Relationship between spatio-temporal evolution of soil pH and geological environment/surface cover in the eastern Nenjiang River Basin of Northeast China during the past 30 years

To illuminate the spatio-temporal variation characteristics and geochemical driving mechanism of soil pH in the Nenjiang River Basin,the National Multi-objective Regional Geochemical Survey data of topsoil,the Second National Soil Survey data and Normalized Difference Vegetation Index(NDVI)were analyzed.The areas of neutral and alkaline soil decreased by 21100 km^(2)and 30500 km^(2),respectively,while that of strongly alkaline,extremely alkaline,and strongly acidic soil increased by 19600 km^(2),18200 km^(2),and 15500 km^(2),respectively,during the past 30 years.NDVI decreased with the increase of soil pH when soil pH>8.0,and it was reversed when soil pH<5.0.There were significant differences in soil pH with various surface cover types,which showed an ascending order:Arbor<reed<maize<rice<high and medium-covered meadow<low-covered meadow<Puccinellia.The weathering products of minerals rich in K_(2)O,Na_(2)O,CaO,and MgO entered into the low plain and were enriched in different parts by water transportation and lake deposition,while Fe and Al remained in the low hilly areas,which was the geochemical driving mechanism.The results of this study will provide scientific basis for making scientific and rational decisions on soil acidification and salinization.

Spatio-temporal Evolution of the Rural Regional System and Its Evolution Mechanism in Huang-Huai-Hai Area of China

The problem of rural development arises from the evolution of rural regional system.It is urgent to deepen the research on the evolution process and mechanism of rural regional system.However,there are relatively few studies on rural development from the perspective of the evolution process,driving mechanism and evolution mechanism of rural regional system.Therefore,this study took Huang-Huai-Hai Area for example,started with the systematicness of the rural regional system,the spatio-temporal pattern and driving mechanism of rural regional system evolution,and further summarized and refined the evolution mechanism of the rural regional system.The methods of spatial pattern analysis,gray correlation degree and geographical detection were adopted.The results showed that the problems in rural areas were often dominated by one factor and produced by the joint action of many factors.Factors such as county urbanization,county economy,county public service,agricultural mechanization,surrounding cities and convenient transportation will affect the evolution of rural regional systems.Based on the evolution of the elements in the rural regional system,the evolution types of rural regional system can be divided into decline type,equilibrium type and growth type.This study can provide a reference for understanding the process of rural rise and fall and can also guide rural revitalization and rural sustainable development.

Spatio-temporal Evolution and Driving Factors of the High-quality Development of Provincial Tourism in China

Accelerating the promotion of high-quality development of tourism(HQDT) is of great significance to the sustainable development of tourism. This paper defined the concept of HQDT, and then built an evaluation system for HQDT measurement to analyze the spatio-temporal evolution characteristics of China’s HQDT based on provincial panel data from 2010 to 2019, using Geodetector to explore the similarities and differences between driving factors of HQDT and tourism development scale(TDS). The results show that:1) Taking the development concepts of innovation, coordination, green, openness and sharing as the guidance, and considering the organic unity of quantity and quality, the evaluation index system of the HQDT consists of six dimensions of economic stability, innovation driving, coordination and linkage, green and sustainability, openness and cooperation, and sharing and harmony, which respectively represent the basis, momentum, means, orientation, direction and purpose of the HQDT;2) The level of China’s HQDT shows an upward trend, presenting the characteristics of eastern region > central region > western region > northeastern region in 2019. The regional differences in China’s HQDT show a downward trend, and the intra-regional differences have replaced the inter-regional differences as the main source of regional differences;3) China’s HQDT shows the characteristics of higher in the east and lower in the west along the Hu line, while the improvement speed of HQDT shows the characteristics of faster in the west and slower in the east, making the decline of east-west differentiation of China’s HQDT and the movement of the gravity center towards southwest;4) Both HQDT and TDS are obviously driven by tourism capital investment and regional consumption. In terms of differences, the HQDT is more driven by government guidance, innovation driving force, and opening up, while the main driving factors of TDS are more biased toward capital elements and hardware facilities, including informatization, tourism resource, traffic, and eco-environment.

