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High throughput N-modular redundancy for error correction design of memristive stateful logic
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作者 朱熙 徐晖 +5 位作者 杨为平 李智炜 刘海军 刘森 王义楠 龙泓昌 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第1期568-579,共12页
Memristive stateful logic is one of the most promising candidates to implement an in-memory computing system that computes within the storage unit.It can eliminate the costs for the data movement in the traditional vo... Memristive stateful logic is one of the most promising candidates to implement an in-memory computing system that computes within the storage unit.It can eliminate the costs for the data movement in the traditional von Neumann system.However,the instability in the memristors is inevitable due to the limitation of the current fabrication technology,which incurs a great challenge for the reliability of the memristive stateful logic.In this paper,the implication of device instability on the reliability of the logic event is simulated.The mathematical relationship between logic reliability and redundancy has been deduced.By combining the mathematical relationship with the vector-matrix multiplication in a memristive crossbar array,the logic error correction scheme with high throughput has been proposed.Moreover,a universal design paradigm has been put forward for complex logic.And the circuit schematic and the flow of the scheme have been raised.Finally,a 1-bit full adder(FA)based on the NOR logic and NOT logic is simulated and the mathematical evaluation is performed.It demonstrates the scheme can improve the reliability of the logic significantly.And compared with other four error corrections,the scheme which can be suitable for all kinds of R–R logics and V–R logics has the best universality and throughput.Compared with the other two approaches which also need additional complementary metal–oxide semiconductor(CMOS)circuits,it needs fewer transistors and cycles for the error correction. 展开更多
关键词 MEMRISTOR stateful logic logic reliability in-memory computing
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广域网整合中Stateful NAT、OSPF双进程相结合的设计与应用 被引量:2
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作者 李健俊 俞先永 +1 位作者 刘鹏 姜学峰 《计算机系统应用》 2010年第3期133-136,共4页
大型企业重组和兼并,需要将多个独立的私网整合为一个统一管理的网络。提出利用Stateful Nat和OSPF双进程技术相结合,解决双路由模式下两个私网间的NAT同步和私网地址发布的问题,从而实现设备的冗余热备和负载均衡,提高网络的可靠性和... 大型企业重组和兼并,需要将多个独立的私网整合为一个统一管理的网络。提出利用Stateful Nat和OSPF双进程技术相结合,解决双路由模式下两个私网间的NAT同步和私网地址发布的问题,从而实现设备的冗余热备和负载均衡,提高网络的可靠性和安全性。 展开更多
关键词 广域网 stateful NAT OSPF
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Automatic discovery of stateful variables in network protocol software based on replay analysis
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作者 Jianxin HUANG Bo YU +1 位作者 Runhao LIU Jinshu SU 《Frontiers of Information Technology & Electronic Engineering》 SCIE EI CSCD 2023年第3期403-416,共14页
Network protocol software is usually characterized by complicated functions and a vast state space.In this type of program,a massive number of stateful variables that are used to represent the evolution of the states ... Network protocol software is usually characterized by complicated functions and a vast state space.In this type of program,a massive number of stateful variables that are used to represent the evolution of the states and store some information about the sessions are prone to potentialflaws caused by violations of protocol specification requirements and program logic.Discovering such variables is significant in discovering and exploiting vulnerabilities in protocol software,and still needs massive manual verifications.In this paper,we propose a novel method that could automatically discover the use of stateful variables in network protocol software.The core idea is that a stateful variable features information of the communication entities and the software states,so it will exist in the form of a global or static variable during program execution.Based on recording and replaying a protocol program’s execution,varieties of variables in the life cycle can be tracked with the technique of dynamic instrument.We draw up some rules from multiple dimensions by taking full advantage of the existing vulnerability knowledge to determine whether the data stored in critical memory areas have stateful characteristics.We also implement a prototype system that can discover stateful variables automatically and then perform it on nine programs in Pro FuzzBench and two complex real-world software programs.With the help of available open-source code,the evaluation results show that the average true positive rate(TPR)can reach 82%and the average precision can be approximately up to 96%. 展开更多
