Hydrothermal Systems Characterized by Crustal Thermally-dominated Structures of Southeastern China

Southeastern China(SE China)is located in the Pacific tectonic domain and has experienced a series of tectono-magmatic events induced by the subduction of the Paleo-Pacific Plate since the late Mesozoic.The subduction formed a series of NE-NNE oriented faults under a NW-SE regional stress field,along which a number of thermal springs occur.Previous studies have focused on the genesis mechanism of specific geothermal fields in SE China,but the general characteristics of hydrothermal systems in SE China remains unclear.In this study,we investigate the correlation between geothermal activity,hydrochemical type and regional faults by studying the distribution of hydrothermal activity and geochemical properties of typical hydrothermal systems in SE China.The hydrothermal systems in SE China have a crustal thermally-dominated structural origin unique to the specific geological and tectonic conditions of the Eurasian Plate margin.The upwelling of the asthenosphere and the widespread granitoids with high radiogenic heat production in SE China provide major heat sources for regional geothermal anomalies.The NE-oriented crustal thermally-dominated faults are critical for the formation of geothermal anomalies and NW-oriented extensional faults have created favorable conditions for meteoric water infiltration,transportation and the formation of thermal springs.

Three Stages of Mesozoic Bimodal Igneous Rocks and Their Tectonic Implications on the Continental Margin of Southeastern China

There are large-scale Mesozoic bimodal igneous rock associations on the continental margin of southeastern China. They aroused extensive attention in the 1980s because of their specific tectonic implications, and have been found frequently during recent geological surveys. This paper reviews the studies of regional Mesozoic bimodal rocks, and concludes that they can be subdivided into three stages, i.e., the Early Jurassic (209-170 Ma, the first (Ⅰ) stage), the Late Jurassic-early Early Cretaceous (154-121 Ma, the second (Ⅱ) stage), and the late Early Cretaceous-Late Cretaceous (115-85 Ma, the third (Ⅲ) stage). These three stages of bimodal rocks were formed in different tectonic settings, and are important indicators for regional Mesozoic tectonic evolution.

Post-Mesozoic Transformation of Tectonic Domain in Southeastern China and Its Geodynamic Mechanism

Since the Mesozoic and Cenozoic, a transformation from a Tethyan Himalayan tectonic domain into a circum Pacific tectonic domain from Indosinian to Yanshanian is indicated in this paper, resulting in conspicuous changes in geophysics, tectono magmatic distribution, lithofacies and paleo geography, tectonic system in southeastern China. Tectonic analysis shows that the tectonic framework resulted from the compounding, transforming and superimposing of the two tectonic domains. The geodynamic mechanism of the transformation is mainly shown as the transverse and longitudinal heterogeneity of lithosphere, and the exchange between the crust and the mantle.

Sources of Cretaceous Bimodal Volcanic Rocks in the Coastal Region of Southeastern China -- Constrains of the Sr content and its isotopes

Cretaceous volcanism in the coastal region of southeastern China was characteristized by occurrenceof bimodal volcanics consisting of basalts and rhyolites, the geneses of which are still controversial. Based on the factthat their isotopic compositions are similar but the Sr content of the former is much higher than that of the latter, thispaper discusses the respective sources of the two end-member rocks, and concludes that basalts were derived fromthe subduction-related enriched upper mantle wedge and their isotopic compositions had not been affected by crustalassimilation, whereas rhyolites were formed by remelting of the old metamorphic basement, but they were mixed upwith the underplating basaltic magmas to various degrees so that their Sr isotopic compositions varied significantlyfrom the sources and tended to be homogeneous to the latter.