Spatio-temporal Evolution Characteristics and Driving Mechanism of the New Infrastructure Construction Development Potential in China

With the advent of the era of big data and artificial intelligence, new infrastructure construction(NIC) has attracted the attention of many countries. The development of NIC provides an opportunity to bridge the digital divide and narrow the regional gap,providing continuous impetus to further promote economic development. Here, we considered 31 provincial-level administrative units in China(not including Hong Kong, Macao, and Taiwan of China due to data unavailable) and established comprehensive evaluation indicators for the development potential of NIC. Afterward, we used the entropy-weight TOPSIS model to determine the development potential of NIC and analyze its spatio-temporal evolution characteristics. Furthermore, the GeoDetector model was applied to explore the driving mechanism of the NIC development potential. The conclusions were as follows: (1) The Chinese NIC development potential is generally low. The eastern China was the region with the highest development potential year by year, while the development potential in the central China was found to be in an accelerating phase. (2) The evolution of the Chinese NIC development potential’s spatial pattern has been characterized by an inland extension and coastal agglomeration. Moreover, we identified a superior development zone, a rising development zone, an inferior development zone, and a declining development zone. (3) The scope of Chinese NIC development potential agglomeration areas has gradually expanded and its degree has gradually deepened. The range of high-value agglomeration in eastern area gradually expanded and its degree gradually deepened. (4) Investment in innovative talents appears as the core factor affecting the Chinese NIC development potential. Whether acting alone or synergistically with other factors, its promoting effect on Chinese NIC development potential is the strongest.

Spatio-temporal Evolution of Marine Fishery Industry Ecosystem Vulnerability in the Bohai Rim Region

The building of the ocean power strategy and the implementation of the blue agriculture plan urgently need to strengthen the sustainable development of marine fishery.Taking vulnerability as the starting point, this paper constructs the vulnerability index system of marine fishery industry ecosystem from the aspects of sensitivity and response capacity, and combines the entropy method with the Topsis to comprehensively analyze the spatio-temporal evolution characteristics of vulnerability of marine fishery industry ecosystem in the Bohai Rim Region from 2001 to 2015.The results show that: 1) In the time dimension, from 2001 to 2015, the vulnerability of the marine fishery industry ecosystem in the Bohai Rim Region shows a fluctuant and degressive trend;2) In the spatial dimension, the spatial distribution of the marine fishery industry ecosystem vulnerability in the Bohai Rim Region presents the gradient characteristics which shows high vulnerability in the east and low vulnerability in the west.According to the evolution track of the system’s vulnerability level, the vulnerability of the marine fishery industry ecosystem is divided into ‘declining’ and ‘stable’ types of evolutionary structures;3) The development of marine fishery in the Bohai Rim Region needs to be derived from the marine fishery’s ecological environment and the industrial development mode and structure, which can improve the marine environment remediation efforts, optimize the marine fishery industry structure, vigorously focus on pelagic fishery, and enhance the introduction of marine fishery’s science and technology talents, etc.Then, the marine fishery’s development in the Bohai Rim Region will be moving in the green, circular and sustainable direction.

Spatio-temporal evolution of ecologically-sustainable land use in China's Loess Plateau and detection of its influencing factors

Ecological land(Eco-land) is a basic resource for human beings to survive, and eco-land use is a strategy, a way to manage the land resource. So, ecologically-sustainable land use is essential for human beings to survive. This paper investigates the spatiotemporal characteristics and mechanisms of urban-rural eco-land using a new and innovative integration way based on eco-land change data in China's Loess Plateau(LP) prefecture level cities and explores factors of eco-land change. The spatial difference characteristic of eco-land among different level cities in the LP is that: small cities > big cities > middle cities. From 2009 to 2016, the eco-land in the LP from the perspective of urban-rural areas has changed significantly. Significant differences of urban-rural eco-land were identified among various urban growth types, and all the cities in the LP were further classified into four types based on eco-land change trend, with type A and B cities identified as the vital zone and major zone. Taking the eco-fragile region Loess Plateau(LP) as an example, our results demonstrated that the migrants to cities in LP could relieve ecological pressures and promote restoration of ecological vegetation. We have demonstrated that urbanization and the influence of government policy can be discerned through the quantification of the spatial-temporal change of eco-land and suggest that combining both urban and rural eco-land can support more effective land use decisions and provide theoretical basis for the practical application of urban planning, policy-making and sustainable development. What's more, governments should strive to population mobility and restore vegetation to sustain this fragile ecological environment.