关键词 stateful variables Network protocol software Program analysis technology Network security
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Test Data Generation for Stateful Network Protocol Fuzzing Using a Rule-Based State Machine 被引量:13
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作者 Rui Ma Daguang Wang +2 位作者 Changzhen Hu Wendong Ji Jingfeng Xue 《Tsinghua Science and Technology》 SCIE EI CAS CSCD 2016年第3期352-360,共9页
To improve the efficiency and coverage of stateful network protocol fuzzing, this paper proposes a new method, using a rule-based state machine and a stateful rule tree to guide the generation of fuzz testing data. Th... To improve the efficiency and coverage of stateful network protocol fuzzing, this paper proposes a new method, using a rule-based state machine and a stateful rule tree to guide the generation of fuzz testing data. The method first builds a rule-based state machine model as a formal description of the states of a network protocol. This removes safety paths, to cut down the scale of the state space. Then it uses a stateful rule tree to describe the relationship between states and messages, and then remove useless items from it. According to the message sequence obtained by the analysis of paths using the stateful rule tree and the protocol specification, an abstract data model of test case generation is defined. The fuzz testing data is produced by various generation algorithms through filling data in the fields of the data model. Using the rule-based state machine and the stateful rule tree, the quantity of test data can be reduced. Experimental results indicate that our method can discover the same vulnerabilities as traditional approaches, using less test data, while optimizing test data generation and improving test efficiency. 展开更多
关键词 FUZZING stateful network protocol test data generation rule-based state machine stateful rule tree
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A Study on the Transmission Dynamics of the Omicron Variant of COVID-19 Using Nonlinear Mathematical Models 被引量:1
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作者 S.Dickson S.Padmasekaran +2 位作者 Pushpendra Kumar Kottakkaran Sooppy Nisar Hamidreza Marasi 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第6期2265-2287,共23页
This research examines the transmission dynamics of the Omicron variant of COVID-19 using SEIQIcRVW and SQIRV models,considering the delay in converting susceptible individuals into infected ones.The significant delay... This research examines the transmission dynamics of the Omicron variant of COVID-19 using SEIQIcRVW and SQIRV models,considering the delay in converting susceptible individuals into infected ones.The significant delays eventually resulted in the pandemic’s containment.To ensure the safety of the host population,this concept integrates quarantine and the COVID-19 vaccine.We investigate the stability of the proposed models.The fundamental reproduction number influences stability conditions.According to our findings,asymptomatic cases considerably impact the prevalence of Omicron infection in the community.The real data of the Omicron variant from Chennai,Tamil Nadu,India,is used to validate the outputs. 展开更多
关键词 Omicron local stability reproduction number steady states global stability
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Challenges and opportunities for battery health estimation:Bridging laboratory research and real-world applications 被引量:1
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作者 Te Han Jinpeng Tian +1 位作者 C.Y.Chung Yi-Ming Wei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期434-436,I0011,共4页
Addressing climate change demands a significant shift away from fossil fuels,with sectors like electricity and transportation relying heavily on renewable energy.Integral to this transition are energy storage systems,... Addressing climate change demands a significant shift away from fossil fuels,with sectors like electricity and transportation relying heavily on renewable energy.Integral to this transition are energy storage systems,notably lithium-ion batteries.Over time,these batteries degrade,affecting their efficiency and posing safety risks.Monitoring and predicting battery aging is essential,especially estimating its state of health(SOH).Various SOH estimation methods exist,from traditional model-based approaches to machine learning approaches. 展开更多
关键词 Energy storage systems State of health Multi-source data Scientific AI Data-sharing mechanism
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Incombustible solid polymer electrolytes:A critical review and perspective
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作者 Kai Wu Jin Tan +4 位作者 Zhenfang Liu Chenguang Bao Ao Li Qi Liu Baohua Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期264-281,I0007,共19页
