Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity grad...Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold.展开更多
Global crises, notably climate shocks, degraded ecosystems, and growing energy demand, enforce sustainable production and consumption pathways. A circular bioeconomy offers the opportunities to actualize resource and ...Global crises, notably climate shocks, degraded ecosystems, and growing energy demand, enforce sustainable production and consumption pathways. A circular bioeconomy offers the opportunities to actualize resource and eco-efficiency enhancement, valorization of waste streams, reduction of fossil energy and greenhouse gas (GHG) emissions. Albeit biomass resources are a potential feedstock for bio-hydrogen (bio-H2) production, Ghana’s agricultural residues are not fully utilized. This paper examines the economic and environmental impact of bio-H2 electricity generation using agricultural residues in Ghana. The bio-H2 potential was determined based on biogas steam reforming (BSR). The research highlights that BSR could generate 2617 kt of bio-H2, corresponding to 2.78% of the global hydrogen demand. Yam and maize residues contribute 50.47% of the bio-H2 produced, while millet residues have the most negligible share. A tonne of residues could produce 16.59 kg of bio-H2 and 29.83 kWh of electricity. A total of 4,705.89 GWh of electricity produced could replace the consumption of 21.92% of Ghana’s electricity. The economic viability reveals that electricity cost is $0.174/kWh and has a positive net present value of $2135550609.45 with a benefit-to-cost ratio of 1.26. The fossil diesel displaced is 1421.09 ML, and 3862.55 kt CO2eq of carbon emissions decreased corresponding to an annual reduction potential of 386.26 kt CO2eq. This accounts for reducing 10.26% of Ghana’s GHG emissions. The study demonstrates that hydrogen-based electricity production as an energy transition is a strategic innovation pillar to advance the circular bioeconomy and achieve sustainable development goals.展开更多
基金This work was supported by the National Key Research and Development Program of China(2022YFB4101600,2022YFB4101605)the National Natural Science Foundation of China(52372175,51972040)+1 种基金the Innovation and Technology Fund of Dalian(N2023JJ12GX020,2022JJ12GX023)Liaoning Normal University 2022 Outstanding Research Achievements Cultivation Fund(No.22GDL002).The authors also acknowledge the assistance of the DUT Instrumental Analysis Center.
文摘Solar-driven interfacial water evaporation(SIWE)offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination.It also engenders overlapped temperaturesalinity gradient(TSG)between water-air interface and adjacent seawater,affording opportunities of harnessing electricity.However,the efficiency of conventional SIWE technologies is limited by significant challenges,including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously.Herein,we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG.It enables spontaneous circulation of salt flux upon seawater evaporation,inducing a self-cleaning evaporative interface without salt passivation for stable steam generation.Meanwhile,this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation.These benefits render a remarkable efficiency of90.8%in solar energy utilization,manifesting in co-generation of solar steam at a fast rate of 2.01 kg m^(-2)-h^(-1)and electricity power of 1.91 W m^(-2)with high voltage.Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply.It produces hydrogen at a rapid rate of 1.29 L h^(-1)m^(-2)and freshwater with 22 times lower Na+concentration than the World Health Organization(WHO)threshold.
文摘Global crises, notably climate shocks, degraded ecosystems, and growing energy demand, enforce sustainable production and consumption pathways. A circular bioeconomy offers the opportunities to actualize resource and eco-efficiency enhancement, valorization of waste streams, reduction of fossil energy and greenhouse gas (GHG) emissions. Albeit biomass resources are a potential feedstock for bio-hydrogen (bio-H2) production, Ghana’s agricultural residues are not fully utilized. This paper examines the economic and environmental impact of bio-H2 electricity generation using agricultural residues in Ghana. The bio-H2 potential was determined based on biogas steam reforming (BSR). The research highlights that BSR could generate 2617 kt of bio-H2, corresponding to 2.78% of the global hydrogen demand. Yam and maize residues contribute 50.47% of the bio-H2 produced, while millet residues have the most negligible share. A tonne of residues could produce 16.59 kg of bio-H2 and 29.83 kWh of electricity. A total of 4,705.89 GWh of electricity produced could replace the consumption of 21.92% of Ghana’s electricity. The economic viability reveals that electricity cost is $0.174/kWh and has a positive net present value of $2135550609.45 with a benefit-to-cost ratio of 1.26. The fossil diesel displaced is 1421.09 ML, and 3862.55 kt CO2eq of carbon emissions decreased corresponding to an annual reduction potential of 386.26 kt CO2eq. This accounts for reducing 10.26% of Ghana’s GHG emissions. The study demonstrates that hydrogen-based electricity production as an energy transition is a strategic innovation pillar to advance the circular bioeconomy and achieve sustainable development goals.
