The oxygen evolution reaction(OER)represents one of the major bottlenecks for broad-based applications of many clean energy storage/conversion technologies.The key to solving this problem lies in developing high-perfo...The oxygen evolution reaction(OER)represents one of the major bottlenecks for broad-based applications of many clean energy storage/conversion technologies.The key to solving this problem lies in developing high-performing,cost effective and stable catalysts for the OER.Herein,we demonstrate that ubiquitous stainless steel mesh(SSM)materials activated by a facile cathodization treatment can be employed as a high performing OER catalyst,as showcased by the impressively low overpotentials of 275 and 319 mV to reach the benchmark current densities of 10 and 100 mA cm^−2(1.0 M KOH),respectively.Cathodized SSM also exhibits excellent performance in a two-electrode water electrolyzer,which requires a low cell voltage of 1.58 at 10 mA cm^−2 and outperforms many of water electrolyzers using earth-abundant OER catalysts.Moreover,cathodized SSM with minor performance degradation after the stability test can also be readily healed by subjecting it to an additional cathodization treatment.It is disclosed that the superior performance of cathodized SSMs stems from the surface enrichment of OER active Ni(oxy)hydroxide,facile gas-bubble removal and transportation over the unique mesh-structured surfaces,while the abundant reservoir of nickel in the bulk allows healing of the catalyst by a facile cathodization.展开更多
The development of an electrocatalyst based on abundant elements for the oxygen evolution reaction （OER） is important for water splitting associated with renewable energy sources. In this study, we develop an interc...The development of an electrocatalyst based on abundant elements for the oxygen evolution reaction （OER） is important for water splitting associated with renewable energy sources. In this study, we develop an interconnected Ni（Fe）OxHy nanosheet array on a stainless steel mesh （SSNNi） as an integrated OER electrode, without using any polymer binder. Benefiting from the well- defined three-dimensional （3D） architecture with highly exposed surface area, intimate contact between the active species and conductive substrate improved electron and mass transport capacity, facilitated electrolyte penetration, and improved mechanical stability. The SSNNi electrode also has excellent OER performance, including low overpotential, a small Tafel slope, and long-term durability in the alkaline electrolyte, making it one of the most promising OER electrodes developed.展开更多
Because of the increasing amount of oily wastewater produced each day,it is important to develop superhydrophilic/underwater superoleophobic oil/water separation membranes with ultrahigh flux and high separation effic...Because of the increasing amount of oily wastewater produced each day,it is important to develop superhydrophilic/underwater superoleophobic oil/water separation membranes with ultrahigh flux and high separation efficiency.In this paper,a superhydrophilic/underwater superoleophobic N-isopropylacrylamide-coated stainless steel mesh was prepared through a simple and convenient graft polymerization approach.The obtained mesh was able to separate oil/water mixtures only by gravity.In addition,the mesh showed high-efficiency separation ability(99.2%)and ultrahigh flux(235239 L·m^(−2)·h^(−1)).Importantly,due to the complex cross-linked bilayer structure,the prepared mesh exhibited good recycling performance and chemical stability in highly saline,alkaline and acidic environments.展开更多
A series of zinc oxide(ZnO)nanorods arrays with different morphologies are synthesized on stainless steel mesh via a facile electrodeposition method.The influences of electrodeposition parameters on the diameter,lengt...A series of zinc oxide(ZnO)nanorods arrays with different morphologies are synthesized on stainless steel mesh via a facile electrodeposition method.The influences of electrodeposition parameters on the diameter,length,density and morphology of obtained ZnO nanorods are investigated systematically.The results indicate that the electrodeposition potential is the key factor for the morphology of the obtained ZnO nanorods,which further showed the effect on the photocatalytic property of the obtained samples.Meanwhile,the prepared ZnO nanorods array exhibits an excellent photocatalytic activity for methylene blue(MB)in ultraviolet light.The degradation efficiency for MB solution reaches 95.1%under the irradiation of ultraviolet light for 120 min.In addition,the photocatalytic property of the prepared ZnO nanorods can be extended to the visible light region after the modified with graphene oxide(GO).The obtained GO/ZnO composite also shows remarkable photocatalytic activity and photostability.The photodegradation efficiency for MB is 83.6%,and the catalytic performance retains 97.3% of its initial photocatalytic activity after five cycles.展开更多