Early Cretaceous Magma Mingling in Xiaocuo,Southeastern China Continental Margin:Implications for Subduction of Paleo-Pacific Plate

Magma mingling has been identified within the continental margin of southeastern China.This study focuses on the relationship between mafic and felsic igneous rocks in composite dikes and plutons in this area,and uses this relationship to examine the tectonic and geodynamic implications of the mingling of mafic and felsic magmas.Mafic magmatic enclaves（MMEs） show complex relationships with the hosting Xiaocuo granite in Fujian area,including lenticular to rounded porphyritic microgranular enclaves containing abundant felsic/mafic phenocrysts,elongate mafic enclaves,and back-veining of the felsic host granite into mafic enclaves.LA-ICP-MS zircon U-Pb analyses show crystallization of the granite and dioritic mafic magmatic enclave during ca.132 and 116 Ma.The host granite and MMEs both show zircon growth during repeated thermal events at-210 Ma and 160-180 Ma.Samples from the magma mingling zone generally contain felsic-derived zircons with well-developed growth zoning and aspect ratios of 2-3,and maficderived zircons with no obvious oscillatory zoning and with higher aspect ratios of 5-10.However,these two groups of zircons show no obvious trace element or age differences.The Hf-isotope compositions show that the host granite and MMEs have similar ε（Hf）（t） values from negative to positive which suggest a mixed source from partial melting of the Meso-Neoproterozoic with involvement of enriched mantlederived magmas or juvenile components.The lithologies,mineral associations,and geochemical characteristics of the mafic and felsic rocks in this study area indicate that both were intruded together,suggesting Early Cretaceous mantle—crustal interactions along the southeastern China continental margin.The Early Cretaceous magma mingling is correlated to subduction of Paleo-Pacific plate.

First Report LA-ICP-MS Zircon U-Pb Age of Early Jurassic Volcanic Rocks from Rencha Volcanic Basin, Northeast Guangdong Province, Southeastern China

Objective Most scholars agreed that the tectonic setting of South China block（SBC）changed from Tethys during the Indosinian to Pacific tectonic regime in the Yanshanian.However,the specific change time for the transition is still in debate and the Triassic to Jurassic magmatic activity will provide a clue to better understanding the transition.

Cloud-Base Distribution and Cirrus Properties Based on Micropulse Lidar Measurements at a Site in Southeastern China

The cloud fraction （CF） and cloud-base heights （CBHs）, and cirrus properties, over a site in southeastern China from June 2008 to May 2009, are examined by a ground-based lidar. Results show that clouds occupied the sky 41% of the time. Significant seasonal variations in CF were found with a maximum/minimum during winter/summer and similar magnitudes of CF in spring and autumn. A distinct diurnal cycle in the overall mean CF was seen. Total, daytime, and nighttime annual mean CBHs were 3.05 ± 2.73 km, 2.46 ± 2.08 kin, and 3.51 ± 3.07 km, respectively. The lowest/highest CBH occurred around noon/midnight. Cirrus clouds were present ～36.2% of the time at night with the percentage increased in summer and decreased in spring. Annual mean values for cirrus geometrical properties were 8.89 ± 1.65 km, 9.80 ± 1.70 kin, 10.73 ± 1.86 km and 1.83± 0.91 km for the base, mid-cloud, top height, and the thickness, respectively. Seasonal variations in cirrus geometrical properties show a maximum/minimum in summer/winter for all cirrus geometrical parameters. The mean cirrus lidar ratio for all cirrus cases in our study was ～ 25 ± 17 sr, with a smooth seasonal trend. The cirrus optical depth ranged from 0.001 to 2.475, with a mean of 0.34 ± 0.33. Sub-visual, thin, and dense cirrus were observed in ～12%, 43%, and 45% of the cases, respectively. More frequent, thicker cirrus clouds occurred in summer than in any other season. The properties of cirrus cloud over the site are compared with other lidar-based retrievals of midlatitude cirrus cloud properties.

