Based on the conventional meteorological data and the NCEP/NCAR 1° × 1° reanalysis data and those related to mid-scale automatic station, satellite cloud picture and radar return, with the dynamic...Based on the conventional meteorological data and the NCEP/NCAR 1° × 1° reanalysis data and those related to mid-scale automatic station, satellite cloud picture and radar return, with the dynamic diagnosis analysis method, an analysis is made on the process of the convective rainstorm of quasi-stationary front triggered by the weak cold air on June 4-7, 2014, showing: 1) the process occurred in the event of convection of a stationary front triggered by the eastward moving south trough and the southward moving weak cold air from west under the background of circulation of two ridges and one trough at the Asian-European mid-high latitude and weakening and southeastward moving subtropical high;2) a system configuration that contributes to convective rainstorms formed in the event of the convergence of low-level moisture, upper-level divergence and the continuous vertical ascending motion after the 200 hPa upper-level jet stream moved westwards from east and the 850 hPa southwest jet stream intensified;3) after the intrusion by weak cold air of the meso-scale katallobaric area formed by the accumulated warm moist air of Guangxi before the intrusion, the warm moist air rose to trigger convection;convection cells developed and spread nearby the boundary between anallobaric area and katallobaric area, during which total 5 MCSs developed and each formed a rainstorm center at the part where the MCSs coincide;a meso-scale katallobaric area forms and develops 2 - 5 hours earlier than convection, so that it is also a warning of heavy rains.展开更多
In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary rando...In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary random field in a small range,we give an entropy estimation and obtain the average entropy estimation formula in a certain bounded space region.It can be proven that the estimation of the average differential entropy converges to the theoretical value with a probability of 1.In addition,we also conducted numerical experiments for different parameters to verify the convergence result obtained in the theoretical proofs.展开更多
2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed...2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.展开更多
Capillary electrochromatography(CEC)plays a significant role in chiral separation via the double separation principle,partition coefficient difference between the two phases,and electroosmotic flow-driven separation.G...Capillary electrochromatography(CEC)plays a significant role in chiral separation via the double separation principle,partition coefficient difference between the two phases,and electroosmotic flow-driven separation.Given the distinct properties of the inner wall stationary phase(SP),the separation ability of each SP differs from one another.Particularly,it provides large room for promising applications of open tubular capillary electrochromatography(OT-CEC).We divided the OT-CEC SPs developed over the past four years into six types:ionic liquids,nanoparticle materials,microporous materials,biomaterials,non-nanopolymers,and others,to mainly introduce their characteristics in chiral drug separation.There also added a few classic SPs that occurred within ten years as supplements to enrich the features of each SP.Additionally,we discuss their applications in metabolomics,food,cosmetics,environment,and biology as analytes in addition to chiral drugs.OT-CEC plays an increasingly significant role in chiral separation and may promote the development of capillary electrophoresis(CE)combined with other instruments in recent years,such as CE with mass spectrometry(CE/MS)and CE with ultraviolet light detector(CE/UV).展开更多
Long memory is an important phenomenon that arises sometimes in the analysis of time series or spatial data.Most of the definitions concerning the long memory of a stationary process are based on the second-order prop...Long memory is an important phenomenon that arises sometimes in the analysis of time series or spatial data.Most of the definitions concerning the long memory of a stationary process are based on the second-order properties of the process.The mutual information between the past and future I_(p−f) of a stationary process represents the information stored in the history of the process which can be used to predict the future.We suggest that a stationary process can be referred to as long memory if its I_(p−f) is infinite.For a stationary process with finite block entropy,I_(p−f) is equal to the excess entropy,which is the summation of redundancies that relate the convergence rate of the conditional(differential)entropy to the entropy rate.Since the definitions of the I_(p−f) and the excess entropy of a stationary process require a very weak moment condition on the distribution of the process,it can be applied to processes whose distributions are without a bounded second moment.A significant property of I_(p−f) is that it is invariant under one-to-one transformation;this enables us to know the I_(p−f) of a stationary process from other processes.For a stationary Gaussian process,the long memory in the sense of mutual information is more strict than that in the sense of covariance.We demonstrate that the I_(p−f) of fractional Gaussian noise is infinite if and only if the Hurst parameter is H∈(1/2,1).展开更多
