Spectra analysis and O_2 evolution for TiO_2 photocatalyst compounded with indirect transition semiconductors

The photo absorbing, photo transmitting and photoluminescence performances of WiO2 photocatalysts compounded with V2O5 or WO3 were investigated by UV-Vis spectra, transmitting spectra, and PL spectra, respectively. The energy band structures of TiO2 photocatalysts were analyzed. The photocatalytic activities of the TiO2 photocatalysts were investigated by splitting of water for 02 evolution. The results indicate that the band gaps of WO3 and V205 are about 2.8 and 2.14 eV, respectively, and the band gap of rutile TiO2 is about 3.08 eV. Speeds of water splitting for 2%WO3-TiO2 and 8%V2O5-TiO2 photocatalysts are 420 and 110 μmol/（L.h）, respectively, under UV light irradiation. V2O5 and WO3 compounded with suitable concentration can improve the photocatalytic activity of TiO2 with Fe3＋ as electron acceptor.

X-RAY FLUORESCENCE SPECTRA ANALYSIS ON THE STRUCTURE AROUND Ti^(4+) OF BaO-SiO_2-B_2O_3-TiO_2 SYSTEM GLASSES

The structure around Ti^(4+) in Bao-SiO_2 -B_2O_3-TiO_2 had been studied by X-ray fluorescence spectra. The results show that the Ti^(4+) mainly exists in the [TiO_4] and enters the network of [SiO_4]. [TiO_4] has the tendency to change to [TiO_6] with the increase of TiO_2 con-tent. When the TiO_2 content increases to about 20mol% the tendency reaches its maximum.

A method for neutron-induced gamma spectra decomposition analysis based on Geant4 simulation

In various monitoring and detection tools that use pulsed neutron generators as radiation sources,the gamma rays induced by the interaction with various nuclei at different stages of neutron transport can reflect information about the medium.These gamma rays are generated in two major interactions:inelastic scattering of fast neutrons and radiative capture of thermal neutrons,corresponding to the inelastic and capture gamma rays,respectively.However,the two types of gamma rays that reflect different properties of the medium are difficult to collect by normal detectors independently.The proportion of the two gamma rays needs to be solved for the separation of inelastic and capture gamma.Therefore,this study proposes an optimized spectra decomposition method to calculate the inelastic-to-capture ratio in the measured total gamma spectra based on the net inelastic and capture spectra obtained using the Geant4 simulation.Because the simulated data cannot reflect the energy resolution of the measured spectra,we introduce the Gaussian broadening function of the gamma detector while calculating the proportion of the spectra components,and achieve optimization of the proportion values and resolution parameters simultaneously.Based on the results,the total simulated spectra obtained by superimposing the broadened net inelastic and capture gamma spectra according to the calculated inelastic-to-capture ratio are in good agreement with their measured counterpart.

Theoretical Analysis of Rydberg and Autoionizing State Spectra of Antimony

We calculate the Rydberg and autoionization Rydberg spectra of antimony （Sb） from first principles by relativistic multichannel theory within the framework of multichannel quantum defect theory. Our calculation can be used to classify and assign the atomic states described in recently reported three Rydberg series and four autoionizing states. The perturbation effects on line intensity, variation and line profile are discussed. Assignments of the perturber states and autoionizing states are presented.

Characteristic wavelength selection of volatile organic compounds infrared spectra based on improved interval partial least squares

As important components of air pollutant,volatile organic compounds(VOCs)can cause great harm to environment and human body.The concentration change of VOCs should be focused on in real-time environment monitoring system.In order to solve the problem of wavelength redundancy in full spectrum partial least squares(PLS)modeling for VOCs concentration analysis,a new method based on improved interval PLS(iPLS)integrated with Monte-Carlo sampling,called iPLS-MC method,was proposed to select optimal characteristic wavelengths of VOCs spectra.This method uses iPLS modeling to preselect the characteristic wavebands of the spectra and generates random wavelength combinations from the selected wavebands by Monte-Carlo sampling.The wavelength combination with the best prediction result in regression model is selected as the characteristic wavelengths of the spectrum.Different wavelength selection methods were built,respectively,on Fourier transform infrared(FTIR)spectra of ethylene and ethanol gas at different concentrations obtained in the laboratory.When the interval number of iPLS model is set to 30 and the Monte-Carlo sampling runs 1000 times,the characteristic wavelengths selected by iPLS-MC method can reduce from 8916 to 10,which occupies only 0.22%of the full spectrum wavelengths.While the RMSECV and correlation coefficient(Rc)for ethylene are 0.2977 and 0.9999 ppm,and those for ethanol gas are 0.2977 ppm and 0.9999.The experimental results show that the iPLS-MC method can select the optimal characteristic wavelengths of VOCs FTIR spectra stably and effectively,and the prediction performance of the regression model can be significantly improved and simplified by using characteristic wavelengths.