First Surface-based Estimation of the Aerosol Indirect Effect over a Site in Southeastern China

The deployment of the U.S. Atmospheric Radiation Measurement mobile facility in Shouxian from May to December 2008 amassed the most comprehensive set of measurements of atmospheric, surface, aerosol, and cloud variables in China. This deployment provided a unique opportunity to investigate the aerosol-cloud interactions, which are most challenging and, to date, have not been examined to any great degree in China. The relationship between cloud droplet effective radius （CER） and aerosol index （AI） is very weak in summer because the cloud droplet growth is least affected by the competition for water vapor. Mean cloud liquid water path （LWP） and cloud optical depth （COD） significantly increase with increasing AI in fall. The sensitivities of CER and LWP to aerosol loading increases are not significantly different under different air mass conditions. There is a significant correlation between the changes in hourly mean AI and the changes in hourly mean CER, LWP, and COD. The aerosol first indirect effect （FIE） is estimated in terms of relative changes in both CER （FIEcER） and COD （FIEcoD） with changes in AI for different seasons and air masses. FIEcoD and FIEcER are similar in magnitude and close to the typical FIE value of - 0.23, and do not change much between summer and fall or between the two different air mass conditions. Similar analyses were done using spaceborne Moderate Resolution Imaging Spectroradiometer data. The satellite-derived FIE is contrary to the FIE estimated from surface retrievals and may have large uncertainties due to some inherent limitations.

Sr and Nd Isotopic Characteristics and Magma Genesis of Mesozoic Volcanic Rocks Along the Coastal Region of Southeastern China

The Mesozoic volcanic rocks in the coastal region of southeastern China were superimposed on some different basement tectonic elements. The volcanic rocks developed in these different basement tectonic elements have great differences in Sr and Nd isotopic compositions. The rocks in western Zhejiang and northeastern Jiangxi Provinces which belong to the Lower Yangtze subplate have lower initial 87Sr/ 86Sr ratios, but are higher in initial Nd isotopic ratios. The initial 143Nd / 144Nd values of the volcanic rocks developed in the Cathaysian subplate increase clearly from early to late in time, and from the core of the Wuyishan uplift coastwards constantly, but the initial 87Sr/86Sr values tend to decrease. The isotopic characteristics and their spatial variations in Mesozoic volcanic rocks in the study region are, to a great extent, manifestations of the isotopic characteristics in basement metamorphic complexes, and the generation of the Mesozoic acid magma in this region is attributed to the recycling of pre-existing crustal materials.

Minerogenetic Model for Two Types of Fluorite Deposits in Southeastern China

On the basis of the studies of field geology, strontium, hydrogen and oxygen isotopes and REEgeochemistry, coupled with the dating of mineralization, the authors suggest a minerogenetic model of circula-tion and drawing of Late Cretaceous geothermal waters for the fluorite deposits in southeastern China. Thismodel includes two types of mechanism: 1) the leaching-out and drawing through deep circulation of thegeothermal water, and 2) the leaching-out and drawing through shallow circulation of the water. The fluoritemineralization of Mesozoic volcanic rock terrain is related mainly to the former mechanism, with the mineraliz-ing material coming chiefly from the Precambrian metamorphic rocks of the basement underlying the hostrocks; while that of Yanshanian granite terrain is associated with the latter mechanism, with the mineralizingmaterial derived primarily from the host granites and sedimentary rocks.

LATE MESOZOIC SUBDUCTION PROCESS BENEATH SOUTHEASTERN CHINA AS REVEALEDBY THE SPATIAL- TEMPORAL PATTERN OFMAGMATISM

Southeastern China covers an extensive area from the lowerreaches of the Yangtze Riverto the southeast coastof China mainland.One of its main geological features isthe extensiveJura- Cretaceous (Yanshanian) magmatism and related metallogenesis. Recently,some re-searchers advocate the mantle plume model as an explanation,but all of their evidences artoo ambiguous.Meanwhile,the seaward convex shape of the SE China coastline,which isdominantly composed of Jura- Cretaceous batholiths and volcanic strata,implies thatit was aconvergent margin between SE China continent and the palaeo- Pacific plate during the lateMesozoic era.Fora betterunderstanding on the relation among magmatism,tectonic regimeand dynamics,the spatial- temporal pattern of late Mesozoic (180 - 90 Ma) igneous rocks isconstructed by nearly2 0 0 isotope age valuesfrom literatures.Among these age values,mostwere obtained by Rb- Sr isochron method,and others from zircon U- Pb or40 Ar- 3