Efficient numerical algorithm for stochastic differential equation has been an important object in the research of statistical physics and mathematics for a long time.In this work we study the highly accurate numerica...Efficient numerical algorithm for stochastic differential equation has been an important object in the research of statistical physics and mathematics for a long time.In this work we study the highly accurate numerical algorithm for the overdamped Langevin equation.In particular,our interest is in the behaviour of the numerical schemes for solving the overdamped Langevin equation in the harmonic system.Based on the large friction limit of the underdamped Langevin dynamic scheme,three algorithms for overdamped Langevin equation are obtained.We derive the explicit expression of the stationary distribution of each algorithm by analysing the discrete time trajectory for both one-dimensional case and multi-dimensional case.The accuracy of the stationary distribution of each algorithm is illustrated by comparing with the exact Boltzmann distribution.Our results demonstrate that the“BAOA-limit”algorithm generates an accurate distribution of the harmonic system in a canonical ensemble,within a stable range of time interval.The other algorithms do not produce the exact distribution of the harmonic system.展开更多
This study aims at establishing if climate change exists in the Niger Delta environment using non-stationary rainfall Intensity-Duration-Frequency (IDF) modelling incorporating time-variant parameters. To compute the ...This study aims at establishing if climate change exists in the Niger Delta environment using non-stationary rainfall Intensity-Duration-Frequency (IDF) modelling incorporating time-variant parameters. To compute the intensity levels, the open-access R-studio software was used based on the General Extreme Value (GEV) distribution function. Among the four linear parameter models adopted for integrating time as a covariate, the fourth linear model incorporating scale and location with the shape function constant produced the least corrected Akaike Information Criteria (AICc), varying between 306.191 to 101.497 for 15 and 1440 minutes, respectively, selected for calibration of the GEV distribution equation. The non-stationary intensities yielded higher values above those of stationary models, proving that the assumption of stationary IDF models underestimated extreme events. The difference of 13.71 mm/hr (22.71%) to 14.26 mm/hr (17.0%) intensities implies an underestimation of the peak flood from a stationary IDF curve. The statistical difference at a 95% confidence level between stationary and non-stationary models was significant, confirming evidence of climatic change influenced by time-variant parameters. Consequently, emphasis should be on applying shorter-duration storms for design purposes occurring with higher intensities to help reduce the flood risk and resultant infrastructural failures.展开更多
In this paper, we focus on the space-inhomogeneous three-state on the one-dimension lattice, a one-phase model and a two-phase model include. By using the transfer matrices method by Endo et al., we calculate the stat...In this paper, we focus on the space-inhomogeneous three-state on the one-dimension lattice, a one-phase model and a two-phase model include. By using the transfer matrices method by Endo et al., we calculate the stationary measure for initial state concrete eigenvalue. Finally we found the transfer matrices method is more effective for the three-state quantum walks than the method obtained by Kawai et al.展开更多
The tide level displays information about the state of the sea current and the tidal motion. The tide level of the southern coast of Japan Island is affected strongly by Kuroshio Current flowing in the western part of...The tide level displays information about the state of the sea current and the tidal motion. The tide level of the southern coast of Japan Island is affected strongly by Kuroshio Current flowing in the western part of North Pacific Ocean. When Kuroshio takes the straight path and flow along the Japan Islands, the tide level increases, and it is calculated from two tide level data observed at Kushimoto and Uragami in the southern part of Kii Peninsula. In contrast, the tide level decreases at the time when Kuroshio leaves from the Japan Islands. In this paper, the hourly tidal data are analyzed using the Autocorrelation Function (ACF) and the Mutual Information (MI) and the phase trajectories at first. We classify the results into 5 types of tidal motion. Each categorized type is investigated and characterized precisely using the mean tide level and the unit root test (ADF test) next. The frequency of the type having unstable tidal motion increases when the Kuroshio Current is non-meandering or in a transition state or the tide level is high, and the type shows a non-stationary process. On the other hand, when the Kuroshio Current meanders, the tidal motion tends to take a periodical and stable state and the motion is a stationary process. Though it is not frequent, we also discover a type of stationary and irregular tidal motion.展开更多
By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components ...By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components in different transformed sub-images corresponding to a pixel are employed to form a feature vector of the pixel. All the feature vectors are classified with unsupervised fuzzy c-means to segment the image, and then the edge pixels are checked out by the Canny detector. A series of images contaminated with different intensive Gaussian noises are used to test the novel algorithm. Experiments show that fairly precise edges can be checked out robustly from those images with fairly intensive noise by the proposed algorithm.展开更多
