We present a short retrospective review of the existing literature about the dynamics of(dry)granular matter under the effect of vibrations.The main objective is the development of an integrated resource where vital i...We present a short retrospective review of the existing literature about the dynamics of(dry)granular matter under the effect of vibrations.The main objective is the development of an integrated resource where vital information about past findings and recent discoveries is provided in a single treatment.Special attention is paid to those works where successful synthetic routes to as-yet unknown phenomena were identified.Such landmark results are analyzed,while smoothly blending them with a history of the field and introducing possible categorizations of the prevalent dynamics.Although no classification is perfect,and it is hard to distillate general properties out of specific observations or realizations,two possible ways to interpret the existing results are defined according to the type of forcing or the emerging(ensuing)regime of motion.In particular,first results concerning the case where vibrations and gravity are concurrent(vertical shaking)are examined,then the companion situation with vibrations perpendicular to gravity(horizontal shaking)is described.Universality classes are introduced as follows:(1)Regimes where sand self-organizes leading to highly regular geometrical“pulsating”patterns(thin layer case);(2)Regimes where the material undergoes“fluidization”and develops an internal multicellular convective state(tick layers case);(3)Regimes where the free interface separating the sand from the overlying gas changes inclination or develops a kind a patterned configuration consisting of stable valleys and mountains or travelling waves;(4)Regimes where segregation is produced,i.e.,particles of a given size tend to be separated from the other grains(deep containers).Where possible,an analogy or parallelism is drawn with respect to the companion field of fluid-dynamics for which the assumption of“continuum”can be applied.展开更多
The homogeneous/particulate fluidization flow regime is particularly suitable for handling the various gas–solid contact processes encountered in the chemical and energy industry.This work aimed to extend such a regi...The homogeneous/particulate fluidization flow regime is particularly suitable for handling the various gas–solid contact processes encountered in the chemical and energy industry.This work aimed to extend such a regime of Geldart-A particles by exerting the axial uniform and steady magnetic field.Under the action of the magnetic field,the overall homogeneous fluidization regime of Geldart-A magnetizable particles became composed of two parts:inherent homogeneous fluidization and newly-created magnetic stabilization.Since the former remained almost unchanged whereas the latter became broader as the magnetic field intensity increased,the overall homogeneous fluidization regime could be extended remarkably.As for Geldart-A nonmagnetizable particles,certain amount of magnetizable particles had to be premixed to transmit the magnetic stabilization.Among others,the mere addition of magnetizable particles could broaden the homogeneous fluidization regime.The added content of magnetizable particles had an optimal value with smaller/lighter ones working better.The added magnetizable particles might raise the ratio between the interparticle force and the particle gravity.After the magnetic field was exerted,the homogeneous fluidization regime was further expanded due to the formation of magnetic stabilization flow regime.The more the added magnetizable particles,the better the magnetic performance and the broader the overall homogeneous fluidization regime.Smaller/lighter magnetizable particles were preferred to maximize the magnetic performance and extend the overall homogeneous fluidization regime.This phenomenon could be ascribed to that the added magnetizable particles themselves became more Geldart-A than-B type as their density or size decreased.展开更多
To break through the thermodynamic limitation that sodium fluosilicate only can be completely decomposed at high temperature,the technology of pre-decomposition under SiF_(4) atmosphere and deep decomposition under ai...To break through the thermodynamic limitation that sodium fluosilicate only can be completely decomposed at high temperature,the technology of pre-decomposition under SiF_(4) atmosphere and deep decomposition under air condition at lower temperature was developed.The hydrolysis reaction of sodium fluosilicate can be effectively restrained when drying under vacuum or low temperature.Thermal decomposition results of sodium fluosilicate indicate that temperature has a very significant effect on its decomposition.The decomposition ratio can reach 79.4%at 600℃ for 1 h,and 99.6% at 700℃ for 1 h under air condition,respectively.Gas velocity and the type of inert gas have no significant effect on its decomposition.Fine particles affect its decomposition performance due to agglomeration,while coarse particles have good thermal decomposition performance without significant differences.The decomposition reaction process in fluidized bed satisfies the classical Avrami Erofe'EV model,with the reaction order of 1.5 and the activation energy of 61.35 kJ·mol^(-1).展开更多
A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four type...A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.展开更多
The multiphase flow characteristic is one of the most concerning problems during solid fluidization exploitation of marine natural gas hydrate reservoirs.In this research,a new transient gas-liquid-solid multiphase fl...The multiphase flow characteristic is one of the most concerning problems during solid fluidization exploitation of marine natural gas hydrate reservoirs.In this research,a new transient gas-liquid-solid multiphase flow model with hydrate phase transition was developed.Meanwhile,this model considered the coupling relationship among convective heat transfer,hydrate dynamic decomposition,and multi-phase flow.The model can simulate the change of flow pattern from solid-liquid to gas-liquid-solid flow,and describe the distribution character of volume fraction of phase,wellbore temperature and pressure,and hydrate decomposition rate during transportation.The simulation results indicate that the hydrate decomposition region in the wellbore gradually expands,but the hydrate decomposition rate gradually decreases during the solid fluidization exploitation of hydrate.When mining time lasts for 4 h,and the bottom hole pressure decreases by about 0.4 MPa.Increasing NaCl concentration in seawater helps expand hydrate decomposition regions and improves the wellbore hydrate decomposition rate.When the Nacl mass fraction in seawater reaches 15%,it will raise the hydrate decomposition regions to the whole wellbore.In addition,the higher the wellhead backpressure,the lower the decomposition area and decomposition rate of hydrate in the wellbore.When wellhead backpressure reaches 2 MPa,the volume fraction of gas near the wellhead will reduce to about 12%.This work is expected to provide a theoretical basis for the development of marine hydrate reservoirs.展开更多