Resource and Environmental Quality Changes and Adjustment Principles for Sustainable Development in Rapidly Developing Coastal Region of Southeastern China

Problems in water-land resources and environmental quality increase with the fast economic development in the coastal region of southeastern China. This region has the highest density in population, industry and towns in China, and the large export-oriented economy makes itself a strategic importance while China enters into international markets. The problems facing to this region include arable land reduction, land degradation aggravation, high percentage of built-up land with high rate of expansion, expanded non-point pollution, deteriorated water quality, decreasing biodiversity, destroyed ecosystems, severe air pollution, frequently occurred acid rain, and multi-pollutants. The important research fields in the near future should include a) influence of high-intensity exploitation of resources on changes of environment quality and its feedback; b) interface processes, key mechanisms and adjustment principles for degradation of water-, land-, and air-resources and environmental quality; c) evolvement processes and nurturing theory of biodiversity and ecological resources; and d) spatio-temporal variation and human-induced effects on regional resources and environment quality. Strategies for sustainable development in the region are as follows: a) controlling to ensure basic cultivated land area; b) enforcing remediation of polluted water environment, and controlling non-point pollution; c) strengthening ecological construction and ecological security; and d) controlling multi-pollution and preventing trace toxic pollutants.

Identification of ^(137)Cs Reference Sites in Southeastern China

The 137Cs vertical distributions in uncultivated and cultivated soils, developed from Quaternary red clay, granite, argillaceous shale, and red sandstone, were studied to develop reliable guidelines for selecting reference sites in southeastern China, which is dominated by strong acidic and/or clay-textured soils, and examine their reliability by comparing them to the reported 137Cs reference inventory data to see whether they agreed with the global distribution pattern. It was observed that a relatively high proportion of 137Cs was concentrated in the surface layers of soils with relatively high clay content. In the paddy soils developed from granite more 137Cs penetrated to depths below the plow layer (about 45.3%), when compared to those from the other three parent materials. The relatively low soil 137Cs inventories on crests excluded using the crest as the 137Cs reference site; instead the paddy field on the hillock plain was selected. Furthermore, within a specific county characterized by great systematic spatial variations of rainfall and topography across the landscape, a significant (P<0.01) and positive linear relationship (r2=0.81) between local 137Cs inventory and corresponding local annual rainfall was observed. Thus, for areas with large variations in rainfall, a single uniform value of local 137Cs reference inventory should be used with caution.

Bioavailability of heavy metals in soil of the Tieguanyin tea garden, southeastern China

The bioavailability of 22 heavy metals was investigated at 19 sampling sites in Tieguanyin tea garden in Anxi County,Fujian Province,southeastern China.Heavy metal concentrations were determined by inductively coupled plasma-mass spectrometry(ICP-MS)and evaluated by geo-accumulation index(I_(geo)).Dilute nitric acid extraction was used to evaluate biological activity.Cu,Pb,and Cd were highly bioavailable and most easily absorbed by tea trees.Heavy metal bioavailability in the surface soil was as the ratio of the effective state to the total amount.Cd had the highest I_(geo)values,and the respective samples and sites were classified as moderately/strongly contaminated.Cd element is considered the main factor of heavy metal pollution in the tea garden in Anxi.The other heavy metals studied were present in lower concentrations;thus,the samples were classified as uncontaminated or slightly contaminated.

SHRIMP Geochronology of Volcanics of the Zhangjiakou and Yixian Formations, Northern Hebei Province, with a Discussion on the Age of the Xing'anling Group of the Great Hinggan Mountains and Volcanic Strata of the Southeastern Coastal Area of China