Since the advent of the solid-state batteries,employing solid polymer electrolytes(SPEs)to replace routine flammable liquid electrolytes is regarded to be one of the most promising solutions in pursing highenergy-dens... Since the advent of the solid-state batteries,employing solid polymer electrolytes(SPEs)to replace routine flammable liquid electrolytes is regarded to be one of the most promising solutions in pursing highenergy-density battery systems.SPEs with superior thermal stability,good processability,and high mechanical modulus obtain increasing attentions.However,SPE-based batteries are not impenetrable due to their decomposition and combustibility under extreme conditions.Researchers believe incorporating appropriate flame-retardant additives/solvents/fragments into SPEs can intrinsically reduce their flammability to solve the battery safety issues.In this review,the recent research progress of incombustible SPEs,with special emphasis on flame-retardant structural design,is summarized.Specifically,a brief introduction of flame-retardant mechanism,evaluation index for safety of SPEs,and a detailed overview of the latest advances on diverse-types SPEs in various battery systems are highlighted.The deep insight into thermal ru naway process,the free-standing incombustible GPEs,and the ratio nal design of pouch cell structures may be the main directions to motivate revolutionary next-generation for safety batteries. 展开更多
关键词 Non-flammable electrolyte Solid polymer electrolyte High safety electrolyte Solid state electrolyte Solid state battery
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Topological edge and corner states of valley photonic crystals with zipper-like boundary conditions
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作者 沈云峰 许孝芳 +2 位作者 孙铭 周文佶 常雅箐 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期480-491,共12页
We present a stable valley photonic crystal(VPC)unit cell with C_(3v)symmetric quasi-ring-shaped dielectric columns and realize its topological phase transition by breaking mirror symmetry.Based on this unit cell stru... We present a stable valley photonic crystal(VPC)unit cell with C_(3v)symmetric quasi-ring-shaped dielectric columns and realize its topological phase transition by breaking mirror symmetry.Based on this unit cell structure,topological edge states(TESs)and topological corner states(TCSs)are realized.We obtain a new type of wave transmission mode based on photonic crystal zipper-like boundaries and apply it to a beam splitter assembled from rectangular photonic crystals(PCs).The constructed beam splitter structure is compact and possesses frequency separation functions.In addition,we construct a box-shaped triangular PC structures with zipper-like boundaries and discover phenomena of TCSs in the corners,comparing its corner states with those formed by other boundaries.Based on this,we explore the regularities of the electric field patterns of TESs and TCSs,explain the connection between the characteristic frequencies and locality of TCSs,which helps better control photons and ensures low power consumption of the system. 展开更多
关键词 valley photonic crystal topological edge states topological corner states higher-order topological insulators topological phase transition
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Target layer state estimation in multi-layer complex dynamical networks considering nonlinear node dynamics
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作者 吴亚勇 王欣伟 蒋国平 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期245-252,共8页
In many engineering networks, only a part of target state variables are required to be estimated.On the other hand,multi-layer complex network exists widely in practical situations.In this paper, the state estimation ... In many engineering networks, only a part of target state variables are required to be estimated.On the other hand,multi-layer complex network exists widely in practical situations.In this paper, the state estimation of target state variables in multi-layer complex dynamical networks with nonlinear node dynamics is studied.A suitable functional state observer is constructed with the limited measurement.The parameters of the designed functional observer are obtained from the algebraic method and the stability of the functional observer is proven by the Lyapunov theorem.Some necessary conditions that need to be satisfied for the design of the functional state observer are obtained.Different from previous studies, in the multi-layer complex dynamical network with nonlinear node dynamics, the proposed method can estimate the state of target variables on some layers directly instead of estimating all the individual states.Thus, it can greatly reduce the placement of observers and computational cost.Numerical simulations with the three-layer complex dynamical network composed of three-dimensional nonlinear dynamical nodes are developed to verify the effectiveness of the method. 展开更多