As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in th...As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in the industrial production of carbon nanotubes.To improve the production volume and product quality of carbon nanotubes,the study of fluidized-bed-diameter scaling is important.Three different diameters of distributor-less conical fluidized beds were established,and then the particle behavior and bubble characteristics of carbon nanotube clusters at these bed diameters were investigated.Time-series and wavelet analysis methods were used to analyze the pressure-fluctuation signals inside the fluidized beds.Results showed that the distributor-less design caused the airflow to break through the middle of the bed,which did not change with the change in bed diameter.The powder-bridging phenomenon of carbon nanotube clusters in a 100-mm-diameter fluidized bed was related to the special microstructure of carbon nanotube clusters.The frequency of pressure fluctuations in the bed decreased nonlinearly with increasing bed diameter.This study can guide the design and scale-up of distributor-less conical fluidized beds,especially for the scale-up of carbon nanotube production equipment,which can contribute to the improvement of carbon nanotubes’capacity and quality in industrial production.展开更多
This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglomeration and...This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglomeration and defluidization.Adding kaolin could effectively inhibit the particle agglomeration during the fluidized pyrolysis reaction through physical isolation and chemical reaction.On the one hand,kaolin could form a coating layer on the surface of ceramic particles to prevent the adhesion of organic ash generated by the pyrolysis of resin.On the other hand,when a sufficient amount of kaolin(-0.2%(mass))was added,the activated kaolin could fully contact with the Na+ ions generated by the pyrolysis of resin and react to form a high-melting aluminosilicate mineral(nepheline),which could reduce the formation of low-melting-point sodium sulfate and thereby avoid the agglomeration of ceramic particles.展开更多
The particle residence time distribution(RTD)and axial dispersion coefficient are key parameters for the design and operation of a pressurized circulating fluidized bed(PCFB).In this study,the effects of pressure(0.1-...The particle residence time distribution(RTD)and axial dispersion coefficient are key parameters for the design and operation of a pressurized circulating fluidized bed(PCFB).In this study,the effects of pressure(0.1-0.6 MPa),fluidizing gas velocity(2-7 m·s^(-1)),and solid circulation rate(10-90 kg·m^(-2)·s^(-1))on particle RTD and axial dispersion coefficient in a PCFB are numerically investigated based on the multiphase particle-in-cell(MP-PIC)method.The details of the gas-solid flow behaviors of PCFB are revealed.Based on the gas-solid flow pattern,the particles tend to move more orderly under elevated pressures.With an increase in either fluidizing gas velocity or solid circulation rate,the mean residence time of particles decreases while the axial dispersion coefficient increases.With an increase in pressure,the core-annulus flow is strengthened,which leads to a wider shape of the particle RTD curve and a larger mean particle residence time.The back-mixing of particles increases with increasing pressure,resulting in an increase in the axial dispersion coefficient.展开更多
Deep-sea pipelines play a pivotal role in seabed mineral resource development,global energy and resource supply provision,network communication,and environmental protection.However,the placement of these pipelines on ...Deep-sea pipelines play a pivotal role in seabed mineral resource development,global energy and resource supply provision,network communication,and environmental protection.However,the placement of these pipelines on the seabed surface exposes them to potential risks arising from the complex deep-sea hydrodynamic and geological environment,particularly submarine slides.Historical incidents have highlighted the substantial damage to pipelines due to slides.Specifically,deep-sea fluidized slides(in a debris/mud flow or turbidity current physical state),characterized by high speed,pose a significant threat.Accurately assessing the impact forces exerted on pipelines by fluidized submarine slides is crucial for ensuring pipeline safety.This study aimed to provide a comprehensive overview of recent advancements in understanding pipeline impact forces caused by fluidized deep-sea slides,thereby identifying key factors and corresponding mechanisms that influence pipeline impact forces.These factors include the velocity,density,and shear behavior of deep-sea fluidized slides,as well as the geometry,stiffness,self-weight,and mechanical model of pipelines.Additionally,the interface contact conditions and spatial relations were examined within the context of deep-sea slides and their interactions with pipelines.Building upon a thorough review of these achievements,future directions were proposed for assessing and characterizing the key factors affecting slide impact loading on pipelines.A comprehensive understanding of these results is essential for the sustainable development of deep-sea pipeline projects associated with seabed resource development and the implementation of disaster prevention measures.展开更多
In order to avoid the formation ofηphase(W_(6)Co_(6)C or W_(3)Co_(3)C)that adversely affects the sintering process and its products in the preparation process of ultra-fine WC-Co powder,a technical route of prereduct...In order to avoid the formation ofηphase(W_(6)Co_(6)C or W_(3)Co_(3)C)that adversely affects the sintering process and its products in the preparation process of ultra-fine WC-Co powder,a technical route of prereduction of WO_(3)-Co_(3)O_(4)to WO_(2)-Co and then deep reduction carbonization to WC-Co powder has been proposed.This study mainly investigates the influence of gas partial pressure on the pre-reduction process of WO_(3)-Co_(3)O_(4)under a mixed atmosphere of H_(2)-C_(2)H_(4)-Ar at 600℃and establishes the kinetic equations of pre-reduction and carbon evolution.The results indicate that increasing the partial pressure of hydrogen is conducive to the rapid and complete conversion of WO_(3) to WO_(2).High carbon content can be generated by the deposition of C_(2)H_(4),and it hinders the diffusion of the reducing gas;WO_(3)still cannot be completely reduced to WO_(2)as the partial pressure of C_(2)H_(4) increases to 60%.For the carbon evolution of C_(2)H_(4),the carbon amount is positively related to the H_(2)partial pressure,but it shows the highest amount and evolution rate when the ethylene partial pressure is 20%.Based on the reduction rate curves of WO_(3) and carbon evolution rate curves of C_(2)H_(4),the rate equations of pre-reduction and carbon evolution of WO_(3)-Co_(3)O_(4)system at 600℃are established.The pre-reduction reaction belongs to the first-order reaction,and its equation is expressed as follows:r=-(dw_(WO_(3)))/dt=(9±0.15)×10^(-2)×P_(H_(2))^(0.44)P_(C_(2)H_(4))&(0.57)The carbon deposition rate equation of C_(2)H_(4) can be expressed as follows:r=-(dc_C)/dt=r_f-r_b≌7.35×10^(-2)×P_(C_(2)H_(4))^(0.31)展开更多
