Photocatalytic ozonation-based degradation of phenol by ZnO—TiO_(2)nanocomposites in spinning disk reactor

Spinning disk reactor(SDR)has emerged as a novel process intensification photocatalytic reactor,and it has higher mass transfer efficiency and photon utilization for the degradation of toxic organic pollutants by advanced oxidation processes(AOPs).In this study,ZnO—TiO_(2)nanocomposites were prepared by solgel method,and coated on the disk of SDR by impregnation-pull-drying-calcination method.The performance of catalyst was characterized by X-ray diffraction,scanning electron microscope,X-ray photoelectron spectroscopy,photoluminescence and ultraviolet—visible diffuse reflectance spectroscopy.Photocatalytic ozonation in SDR was used to remove phenol,and various factors on degradation effect were studied in detail.The results showed that the rate of degradation and mineralization reached 100%and 83.4%under UV light irradiation after 50 min,compared with photocatalysis and ozonation,the removal rate increased by 69.3%and 34.7%,and mineralization rate increased by 56.7%and 62.9%,which indicated that the coupling of photocatalysis and ozonation had a synergistic effect.The radical capture experiments demonstrated that the active species such as photogenerated holes(h^(+)),hydroxyl radicals(·OH),superoxide radical(·O_(2)-)were responsible for phenol degradation,and·OH played a leading role in the degradation process,while h+and·O_(2)^(-)played a non-leading role.

Transverse nonlinear vibrations of a circular spinning disk with a varying rotating speed

We analyze the transverse nonlinear vibrations of a rotating flexible disk subjected to a rotating point force with a periodically varying rotating speed. Based on Hamilton’s principle, the nonlinear governing equations of motion (coupled equations among the radial, tangential and transverse displacements) are derived for the rotating flexible disk. When the in-plane inertia is ignored and a stress function is introduced, the three nonlinearly coupled partial differential equations are reduced to two nonlinearly coupled partial differential equations. According to Galerkin’s approach, a four-degree-of-freedom nonlinear system governing the weakly split resonant modes is derived. The resonant case considered here is 1:1:2:2 internal resonance and a critical speed resonance. The primary parametric resonance for the first-order sin and cos modes and the fundamental parametric resonance for the second-order sin and cos modes are also considered. The method of multiple scales is used to obtain a set of eight-dimensional nonlinear averaged equations. Based on the averaged equations, using numerical simulations, the influence of different parameters on the nonlinear vibrations of the spinning disk is detected. It is concluded that there exist complicated nonlinear behaviors including the periodic, period-n and multi-pulse type chaotic motions for the spinning disk with a varying rotating speed. It is also found that among all parameters, the damping and excitation have great influence on the nonlinear responses of the spinning disk with a varying rotating speed.