关键词 multi-layer complex dynamical network nonlinear node dynamics target state estimation functional state observer
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Hamiltonian system for the inhomogeneous plane elasticity of dodecagonal quasicrystal plates and its analytical solutions
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作者 孙志强 侯国林 +1 位作者 乔艳芬 刘金存 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期581-590,共10页
A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions o... A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions of the phonon and phason displacements are obtained further for the quasicrystal plates. In addition, the effectiveness of the approach is verified by comparison with the data of the finite integral transformation method. 展开更多
关键词 Hamiltonian system symplectic elasticity QUASICRYSTALS analytic solution state function
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Morphology and valence state evolution of Cu:Unraveling the impact on nitric oxide electroreduction
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作者 Ting Sun Fengyu Gao +4 位作者 Ya Wang Honghong Yi Qingjun Yu Shunzheng Zhao Xiaolong Tang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期276-286,共11页
Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas denitrification.However,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption... Ammonia(NH3)serves as a critical component in the fertilizer industry and fume gas denitrification.However,the conventional NH3production process,namely the Haber-Bosch process,leads to considerable energy consumption and waste gas emissions.To address this,electrocatalytic nitric oxide reduction reaction(NORR)has emerged as a promising strategy to bridge NH3consumption to NH3production,harnessing renewable electricity for a sustainable future.Copper(Cu)stands out as a prominent electrocatalyst for NO reduction,given its exceptional NH3yield and selectivity.However,a crucial aspect that remains insufficiently explored is the effects of morphology and valence states of Cu on the NORR performance.In this investigation,we synthesized CuO nanowires(CuO-NF)and Cu nanocubes(Cu-NF)as cathodes through an in situ growth method.Remarkably,CuO-NF exhibited an impressive NH3yield of 0.50±0.02 mg cm^(-2)h^(-1)at-0.6 V vs.reversible hydrogen electrode(RHE)with faradaic efficiency of29,68%±1,35%,surpassing that of Cu-NF(0.17±0.01 mg cm^(-2)h^(-1),16.18%±1.40%).Throughout the electroreduction process,secondary cubes were generated on the CuO-NF surface,preserving their nanosheet cluster morphology,sustained by an abundant supply of subsurface oxygen(s-O)even after an extended duration of 10 h,until s-O depletion ensued.Conversely,Cu-NF exhibited inadequate s-O content,leading to rapid crystal collapse within the same timeframe.The distinctive current-potential relationship,akin to a volcano-type curve,was attributed to distinct NO hydrogenation mechanisms.Further Tafel analysis revealed the exchange current density(i0)and standard heterogeneous rate constant(k0)for CuO-NF,yielding 3.44×10^(-6)A cm^(-2)and 3.77×10^(-6)cm^(-2)s^(-1)when NORR was driven by overpotentials.These findings revealed the potential of CuO-NF for NO reduction and provided insights into the intricate interplay between crystal morphology,valence states,and electrochemical performance. 展开更多
关键词 NORR Ammonia Synthesis COPPER MORPHOLOGY Valence States Mechanism
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Spectroscopy and molecule opacity investigation on excited states of SiS
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作者 李瑞 吕浩男 +3 位作者 桑纪群 刘晓华 梁桂颖 吴勇 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第5期381-387,共7页
The SiS molecule,which plays a significant role in space,has attracted a great deal of attention for many years.Due to complex interactions among its low-lying electronic states,precise information regarding the molec... The SiS molecule,which plays a significant role in space,has attracted a great deal of attention for many years.Due to complex interactions among its low-lying electronic states,precise information regarding the molecular structure of SiS is limited.To obtain accurate information about the structure of its excited states,the high-precision multireference configuration interaction(MRCI)method has been utilized.This method is used to calculate the potential energy curves(PECs)of the 18Λ–S states