This research entails the study of heat and mass transfer of nanofluid flow in a fluidized bed dryer used in tea drying processes in presence of induced magnetic field. A mathematical model describing the fluid flow i...This research entails the study of heat and mass transfer of nanofluid flow in a fluidized bed dryer used in tea drying processes in presence of induced magnetic field. A mathematical model describing the fluid flow in a Fluidized bed dryer was developed using the nonlinear partial differential equations. Due to their non-linearity, the equations were solved numerically by use of the finite difference method. The effects of physical flow parameters on velocity, temperature, concentration and magnetic induction profiles were studied and results were presented graphically. From the mathematical analysis, it was deduced that addition of silver nanoparticles into the fluid flow enhanced velocity and temperature profiles. This led to improved heat transfer in the fluidized bed dryer, hence amplifying the tea drying process. Furthermore, it was noted that induced magnetic field tends to decrease the fluid velocity, which results in uniform distribution of heat leading to efficient heat transfer between the tea particles and the fluid, thus improving the drying process. The research findings provide information to industries on ways to optimize thermal performance of fluidized bed dryers.展开更多
Fluidization processes based on experiments are reviewed to gain some useful insights and comparisons with those that occur in hydrothermal systems. Field and petrographic work, and microscope observation were carried...Fluidization processes based on experiments are reviewed to gain some useful insights and comparisons with those that occur in hydrothermal systems. Field and petrographic work, and microscope observation were carried out on samples from the Qiyugou Au-bearing breccia pipes from the East Qinling region, Henan Province. Evidence from macro- and micro-textures suggests that the style of breccias in the Qiyugou area can be grouped into three types: (1) jigsaw fit-stockwork texture, in which the interval between clasts is marked by fractures or filled with calcite or quartz veins; (2) larger breccias that are supported by smaller breccias, rock flour and alteration materials; in this type clasts moved over short distances, creating open spaces; (3) fluidized texture, where the clasts of different lithologies have rounded shapes. These observations are compared with those resulting from experiments on fluidization processes. The results of this comparison suggest that fluidization is an important geological process in the formation of the Qiyugou Au-bearing breccia pipes and gold mineralization. In addition, fluidization processes such as expansion, bubbling, slugging, channeling and spouting must have contributed to the formation of the pipes and were conducive to the development of gold mineralization. In the Qiyugou breccia pipes, gold mineralization occurs as disseminations, in stockwork veins, and open space infills. The ore zones form subparallel sheets that are nearly perpendicular to the walls of the pipes.展开更多
The EMMS/bubbling model originally proposed for fluidization of monodisperse particles is extended to fluidization of binary particle mixture in this study.The dense and dilute phases are considered to comprise of two...The EMMS/bubbling model originally proposed for fluidization of monodisperse particles is extended to fluidization of binary particle mixture in this study.The dense and dilute phases are considered to comprise of two types of particles differing in size and/or density.Governing equations and the stability condition are then formulated and solved by using an optimization numerical scheme.The effects of bubble diameter are first investigated and a suitable bubble diameter correlation is chosen.Preliminary validation for steady state behavior shows the extended model can fairly capture the overall hydrodynamic behaviors in terms of volume fraction of bubbles and average bed voidage for both monodisperse and binary particle systems.This encourages us to integrate this model with CFD for more validations in the future.展开更多
Accurate prediction of the onset of turbulent fluidization still remains elusive owing to the dependence of the transition velocity on several factors including measurement methods and interpretation of results. In th...Accurate prediction of the onset of turbulent fluidization still remains elusive owing to the dependence of the transition velocity on several factors including measurement methods and interpretation of results. In this work, numerical simulations using the two fluid model (TFM) are performed in an attempt to predict the regime change reported by Gopalan etal.(2016) in a small scale pseudo-2D gas-solid fluidized bed containing Geldart D particles. Various time and frequency domain analyses were applied on predicted absolute and differential pressure time series data to reveal the bed dynamics. Numerical predictions of the transition velocity, Uc are in reasonably good agreement with experimental results from the small scale challenge problem. The literature correlations completely fail to predict the transition velocity for the system considered in this work. This work thus provides a different approach for validating the CFD model against experimental measurements.展开更多
The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidizat...The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidization to the literature under high temperature conditions.The experiments were carried out to evaluate the minimum fluidizing velocity over a vast range of temperature levels from 20℃ to 850℃ using silica sand with a particle size of 300-425μm,425-500μm,500-600μm,and 600-710μm.Furthermore,the variation in the minimumfluidized voidage was determined experimentally at the same conditions.The experimental data revealed that the Umf directly varied with particle size and inversely with temperature,whileεmf increases slightly with temperature based on the measurements of height at incipient fluidization.However,for all particle sizes used in this test,temperatures above 700℃ has a marginal effect on Umf.The results were compared with many empirical equations,and it was found that the experimental result is still in an acceptable range of empirical equations used.In which,our findings are not well predicted by the widely accepted correlations reported in the literature.Therefore,a new predicted equation has been developed that also accounts for the affecting of mean particle size in addition to other parameters.A good mean relative deviation of 5.473% between the experimental data and the predicted values was estimated from the correlation of the effective dimensionless group.Furthermore,the experimental work revealed that the minimum fluidizing velocity was not affected by the height of the bed even at high temperature.展开更多