Investigation on Physiological Status of Regional Vegetation Using Pushbroom Hyperspectral Imager Data

To extract vegetation pigment concentration and physiological status has been studied in two test areas covered with swamp and flourish vegetation using pushbroom hyperspectral imager (PHI) data which flied in September of 2000 at Daxing'anling district of Heilongjiang Province, China. The ratio analysis of reflectance spectra (RARS) indices, which were put forward by Chappelle et al (1992), are chosen in this paper owing to their effect and simpleness against both comparison with various methods and techniques for exploration of pigment concentration and characteristics of PHI data. The correlation coefficients between RARS indices and pigment concentration of vegetation were up to 0.8. The new RARS indices modes are established in the two test areas using both PHI data and spectra of different vegetations measured in the field. The indices' parameter images of chlorophyll a (Chl a), chlorophyll b (Chl b) and carotenoids (Cars) of the test areas covered with swamp and flourish vegetation are acquired by the new RARS indices modes. Furthermore, the regional concentration of Chl a and Chl b are extracted and quantified using regression equations between RARS indices and pigment concentrations, which were built by Blackburn (1998). The results showed the physiological status and variety clearly, and are in good agreement with the distribution of vegetation in the field.

Fluorometric Discrimination Technique of Phytoplankton Population Based on Wavelet Analysis

The discrete excitation-emission-matrix fluorescence spectra (EEMS) at 12 excitation wavelengths (400, 430, 450, 460, 470, 490, 500, 510, 525, 550, 570, and 590 nm) and emission wavelengths ranging from 600-750 nm were determined for 43 phytoplankton species. A two-rank fluorescence spectra database was established by wavelet analysis and a fluorometric discrimination technique for determining phytoplankton population was developed. For laboratory simulatively mixed samples, the samples mixed from 43 algal species (the algae of one division accounted for 25%, 50%, 75%, 85%, and 100% of the gross biomass, respectively), the average discrimination rates at the level of division were 65.0%, 87.5%, 98.6%, 99.0%, and 99.1%, with average relative contents of 18.9%, 44.5%, 68.9%, 73.4%, and 82.9%, respectively; the samples mixed from 32 red tide algal species (the dominant species accounted for 60%, 70%, 80%, 90%, and 100% of the gross biomass, respectively), the average correct discrimination rates of the dominant species at the level of genus were 63.3%, 74.2%, 78.8%, 83.4%, and 79.4%, respectively. For the 81 laboratory mixed samples with the dominant species accounting for 75% of the gross biomass (chlorophyll), the discrimination rates of the dominant species were 95.1% and 72.8% at the level of division and genus, respectively. For the 12 samples collected from the mesocosm experiment in Maidao Bay of Qingdao in August 2007, the dominant species of the 11 samples were recognized at the division level and the dominant species of four of the five samples in which the dominant species accounted for more than 80% of the gross biomass were discriminated at the genus level; for the 12 samples obtained from Jiaozhou Bay in August 2007, the dominant species of all the 12 samples were recognized at the division level. The technique can be directly applied to fluorescence spectrophotometers and to the developing of an in situ algae fluorescence auto-analyzer for phytoplankton population.

Impact of Impeller Stagger Angles on Pressure Fluctuation for a Double-Suction Centrifugal Pump

Pressure fluctuation may cause high amplitude of vibration of double-suction centrifugal pumps, but the impact of impeller stagger angles is still not well understood. In this paper, pressure fluctuation experiments are carried out for five impeller configurations with different stagger angles by using the same test rig system. Results show that the stagger angles exert negligible effects on the characteristics of head and efficiency. The distributions of pressure fluctuations are relatively uniform along the suction chamber wall, and the maximum pressure fluctuation amplitude is reached near the suction inlet tongue region. The pressure fluctuation characteristics are affected largely by impeller rotation, whose dominant frequencies include impeller rotation frequency and its harmonic frequencies, and half blade passage frequency. The stagger angle exerts a small effect on the pressure fluctuations in the suction chamber while a great effect on the pressure fluctuation in volute casing, especially on the aspect of decreasing the amplitude on blade passage frequency. Among the tested cases, the distribution of pressure fluctuations in the volute becomes more uniform than the other impeller configurations and the level of pressure fluctuation may be reduced by up to 50% when the impeller stagger angle is close to 24° or 360°.The impeller structure pattern needs to be taken into consideration during the design period, and the halfway staggered impeller is strongly recommended.