corresponding to the lowest dissociation limit of SiS.The core–valence correlation effect,Davidson’s correction and the scalar relativistic effect are also included to guarantee the precision of the MRCI calculation.Based on the calculated PECs,the spectroscopic constants of quasi-bound and bound electronic states are calculated and they are in accordance with previous experimental results.The transition dipole moments(TDMs)and dipole moments(DMs)are determined by the MRCI method.In addition,the abrupt variations of the DMs for the 1^(5)Σ^(+)and 2^(5)Σ^(+)states at the avoided crossing point are attributed to the variation of the electronic configuration.The opacity of SiS at a pressure of 100 atms is presented across a series of temperatures.With increasing temperature,the expanding population of excited states blurs the band boundaries. 展开更多
关键词 SIS OPACITY excited state spectroscopic constant configuration interaction
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THE LIMITING PROFILE OF SOLUTIONS FOR SEMILINEAR ELLIPTIC SYSTEMS WITH A SHRINKING SELF-FOCUSING CORE
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作者 金可 石影 谢华飞 《Acta Mathematica Scientia》 SCIE CSCD 2024年第2期583-608,共26页
In this paper,we consider the semilinear elliptic equation systems{△u+u=αQ_(n)(x)|u|^(α-2)|v|^(β)u in R^(N),-△v+v=βQ(x)|u|^(α)|v|^(β-2)v in R^(N),where N≥3,α,β>1,α+β<2^(*),2^(*)=2N/N-2 and Q_(n) are... In this paper,we consider the semilinear elliptic equation systems{△u+u=αQ_(n)(x)|u|^(α-2)|v|^(β)u in R^(N),-△v+v=βQ(x)|u|^(α)|v|^(β-2)v in R^(N),where N≥3,α,β>1,α+β<2^(*),2^(*)=2N/N-2 and Q_(n) are bounded given functions whose self-focusing cores{x∈R^(N)|Q_(n)(x)>0} shrink to a set with finitely many points as n→∞.Motivated by the work of Fang and Wang[13],we use variational methods to study the limiting profile of ground state solutions which are concentrated at one point of the set with finitely many points,and we build the localized concentrated bound state solutions for the above equation systems. 展开更多
关键词 Schrödinger system ground states solutions bound state solutions
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Assessment of Wet Season Precipitation in the Central United States by the Regional Climate Simulation of the WRFG Member in NARCCAP and Its Relationship with Large-Scale Circulation Biases
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作者 Yating ZHAO Ming XUE +2 位作者 Jing JIANG Xiao-Ming HU Anning HUANG 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2024年第4期619-638,共20页
Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional climate.Here,we assess the performance and discuss pos... Assessment of past-climate simulations of regional climate models(RCMs)is important for understanding the reliability of RCMs when used to project future regional climate.Here,we assess the performance and discuss possible causes of biases in a WRF-based RCM with a grid spacing of 50 km,named WRFG,from the North American Regional Climate Change Assessment Program(NARCCAP)in simulating wet season precipitation over the Central United States for a period when observational data are available.The RCM reproduces key features of the precipitation distribution characteristics during late spring to early summer,although it tends to underestimate the magnitude of precipitation.This dry bias is partially due to the model’s lack of skill in simulating nocturnal precipitation related to the lack of eastward propagating convective systems in the simulation.Inaccuracy in reproducing large-scale circulation and environmental conditions is another contributing factor.The too weak simulated pressure gradient between the Rocky Mountains and the Gulf of Mexico results in weaker southerly winds in between,leading to a reduction of warm moist air transport from the Gulf to the Central Great Plains.The simulated low-level horizontal convergence fields are less favorable for upward motion than in the NARR and hence,for the development of moist convection as well.Therefore,a careful examination of an RCM’s deficiencies and the identification of the source of errors are important when using the RCM to project precipitation changes in future climate scenarios. 展开更多
关键词 NARCCAP Central United States PRECIPITATION low-level jet large-scale environment diurnal variation
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Numerical simulation for the initial state of avalanche in polydisperse particle systems
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作者 韩韧 李亭 +2 位作者 迟志鹏 杨晖 李然 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第2期405-412,共8页