Analysis of Characteristics of Spatio-temporal Evolution of Land Use in Inhabited Islands of Pearl River Estuary

Under the support of the remote sensing and geographical information system(GIS) techniques,we acquire the land use data in 1990 and 2008 regarding 6 inhabited islands,namely Longxue Island,Hengmen Island,Weiyuan Island,Qi'ao Island,Hengqin Island and Gaolan Island in Pearl River Estuary.By using dynamic degree of land use,land use change intensity,relative change rate and other indicators,we conduct quantitative description,and thus quantitatively and qualitatively analyse characteristics of temporal evolution and law of spatial pattern change concerning land use of each island.The study indicates that in the period 1990-2008,the area of construction land and water in 6 islands increased,while the area of agricultural land and unused land increased in some islands and decreased in others.The land use change shows spatial disparity;the holistic land use change degree in Hengmen Island is higher than that of other islands;the dynamic degree of land use,intensity of land use,and relative change rate differ in different islands.

Spatio-temporal evolution of Allium L. in the Qinghaie-Tibet-Plateau region: Immigration and in situ radiation

A plethora of studies investigating the origin and evolution of diverse mountain taxa has assumed a causal link between geological processes(orogenesis) and a biological response(diversification). Yet, a substantial delay(up to 30 Myr) between the start of orogenesis and diversification is often observed.Evolutionary biologists should therefore identify alternative drivers of diversification and maintenance of biodiversity in mountain systems. Using phylogenetic, biogeographic, and diversification rate analyses,we could identify two independent processes that most likely explain the diversity of the widespread genus Allium in the Qinghaie-Tibet Plateau(QTP) region:(1) While the QTP-related taxa of the subgenus Melanocrommyum diversified in situ,(2) QTP-related taxa of other subgenera migrated into the QTP from multiple source areas. Furthermore, shifts in diversification rates within Allium could not be attributed spatially and temporally to the uplift history of the QTP region. Instead, global cooling and climate oscillations in the Quaternary were major contributors to increased speciation rates in three clades of Allium. Our study therefore adds to the growing evidence supporting the "mountain-geo-biodiversity hypothesis", which highlights the role of climate oscillations for the diversification of mountain organisms.

Spatio-temporal Evolution of China’s Economic Power Based on Asymmetric Theory

In the 21 st century, economic interdependence between countries has gradually become an important source of state power. Globalization and the rise of China’s economy have had a significant impact on other economies around the world. China’s economic influence is becoming more and more important. On the basis of the sensitivity dependence and vulnerability dependence of asymmetric interdependence theory, the economic spillover between countries is selected to construct a quantitative model to measure economic power. This paper analyzes the evolution of China’s economic power both in time and space from 2000 to 2014. Four conclusions were drawn from the study: 1) The spatial spillover effect of China’s economy on other countries has been continuously growing since the beginning of the 21 st century, which has brought about the rapid increase in China’s economic power;2) China’s economic power has been significantly strengthened both in intensity and scope, having expanded from the surrounding countries to the whole world. In 2014, China had a high amount of economic power over 18 countries from the 41 main countries in the world, compared to 2 in 2000;3) China’s power in terms of sensitivity dependence takes on an evolutionary trend from point distribution to flaky growth, and it shows a process ‘from point to line’ from the aspect of spatial diffusion. Furthermore, China’s power in terms of vulnerability dependence shows a trend that extends from the surrounding countries to European and South American countries;4) comprehensively, China’s power in terms of vulnerability dependence is higher than that of sensitivity dependence, and the spatial distribution pattern demonstrates a process from centralization to decentralization from 2000 to 2014.