A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It ex...A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.展开更多
In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each ...In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each other;(2) The spatial duration of the wavelet of the depthmigrated image is short.For the isochrones that are not tangential to the target reflector and for the depth-migrated images that have a large spatial duration,the published stationary phase equation for the demigrated field will become invalid.For performing the stationary phase analysis of the Kirchhoff-type demigrated field under the conditions that the considered isochrone and the target reflector are not tangential to each other and that the spatial duration of the wavelet of the depth-migrated image is not short(the general conditions),I derive the formulas for the factors appearing in the stationary phase formula in two dimensions,from which I find that for different isochrones the horizontal coordinates of the stationary point of the depth difference function are different.Also,the equation for the Kirchhoff-type demigrated field consists of two parts.One is the true-amplitude demigrated signal and the other is the amplitude distortion factor.From these facts the following two conclusions can be drawn:(1) A demigrated signal is composed of many depth-migrated images and one depth-migrated image trace provides only one sample to the demigrated signal;and(2) The amplitude distortion effect is an effect inherent in the Kirchhoff-type demigration and cannot be eliminated during demigration.If this effect should be eliminated,one should do an amplitude correction after demigration.展开更多
Utilizing the European Centre for Medium-Range Weather Forecast(ECMWF)Reanalysis v5(ERA5),for the first time,we have confirmed close links among Sudden Stratospheric Warmings(SSWs)in the Northern Hemisphere(NH),the po...Utilizing the European Centre for Medium-Range Weather Forecast(ECMWF)Reanalysis v5(ERA5),for the first time,we have confirmed close links among Sudden Stratospheric Warmings(SSWs)in the Northern Hemisphere(NH),the polar vortices,and stratospheric Planetary Waves(PWs)by analyzing and comparing their trends.Interestingly,within overall increasing trends,the duration and strength of SSWs exhibit increasing and decreasing trends before and after the winter of 2002,respectively.To reveal possible physical mechanisms driving these trends,we analyzed the long-term trends of the winter(from December to February)polar vortices and of stratospheric PWs with zonal wave number 1.Notably,our results show that in all three time periods(the entire period of 41winters,1980 to 2020,and the two subperiods—1980-2002 and 2002-2020)enhancing SSWs were always accompanied by weakening winter polar vortices and strengthening polar PWs like Stationary Planetary Waves(SPWs)and 16-day waves,and vice versa.This is the first proof,based on ERA5 long-term trend data,that weakening polar vortices and enhancing stratospheric PWs(especially SPWs)could cause an increase in SSWs.展开更多
This paper develops and analyzes a stochastic derivative-free optimization strategy.A key feature is the state-dependent adaptive variance.We prove global convergence in probability with algebraic rate and give the qu...This paper develops and analyzes a stochastic derivative-free optimization strategy.A key feature is the state-dependent adaptive variance.We prove global convergence in probability with algebraic rate and give the quantitative results in numerical examples.A striking fact is that convergence is achieved without explicit information of the gradient and even without comparing different objective function values as in established methods such as the simplex method and simulated annealing.It can otherwise be compared to annealing with state-dependent temperature.展开更多
The evolution of ablative Rayleigh–Taylor instability(ARTI)induced by single-mode stationary and time-varying perturbations in heat flux is studied numerically in two dimensions.Compared with the stationary case,time...The evolution of ablative Rayleigh–Taylor instability(ARTI)induced by single-mode stationary and time-varying perturbations in heat flux is studied numerically in two dimensions.Compared with the stationary case,time-varying heat-flux perturbation mitigates ARTI growth because of the enhanced thermal smoothing induced by the wave-like traveling heat flux.A resonance is found to form when the phase velocity of the heat-flux perturbation matches the average sound speed in the ablation region.In the resonant regime,the coherent density and temperature fluctuations enhance the electron thermal conduction in the ablation region and lead to larger ablation pressure and effective acceleration,which consequently yield higher linear growth rate and saturated bubble velocity.The enhanced effective acceleration offers increased implosion velocity but can also compromise the integrity of inertial confinement fusion shells by causing faster ARTI growth.展开更多
Aim To study the chromatographis beheviors of three new cinnamyl cyclodextrin derivative stationary phases. Mehtods Three new cinnamyl β-cyclodextrins, heptakis-(2, 6-di-O-cinnamyl-3-O-methyl)-β-CD, heptakis-(2, 6-...Aim To study the chromatographis beheviors of three new cinnamyl cyclodextrin derivative stationary phases. Mehtods Three new cinnamyl β-cyclodextrins, heptakis-(2, 6-di-O-cinnamyl-3-O-methyl)-β-CD, heptakis-(2, 6-di-O-cinnamyl-3-O-acetyl-)-β-CD and heptakis-2, 6-di-O-cirinamyl-3-O-trifluoroacetyl)-β-CD were synthesized and coatal on fused-silica capillary columns . Results The new stationary phases have better thermal stability, good column efficiency and excellent mpaxation power for some sutstituted benzene positional isomers. It was found that the introduction of cinnamyl groups has a significant effect on these stationary phases. Conclusion There new subetituted β-CD compounds are very suitable to be ed as gas chromatographic stationary phases.展开更多
