternate connection of these trimeric zinc clusters and BTC linkers results in a three-dimensional(3,6)-connected frame-work with rutile topology.
基金supported by the Postdoctoral Science Foundation of China(No.2014M562403)National Natural Science Foundation of China(No.21573189)
文摘Solvothermal reaction of manganese(II) salt with monosodium 2-sulfoterephthalate(2-NaH2stp) and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated with [Mn2(Hstp)2(bpp)2(H2O)4](1) and [Mn3(stp)2(tpy)3(H2O)](H2O)5(2)(bpp = benz-2,3-pyrimidine-[2,3-f]-1,10-phenanthroline, tpy = 2,2':6',2''-terpyridine). X-ray diffraction structural analyses of two complexes reveal their structural diversity(0D and 1D) due to the difference of auxiliary ligands. 1 is a discrete structure, in which the Mn(Ⅱ) ion is hexa-coordinated with one stp, one bpp ligand and two water molecules. Complex 2 is a one-dimensional(1D) chain-like structure with three crystallographically independent Mn(Ⅱ) ions. The photoluminescent properties could be assigned to the π-π* transition of 2-sulfoterephthalate ligands.
基金the National Natural Science Foundation of China(21501178)Natural Science Funds of Fujian Province(No.2014H0055)for financial support of this work
文摘Two novel complexes, namely {[Cd(AIP)(4,4'-bpy)]·1.3DMF}n(1) and [Cd(AIP)(2,2'- bpy)]n(2), have been synthesized through solvothermal reaction(H2AIP = 5-aminoisophthalic acid, 2,2'-bpy = 2,2'-bipyridine, 4,4'-bpy = 4,4'-bipyridine, and DMF = N,N'-dimethylformamide) and structurally determined by single-crystal X-ray diffraction. Complex 1 shows a three-dimensional(3D) layer-pillar framework with rectangular channels, while complex 2 displays a two-dimensional(2D) wave net architecture. Furthermore, 1 and 2 were characterized by elemental analysis, infrared spectra(IR), thermal gravimetric analyses(TGA) and fluorescence measurements. The luminescent properties of 1 dispersed in various organic solvents have been investigated systematically, demonstrating high selectivity for acetone via the fluorescence quenching effect.
基金Supported by the National Natural Science Foundation of China(Nos.20371007,20476011).
文摘In recent years, considerable attention has been paid to supramolecular networks based on metal organic building blocks because of their potential applications in diverse fields, such as, catalysis, optics, sensors, magnetism, and molecular recognition^[1-3]. On the ba- sis of the principles of crystal engineering and special synthesis strategies, several novel supramolecular frameworks have been assembled from various organic, inorganic and metal-organic moieties, which largely en- riches the structure chemistry of solid state materi-als^[4-9].
基金This work was supported by the State Key Laboratory of Structural Chemistry, the Ministry of Science and Technology of China (001CB108906)the National Natural Science Foundation of China (20333070)
文摘The organic-inorganic hybrid polymer [Mn(mbbimb)2(1,5-nds)]n 1 has been synthesized using 1,5-naphthalenedisulfonate (1,5-nds) and 1,3-bis(benzimidazol-1-ylmethyl)- 2,4,structure analysis indicates that 1 crystallizes in monoclinic, space group C2/c with a=21.3546(17), b=11.8841(7), c=22.1588(16)A, β=108.058(3)°, C60H54MnN8O6S2, Mr=1102.17, Z=4, V=5346.5(7)A^3, Dc=1.369 g/cm^3, μ=0.386 mm^-1, F(000)=2300, S=1.091, R=0.0634 and wR=0.1559 for 4641 observed reflections (I 〉 2σ(I)). The Mn center is six-coordinated to furnish a distorted octahedral geometry, and the overall framework is a 6-connected 3D net.
基金supported by the National Natural Science Foundation of China(21503230 and 21571175)State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences
文摘Two novel coordination compounds formulated as [Co2(EY)2(L1)]·2C2H5OH(1) and [Mn2(EY)2(L1)]·2C2H5OH(2)(EY = Eosin Y dianion, L1 = 4,4'-bipyridine) based on Eosin Y dye ligand have been prepared by solvothermal reactions and structurally characterized. Single-crystal X-ray diffraction studies reveal that compounds 1 and 2 are isostructural. They show weak antiferromagnetic coupling between the adjacent Co^Ⅱ and Mn^Ⅱ ions, respectively.
