In millimeter wave(mmWave) multiple-input multiple-output(MIMO) systems, hybrid precoding has been widely used to overcome the severe propagation loss. In order to improve the spectrum efficiency with low complexity, ...In millimeter wave(mmWave) multiple-input multiple-output(MIMO) systems, hybrid precoding has been widely used to overcome the severe propagation loss. In order to improve the spectrum efficiency with low complexity, we propose a joint hybrid precoding algorithm for single-user mmWave MIMO systems in this paper. By using the concept of equivalent channel, the proposed algorithm skillfully utilizes the idea of alternating optimization to complete the design of RF precoder and combiner. Then, the baseband precoder and combiner are computed by calculating the singular value decomposition of the equivalent channel. Simulation results demonstrate that the proposed algorithm can achieve satisfactory performance with quite low complexity. Moreover, we investigate the effects of quantization on the analog components and find that the proposed scheme is effective even with coarse quantization.展开更多
Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymeriz...Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymerization of EMA, the hybrid material containing Tb(acac) 3·dam was obtained. The hybrid material exhibited good toughness and transparency and higher thermal stability than that of the pure complex and pure polymer matrix. In the range of doping concentration of Tb(acac) 3·dam (0.05%, 0.1%, 0.2%, 0.5%, 1.0%, 2.0% and 5.0%), emission intensity increases with the increasing of corresponding doping concentration and concentration quenching effect has not taken place.展开更多
Polyoxometalates(POMs) with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block(polyanion) is generally established on termin...Polyoxometalates(POMs) with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block(polyanion) is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule(pyridine, C5NH5) as assistant "structure-directing agent", we obtained a novel organic-inorganic hybrid polytungstate,(Hpy)4[Cd(phen)2(P2W18O62)]·nH2O(1, n ≈ 3, py = pyridine, phen = 1,10-phenanthroline), under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion, [Cd(phen)2(P2W18O62)]4–, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.展开更多
Ternary europium complex with dibenzoylmethane(DBM)and 1,10phenanthroline(phen)was insitu synthesized in thin SiO2/polyvinyl butyral(PVB)hybrid films by a twostep solgel process and characterized by means of fluoresce...Ternary europium complex with dibenzoylmethane(DBM)and 1,10phenanthroline(phen)was insitu synthesized in thin SiO2/polyvinyl butyral(PVB)hybrid films by a twostep solgel process and characterized by means of fluorescence spectroscopy.The luminescence spectra,fluorescence lifetimes and photostability were all investigated.The results showed that the hybrid films exhibited the characteristic emission bands of the central rare earth Eu3+.In addition,Eu3+presented longer fluorescence lifetime than in an ethanol solution and the complex had a higher photostability in the hybrid film than in the PVB film containing the corresponding pure complex.展开更多
Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research top...Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research topic to enhance the robustness.However, most of the existing works in the CPCM robust design optimization neglect the mixed uncertainties, which might result in an unstable design or even an infeasible design. To solve this issue, a response surface methodology-based hybrid robust design optimization(RSM-based HRDO) approach is proposed to improve the robustness of the quality characteristic for the CPCM via considering the mixed uncertainties in the robust design optimization. A bridge-type amplification mechanism is used to manifest the effectiveness of the proposed approach. The comparison results prove that the proposed approach can not only keep its superiority in the robustness, but also provide a robust scheme for optimizing the design parameters.展开更多
The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO...The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO3]2·2.33H2O(1), [CuL]3[V(10)O(28)]·8H2O(2) and [Cu L]3[V6O(18)]·8H2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V6O(18)]6- ring, [V(10)O(28)]6- cluster, and [V(12)O(35)]^10- ring, were isolated from the same reactant NH4VO3 under different conditions. The [CuL]^2+ bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V6O(18)]^6- rings in 1 and [V(12)O(35)]^10- rings in 3 into three-dimensional frameworks, respectively.展开更多
A novel pyridine-phenol boron complex[(dppy)BF] was encapsulated into polymer/silica composite matrix by sol-gel process. UV-Vis absorption spectra show that this process can control the aggregation structure of com...A novel pyridine-phenol boron complex[(dppy)BF] was encapsulated into polymer/silica composite matrix by sol-gel process. UV-Vis absorption spectra show that this process can control the aggregation structure of complex (dppy)BF. The results of photoluminescence of (dppy)BF in sol-gel composite film indicate that both fluorescence intensity and photostability are markedly increased using this method compared with other methods, which increases the practical significance of such composite film.展开更多