Carbon Emission Effects Driven by Evolution of Chinese Dietary Structure from 1987 to 2020

Exploring carbon emission effects based on the evolution of residents’ dietary structure to achieve the carbon neutrality goal and mitigate climate change is an important task.This study took China as the research object(data excluding Hong Kong,Macao and Taiwan) and used the carbon emission coefficient method to quantitatively measure the food carbon emissions from 1987–2020,then analyzed the carbon emission effects under the evolution of dietary structure.The results showed that during the study period,the Chinese dietary structure gradually changed to a high-carbon consumption pattern.The dietary structure of urban residents developed to a balanced one,while that of rural residents developed to a high-quality one.During the study period,the per capita food carbon emissions and total food consumption of Chinese showed an increasing trend.The per capita food carbon emissions of residents in urban and rural showed an overall upward trend.The total food carbon emissions in urban increased significantly,while that in rural increased first and then decreased.The influence of beef and mutton on carbon emissions is the highest in dietary structure.Compared with the balanced dietary pattern,the food carbon emissions of Chinese residents had not yet reached the peak,but were evolving to a high-carbon consumption pattern.

Tuning electronic structure of RuO_(2)by single atom Zn and oxygen vacancies to boost oxygen evolution reaction in acidic medium

The poor stability of RuO_(2)electrocatalysts has been the primary obstacles for their practical application in polymer electrolyte membrane electrolyzers.To dramatically enhance the durability of RuO_(2)to construct activity-stability trade-off model is full of significance but challenging.Herein,a single atom Zn stabilized RuO_(2)with enriched oxygen vacancies(SA Zn-RuO_(2))is developed as a promising alternative to iridium oxide for acidic oxygen evolution reaction(OER).Compared with commercial RuO_(2),the enhanced Ru–O bond strength of SA Zn-RuO_(2)by forming Zn-O-Ru local structure motif is favorable to stabilize surface Ru,while the electrons transferred from Zn single atoms to adjacent Ru atoms protects the Ru active sites from overoxidation.Simultaneously,the optimized surrounding electronic structure of Ru sites in SA ZnRuO_(2)decreases the adsorption energies of OER intermediates to reduce the reaction barrier.As a result,the representative SA Zn-RuO_(2)exhibits a low overpotential of 210 mV to achieve 10 mA cm^(-2)and a greatly enhanced durability than commercial RuO_(2).This work provides a promising dual-engineering strategy by coupling single atom doping and vacancy for the tradeoff of high activity and catalytic stability toward acidic OER.

Damage evolution of rock-encased-backfill structure under stepwise cyclic triaxial loading

Rock-encased-backfill(RB)structures are common in underground mining,for example in the cut-andfill and stoping methods.To understand the effects of cyclic excavation and blasting activities on the damage of these RB structures,a series of triaxial stepwise-increasing-amplitude cyclic loading experiments was conducted with cylindrical RB specimens(rock on outside,backfill on inside)with different volume fractions of rock(VF=0.48,0.61,0.73,and 0.84),confining pressures(0,6,9,and 12 MPa),and cyclic loading rates(200,300,400,and 500 N/s).The damage evolution and meso-crack formation during the cyclic tests were analyzed with results from stress-strain hysteresis loops,acoustic emission events,and post-failure X-ray 3D fracture morphology.The results showed significant differences between cyclic and monotonic loadings of RB specimens,particularly with regard to the generation of shear microcracks,the development of stress memory and strain hardening,and the contact forces and associated friction that develops along the rock-backfill interface.One important finding is that as a function of the number of cycles,the elastic strain increases linearly and the dissipated energy increases exponentially.Also,compared with monotonic loading,the cyclic strain hardening characteristics are more sensitive to rising confining pressures during the initial compaction stage.Another finding is that compared with monotonic loading,more shear microcracks are generated during every reloading stage,but these microcracks tend to be dispersed and lessen the likelihood of large shear fracture formation.The transition from elastic to plastic behavior varies depending on the parameters of each test(confinement,volume fraction,and cyclic rate),and an interesting finding was that the transformation to plastic behavior is significantly lower under the conditions of 0.73 rock volume fraction,400 N/s cyclic loading rate,and 9 MPa confinement.All the findings have important practical implications on the ability of backfill to support underground excavations.