Experiments have been carried out to investigate the effects of operating temperature(50 to 500℃)andpressure(1×10~5 to 8×10~5 Pa)on the transition from bubbling to turbulent fluidization by computer analysi...Experiments have been carried out to investigate the effects of operating temperature(50 to 500℃)andpressure(1×10~5 to 8×10~5 Pa)on the transition from bubbling to turbulent fluidization by computer analysisof the pressure fluctuation in dense phase.In order to reveal the influence of particle properties on the tran-sition process,eight kinds of particles were employed.A empirical correlaton which takes into accountthe effects of temperature and pressure is recommended for the prediction of transition展开更多
There are great interests to capture the CO2 to control the greenhouse gas emission.Amine absorption of CO2 is being taken as an effective way to capture CO2 in industry.However,the amine absorption of CO2 is cost-ine...There are great interests to capture the CO2 to control the greenhouse gas emission.Amine absorption of CO2 is being taken as an effective way to capture CO2 in industry.However,the amine absorption of CO2 is cost-ineffective due to great energy consumption and solution consumption.In order to reduce the capture cost,catalyst fluidization is proposed here to intensify the mass transfer and heat transfer.Catalyst fluidization with field synergy and DFT model is developed by incorporating the effects of catalyst reaction kinetics,drag force and multi-field into the mass transfer,heat transfer,fluid flow and catalyst collision.Experiments with an improved distributor are performed well to validate the model.The reaction kinetics is determined by the DFT simulation and experiment.The mass transfer coefficient in the fluidized reactor is identified as 17%higher than the conventional packed reactor.With the field synergy of catalyst fluidization,the energy consumption for CO2 desorption is reduced by 9%.Stepwise operation and inclination reactor are used to improve catalyst fluidization process.展开更多
Hydrodynamic features of gas-solid generalized fluidization can be well expressed in the form of phase diagrams,which are important for engineering design.Mesoscale structure presents almost universally in generalized...Hydrodynamic features of gas-solid generalized fluidization can be well expressed in the form of phase diagrams,which are important for engineering design.Mesoscale structure presents almost universally in generalized fluidization and should be considered in such phase diagrams.However,current phase diagrams were mainly proposed for cocurrent upward flow according to experimental data or empirical correlations with homogeneous assumption.The energy-minimization multiscale(EMMS)model has shown the capability of capturing mesoscale structure in generalized fluidization,so EMMS-based phase diagrams of generalized fluidization were proposed in this article,which describe more reasonable global hydrodynamics over all regimes including the important engineering phenomena of choking and flooding.These characteristics were also found in discrete particle simulation under various conditions.For wider range of application,the typical hydrodynamic parameters of the phase diagrams were correlated to non-dimensional numbers reflecting the effects of material properties and operation conditions.This study thus shows a possible route to develop a unified phase diagram in the future.展开更多
In the present paper,the experimental method and computational fluid dynamics(CFD)method were used to investigate the effect of gas distributors with different orifice sizes and orifice pitches on fluidization charact...In the present paper,the experimental method and computational fluid dynamics(CFD)method were used to investigate the effect of gas distributors with different orifice sizes and orifice pitches on fluidization characteristics in a gas-solid fluidized bed.The Euler-Euler two fluid model(TFM)approach based on the kinetic theory of granular flow(KTGF)and the standard k-epsilon turbulence model was employed in the numerical simulation by using ANSYS Fluent 15.0.The results showed that the orifice size and the orifice pitch of gas distributor had a significant influence on the flow characteristics in the gas-solid fluidized bed.With a decreasing orifice size and orifice pitch of gas distributor having the same opening area,the distributor pressure drop,the initial bubble size,and the height of dead zone just above the distributor were decreased,and the bed pressure drop was increased more than that of the larger orifice size and orifice pitch of distributors,the distribution of solid volume fraction was also more homogeneous for the smaller orifice size.展开更多
Fluidization characteristics of quartz particles with different sizes are experimentally investigated in a fluidized bed with an inner diameter of 300 mm and height of 8250 mm.Results show that the average solid holdu...Fluidization characteristics of quartz particles with different sizes are experimentally investigated in a fluidized bed with an inner diameter of 300 mm and height of 8250 mm.Results show that the average solid holdup increases with the increase in superficial gas velocity and the decrease in initial solid holdup in the dense zone of the fluidized bed.The average cross-sectional solid holdup decreases with increasing bed height and superficial gas velocity.The bed expansion coefficient increases with the increase in superficial gas velocity and the decrease in solid holdup.Correlations of average solid holdup,average cross-sectional solid holdup and bed expansion coefficient are also established and discussed.These correlations can provide guidelines for better understanding of the fluidization characteristics.展开更多
文摘We present a short retrospective review of the existing literature about the dynamics of(dry)granular matter under the effect of vibrations.The main objective is the development of an integrated resource where vital information about past findings and recent discoveries is provided in a single treatment.Special attention is paid to those works where successful synthetic routes to as-yet unknown phenomena were identified.Such landmark results are analyzed,while smoothly blending them with a history of the field and introducing possible categorizations of the prevalent dynamics.Although no classification is perfect,and it is hard to distillate general properties out of specific observations or realizations,two possible ways to interpret the existing results are defined according to the type of forcing or the emerging(ensuing)regime of motion.In particular,first results concerning the case where vibrations and gravity are concurrent(vertical shaking)are examined,then the companion situation with vibrations perpendicular to gravity(horizontal shaking)is described.Universality classes are introduced as follows:(1)Regimes where sand self-organizes leading to highly regular geometrical“pulsating”patterns(thin layer case);(2)Regimes where the material undergoes“fluidization”and develops an internal multicellular convective state(tick layers case);(3)Regimes where the free interface separating the sand from the overlying gas changes inclination or develops a kind a patterned configuration consisting of stable valleys and mountains or travelling waves;(4)Regimes where segregation is produced,i.e.,particles of a given size tend to be separated from the other grains(deep containers).Where possible,an analogy or parallelism is drawn with respect to the companion field of fluid-dynamics for which the assumption of“continuum”can be applied.