Three kinds of mathematical models representing welding heat sources are presented. Among them, Gaussian model and double ellipsoidal model are used to analyze the thermal distributions with finite element method. At ...Three kinds of mathematical models representing welding heat sources are presented. Among them, Gaussian model and double ellipsoidal model are used to analyze the thermal distributions with finite element method. At the same time, this paper analyzed the influences of the heat source models, the latent heat and the welding parameters on the temperature distributions. The comparisons between the simulated results and the experiments show double ellipsoidal model is good for three-dimensional numerical simulations. Furthermore, the adaptive mesh technique is applied in the three-dimensional model which greatly reduces the number of nodes and elements in the simulation.展开更多
An anode was constructed using a novel technique and subsequently tested in a bio-battery. The anode comprised of a composite electrode coated with immobilized bacteria. The immobilized bacteria used in this study wer...An anode was constructed using a novel technique and subsequently tested in a bio-battery. The anode comprised of a composite electrode coated with immobilized bacteria. The immobilized bacteria used in this study were Escherichia coli K-12. The composite electrode contained three layers: a 304 L stainless steel mesh base, an electro-polymerized layer of pyrrole, and an electro-polymerized layer of methylene blue. The bacteria were immobilized utilizing a technique incorporating a carbon nanoparticle and Teflon<sup>TM</sup> emulsion. The composite electrode combined with immobilized bacteria was examined whilst incorporated into the anodic chamber of a bio-battery. Different tests were conducted, including Electrochemical Impedance Spectroscopy. Results from these tests were compared with data obtained from alternate configurations and values from the open literature. The maximum power density generated by the composite electrode with immobilized bacteria whilst incorporated into the anodic chamber of a bio-battery was 378 mW/m<sup>2</sup>. Results demonstrate this composite anode configuration with immobilized bacteria produced approximately 69% more power density and 53% more current density than alternate electrode configurations with bacteria suspended in solution. Also, it was found that a significant portion of the bio-battery’s resistance to charge transfer occurred at the surface of the anode and this resistance was lowered by 51% through bacteria immobilization.展开更多
基金funding from the European Research Council(ERC)under the European Union’s Horizon 2020 research and innovation program(grant agreement No.681719)L.-L.S.acknowledges the funding from the China Scholarship Council(No.201506210077)。
文摘The oxygen evolution reaction(OER)represents one of the major bottlenecks for broad-based applications of many clean energy storage/conversion technologies.The key to solving this problem lies in developing high-performing,cost effective and stable catalysts for the OER.Herein,we demonstrate that ubiquitous stainless steel mesh(SSM)materials activated by a facile cathodization treatment can be employed as a high performing OER catalyst,as showcased by the impressively low overpotentials of 275 and 319 mV to reach the benchmark current densities of 10 and 100 mA cm^−2(1.0 M KOH),respectively.Cathodized SSM also exhibits excellent performance in a two-electrode water electrolyzer,which requires a low cell voltage of 1.58 at 10 mA cm^−2 and outperforms many of water electrolyzers using earth-abundant OER catalysts.Moreover,cathodized SSM with minor performance degradation after the stability test can also be readily healed by subjecting it to an additional cathodization treatment.It is disclosed that the superior performance of cathodized SSMs stems from the surface enrichment of OER active Ni(oxy)hydroxide,facile gas-bubble removal and transportation over the unique mesh-structured surfaces,while the abundant reservoir of nickel in the bulk allows healing of the catalyst by a facile cathodization.
基金This work is financially supported by the National Natural Science Foundation of China （Nos. 51472209, U1401241, 51522101, 51471075, 5163100, and 51401084）, and Specialized Research Fund for the Doctoral Program of Higher Education of China （No. 20110061120040）.