Aim To study the chromatographic behaviors of two dipentyl cyclodextrin derivative stationary phases. Methods Two new β-cyclodextrin derivatives, heptakis-[2, 6-di-O-pentyl-3-O-(4-nitrobenzyl)] -β-CD and heptakis-[...Aim To study the chromatographic behaviors of two dipentyl cyclodextrin derivative stationary phases. Methods Two new β-cyclodextrin derivatives, heptakis-[2, 6-di-O-pentyl-3-O-(4-nitrobenzyl)] -β-CD and heptakis-[2, 6-di-O-pentyl-3 -O-(5 -hexenyl)]-β-CD, were synthesized and coatal on fed-silica capillary columns. The chromatographic behaviors of the columns were characterized . Results It was found that the she, polarity, and aromatic property of the substituted group at the 3-position of heptakis-(2, 6 - di - O - pentyl) - β - cyclodextrins greatly influenced their chromatographic properties and separation ability. The introduction of aromatic group or a group containing a double-bond may bring π-π interactions between the host and guest molecules, and therefore increases the separation ability of the β-CDs for substituted benzene isomers. Conclusion The new substituted β-CD compounds are very suitable for being used as gas chromatogaphic stationary phases.展开更多
Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC...Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC). Single-walled carbon nanotubes mixed with cellulose trisphenylcarbamate are coated on the silica gel as chiral stationary phases and higher enantioseparation factors are obtained. After a single-walled carbon nanotube is linked to the 6-pesition of cellulose 2,3-bisphenylcarbamate, its enantioseparation resolution increases compared to that of the cellulose trisphenylcarbamate. It is the first time that SWNTs have been applied to enantioseparation. The results indicate that the single-walled carbon nanotubes are good promoters of chiral recognition. This method can be used to improve the enantioseparation efficiency of the polysaccharide chiral stationary phases.展开更多
A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in al...A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in all cases under some weaker conditions, and the structure of optimal control may be characterized.展开更多
The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improv...The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improving depends on the design quality of the stationary platen. Compared with the parametric design of stationary platen, structural scheme design could obtain the optimization model with double objectives and multi-constraints. In this paper, a SE-160 precision plastic injection molding machine with 1600 kN clamping force is selected as the subject in the case study. During the motion of mold closing and opening, the stationary platen of SE-160 is subjected to a cyclic loading, which would cause the fatigue rupture of the tie bars in periodically long term operations. In order to reduce the deflection of the stationary platen, the FEA method is introduced to optimize the structure of the stationary platen. Firstly, an optimal topology model is established by variable density method. Then, structural topology optimizations of the stationary platen are done with the removable material from 50%, 60% to 70%. Secondly, the other two recommended optimization schemes are given and compared with the original structure. The result of performances comparison shows that the scheme II of the platen is the best one. By choosing the best alternative, the volume and the local maximal stress of the platen could be decreased, corresponding to cost-saving material and better mechanical properties. This paper proposes a structural optimization design scheme, which can save the material as well as improve the clamping precision of the precision plastic injection molding machine.展开更多
文摘Based on the conventional meteorological data and the NCEP/NCAR 1° × 1° reanalysis data and those related to mid-scale automatic station, satellite cloud picture and radar return, with the dynamic diagnosis analysis method, an analysis is made on the process of the convective rainstorm of quasi-stationary front triggered by the weak cold air on June 4-7, 2014, showing: 1) the process occurred in the event of convection of a stationary front triggered by the eastward moving south trough and the southward moving weak cold air from west under the background of circulation of two ridges and one trough at the Asian-European mid-high latitude and weakening and southeastward moving subtropical high;2) a system configuration that contributes to convective rainstorms formed in the event of the convergence of low-level moisture, upper-level divergence and the continuous vertical ascending motion after the 200 hPa upper-level jet stream moved westwards from east and the 850 hPa southwest jet stream intensified;3) after the intrusion by weak cold air of the meso-scale katallobaric area formed by the accumulated warm moist air of Guangxi before the intrusion, the warm moist air rose to trigger convection;convection cells developed and spread nearby the boundary between anallobaric area and katallobaric area, during which total 5 MCSs developed and each formed a rainstorm center at the part where the MCSs coincide;a meso-scale katallobaric area forms and develops 2 - 5 hours earlier than convection, so that it is also a warning of heavy rains.