基金supported by Shandong Provincial Natural Science Foundation (ZR2023MB038)National Natural Science Foundation of China (21808232 and 21978143)Financial support from the Qingdao University of Science and Technology
文摘The homogeneous/particulate fluidization flow regime is particularly suitable for handling the various gas–solid contact processes encountered in the chemical and energy industry.This work aimed to extend such a regime of Geldart-A particles by exerting the axial uniform and steady magnetic field.Under the action of the magnetic field,the overall homogeneous fluidization regime of Geldart-A magnetizable particles became composed of two parts:inherent homogeneous fluidization and newly-created magnetic stabilization.Since the former remained almost unchanged whereas the latter became broader as the magnetic field intensity increased,the overall homogeneous fluidization regime could be extended remarkably.As for Geldart-A nonmagnetizable particles,certain amount of magnetizable particles had to be premixed to transmit the magnetic stabilization.Among others,the mere addition of magnetizable particles could broaden the homogeneous fluidization regime.The added content of magnetizable particles had an optimal value with smaller/lighter ones working better.The added magnetizable particles might raise the ratio between the interparticle force and the particle gravity.After the magnetic field was exerted,the homogeneous fluidization regime was further expanded due to the formation of magnetic stabilization flow regime.The more the added magnetizable particles,the better the magnetic performance and the broader the overall homogeneous fluidization regime.Smaller/lighter magnetizable particles were preferred to maximize the magnetic performance and extend the overall homogeneous fluidization regime.This phenomenon could be ascribed to that the added magnetizable particles themselves became more Geldart-A than-B type as their density or size decreased.
基金financial support from the National Natural Science Foundation of China (22078326,21878305,22078342)the financial supports of the National Key Research and Development Project of China (2020YFC1909701)。
文摘To break through the thermodynamic limitation that sodium fluosilicate only can be completely decomposed at high temperature,the technology of pre-decomposition under SiF_(4) atmosphere and deep decomposition under air condition at lower temperature was developed.The hydrolysis reaction of sodium fluosilicate can be effectively restrained when drying under vacuum or low temperature.Thermal decomposition results of sodium fluosilicate indicate that temperature has a very significant effect on its decomposition.The decomposition ratio can reach 79.4%at 600℃ for 1 h,and 99.6% at 700℃ for 1 h under air condition,respectively.Gas velocity and the type of inert gas have no significant effect on its decomposition.Fine particles affect its decomposition performance due to agglomeration,while coarse particles have good thermal decomposition performance without significant differences.The decomposition reaction process in fluidized bed satisfies the classical Avrami Erofe'EV model,with the reaction order of 1.5 and the activation energy of 61.35 kJ·mol^(-1).
基金supported by the open foundation of State Key Laboratory of Chemical Engineering (SKL–ChE–18B03)the Municipal Science and Technology Commission of Tianjin, China (2009ZCKFGX01900)。
文摘A liquid-solid circulating fluidized bed boiler is designed and built for visualization research by applying the fluidized bed heat transfer and fouling prevention technology to the water side of the boiler. Four types of engineering plastic particles with different physical properties are selected as the solid working media. The effect of particle types on the fluidization and distribution of particles in the boiler is investigated under different feedwater flow rates and amount of added particles by using the charge couple device image measurement and acquisition system. The results show that all kinds of particles can't be normally fluidized and accumulate in the drum at low amount of added particles and feedwater flow rate. The particles with great density and low sphericity are more likely to accumulate. The average solid holdup in the riser tubes increases with the increase in feedwater flow rate and the amount of added particles. The non-uniform degree of particle distribution in the riser tubes generally decreases with the increase in feedwater flow rate and the amount of added particles. The particles with small density and settling velocity have high average solid holdup in the riser tubes under close sphericity. In generally,the smaller the density and settling velocity, the more uniform the particle distribution in the riser tubes.Three-dimensional diagrams of the non-uniform degree of particle distribution in the riser tubes of the boiler are established.
基金supported by the Youth Program of National Natural Science Foundation of China(Grant No.52104012)the Key Program of the National Natural Science Foundation of China(Grant No.51734010)the Key Natural Science Projects of Scientific Research Plan in Colleges and Universities of Xinjiang Uygur Autonomous Region(Grant No.XJEDU20211028).
文摘The multiphase flow characteristic is one of the most concerning problems during solid fluidization exploitation of marine natural gas hydrate reservoirs.In this research,a new transient gas-liquid-solid multiphase flow model with hydrate phase transition was developed.Meanwhile,this model considered the coupling relationship among convective heat transfer,hydrate dynamic decomposition,and multi-phase flow.The model can simulate the change of flow pattern from solid-liquid to gas-liquid-solid flow,and describe the distribution character of volume fraction of phase,wellbore temperature and pressure,and hydrate decomposition rate during transportation.The simulation results indicate that the hydrate decomposition region in the wellbore gradually expands,but the hydrate decomposition rate gradually decreases during the solid fluidization exploitation of hydrate.When mining time lasts for 4 h,and the bottom hole pressure decreases by about 0.4 MPa.Increasing NaCl concentration in seawater helps expand hydrate decomposition regions and improves the wellbore hydrate decomposition rate.When the Nacl mass fraction in seawater reaches 15%,it will raise the hydrate decomposition regions to the whole wellbore.In addition,the higher the wellhead backpressure,the lower the decomposition area and decomposition rate of hydrate in the wellbore.When wellhead backpressure reaches 2 MPa,the volume fraction of gas near the wellhead will reduce to about 12%.This work is expected to provide a theoretical basis for the development of marine hydrate reservoirs.