Improved spatio-temporal alignment measurement method for hull deformation

In this paper,an improved spatio-temporal alignment measurement method is presented to address the inertial matching measurement of hull deformation under the coexistence of time delay and large misalignment angle.Large misalignment angle and time delay often occur simultaneously and bring great challenges to the accurate measurement of hull deformation in space and time.The proposed method utilizes coarse alignment with large misalignment angle and time delay estimation of inertial measurement unit modeling to establish a brand-new spatiotemporal aligned hull deformation measurement model.In addition,two-step loop control is designed to ensure the accurate description of dynamic deformation angle and static deformation angle by the time-space alignment method of hull deformation.The experiments illustrate that the proposed method can effectively measure the hull deformation angle when time delay and large misalignment angle coexist.

Deformable Catalytic Material Derived from Mechanical Flexibility for Hydrogen Evolution Reaction

Deformable catalytic material with excellent flexible structure is a new type of catalyst that has been applied in various chemical reactions,especially electrocatalytic hydrogen evolution reaction(HER).In recent years,deformable catalysts for HER have made great progress and would become a research hotspot.The catalytic activities of deformable catalysts could be adjustable by the strain engineering and surface reconfiguration.The surface curvature of flexible catalytic materials is closely related to the electrocatalytic HER properties.Here,firstly,we systematically summarized self-adaptive catalytic performance of deformable catalysts and various micro–nanostructures evolution in catalytic HER process.Secondly,a series of strategies to design highly active catalysts based on the mechanical flexibility of lowdimensional nanomaterials were summarized.Last but not least,we presented the challenges and prospects of the study of flexible and deformable micro–nanostructures of electrocatalysts,which would further deepen the understanding of catalytic mechanisms of deformable HER catalyst.

Microdynamic mechanical properties and fracture evolution mechanism of monzogabbro with a true triaxial multilevel disturbance method

The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated.

Identification of S-RNase genotype and analysis of its origin and evolutionary patterns in Malus plants

Identification of the S genotype of Malus plants will greatly promote the discovery of new genes,the cultivation and production of apple,the breeding of new varieties,and the origin and evolution of self-incompatibility in Malus plants.In this experiment,88 Malus germplasm resources,such as Aihuahong,Xishuhaitang,and Reguanzi,were used as materials.Seven gene-specific primer combinations were used in the genotype identification.PCR amplification using leaf DNA produced a single S-RNase gene fragment in all materials.The results revealed that 70 of the identified materials obtained a complete S-RNase genotype,while only one S-RNase gene was found in 18 of them.Through homology comparison and analysis,13 S-RNase genotypes were obtained:S_(1)S_(2)(Aihuahong,etc.),S_(1)S_(28)(Xixian Haitang,etc.),S_(1)S_(51)(Hebei Pingdinghaitang),S_(1)S_(3)(Xiangyangcun Daguo,etc.),S_(2)S_(3)(Zhaiyehaitang,etc.),S_(3)S_(51)(Xishan 1),S_(3)S_(28)(Huangselihaerde,etc.),S_(2)S_(28)(Honghaitang,etc.),S_(4)S_(28)(Bo 11),S_(7)S_(28)(Jiuquan Shaguo),S_(10)S_e(Dongchengguan 13),S_(10)S_(21)(Dongxiangjiao)and S_(3)S_(51)(Xiongyue Haitang).Simultaneously,the frequency of the S gene in the tested materials was analyzed.The findings revealed that different S genes had varying frequencies in Malus resources,as well as varying frequencies between intraspecific and interspecific.S_(3) had the highest frequency of 68.18%,followed by S_(1)(42.04%).In addition,the phylogenetic tree and origin evolution analysis revealed that the S gene differentiation was completed prior to the formation of various apple species,that cultivated species also evolved new S genes,and that the S_(50) gene is the oldest S allele in Malus plants.The S_(1),S_(29),and S_(33) genes in apple-cultivated species,on the other hand,may have originated in M.sieversii,M.hupehensis,and M.kansuensis,respectively.In addition to M.sieversii,M.kansuensis and M.sikkimensis may have also played a role in the origin and evolution of some Chinese apples.