Numerical simulation is employed to investigate the initial state of avalanche in polydisperse particle systems.Nucleation and propagation processes are illustrated for pentadisperse and triadisperse particle systems,... Numerical simulation is employed to investigate the initial state of avalanche in polydisperse particle systems.Nucleation and propagation processes are illustrated for pentadisperse and triadisperse particle systems,respectively.In these processes,particles involved in the avalanche grow slowly in the early stage and explosively in the later stage,which is clearly different from the continuous and steady growth trend in the monodisperse system.By examining the avalanche propagation,the number growth of particles involved in the avalanche and the slope of the number growth,the initial state can be divided into three stages:T1(nucleation stage),T2(propagation stage),T3(overall avalanche stage).We focus on the characteristics of the avalanche in the T2 stage,and find that propagation distances increase almost linearly in both axial and radial directions in polydisperse systems.We also consider the distribution characteristics of the average coordination number and average velocity for the moving particles.The results support that the polydisperse particle systems are more stable in the T2 stage. 展开更多
关键词 AVALANCHE initial state polydisperse particle systems PROPAGATION
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Optical-Microwave Entanglement Paves the Way for Distributed Quantum Computation
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作者 胡志刚 许凯 +1 位作者 张玉祥 李贝贝 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第1期21-24,共4页
Over the past few years,quantum computation based on superconducting circuits has achieved remarkable progress.A milestone occurred in 2019 when Google released Sycamore,a processor with 54 qubits,and claimed quantum ... Over the past few years,quantum computation based on superconducting circuits has achieved remarkable progress.A milestone occurred in 2019 when Google released Sycamore,a processor with 54 qubits,and claimed quantum supremacy by performing in just 100 s a specific computation which would take a classical supercomputer,as stated by Google’s team,10000 years to complete.[1]In 2021,a strong quantum advantage was demonstrated by Pan and his colleagues from the University of Science and Technology of China,using a quantum processor named Zuchongzhi,which has 66 functional qubits.[2]This year,the record of the number of quantum qubits has been lifted to 127 qubits.[3]Indeed,the number of qubits is limited to a few hundreds due to the finite space of dilution refrigerators,where the superconducting qubits must be placed to be isolated from thermal noise.However,this number is still several orders of magnitude away from the requirement of quantum error correction,which is essential for general-purpose quantum computers.[4–8]. 展开更多
关键词 QUANTUM stated CORRECTION
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Predicted Critical State Based on Invariance of the Lyapunov Exponent in Dual Spaces
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作者 刘通 夏旭 《Chinese Physics Letters》 SCIE EI CAS CSCD 2024年第1期68-76,共9页
Critical states in disordered systems,fascinating and subtle eigenstates,have attracted a lot of research interests.However,the nature of critical states is difficult to describe quantitatively,and in general,it canno... Critical states in disordered systems,fascinating and subtle eigenstates,have attracted a lot of research interests.However,the nature of critical states is difficult to describe quantitatively,and in general,it cannot predict a system that hosts the critical state.We propose an explicit criterion whereby the Lyapunov exponent of the critical state should be 0 simultaneously in dual spaces,namely the Lyapunov exponent remains invariant under the Fourier transform.With this criterion,we can exactly predict a one-dimensional quasiperiodic model which is not of self-duality,but hosts a large number of critical states.Then,we perform numerical verification of the theoretical prediction and display the self-similarity of the critical state.Due to computational complexity,calculations are not performed for higher dimensional models.However,since the description of extended and localized states by the Lyapunov exponent is universal and dimensionless,utilizing the Lyapunov exponent of dual spaces to describe critical states should also be universal.Finally,we conjecture that some kind of connection exists between the invariance of the Lyapunov exponent and conformal invariance,which can promote the research of critical phenomena. 展开更多
关键词 STATE EXPONENT CRITICAL
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List of 85 typical catastrophic landslides from March 2004 to February 2024