基金supported by the National Natural Science Foundation of China(52336003,52206096,52176076)the Special Expert Project of Shandong Province Taishan Scholars Program(ts20190937).
文摘As a high-performance material with great application potential,the application of carbon nanotubes has been limited by their production volume.A distributor-less conical fluidized bed is the main equipment used in the industrial production of carbon nanotubes.To improve the production volume and product quality of carbon nanotubes,the study of fluidized-bed-diameter scaling is important.Three different diameters of distributor-less conical fluidized beds were established,and then the particle behavior and bubble characteristics of carbon nanotube clusters at these bed diameters were investigated.Time-series and wavelet analysis methods were used to analyze the pressure-fluctuation signals inside the fluidized beds.Results showed that the distributor-less design caused the airflow to break through the middle of the bed,which did not change with the change in bed diameter.The powder-bridging phenomenon of carbon nanotube clusters in a 100-mm-diameter fluidized bed was related to the special microstructure of carbon nanotube clusters.The frequency of pressure fluctuations in the bed decreased nonlinearly with increasing bed diameter.This study can guide the design and scale-up of distributor-less conical fluidized beds,especially for the scale-up of carbon nanotube production equipment,which can contribute to the improvement of carbon nanotubes’capacity and quality in industrial production.
基金support and encouragement of the Joint Funds of the National Natural Science Foundation of China(No.U21B2095)the Major Research Project of National Natural Science Foundation of China(No.91834303).
文摘This work investigated the pyrolysis reaction of waste resin in a fluidized bed reactor.It was found that the pyrolysis-generated ash would adhere to the surface of ceramic particles,causing particle agglomeration and defluidization.Adding kaolin could effectively inhibit the particle agglomeration during the fluidized pyrolysis reaction through physical isolation and chemical reaction.On the one hand,kaolin could form a coating layer on the surface of ceramic particles to prevent the adhesion of organic ash generated by the pyrolysis of resin.On the other hand,when a sufficient amount of kaolin(-0.2%(mass))was added,the activated kaolin could fully contact with the Na+ ions generated by the pyrolysis of resin and react to form a high-melting aluminosilicate mineral(nepheline),which could reduce the formation of low-melting-point sodium sulfate and thereby avoid the agglomeration of ceramic particles.
基金Financial support of this work by National Natural Science Foundation of China(51976037)。
文摘The particle residence time distribution(RTD)and axial dispersion coefficient are key parameters for the design and operation of a pressurized circulating fluidized bed(PCFB).In this study,the effects of pressure(0.1-0.6 MPa),fluidizing gas velocity(2-7 m·s^(-1)),and solid circulation rate(10-90 kg·m^(-2)·s^(-1))on particle RTD and axial dispersion coefficient in a PCFB are numerically investigated based on the multiphase particle-in-cell(MP-PIC)method.The details of the gas-solid flow behaviors of PCFB are revealed.Based on the gas-solid flow pattern,the particles tend to move more orderly under elevated pressures.With an increase in either fluidizing gas velocity or solid circulation rate,the mean residence time of particles decreases while the axial dispersion coefficient increases.With an increase in pressure,the core-annulus flow is strengthened,which leads to a wider shape of the particle RTD curve and a larger mean particle residence time.The back-mixing of particles increases with increasing pressure,resulting in an increase in the axial dispersion coefficient.
基金supported by the opening fund of State Key Laboratory of Coastal and Offshore Engineering at Dalian University of Technology(No.LP2310)the opening fund of State Key Laboratory of Geohazard Prevention and Geoenvironment Protection at Chengdu University of Technology(No.SKLGP2023K001)+2 种基金the Shandong Provincial Key Laboratory of Ocean Engineering with grant at Ocean University of China(No.kloe200301)the National Natural Science Foundation of China(Nos.42022052,42077272 and 52108337)the Science and Technology Innovation Serve Project of Wenzhou Association for Science and Technology(No.KJFW65).
文摘Deep-sea pipelines play a pivotal role in seabed mineral resource development,global energy and resource supply provision,network communication,and environmental protection.However,the placement of these pipelines on the seabed surface exposes them to potential risks arising from the complex deep-sea hydrodynamic and geological environment,particularly submarine slides.Historical incidents have highlighted the substantial damage to pipelines due to slides.Specifically,deep-sea fluidized slides(in a debris/mud flow or turbidity current physical state),characterized by high speed,pose a significant threat.Accurately assessing the impact forces exerted on pipelines by fluidized submarine slides is crucial for ensuring pipeline safety.This study aimed to provide a comprehensive overview of recent advancements in understanding pipeline impact forces caused by fluidized deep-sea slides,thereby identifying key factors and corresponding mechanisms that influence pipeline impact forces.These factors include the velocity,density,and shear behavior of deep-sea fluidized slides,as well as the geometry,stiffness,self-weight,and mechanical model of pipelines.Additionally,the interface contact conditions and spatial relations were examined within the context of deep-sea slides and their interactions with pipelines.Building upon a thorough review of these achievements,future directions were proposed for assessing and characterizing the key factors affecting slide impact loading on pipelines.A comprehensive understanding of these results is essential for the sustainable development of deep-sea pipeline projects associated with seabed resource development and the implementation of disaster prevention measures.