Mg/MgO interfaces as efficient hydrogen evolution cathodes causing accelerated corrosion of additive manufactured Mg alloys:A DFT analysis

The corrosion rates of additive-manufactured Mg alloys are higher than their as-cast counterparts,possibly due to increased kinetics for the hydrogen evolution reaction on secondary phases,which may include oxide inclusions.Scanning Kelvin Probe Force Microscopy demonstrated that MgO inclusions could act as cathodes for Mg corrosion,but their low conductivity likely precludes this.However,the density of state calculations through density functional theory using hybrid HSE06 functional revealed overlapping electronic states at the Mg/MgO interface,which facilitates electron transfers and participates in redox reactions.Subsequent determination of the hydrogen absorption energy at the Mg/MgO interface reveals it to be an excellent catalytic site,with HER being found to be a factor of 23x more efficient at the interface than on metallic Mg.The results not only support the plausibility of the Mg/MgO interface being an effective cathode to the adjacent anodic Mg matrix during corrosion but also contribute to the understanding of the enhanced cathodic activities observed during the anodic dissolution of magnesium.

Temporal and spatial evolution of global major grain trade patterns

The complex and volatile international landscape has significantly impacted global grain supply security. This study uses a complex network analysis model to examine the evolution and trends of the global major grain trade from 1990 to 2020, focusing on network topology, centrality ranking, and community structure. There are three major findings. First, the global major grain trade network has expanded in scale, with a growing emphasis on diversification and balance. During the study period, the United States, Canada, China, and Brazil were the core nodes of the network. Grain-exporting countries were mainly situated in Asia, the Americas, and Europe, and importing countries in Asia, Africa, and Europe. Second, a significant increase in the number of high centrality countries with high export capacity occurred, benefiting from natural advantages such as fertile land and favorable climates. Third, the main global grain trade network is divided into four communities, with the Americas-Europe community being the largest and most widespread. The formation of the community pattern was influenced by geographic proximity, driven by the core exporting countries. Therefore, the world needs to enhance the existing trade model, promote the multi-polarization of the grain trade network, and establish a global vision for the future community. Countries and regions should participate actively in global grain trade security governance and institutional reform, expand trade links with other countries, and optimize import and export policies to reduce trade risks.

Evolution of molecular structure of TATB under shock loading from transient Raman spectroscopic technique

By combination of the transient Raman spectroscopic measurement and the density functional theoretical calculations,the structural evolution and stability of TATB under shock compression was investigated.Due to the improvement in synchronization control between two-stage light gas gun and the transient Raman spectra acquisition,as well as the sample preparation,the Raman peak of the N-O mode of TATB was firstly observed under shock pressure up to 13.6 GPa,noticeably higher than the upper limit of 8.5 GPa reported in available literatures.By taking into account of the continuous shift of the main peak and other observed Raman peaks,we did not distinguish any structural transition or any new species.Moreover,both the present Raman spectra and the time-resolved radiation of TATB during shock loading showed that TATB exhibits higher chemical stability than previous declaration.To reveal the detailed structural response and evolution of TATB under compression,the density functional theoretical calculations were conducted,and it was found that the pressure make N-O bond lengths shorter,nitro bond angles larger,and intermolecular and intra-molecular hydrogen bond interactions enhanced.The observed red shift of Raman peak was ascribed to the abnormal enhancement of H-bound effect on the scissor vibration mode of the nitro group.

Precisely Control Relationship between Sulfur Vacancy and H Absorption for Boosting Hydrogen Evolution Reaction

Ef fective and robust catalyst is the core of water splitting to produce hydrogen.Here, we report an anionic etching method to tailor the sulfur vacancy(VS) of NiS_(2) to further enhance the electrocatalytic performance for hydrogen evolution reaction(HER). With the VS concentration change from 2.4% to 8.5%, the H* adsorption strength on S sites changed and NiS_(2)-VS 5.9% shows the most optimized H* adsorption for HER with an ultralow onset potential(68 m V) and has long-term stability for 100 h in 1 M KOH media. In situ attenuated-total-reflection Fourier transform infrared spectroscopy(ATR-FTIRS) measurements are usually used to monitor the adsorption of intermediates. The S-H* peak of the Ni S_(2)-VS 5.9% appears at a very low voltage, which is favorable for the HER in alkaline media. Density functional theory calculations also demonstrate the Ni S_(2)-VS 5.9% has the optimal |ΔG^(H*)| of 0.17 e V. This work offers a simple and promising pathway to enhance catalytic activity via precise vacancies strategy.