基金supported by the research grant of Phytochemistry Key Laboratory of Shaanxi Province (No.11JS006,11JS007)the Scientific Research Fund of shaanxi Provincial Education Department (No.11JK0603)
文摘A new cadmium(Ⅱ) nitrite complex Cd2(H2C3PIm)2(BDC)(NO2)2(1,H2C3PIm = 2,2'-(1,3-propanediyl)bis(1H-benzimidazole),H2BDC = 1,4-benzenedicarboxylic acid) has been synthesized by solvothermal reaction in formamide,and its structure(C42H36Cd2N10O8,Mr = 1033.61) was determined by single-crystal X-ray diffraction analysis.The crystal belongs to the monoclinic system,space group P21/n with a = 0.9859(5),b = 0.8936(5),c = 2.3188(5) nm,β = 97.576(5)°,V = 2.025(16) nm3,Z = 2,Dc = 1.695 g/cm3,μ(MoKα) = 1.118 mm-1,F(000) = 1036,S = 1.017,the final R = 0.0304 and wR = 0.0752 for 3761 reflections with I 〉 2σ(I).The centrosymmetric complex 1 contains a dimer in which two distorted octahedral Cd(II) centers are bridged by BDC ligand and chelated by H2C3PIm.The units of the complex are linked via weak N-H···O hydrogen bonds between the nitrito and the BDC ligands,leading to the formation of a 1D zigzag chain along the b axis.The π-π packing interactions contribute to the formation of a three-dimensional supramolecular architecture.The complex exhibits strong photoluminescence at room temperature.
基金Supported by the Cultivation Fund of the Key Scientific and Technical Innovation Project,Ministry of Education of China(No.708084) the Opening Project of Key Laboratory of Synthetic and Natural Functional Molecule Chemistry(Northwest University),Ministry of Education
文摘The title compound, [Zn(4-pytpy)(NO3)2] (4-pytpy = 4′-(4-pyridyl)-2,2′:6′,2"- terpyridine) 1, has been synthesized by the solvothermal reaction of Zn(NO3)2·6H2O with 4-pytpy in CH3OH solution. It crystallizes in the triclinic system, space group P1 with a = 8.358(6), b = 11.121(8), c = 11.374(8)A, α = 74.226(11), β = 74.532(11), γ = 83.085(12)°, Mr= 499.74, V= 979.3(12) A3, Z = 2, Dc = 1.695 g/cm3, F(000) = 508,μ = 1.309 mm^-1, the final R = 0.0547 and wR = 0.1588. X-ray crystal structure analysis revealed that the Znn is hexa-eoordinated by two oxygen atoms from two nitrate groups and four nitrogen atoms, three of which are from the tridentate domain of one 4-pytpy and the other from the monodentate domain of another 4-pytpy. 4-pytpy as a bridging ligand connects ZnⅡ into a one-dimensional coordination polymer.
基金financially supported by the National Natural Science Foundation of China (Nos. 21603019,51772034 and 12075224)the Opening Project of State Key Laboratory of High Performance Ceramics and Superfine Microstructure(No. SKL201807SIC)The Fundamental Research Funds for the Central Universities (No. 2019CDJGFCL004)。
文摘Three-dimensional(3D) ultra-tiny Fe_(2)O_(3) nanoparticles/graphene hydrogels were prepared using a facile and efficient solvothermal reaction, by which the phase of iron oxide, particle size and the morphology of hydrogels can be precisely controlled by simply adjusting the solvothermal reaction time. Accordingly, the effect of the microstructures of hydrogels on electrochemical performance was systematically studied. It was found that Fe_(2)O_(3)/r GO-50 hydrogels(with a solvothermal reaction time of 50 min) possessed a desirable crystallinity, suitable particle size, decent porous structure, large specific surface area and high electrical conductivity, thus exhibiting a superior electrochemical performance as binder-free anode of supercapacitors: a large potential range of 1.15 V, an ultrahigh specific capacitance of 1090 F·g^(-1) at a current density of 2A·g^(-1) and excellent rate capability (531 F·g^(-1) at 10 A·g^(-1)). The rational design and systematic research of electrode materials will provide new lights for the preparation of advanced electrochemical energy storage devices.
基金supported financially by the National Natural Science Foundation of China (No. 51572238)the Strategic Emerging Industry Project of Hunan Province, China (No. 2016GK4030)
文摘As a potential substitute for LiFePO4, LiMnPO4 has attracted more and more attention due to its higher energy, showing potential application in electric vehicle(EV) or hybrid electric vehicle(HEV). In this work,solvothermal method was used to prepare nano-sized LiMnPO4, where ethylene glycol was used as solvent, and lithium acetate(LiAc), phosphoric acid(H3 PO4) and manganese chloride(MnCl2) were used as precursors. The crystal structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The electrochemical performance was evaluated by charge-discharge cycling, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the molar ratio of LiAc:H3 PO4:MnCl2 plays a critical role in directing the morphology of LiMnPO4. Large plates transform into irregular nanoparticles when the molar ratio changes from 2:1:1 to 6:1:1. After carbon coating, the product prepared from the 6:1:1 precursor could deliver discharge capacities of 156.9,122.8, and 89.7 mAhg-1 at 0.05 C, 1 C and 10 C, respectively.The capacity retention can be maintained at 85.1% after 200 cycles at 1 C rate for this product.