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作者 Rui-chen Chen Yong-shuang Zhang 《China Geology》 CAS CSCD 2024年第2期369-370,共2页
Landslides are one of the most dangerous natural hazards that cause significant property damage and loss of life.Landslides often destroy farmland,villages,houses,factories,schools,roads and other facilities,injuring ... Landslides are one of the most dangerous natural hazards that cause significant property damage and loss of life.Landslides often destroy farmland,villages,houses,factories,schools,roads and other facilities,injuring humans and livestock.Sometimes,entire towns are devastated by landslides.Due to their pervasiveness,varied triggering factors,and sudden occurrence,landslides are currently one of the most challenging natural disasters to prevent and mitigate. 展开更多
关键词 stated FARMLAND CATASTROPHIC
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Effect of mesopore spatial distribution of HZSM-5 catalyst on zinc state and product distribution in 1-hexene aromatization
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作者 Chenhao Wei Di Gao +3 位作者 Guohao Zhang Liang Zhao Jinsen Gao Chunming Xu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第3期16-26,共11页
1-hexene aromatization is a promising technology to convert excess olefin in fluid catalytic cracking(FCC)gasoline to high-value benzene(B),toluene(T),and xylene.Besides,the increasing market demand of xylene has put ... 1-hexene aromatization is a promising technology to convert excess olefin in fluid catalytic cracking(FCC)gasoline to high-value benzene(B),toluene(T),and xylene.Besides,the increasing market demand of xylene has put forward higher requirements for new generation of catalyst.For increasing xylene yield in 1-hexene aromatization,the effect of mesopore structure and spatial distribution on product distribution and Zn loading was studied.Catalysts with different mesopore spatial distribution were prepared by post-treatment of parent HZSM-5 zeolite,including NaOH treatment,tetra-propylammonium hydroxide(TPAOH)treatment,and recrystallization.It was found the evenly distributed mesopore mainly prolongs the catalyst lifetime by enhancing diffusion properties but reduces the aromatics selectivity,as a result of damage of micropores close to the catalyst surface.While the selectivity of high-value xylene can be highly promoted when the mesopore is mainly distributed interior the catalyst.Besides,the state of loaded Zn was also affected by mesopores spatial distribution.On the optimized catalyst,the xylene selectivity was enhanced by 12.4%compared with conventional Zn-loaded parent HZSM-5 catalyst at conversion over 99%.It was attributed to the synergy effect of mesopores spatial distribution and optimized acid properties.This work reveals the role of mesopores in different spatial positions of 1-hexene aromatization catalysts in the reaction process and the influence on metal distribution,as well as their synergistic effect two on the improvement of xylene selectivity,which can improve our understanding of catalyst pore structure and be helpful for the rational design of high-efficient catalyst. 展开更多
关键词 1-Hexene aromatization Alkali treatment Xylene selectivity MESOPORES Zinc state
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Valleytronic topological filters in silicene-like inner-edge systems
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作者 谢航 吕小龙 杨加恩 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期66-74,共9页
Inner edge state with spin and valley degrees of freedom is a promising candidate for designing a dissipationless device due to the topological protection. The central challenge for the application of the inner edge s... Inner edge state with spin and valley degrees of freedom is a promising candidate for designing a dissipationless device due to the topological protection. The central challenge for the application of the inner edge state is to generate and modulate the polarized currents. In this work, we discover a new mechanism to generate fully valley-and spin–valley-polarized current caused by the Bloch wavevector mismatch(BWM). Based on this mechanism, we design some serial-typed inner-edge filters. By using once of the BWM, the coincident states could be divided into transmitted and reflected modes, which can serve as a valley or spin–valley filter. In particular, while with twice of the BWM, the incident current is absolutely reflected to support an off state with a specified valley and spin, which is different from the gap effect.These findings give rise to a new platform for designing valleytronics and spin-valleytronics. 展开更多
关键词 topological insulator inner-edge state valley polarization spin polarization quantum transport
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