基金supported by the Shenzhen sustainable development project:KCXFZ 20201221173013036 and the National Natural Science Foundation of China(91746107).
文摘In this paper,we mainly discuss a discrete estimation of the average differential entropy for a continuous time-stationary ergodic space-time random field.By estimating the probability value of a time-stationary random field in a small range,we give an entropy estimation and obtain the average entropy estimation formula in a certain bounded space region.It can be proven that the estimation of the average differential entropy converges to the theoretical value with a probability of 1.In addition,we also conducted numerical experiments for different parameters to verify the convergence result obtained in the theoretical proofs.
基金supported by the Research and Development Project of“Jianbing”in Zhejiang Province(2024C01085)Natural Science and Foundation of Ningbo(2022J052).
文摘2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.
基金This study was funded by the Project of National Natural Science Foundation of China(Grant No.:82003705)the Shanghai Science and Technology Innovation Foundation(Grant Nos.:23010500200 and 23ZR1422700).
文摘Capillary electrochromatography(CEC)plays a significant role in chiral separation via the double separation principle,partition coefficient difference between the two phases,and electroosmotic flow-driven separation.Given the distinct properties of the inner wall stationary phase(SP),the separation ability of each SP differs from one another.Particularly,it provides large room for promising applications of open tubular capillary electrochromatography(OT-CEC).We divided the OT-CEC SPs developed over the past four years into six types:ionic liquids,nanoparticle materials,microporous materials,biomaterials,non-nanopolymers,and others,to mainly introduce their characteristics in chiral drug separation.There also added a few classic SPs that occurred within ten years as supplements to enrich the features of each SP.Additionally,we discuss their applications in metabolomics,food,cosmetics,environment,and biology as analytes in addition to chiral drugs.OT-CEC plays an increasingly significant role in chiral separation and may promote the development of capillary electrophoresis(CE)combined with other instruments in recent years,such as CE with mass spectrometry(CE/MS)and CE with ultraviolet light detector(CE/UV).
基金supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of State Education Ministry,the Key Scientific Research Project of Hunan Provincial Education Department (19A342)the National Natural Science Foundation of China (11671132,61903309 and 12271418)+2 种基金the National Key Research and Development Program of China (2020YFA0714200)Sichuan Science and Technology Program (2023NSFSC1355)the Applied Economics of Hunan Province.
文摘Long memory is an important phenomenon that arises sometimes in the analysis of time series or spatial data.Most of the definitions concerning the long memory of a stationary process are based on the second-order properties of the process.The mutual information between the past and future I_(p−f) of a stationary process represents the information stored in the history of the process which can be used to predict the future.We suggest that a stationary process can be referred to as long memory if its I_(p−f) is infinite.For a stationary process with finite block entropy,I_(p−f) is equal to the excess entropy,which is the summation of redundancies that relate the convergence rate of the conditional(differential)entropy to the entropy rate.Since the definitions of the I_(p−f) and the excess entropy of a stationary process require a very weak moment condition on the distribution of the process,it can be applied to processes whose distributions are without a bounded second moment.A significant property of I_(p−f) is that it is invariant under one-to-one transformation;this enables us to know the I_(p−f) of a stationary process from other processes.For a stationary Gaussian process,the long memory in the sense of mutual information is more strict than that in the sense of covariance.We demonstrate that the I_(p−f) of fractional Gaussian noise is infinite if and only if the Hurst parameter is H∈(1/2,1).