A zircon U-Pb geochronological study on the volcanic rocks reveals that both of the Zhangjiakou and Yixian Formations, northern Hebei Province, are of the Early Cretaceous, with ages of 135-130 Ma and 129-120 Ma, respectively. It is pointed out that the ages of sedimentary basins and volcanism in the northern Hebei -western Liaoning area become younger from west to east, i. e. the volcanism of the Luanping Basin commenced at c. 135 Ma, the Luotuo Mount area of the Chengde Basin c. 130 Ma, and western Liaoning c. 128 Ma. With a correlation of geochronological stratigraphy and biostratigraphy, we deduce that the Xing'anling Group, which comprises the Great Hinggan Mountains volcanic rock belt in eastern China, is predominantly of the early-middle Early Cretaceous, while the Jiande and Shimaoshan Groups and their equivalents, which form the volcanic rock belt in the southeastern coast area of China, are of the mid-late Early Cretaceous, and both the Jehol and Jiande Biotas are of the Early Cretaceous, not Late Jurassic or Late Jurassic-Early Cretaceous. Combining the characteristics of the volcanic rocks and, in a large area, hiatus in the strata of the Late Jurassic or Late Jurassic-early Early Cretaceous between the formations mentioned above and the underlying sequences, we can make the conclusion that, in the Late Jurassic-early Early Cretaceous, the eastern China region was of high relief or plateau, where widespread post-orogenic volcanic series of the Early Cretaceous obviously became younger from inland in the west to continental margin in the east. This is not the result of an oceanward accretion of the subduction belt between the Paleo-Pacific ocean plate and the Asian continent, but rather reflects the extension feature, i.e. after the closure of the Paleo-Pacific ocean, the Paleo-Pacific ancient continent collided with the Asian continent and reached the peak of orogenesis, and then the compression waned and resulted in the retreating of the post-orogenic extension from outer orogenic zone to inner part (or collision zone). The determination of the eruption age of the volcanics of the Zhangjiakou Formation definitely constrains the switch period, which began in the Indosinian and finished in the Yanshanian, that is, 140-135 Ma. The switch is concretely the change from the approximate E-W Paleo-Asian tectonic system to the NE to NNE Pacific system, and the period is also the apex of a continent-continent collision and orogenesis of subduction, being consumed and eventually disappearing of the Paleo-Pacific ancient continent, and all the processes commenced in the Indosinian. While the following post-orogenic large-scale eruption in the Early Cretaceous marks the final completeness of the Paleo-Pacific structure dynamics system.

Melt-Lithosphere Interaction Controlled Compositional Variations in Mafic Dikes from Fujian Province,Southeastern China

Late Mesozoic magmatism in southeastern China has been widely considered to be related to the subduction of the Paleo-Pacific Plate.However,it remains controversial whether mafic rocks are derived from the lithosphere or the asthenosphere.Here we present a comprehensive study on mafic dikes from Fujian Province in southeastern China,aiming to understand their source.Two types of mafic rocks have been recognized based on their trace-element features.Type-Ⅰrocks show arc-like trace-elemental characteristics,while type-Ⅱrocks are distinguished by their relatively flat patterns in primitive-mantle-normalized trace-element diagram.Despite such differences between two types of rocks,these mafic dikes show two trends in the plots of^(87)Sr/^(86)Sr(i)versus La/Nb,which can be explained by the influences of crustal contamination and melt-lithospheric mantle interaction,respectively.^(87)Sr/^(86)Sr(i),La/Nb,Sr/Y and Zr/Y ratios of type-I rocks are significantly correlated to the thickness of the underlying lithosphere,and the signals of lithosphere are clearer with increasing lithospheric thickness.This highlights the important influences of melt-lithosphere interaction during their formation.Such observations also indicate that these mafic rocks are more likely to have been originated from the asthenosphere rather than the lithospheric mantle.