基金supported by the National Natural Science Foundation of China(51103125,51102073)China Postdoctoral Science Foundation(2015M570483)the Priority Academic Program Development of Jiangsu Higher Education Institutions(Chemistry)
文摘Novel mono-dispersed hollow polyhedral ceria nano powders with the average particle size of 250 nm were directly synthesized via a simple template-free mixed solvothermal method by using water-ethanol as the solvent. The formation of such hollow structure with the regular polyhedral particle shape was based on a solvent-controlled Ostwald ripening coupled self-templating process. The mixed solvent promoted the formation of the regular solid particles at the beginning of solvothermal reaction and drove the Ostwald ripening as the reaction went on. Owing to the Ostwald ripening and self-assembly of nano crystallites, ceria nano particles converted into the hollow structures with regular polyhedral shape during the solvothermal process just by increasing solvothermal reaction time. The as-synthesized hollow ceria nano powders exhibited strong absorptions in the UV-vis spectrum and the evaluated energy band gaps increased according to the shape evolution and size decrease of the nano particles, which demonstrated obvious blue shift effects.
文摘To further investigate the influence of metal ions on the allylic rearrangement of 3,4,5,6-tetrahydrophthalic an- hydride during the hydrothermal reaction, metal ions such as manganese(Ⅱ), zinc(Ⅱ) and cadmium(Ⅱ) have been employed in the synthesis, which leads to the formation of three new lamellar coordination polymers, [MnⅡs(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H20)] (3Mn), [ZnⅡs(μ3-OH)3(1-chec)(1,2-chedc)(2,3-chedc)2(H20)] (4Zn), and [CdⅡ3(μ3-OH)2(1,2-chedc)2] (5Cd) (1-chec=cyclohexene-l-carboxylate, 1,2-chedc=cyclohexene-1,2- dicarboxylate, 2,3-chedc=cyclohexene-1,2-dicarboxylate). Interestingly, the allylic rearrangement reaction is metal-dependent, which occurs only in 3Mn and 4Zn, resulting in the formation of one chiral carbon atom of the corresponding dicarboxylate ligands in both compounds. In addition, the magnetic property of compound 3Mn was studied, which revealed strong antiferromagnetic interactions between the metal centers.
基金This work was supported by the National Natural Science Foundation of China(No.21875084)the Fund of the Development and Reform Commission of Jilin Province,China(No.2020C023-5).
文摘Low density and high porosity polyacrylonitrile(PAN)nanofibers prepared by electrospinning were used as brackets for photocatalyst W_(18)O_(49) to prepare a kind of light weight and easy recycling water purification material for the first time.The influence of tungsten source concentration on the formation of W_(18)O_(49) during a solvothermal process was systematically investigated.The prepared PAN@W_(18)O_(49) nanofibers(NFs)utilize the outstanding visible light photocatalytic performance and the adsorption performance of W_(18)O_(49),and at the same time give the advantages of low density and easy recyclability.The pollutant removal performance of the composite nanofibers was investigated by using five contaminants including rhodamine B(RhB),methylene blue(MB),malachite green(MG),methyl orange(MO)and chlortetracycline(CTC)as substrates.Among them,the degradation process of rhodamine B has been studied in detail.After five cycles,the degradation efficiency did not decrease significantly,showing excellent reusability of PAN@W_(18)O_(49) NFs.Besides,the adsorption performance of PAN@W_(18)O_(49) NFs during the photocatalytic process was also studied in detail.Compared with recently reported literature,the degradation efficiency of organic pollutants by PAN@W_(18)O_(49) NFs showed better performance,and PAN@W_(18)O_(49) NFs felt had a promising prospect in the field of degradation of contaminants.
基金Supported by the National Natural Science Foundation of China (10874134 and 61008043)the Fundamental Research Funds for the Central Universities at Wuhan University (1101024)
文摘Cadmium sulfide (CdS) nanowires were synthesized on Cd foil via a simple solvothermal reaction at 180℃ using thiosemicarbazide as the sulfide source and ethylenediamine as the solvent. The CdS nanowires are hexagonal-phase single crystals with an average diameter of 50 nm and length of several microns. The as-prepared CdS nanowires show an absorption peak of around 483 nm in the absorption spectrum. The CdS nanowires exhibit bright photoluminescence (PL) with two distinct emission bands at 503 nm and 697 nm, which shows that the as-prepared CdS nanowires are high-quality nanocrystals.