The long afterglow SrAl_2O_4: Dy, Eu phosphor is liable tohydrolyze in water with deterioration of the lumin- escent property.SrAl_2O_4: Dy, Eu phosphors were therefore heated at 60-90 deg. C inTEOS sol to form a surf...The long afterglow SrAl_2O_4: Dy, Eu phosphor is liable tohydrolyze in water with deterioration of the lumin- escent property.SrAl_2O_4: Dy, Eu phosphors were therefore heated at 60-90 deg. C inTEOS sol to form a surface gel and then heat-treated at 400 deg. C toobtain SiO_2 coated phosphors. Observation by ?Transmission ElectronMicroscope (TE) and X- ray photoelectron spectroscopy (XPS) showsthat a thin silica film forms on the surface of the phosphors. Thecoating procedure can be illustrated by a four-step process and thetransparent silica film can suppress the hydrolysis process, so thatthe luminescent properties of the phosphors are unimpaired or evenbetter.展开更多
基金This project is financially supported by the National Natural Science Foundation of China (No. 59872016)
文摘The long afterglow SrAl_2O_4: Dy, Eu phosphor is liable tohydrolyze in water with deterioration of the lumin- escent property.SrAl_2O_4: Dy, Eu phosphors were therefore heated at 60-90 deg. C inTEOS sol to form a surface gel and then heat-treated at 400 deg. C toobtain SiO_2 coated phosphors. Observation by ?Transmission ElectronMicroscope (TE) and X- ray photoelectron spectroscopy (XPS) showsthat a thin silica film forms on the surface of the phosphors. Thecoating procedure can be illustrated by a four-step process and thetransparent silica film can suppress the hydrolysis process, so thatthe luminescent properties of the phosphors are unimpaired or evenbetter.