Flooding Characteristics of Hydrofoil Impeller in a Two- and Three-phase Stirred Tank

The flooding characteristics of hydrofoil impeller were systematically investigated in a two-and three-phase 383 mm i.d. stirred tank operated on air, water and spherical glass beads. The volumetric solid concen-tration Cs was varied from 0 to 25%. And the superficial gas velocity Ug was at the range of 0-0.096 m·s-1. A fast and objective method for identifying flooding point NF is developed based on the statistical analysis of the pressure fluctuation signals. It is found, the effect of solid concentration on the flooding point NF depends on the gas velocity. At the lower gas velocity (Ug = 0.010 m·s-1), the solid concentration has only a minor effect. However, it displays a very significant effect on the flooding point NF at the medium and high gas velocity. The flooding point NF linearly increases with the gas velocity Ug, at lower solid concentration (Cs = 0, 10%). When Cs = 20%, the behavior of NF versus Ug becomes more complex. The correlations of the flooding characteristics in the slurry stirred tank are proposed by considering the solid concentration effect.

Residual Phase Noise and Time Jitters of Single-Chip Digital Frequency Dividers

In this paper, we demonstrate the residual phase noise of a few microwave frequency dividers which usually limit the performance of frequency synthesizers. In order to compare these dividers under different operation frequencies, we calculate additional time jitters of these dividers by using the measured phase noise. The time jitters are various from -0.1 fs to 43 fs in a bandwidth from 1 Hz to 100 Hz in dependent of models and operation frequencies. The HMC series frequency dividers exhibit outstanding performance for high operation frequencies, and the time jitters can be sub-fs. The time jitters of SP8401, MC10EP139, and MC100LVEL34 are comparable or even below that of HMC series for low operation frequencies.

A Preliminary Study of the Types of Volcanic Earthquakes and Volcanic Activity at the Changbaishan Tianchi Volcano

Since 2002, a significant increase in seismicity, obvious ground deformation and geochemical anomalies have been observed in the Changbaishan Tianchi volcanic area. A series felt earthquakes occur near the caldera, causing great influence to society. In this paper, the types of volcanic earthquakes recorded by the temporal seismic network since 2002 have been classified by analyzing the spectrum, time-frequency characteristics and seismic waveforms at different stations. The risk of volcano eruptions was also estimated. Our results show that almost all earthquakes occurring in Tianchi volcano are volcanic-tectonic earthquakes. The low frequency seismic waveforms observed at a few stations may be caused by local mediums, and have no relation with long-period events. Although the level of seismicity increased obviously and earthquake swarms occurred more frequently than before, we considered that the magma activity is still in its early stage and the eruption risk of Changbaishan Tianchi volcano is still low in the near future.

New simple spectrophotometric method for determination of the binary mixtures(atorvastatin calcium and ezetimibe;candesartan cilexetil and hydrochlorothiazide) in tablets

A new simple spectrophotometric method was developed for the determination of binary mixtures without prior separation.The method is based on the generation of ratio spectra of compound X by using a standard spectrum of compound Y as a divisor.The peak to trough amplitudes between two selected wavelengths in the ratio spectra are proportional to concentration of X without interference from Y.The method was demonstrated by determination of two drug combinations.The first consists of the two antihyperlipidemics：atorvastatin calcium（ATV） and ezetimibe（EZE）,and the second comprises the antihypertensives：candesartan cilexetil（CAN） and hydrochlorothiazide（HCT）.For mixture 1,ATV was determined using 10 μg/mL EZE as the divisor to generate the ratio spectra,and the peak to trough amplitudes between 231 and 276 nm were plotted against ATV concentration.Similarly,by using 10 μg/mL ATV as divisor,the peak to trough amplitudes between 231 and 276 nm were found proportional to EZE concentration.Calibration curves were linear in the range 2.5-40 mg/mL for both drugs.For mixture 2,divisor concentration was 7.5 μg/mL for both drugs.CAN was determined using its peak to trough amplitudes at 251 and 277 nm,while HCT was estimated using the amplitudes between 251 and 276 nm.The measured amplitudes were linearly correlated to concentration in the ranges 2.5-50 and 1-30 μg/mL for CAN and HCT,respectively.The proposed spectrophotometric method was validated and successfully applied for the assay of both drug combinations in several laboratory-prepared mixtures and commercial tablets.

STUDIES ON THE INITIATION MECHANISM OF CERIC ION AND ACETYLACETONE REDOX SYSTEM IN VINYL POLYMERIZATION

The initiation mechanism of acrylamide (AAM)polymerization using ceric ion/acetylacetone system as an initiator has been studied. The redox polymerization was revealed by the low value of overall activation energy of AAm polymerization. The structure of free radicals formed from above-mentioned initiation sytem were detected by radical trapping and ESR spectra techniques and the end groups of polymers obtained were determined by FT-IR spectra analysis method. Based on these results the initiation mechanism is proposed.