基金Project supported by the Basic and Applied Basic Research Foundation of Guangdong Province,China(Grant No.2021A1515010328)the Key-Area Research and Development Program of Guangdong Province,China(Grant No.2020B010183001)the National Natural Science Foundation of China(Grant No.12074126)。
文摘Efficient numerical algorithm for stochastic differential equation has been an important object in the research of statistical physics and mathematics for a long time.In this work we study the highly accurate numerical algorithm for the overdamped Langevin equation.In particular,our interest is in the behaviour of the numerical schemes for solving the overdamped Langevin equation in the harmonic system.Based on the large friction limit of the underdamped Langevin dynamic scheme,three algorithms for overdamped Langevin equation are obtained.We derive the explicit expression of the stationary distribution of each algorithm by analysing the discrete time trajectory for both one-dimensional case and multi-dimensional case.The accuracy of the stationary distribution of each algorithm is illustrated by comparing with the exact Boltzmann distribution.Our results demonstrate that the“BAOA-limit”algorithm generates an accurate distribution of the harmonic system in a canonical ensemble,within a stable range of time interval.The other algorithms do not produce the exact distribution of the harmonic system.
文摘This study aims at establishing if climate change exists in the Niger Delta environment using non-stationary rainfall Intensity-Duration-Frequency (IDF) modelling incorporating time-variant parameters. To compute the intensity levels, the open-access R-studio software was used based on the General Extreme Value (GEV) distribution function. Among the four linear parameter models adopted for integrating time as a covariate, the fourth linear model incorporating scale and location with the shape function constant produced the least corrected Akaike Information Criteria (AICc), varying between 306.191 to 101.497 for 15 and 1440 minutes, respectively, selected for calibration of the GEV distribution equation. The non-stationary intensities yielded higher values above those of stationary models, proving that the assumption of stationary IDF models underestimated extreme events. The difference of 13.71 mm/hr (22.71%) to 14.26 mm/hr (17.0%) intensities implies an underestimation of the peak flood from a stationary IDF curve. The statistical difference at a 95% confidence level between stationary and non-stationary models was significant, confirming evidence of climatic change influenced by time-variant parameters. Consequently, emphasis should be on applying shorter-duration storms for design purposes occurring with higher intensities to help reduce the flood risk and resultant infrastructural failures.
文摘In this paper, we focus on the space-inhomogeneous three-state on the one-dimension lattice, a one-phase model and a two-phase model include. By using the transfer matrices method by Endo et al., we calculate the stationary measure for initial state concrete eigenvalue. Finally we found the transfer matrices method is more effective for the three-state quantum walks than the method obtained by Kawai et al.
文摘The tide level displays information about the state of the sea current and the tidal motion. The tide level of the southern coast of Japan Island is affected strongly by Kuroshio Current flowing in the western part of North Pacific Ocean. When Kuroshio takes the straight path and flow along the Japan Islands, the tide level increases, and it is calculated from two tide level data observed at Kushimoto and Uragami in the southern part of Kii Peninsula. In contrast, the tide level decreases at the time when Kuroshio leaves from the Japan Islands. In this paper, the hourly tidal data are analyzed using the Autocorrelation Function (ACF) and the Mutual Information (MI) and the phase trajectories at first. We classify the results into 5 types of tidal motion. Each categorized type is investigated and characterized precisely using the mean tide level and the unit root test (ADF test) next. The frequency of the type having unstable tidal motion increases when the Kuroshio Current is non-meandering or in a transition state or the tide level is high, and the type shows a non-stationary process. On the other hand, when the Kuroshio Current meanders, the tidal motion tends to take a periodical and stable state and the motion is a stationary process. Though it is not frequent, we also discover a type of stationary and irregular tidal motion.
文摘By combining multiscale stationary wavelet analysis with fuzzy c-means, a robust edge detection algorithm is presented. Based on the translation invafiance built in multiscale stationary wavelet transform, components in different transformed sub-images corresponding to a pixel are employed to form a feature vector of the pixel. All the feature vectors are classified with unsupervised fuzzy c-means to segment the image, and then the edge pixels are checked out by the Canny detector. A series of images contaminated with different intensive Gaussian noises are used to test the novel algorithm. Experiments show that fairly precise edges can be checked out robustly from those images with fairly intensive noise by the proposed algorithm.
文摘A new capillary gas chromatography stationary phase, monokis (2,6 di O benzyl 3 O propyl (3’)) hexakis(2,6 di O benzyl 3 O methyl) β CD bonded polysiloxane, was synthesized. It exhibited separation abilities to disubstituted benzene isomers and some chiral solutes. It was also found that the polarity of CD derivatives can be lowered both by chemically bonding it to polysiloxane and by diluting it in polysiloxane. The separation abilities of the polysiloxane anchored CDs (SP CD) are higher than that of the unbonded CDs (S CD) and the diluted S CD at lower column temperature. Hydrosilylation reaction is one of the best methods to lower the operating temperature of CDs.