Distinctive impacts of atmospheric intraseasonal oscillations on the net ecosystem exchange of the southeastern China forest between spring and summer

The southeastern China(SEC)forest is an important terrestrial biospheric carbon sink in the global carbon cycle,with its total net ecosystem exchange(NEE)accounting for about 3.2%of the global forest NEE.The prevailing atmospheric intraseasonal oscillations(ISOs)over East Asia strongly modulate climatic conditions over the SEC during spring and summer,thus leading to significant ISOs in the NEE of the SEC forest.As atmospheric ISOs show strong seasonality,this study examined the distinctive impacts of atmospheric ISOs on the NEE of the SEC forest between spring and summer.During spring,the vertical coupling of 10–30-d atmospheric ISOs in the lower and upper troposphere leads to strong 10‒30-d ISOs of solar radiation and temperature over the SEC.The 10‒30-d ISOs of solar radiation and temperature further result in the 10‒30-d ISOs of gross primary productivity(GPP)and terrestrial ecosystem respiration(TER).With the covariation in GPP and TER,the NEE of the SEC forest exhibits significant 10‒30-d ISOs.In contrast,the intraseasonal variations in climatic conditions over the SEC are associated with the 15‒60-d tropical atmospheric ISO during summer.While the induced 15‒60-d ISO of solar radiation leads to that of GPP,the induced 15‒60-d ISO of temperature is small and less effective;thus,the 15‒60-d ISO of NEE mainly originates from that of GPP.

The distribution, hydrocarbon potential, and development of the Lower Cretaceous black shales in coastal southeastern China

Lower Cretaceous black shales in coastal southeastern China are of significance to the geological study of the Tethys and Pacific realms and to hydrocarbon exploration of southeastern China and East China Sea. However, the stratigraphic correlation, distribution patterns and hydrocarbon potential of the black shales have not been well constrained so far. In this study, the zircon UePb ages, organic petrologic and geochemical analyses were performed for representative outcrop sections in the region. Zircon UePb ages demonstrate that the Lower Cretaceous black shales in coastal southeastern China can be divided into two regional-scale sets. The first set was deposited during the early stage of the Early Cretaceous（K_1~1, BerriasianeHauterivian）. The second set was deposited during the late stage of the Early Cretaceous（K_1~2）, and might extend to the Taiwan Strait. Detailed organic geochemical analyses including organic matter abundance, type and maturity of the Lower Cretaceous black shales demonstrate that the organic matter abundance of the sources reached medium to good quality by the hydrocarbon source rock standards, and the average TOC values and the chloroform bitumen ＂A＂ of the K_1~1 black shales are higher. The type of organic matter is mainly type III, type II can also be found from the K_1~2 black shales. The thermal maturity of most samples is high to overmature. A relatively comprehensive hydrocarbon resource evaluation indicates that favorable regions are in the northern Guangdong Province for the K_1~1 and in the coastal region of Zhejiang Province and the westernFujian Province for the K_1~2. Sedimentology studies on the Shipu section for the K_1~1 black shales illuminated that the K_1~2 black shales in coastal southeastern China were mainly deposited during transgressive period. The relative sea level changes controlled the sequential development pattern of the K_1~2 black shales.

Solenites (Czekanowskiales) from the Late Mesozoic Jehol Biota of Southeastern Jilin,China and its Paleoclimatic Implications

Situated at the easternmost area of the Late Mesozoic Jehol Biota, China, abundant fossils, including invertebrates, vertebrates and plants, were collected from the Early Cretaceous Yingzuilazi Formation of the Baishan Basin, southeastern Jilin. The faunal remains from this formation distinctly belong to the Early Cretaceous Lycoptera-Ephemeropsis-Eosestheria assemblage of the Jehol Biota. Based on the gross leaf morphology and epidermal structures, two new species and one indeterminate species of genus Solenites （Czekanowskiales）, S. baishanensis sp. nov., S. gracilis sp. nov. and S. sp. are described in this paper. This is the first fossil plant of Czekanowskiales reported from this new fossil locality of the easternmost area of the Late Mesozoic Jehol Biota, China. The new discovery contributes to improve our knowledge for understanding of leaf morphology, epidermal characters and diversity of this genus during the Early Cretaceous time, and extends geologic and geographic distribution of Solenites in northern China and Eurasia. Along with consideration of associated plant and faunal assemblages and sedimentology, we suggest that the regional climate was warm and moderately humid with seasonal temperature and precipitation variations in warm-temperate zone during the Early Cretaceous.