基金the National Natural Science Foundation of China(22078326,21878305,21908227)。
文摘In order to avoid the formation ofηphase(W_(6)Co_(6)C or W_(3)Co_(3)C)that adversely affects the sintering process and its products in the preparation process of ultra-fine WC-Co powder,a technical route of prereduction of WO_(3)-Co_(3)O_(4)to WO_(2)-Co and then deep reduction carbonization to WC-Co powder has been proposed.This study mainly investigates the influence of gas partial pressure on the pre-reduction process of WO_(3)-Co_(3)O_(4)under a mixed atmosphere of H_(2)-C_(2)H_(4)-Ar at 600℃and establishes the kinetic equations of pre-reduction and carbon evolution.The results indicate that increasing the partial pressure of hydrogen is conducive to the rapid and complete conversion of WO_(3) to WO_(2).High carbon content can be generated by the deposition of C_(2)H_(4),and it hinders the diffusion of the reducing gas;WO_(3)still cannot be completely reduced to WO_(2)as the partial pressure of C_(2)H_(4) increases to 60%.For the carbon evolution of C_(2)H_(4),the carbon amount is positively related to the H_(2)partial pressure,but it shows the highest amount and evolution rate when the ethylene partial pressure is 20%.Based on the reduction rate curves of WO_(3) and carbon evolution rate curves of C_(2)H_(4),the rate equations of pre-reduction and carbon evolution of WO_(3)-Co_(3)O_(4)system at 600℃are established.The pre-reduction reaction belongs to the first-order reaction,and its equation is expressed as follows:r=-(dw_(WO_(3)))/dt=(9±0.15)×10^(-2)×P_(H_(2))^(0.44)P_(C_(2)H_(4))&(0.57)The carbon deposition rate equation of C_(2)H_(4) can be expressed as follows:r=-(dc_C)/dt=r_f-r_b≌7.35×10^(-2)×P_(C_(2)H_(4))^(0.31)
文摘This research entails the study of heat and mass transfer of nanofluid flow in a fluidized bed dryer used in tea drying processes in presence of induced magnetic field. A mathematical model describing the fluid flow in a Fluidized bed dryer was developed using the nonlinear partial differential equations. Due to their non-linearity, the equations were solved numerically by use of the finite difference method. The effects of physical flow parameters on velocity, temperature, concentration and magnetic induction profiles were studied and results were presented graphically. From the mathematical analysis, it was deduced that addition of silver nanoparticles into the fluid flow enhanced velocity and temperature profiles. This led to improved heat transfer in the fluidized bed dryer, hence amplifying the tea drying process. Furthermore, it was noted that induced magnetic field tends to decrease the fluid velocity, which results in uniform distribution of heat leading to efficient heat transfer between the tea particles and the fluid, thus improving the drying process. The research findings provide information to industries on ways to optimize thermal performance of fluidized bed dryers.
基金the National Natural Science Foundation of China (grant No. 40032010B).
文摘Fluidization processes based on experiments are reviewed to gain some useful insights and comparisons with those that occur in hydrothermal systems. Field and petrographic work, and microscope observation were carried out on samples from the Qiyugou Au-bearing breccia pipes from the East Qinling region, Henan Province. Evidence from macro- and micro-textures suggests that the style of breccias in the Qiyugou area can be grouped into three types: (1) jigsaw fit-stockwork texture, in which the interval between clasts is marked by fractures or filled with calcite or quartz veins; (2) larger breccias that are supported by smaller breccias, rock flour and alteration materials; in this type clasts moved over short distances, creating open spaces; (3) fluidized texture, where the clasts of different lithologies have rounded shapes. These observations are compared with those resulting from experiments on fluidization processes. The results of this comparison suggest that fluidization is an important geological process in the formation of the Qiyugou Au-bearing breccia pipes and gold mineralization. In addition, fluidization processes such as expansion, bubbling, slugging, channeling and spouting must have contributed to the formation of the pipes and were conducive to the development of gold mineralization. In the Qiyugou breccia pipes, gold mineralization occurs as disseminations, in stockwork veins, and open space infills. The ore zones form subparallel sheets that are nearly perpendicular to the walls of the pipes.
基金Supported by the National Natural Science Foundation of China(21576263,21625605,91334204)the Youth Innovation Promotion Association CAS(2015033)
文摘The EMMS/bubbling model originally proposed for fluidization of monodisperse particles is extended to fluidization of binary particle mixture in this study.The dense and dilute phases are considered to comprise of two types of particles differing in size and/or density.Governing equations and the stability condition are then formulated and solved by using an optimization numerical scheme.The effects of bubble diameter are first investigated and a suitable bubble diameter correlation is chosen.Preliminary validation for steady state behavior shows the extended model can fairly capture the overall hydrodynamic behaviors in terms of volume fraction of bubbles and average bed voidage for both monodisperse and binary particle systems.This encourages us to integrate this model with CFD for more validations in the future.
基金Supported by the National Natural Science Foundation of China(91434205)the National Science Fund for Distinguished Young(21525627)+1 种基金the Natural Science Foundation of Zhejiang Province(LR14B060001)the Specialized Research Fund for the Doctoral Program of Higher Education of China(20130101110063)
文摘Accurate prediction of the onset of turbulent fluidization still remains elusive owing to the dependence of the transition velocity on several factors including measurement methods and interpretation of results. In this work, numerical simulations using the two fluid model (TFM) are performed in an attempt to predict the regime change reported by Gopalan etal.(2016) in a small scale pseudo-2D gas-solid fluidized bed containing Geldart D particles. Various time and frequency domain analyses were applied on predicted absolute and differential pressure time series data to reveal the bed dynamics. Numerical predictions of the transition velocity, Uc are in reasonably good agreement with experimental results from the small scale challenge problem. The literature correlations completely fail to predict the transition velocity for the system considered in this work. This work thus provides a different approach for validating the CFD model against experimental measurements.