基金supported by the National Natural Science Foundation of China (Grant No.40574052)
文摘In the literature,stationary phase analysis of Kirchhoff-type demigrated fields is carried out mainly under the following two conditions:(1) The considered isochrone and the target reflector are tangential to each other;(2) The spatial duration of the wavelet of the depthmigrated image is short.For the isochrones that are not tangential to the target reflector and for the depth-migrated images that have a large spatial duration,the published stationary phase equation for the demigrated field will become invalid.For performing the stationary phase analysis of the Kirchhoff-type demigrated field under the conditions that the considered isochrone and the target reflector are not tangential to each other and that the spatial duration of the wavelet of the depth-migrated image is not short(the general conditions),I derive the formulas for the factors appearing in the stationary phase formula in two dimensions,from which I find that for different isochrones the horizontal coordinates of the stationary point of the depth difference function are different.Also,the equation for the Kirchhoff-type demigrated field consists of two parts.One is the true-amplitude demigrated signal and the other is the amplitude distortion factor.From these facts the following two conclusions can be drawn:(1) A demigrated signal is composed of many depth-migrated images and one depth-migrated image trace provides only one sample to the demigrated signal;and(2) The amplitude distortion effect is an effect inherent in the Kirchhoff-type demigration and cannot be eliminated during demigration.If this effect should be eliminated,one should do an amplitude correction after demigration.
基金supported by the National Key RandD Program of China(2022YFF0503703)the National Natural Science Foundation of China(through grant42127805)。
文摘Utilizing the European Centre for Medium-Range Weather Forecast(ECMWF)Reanalysis v5(ERA5),for the first time,we have confirmed close links among Sudden Stratospheric Warmings(SSWs)in the Northern Hemisphere(NH),the polar vortices,and stratospheric Planetary Waves(PWs)by analyzing and comparing their trends.Interestingly,within overall increasing trends,the duration and strength of SSWs exhibit increasing and decreasing trends before and after the winter of 2002,respectively.To reveal possible physical mechanisms driving these trends,we analyzed the long-term trends of the winter(from December to February)polar vortices and of stratospheric PWs with zonal wave number 1.Notably,our results show that in all three time periods(the entire period of 41winters,1980 to 2020,and the two subperiods—1980-2002 and 2002-2020)enhancing SSWs were always accompanied by weakening winter polar vortices and strengthening polar PWs like Stationary Planetary Waves(SPWs)and 16-day waves,and vice versa.This is the first proof,based on ERA5 long-term trend data,that weakening polar vortices and enhancing stratospheric PWs(especially SPWs)could cause an increase in SSWs.
基金partially supported by the National Science Foundation through grants DMS-2208504(BE),DMS-1913309(KR),DMS-1937254(KR),and DMS-1913129(YY)support from Dr.Max Rossler,the Walter Haefner Foundation,and the ETH Zurich Foundation.
文摘This paper develops and analyzes a stochastic derivative-free optimization strategy.A key feature is the state-dependent adaptive variance.We prove global convergence in probability with algebraic rate and give the quantitative results in numerical examples.A striking fact is that convergence is achieved without explicit information of the gradient and even without comparing different objective function values as in established methods such as the simplex method and simulated annealing.It can otherwise be compared to annealing with state-dependent temperature.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDA25050400 and XDA25010200)the National Natural Science Foundation of China(Grant No.12175229 and 12388101)+1 种基金the Frontier Scientific Research Program of the Deep Space Exploration Laboratory(Grant No.2022-QYKYJH-HXYF-019)by the Fundamental Research Funds for the Central Universities.
文摘The evolution of ablative Rayleigh–Taylor instability(ARTI)induced by single-mode stationary and time-varying perturbations in heat flux is studied numerically in two dimensions.Compared with the stationary case,time-varying heat-flux perturbation mitigates ARTI growth because of the enhanced thermal smoothing induced by the wave-like traveling heat flux.A resonance is found to form when the phase velocity of the heat-flux perturbation matches the average sound speed in the ablation region.In the resonant regime,the coherent density and temperature fluctuations enhance the electron thermal conduction in the ablation region and lead to larger ablation pressure and effective acceleration,which consequently yield higher linear growth rate and saturated bubble velocity.The enhanced effective acceleration offers increased implosion velocity but can also compromise the integrity of inertial confinement fusion shells by causing faster ARTI growth.