文摘The development of an electrocatalyst based on abundant elements for the oxygen evolution reaction （OER） is important for water splitting associated with renewable energy sources. In this study, we develop an interconnected Ni（Fe）OxHy nanosheet array on a stainless steel mesh （SSNNi） as an integrated OER electrode, without using any polymer binder. Benefiting from the well- defined three-dimensional （3D） architecture with highly exposed surface area, intimate contact between the active species and conductive substrate improved electron and mass transport capacity, facilitated electrolyte penetration, and improved mechanical stability. The SSNNi electrode also has excellent OER performance, including low overpotential, a small Tafel slope, and long-term durability in the alkaline electrolyte, making it one of the most promising OER electrodes developed.
基金supported by the National Natural Science Foundation of China(Grant No.51473070).
文摘Because of the increasing amount of oily wastewater produced each day,it is important to develop superhydrophilic/underwater superoleophobic oil/water separation membranes with ultrahigh flux and high separation efficiency.In this paper,a superhydrophilic/underwater superoleophobic N-isopropylacrylamide-coated stainless steel mesh was prepared through a simple and convenient graft polymerization approach.The obtained mesh was able to separate oil/water mixtures only by gravity.In addition,the mesh showed high-efficiency separation ability(99.2%)and ultrahigh flux(235239 L·m^(−2)·h^(−1)).Importantly,due to the complex cross-linked bilayer structure,the prepared mesh exhibited good recycling performance and chemical stability in highly saline,alkaline and acidic environments.
基金supported by the National Natural Science Foundation of China(Nos.51774217,51604202 and 51604201)the Shanghai Sailing Program(No.19YF1415800)the Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education,China(No.FMRU-lab-20-2).
文摘A series of zinc oxide(ZnO)nanorods arrays with different morphologies are synthesized on stainless steel mesh via a facile electrodeposition method.The influences of electrodeposition parameters on the diameter,length,density and morphology of obtained ZnO nanorods are investigated systematically.The results indicate that the electrodeposition potential is the key factor for the morphology of the obtained ZnO nanorods,which further showed the effect on the photocatalytic property of the obtained samples.Meanwhile,the prepared ZnO nanorods array exhibits an excellent photocatalytic activity for methylene blue(MB)in ultraviolet light.The degradation efficiency for MB solution reaches 95.1%under the irradiation of ultraviolet light for 120 min.In addition,the photocatalytic property of the prepared ZnO nanorods can be extended to the visible light region after the modified with graphene oxide(GO).The obtained GO/ZnO composite also shows remarkable photocatalytic activity and photostability.The photodegradation efficiency for MB is 83.6%,and the catalytic performance retains 97.3% of its initial photocatalytic activity after five cycles.
文摘Three kinds of mathematical models representing welding heat sources are presented. Among them, Gaussian model and double ellipsoidal model are used to analyze the thermal distributions with finite element method. At the same time, this paper analyzed the influences of the heat source models, the latent heat and the welding parameters on the temperature distributions. The comparisons between the simulated results and the experiments show double ellipsoidal model is good for three-dimensional numerical simulations. Furthermore, the adaptive mesh technique is applied in the three-dimensional model which greatly reduces the number of nodes and elements in the simulation.
文摘An anode was constructed using a novel technique and subsequently tested in a bio-battery. The anode comprised of a composite electrode coated with immobilized bacteria. The immobilized bacteria used in this study were Escherichia coli K-12. The composite electrode contained three layers: a 304 L stainless steel mesh base, an electro-polymerized layer of pyrrole, and an electro-polymerized layer of methylene blue. The bacteria were immobilized utilizing a technique incorporating a carbon nanoparticle and Teflon<sup>TM</sup> emulsion. The composite electrode combined with immobilized bacteria was examined whilst incorporated into the anodic chamber of a bio-battery. Different tests were conducted, including Electrochemical Impedance Spectroscopy. Results from these tests were compared with data obtained from alternate configurations and values from the open literature. The maximum power density generated by the composite electrode with immobilized bacteria whilst incorporated into the anodic chamber of a bio-battery was 378 mW/m<sup>2</sup>. Results demonstrate this composite anode configuration with immobilized bacteria produced approximately 69% more power density and 53% more current density than alternate electrode configurations with bacteria suspended in solution. Also, it was found that a significant portion of the bio-battery’s resistance to charge transfer occurred at the surface of the anode and this resistance was lowered by 51% through bacteria immobilization.