文摘The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidization to the literature under high temperature conditions.The experiments were carried out to evaluate the minimum fluidizing velocity over a vast range of temperature levels from 20℃ to 850℃ using silica sand with a particle size of 300-425μm,425-500μm,500-600μm,and 600-710μm.Furthermore,the variation in the minimumfluidized voidage was determined experimentally at the same conditions.The experimental data revealed that the Umf directly varied with particle size and inversely with temperature,whileεmf increases slightly with temperature based on the measurements of height at incipient fluidization.However,for all particle sizes used in this test,temperatures above 700℃ has a marginal effect on Umf.The results were compared with many empirical equations,and it was found that the experimental result is still in an acceptable range of empirical equations used.In which,our findings are not well predicted by the widely accepted correlations reported in the literature.Therefore,a new predicted equation has been developed that also accounts for the affecting of mean particle size in addition to other parameters.A good mean relative deviation of 5.473% between the experimental data and the predicted values was estimated from the correlation of the effective dimensionless group.Furthermore,the experimental work revealed that the minimum fluidizing velocity was not affected by the height of the bed even at high temperature.
文摘Experiments have been carried out to investigate the effects of operating temperature(50 to 500℃)andpressure(1×10~5 to 8×10~5 Pa)on the transition from bubbling to turbulent fluidization by computer analysisof the pressure fluctuation in dense phase.In order to reveal the influence of particle properties on the tran-sition process,eight kinds of particles were employed.A empirical correlaton which takes into accountthe effects of temperature and pressure is recommended for the prediction of transition
基金Supported by the National Natural Science Foundation of China(51506165 and21736008)the Natural Science Basic Research Plan in Shaanxi Province of China(2015JQ5192)Fundamental Research Funds for the Central Universities
文摘There are great interests to capture the CO2 to control the greenhouse gas emission.Amine absorption of CO2 is being taken as an effective way to capture CO2 in industry.However,the amine absorption of CO2 is cost-ineffective due to great energy consumption and solution consumption.In order to reduce the capture cost,catalyst fluidization is proposed here to intensify the mass transfer and heat transfer.Catalyst fluidization with field synergy and DFT model is developed by incorporating the effects of catalyst reaction kinetics,drag force and multi-field into the mass transfer,heat transfer,fluid flow and catalyst collision.Experiments with an improved distributor are performed well to validate the model.The reaction kinetics is determined by the DFT simulation and experiment.The mass transfer coefficient in the fluidized reactor is identified as 17%higher than the conventional packed reactor.With the field synergy of catalyst fluidization,the energy consumption for CO2 desorption is reduced by 9%.Stepwise operation and inclination reactor are used to improve catalyst fluidization process.
基金financial supports from the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA21040400)the Innovation Academy for Green manufacture,the Chinese Academy of Sciences(IAGM-2019-A03)the National Natural Science Foundation of China(91834303)。
文摘Hydrodynamic features of gas-solid generalized fluidization can be well expressed in the form of phase diagrams,which are important for engineering design.Mesoscale structure presents almost universally in generalized fluidization and should be considered in such phase diagrams.However,current phase diagrams were mainly proposed for cocurrent upward flow according to experimental data or empirical correlations with homogeneous assumption.The energy-minimization multiscale(EMMS)model has shown the capability of capturing mesoscale structure in generalized fluidization,so EMMS-based phase diagrams of generalized fluidization were proposed in this article,which describe more reasonable global hydrodynamics over all regimes including the important engineering phenomena of choking and flooding.These characteristics were also found in discrete particle simulation under various conditions.For wider range of application,the typical hydrodynamic parameters of the phase diagrams were correlated to non-dimensional numbers reflecting the effects of material properties and operation conditions.This study thus shows a possible route to develop a unified phase diagram in the future.
基金supported by the China Ocean Mineral Resources Research&Development Program(DY125-15-T-08)the National Natural Science Foundation of China(21176026,21176242)。
文摘In the present paper,the experimental method and computational fluid dynamics(CFD)method were used to investigate the effect of gas distributors with different orifice sizes and orifice pitches on fluidization characteristics in a gas-solid fluidized bed.The Euler-Euler two fluid model(TFM)approach based on the kinetic theory of granular flow(KTGF)and the standard k-epsilon turbulence model was employed in the numerical simulation by using ANSYS Fluent 15.0.The results showed that the orifice size and the orifice pitch of gas distributor had a significant influence on the flow characteristics in the gas-solid fluidized bed.With a decreasing orifice size and orifice pitch of gas distributor having the same opening area,the distributor pressure drop,the initial bubble size,and the height of dead zone just above the distributor were decreased,and the bed pressure drop was increased more than that of the larger orifice size and orifice pitch of distributors,the distribution of solid volume fraction was also more homogeneous for the smaller orifice size.
文摘Fluidization characteristics of quartz particles with different sizes are experimentally investigated in a fluidized bed with an inner diameter of 300 mm and height of 8250 mm.Results show that the average solid holdup increases with the increase in superficial gas velocity and the decrease in initial solid holdup in the dense zone of the fluidized bed.The average cross-sectional solid holdup decreases with increasing bed height and superficial gas velocity.The bed expansion coefficient increases with the increase in superficial gas velocity and the decrease in solid holdup.Correlations of average solid holdup,average cross-sectional solid holdup and bed expansion coefficient are also established and discussed.These correlations can provide guidelines for better understanding of the fluidization characteristics.