文摘Aim To study the chromatographis beheviors of three new cinnamyl cyclodextrin derivative stationary phases. Mehtods Three new cinnamyl β-cyclodextrins, heptakis-(2, 6-di-O-cinnamyl-3-O-methyl)-β-CD, heptakis-(2, 6-di-O-cinnamyl-3-O-acetyl-)-β-CD and heptakis-2, 6-di-O-cirinamyl-3-O-trifluoroacetyl)-β-CD were synthesized and coatal on fused-silica capillary columns . Results The new stationary phases have better thermal stability, good column efficiency and excellent mpaxation power for some sutstituted benzene positional isomers. It was found that the introduction of cinnamyl groups has a significant effect on these stationary phases. Conclusion There new subetituted β-CD compounds are very suitable to be ed as gas chromatographic stationary phases.
文摘Aim To study the chromatographic behaviors of two dipentyl cyclodextrin derivative stationary phases. Methods Two new β-cyclodextrin derivatives, heptakis-[2, 6-di-O-pentyl-3-O-(4-nitrobenzyl)] -β-CD and heptakis-[2, 6-di-O-pentyl-3 -O-(5 -hexenyl)]-β-CD, were synthesized and coatal on fed-silica capillary columns. The chromatographic behaviors of the columns were characterized . Results It was found that the she, polarity, and aromatic property of the substituted group at the 3-position of heptakis-(2, 6 - di - O - pentyl) - β - cyclodextrins greatly influenced their chromatographic properties and separation ability. The introduction of aromatic group or a group containing a double-bond may bring π-π interactions between the host and guest molecules, and therefore increases the separation ability of the β-CDs for substituted benzene isomers. Conclusion The new substituted β-CD compounds are very suitable for being used as gas chromatogaphic stationary phases.
基金Supported by the National Natural Science Foundation of China(No.30160092)the Natural Science Foundation of Yunnan Province,China(No.2005E0006Z).
文摘Single-walled carbon nanotubes(SWNTs) have a high adsorption ability and nanoscale interactions. Cellulose trisphenylcarbamates possess high enantioseparation ability in high-performance liquid chromatography(HPLC). Single-walled carbon nanotubes mixed with cellulose trisphenylcarbamate are coated on the silica gel as chiral stationary phases and higher enantioseparation factors are obtained. After a single-walled carbon nanotube is linked to the 6-pesition of cellulose 2,3-bisphenylcarbamate, its enantioseparation resolution increases compared to that of the cellulose trisphenylcarbamate. It is the first time that SWNTs have been applied to enantioseparation. The results indicate that the single-walled carbon nanotubes are good promoters of chiral recognition. This method can be used to improve the enantioseparation efficiency of the polysaccharide chiral stationary phases.
基金Supported by the National Science Foundation of China.
文摘A class of stationary models of singular stochastic control has been studied, in which the state is extended to solution of a class of S.D.E. from Wiener process. The existence of optimal control has been proved in all cases under some weaker conditions, and the structure of optimal control may be characterized.
基金Supported by National Natural Science Foundation of China(Grant No.51205350)Hong Kong Scholars Program of China(Grant No.XJ2013015)Zhejiang Provincial Research Program of Public Welfare Technology Application of China(Grant No.2013C31027)
文摘The current development of precision plastic injection molding machines mainly focuses on how to save material and improve precision, but the two aims contradict each other. For a clamp unit, clamping precision improving depends on the design quality of the stationary platen. Compared with the parametric design of stationary platen, structural scheme design could obtain the optimization model with double objectives and multi-constraints. In this paper, a SE-160 precision plastic injection molding machine with 1600 kN clamping force is selected as the subject in the case study. During the motion of mold closing and opening, the stationary platen of SE-160 is subjected to a cyclic loading, which would cause the fatigue rupture of the tie bars in periodically long term operations. In order to reduce the deflection of the stationary platen, the FEA method is introduced to optimize the structure of the stationary platen. Firstly, an optimal topology model is established by variable density method. Then, structural topology optimizations of the stationary platen are done with the removable material from 50%, 60% to 70%. Secondly, the other two recommended optimization schemes are given and compared with the original structure. The result of performances comparison shows that the scheme II of the platen is the best one. By choosing the best alternative, the volume and the local maximal stress of the platen could be decreased, corresponding to cost-saving material and better mechanical properties. This paper proposes a structural optimization design scheme, which can save the material as well as improve the clamping precision of the precision plastic injection molding machine.