Gd2O3∶Tb3+ luminescent nanoparticles were prepared by the thermal decomposition of the nanosized oxlate prepared in the reverse microemulsions based on triton X-100/n-hexyl alcohol, n-octane, and water. From TG-DTA, ...Gd2O3∶Tb3+ luminescent nanoparticles were prepared by the thermal decomposition of the nanosized oxlate prepared in the reverse microemulsions based on triton X-100/n-hexyl alcohol, n-octane, and water. From TG-DTA, XRD and FTIR analyses, the mechanism of thermal decomposition of the nanosized oxalate precursor is suggested as follows: Gd2(C2O4)3·10H2O → Gd2(C2O4)3 + 10H2O, Gd2(C2O4)3 → Gd2O2(CO3) + 3CO +2CO2, Gd2O2(CO3) → Gd2O3 + CO2. The kinetic parameters of thermal decomposition reaction-activation energy E of stage 2 and 3 are 194.6 kJ·mol-1, 110.9 kJ·mol-1, respectively, using Ozawa method. And the reaction order n is 2.9 and 0.43, respectively, according to the TG curves.展开更多
文摘Gd2O3∶Tb3+ luminescent nanoparticles were prepared by the thermal decomposition of the nanosized oxlate prepared in the reverse microemulsions based on triton X-100/n-hexyl alcohol, n-octane, and water. From TG-DTA, XRD and FTIR analyses, the mechanism of thermal decomposition of the nanosized oxalate precursor is suggested as follows: Gd2(C2O4)3·10H2O → Gd2(C2O4)3 + 10H2O, Gd2(C2O4)3 → Gd2O2(CO3) + 3CO +2CO2, Gd2O2(CO3) → Gd2O3 + CO2. The kinetic parameters of thermal decomposition reaction-activation energy E of stage 2 and 3 are 194.6 kJ·mol-1, 110.9 kJ·mol-1, respectively, using Ozawa method. And the reaction order n is 2.9 and 0.43, respectively, according to the TG curves.
基金Projects(51804136,51764016)supported by the National Natural Science Foundation of ChinaProject(U1402271)supported by the Joint Funds of the National Natural Science Foundation of China+2 种基金Project(20181BAB216017)supported by the Jiangxi Provincial Natural Science Foundation,ChinaProject(GK-201803)supported by the Research Fund Program of State Key Laboratory of Rare Metals Separation and Comprehensive Utilization,ChinaProjects(yy2016001,yy2016012)supported by the Research Fund Program of the State Key Laboratory of Pressure Hydrometallurgical Technology of Associated Nonferrous Metal Resources,China。