A series of SrIn2 O4 ：Eu^3＋ phosphors are synthesized by a high temperature solid-state method, and their luminescent properties are investigated. They can be excited by 395-nm radiation, and produce red emission （...A series of SrIn2 O4 ：Eu^3＋ phosphors are synthesized by a high temperature solid-state method, and their luminescent properties are investigated. They can be excited by 395-nm radiation, and produce red emission （619 nm）; however, they have a low absorption of near-ultraviolet light with the wavelength of 400nm–405 nm. When co-doped with A^＋ （A=Li, Na, K）, the emission intensity of SrIn2O4 ：Eu^3＋ is significantly enhanced, but its emission and excitation spectral profile is unchanged. With co-doping Sm^3＋ , not only is the emission intensity of SrIn2 O4 ：Eu^3＋ enhanced, but also the absorption is broadened and strengthened in the range of 400 nm–405nm. The effect of Sm^3＋ -doped content on the emission intensity of SrIn2O4 ：Eu^3＋ , Sm^3＋ is investigated, and the optimal Sm^3＋ content is 0.02 mol.展开更多
A series of Yb^(3+)/Er^(3+) or Er^(3+) doped SrIn_2O_4 were synthesized by a high temperature solid state method.The up-conversion luminescence property and the phase formation of SrIn_2O_4:Er^(3+) and SrIn_2O_4:Yb^(3...A series of Yb^(3+)/Er^(3+) or Er^(3+) doped SrIn_2O_4 were synthesized by a high temperature solid state method.The up-conversion luminescence property and the phase formation of SrIn_2O_4:Er^(3+) and SrIn_2O_4:Yb^(3+),Er^(3+) were investigated by X-ray diffraction(XRD) and spectral methods.The XRD pattern shows that incorporating different amounts of Yb^(3+)and Er^(3+) have no influence on the phase formation of SrIn_2O_4.The up-conversion luminescence spectrum of SrIn_2O_4:Er^(3+) presented a weak luminescence due to ground state absorption of Er^(3+).However,Yb^(3+)/Er^(3+) codoped SrIn_2O_4 depicted the green(525 and 551 run) and red(662 nm) up-conversion luminescence which were assigned to the energy transfer from the Yb^(3+) transition ~2F_(7/2)-~2F_(5/2) to the Er^(3+) transitions ~2H_(11/2)-~4I_(15/2) and ~4F_(9/2-~4I_(15/2),respectively.The possible up-conversion luminescence mechanism of SrIn_2O_4:Yb^(3+),Er^(3+) was analyzed.All results could be helpful to the development of up-conversion luminescence materials.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No. 50902042)the Natural Science Foundation of Hebei Province, China(Grant Nos. E2009000209 and E2010000283)+1 种基金the Education Bureau Foundation of Hebei Province, China (Grant No. 2009313)the Key Laboratory of Luminescence and Optical Information, Beijing Jiaotong University, Ministry of Education, China (Grant No. 2010LOI12)
文摘A series of SrIn2 O4 ：Eu^3＋ phosphors are synthesized by a high temperature solid-state method, and their luminescent properties are investigated. They can be excited by 395-nm radiation, and produce red emission （619 nm）; however, they have a low absorption of near-ultraviolet light with the wavelength of 400nm–405 nm. When co-doped with A^＋ （A=Li, Na, K）, the emission intensity of SrIn2O4 ：Eu^3＋ is significantly enhanced, but its emission and excitation spectral profile is unchanged. With co-doping Sm^3＋ , not only is the emission intensity of SrIn2 O4 ：Eu^3＋ enhanced, but also the absorption is broadened and strengthened in the range of 400 nm–405nm. The effect of Sm^3＋ -doped content on the emission intensity of SrIn2O4 ：Eu^3＋ , Sm^3＋ is investigated, and the optimal Sm^3＋ content is 0.02 mol.
文摘A series of Yb^(3+)/Er^(3+) or Er^(3+) doped SrIn_2O_4 were synthesized by a high temperature solid state method.The up-conversion luminescence property and the phase formation of SrIn_2O_4:Er^(3+) and SrIn_2O_4:Yb^(3+),Er^(3+) were investigated by X-ray diffraction(XRD) and spectral methods.The XRD pattern shows that incorporating different amounts of Yb^(3+)and Er^(3+) have no influence on the phase formation of SrIn_2O_4.The up-conversion luminescence spectrum of SrIn_2O_4:Er^(3+) presented a weak luminescence due to ground state absorption of Er^(3+).However,Yb^(3+)/Er^(3+) codoped SrIn_2O_4 depicted the green(525 and 551 run) and red(662 nm) up-conversion luminescence which were assigned to the energy transfer from the Yb^(3+) transition ~2F_(7/2)-~2F_(5/2) to the Er^(3+) transitions ~2H_(11/2)-~4I_(15/2) and ~4F_(9/2-~4I_(15/2),respectively.The possible up-conversion luminescence mechanism of SrIn_2O_4:Yb^(3+),Er^(3+) was analyzed.All results could be helpful to the development of up-conversion luminescence materials.