We investigate the dynamic event-triggered state estimation for uncertain complex networks with hybrid delays suffering from both deception attacks and denial-of-service attacks.Firstly,the effects of time-varying del...We investigate the dynamic event-triggered state estimation for uncertain complex networks with hybrid delays suffering from both deception attacks and denial-of-service attacks.Firstly,the effects of time-varying delays and finitedistributed delays are considered during data transmission between nodes.Secondly,a dynamic event-triggered scheme(ETS)is introduced to reduce the frequency of data transmission between sensors and estimators.Thirdly,by considering the discussed plant,dynamic ETS,state estimator,and hybrid attacks into a unified framework,this framework is transferred into a novel dynamical model.Furthermore,with the help of Lyapunov stability theory and linear matrix inequality techniques,sufficient condition to ensure that the system is exponentially stable and satisfies H∞performance constraints is obtained,and the design algorithm for estimator gains is given.Finally,two numerical examples verify the effectiveness of the proposed method.展开更多
For the purpose of investigating two complex networks' hybrid synchronization,a controller with fractional-order is provided.Regarding hybrid synchronization which includes the outer synchronization and inner sync...For the purpose of investigating two complex networks' hybrid synchronization,a controller with fractional-order is provided.Regarding hybrid synchronization which includes the outer synchronization and inner synchronization,some hybrid synchronization's sufficient conditions according to the Lyapunov stability theorem and the LaSalle invariance principle are proposed.Theoretical analysis suggests that,only when the state of driving-response networks is outer synchronization and each network is in inner synchronization,two coupled networks' hybrid synchronization under some suitable conditions could be reached.Finally,theoretical results are illustrated and validated with the given numerical simulations.展开更多
A novel inorganic-organic hybrid based on isopolyanion,{[Cu2(phen)2(μ-ox)][H2Mo8O26]}·4EtOH·Et2O(1) (phen=phenanthroline,ox=oxalate),was synthesized under open-air mild reaction conditions,and chara...A novel inorganic-organic hybrid based on isopolyanion,{[Cu2(phen)2(μ-ox)][H2Mo8O26]}·4EtOH·Et2O(1) (phen=phenanthroline,ox=oxalate),was synthesized under open-air mild reaction conditions,and characterized by elemental analysis,IR,ICP,TG and single crystal X-ray diffraction analysis.The crystal structure belongs to triclinic system with space group Pī and cell parameters:a=1.1075(5) nm,b=1.1608(5) nm,c=1.3333(5) nm,α=91.683(5)o,β=113.996(5)o,γ=112.170(5)o,V=1.4159(10) nm3,Mr=2017.44,Z=1,Dc=2.366 g/cm3 and F(000)=980.0.The structure of hybrid 1 is a 1D chain constructed of alternating octamolybdate isopolyanions [β-(Mo8O26)4-] and oxalato-bridged dinuclear copper complex cations [Cu2(phen)2(μ-ox)]2+.Ultimately,a 3D supramolecular network was formed by hydrogen bond interactions among the adjacent chains.The result shows that hybrid 1 is the first example of inorganic-organic hybrid constructed from isopolyanion and oxalato-bridged dinuclear copper complex fragment (CCDC No.665101).展开更多
For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchange...For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchangensis "Caucasus" obtained using hybrid citrange of American origin _ C. Kinokuni X C.ichanglemon, which gives an eatable lemon with a chemical composition similar to the normal lemon fruit and without any damage it can resist frost at -16 ℃ temperature and b) spontaneous mutations of trifoliata: #1 and #2 which are distinguished among trifoliata species. Their fruits don't contain or contain a small amount of the substances that deteriorate the taste: naringin, porcine and so on. They are characterized by high index of frost resistance. In the experiment when obtaining sexual hybrids of the Washington naval orange the above mentioned components were used and hybrid seedlings were obtained, which are distinguished according to their phenotypic hereditary features. Selected seedlings represent the best initial material for a successful future work.展开更多
Critical aortic valve stenosis in newborns is the cause of a severe clinical condition with the onset of symptoms during first hours after birth.We present a clinical case of a successful surgical correction of a crit...Critical aortic valve stenosis in newborns is the cause of a severe clinical condition with the onset of symptoms during first hours after birth.We present a clinical case of a successful surgical correction of a critical aortic stenosis using a hybrid method applied in a newborn during the first day of life.The infant was diagnosed with a hypoplastic left heart complex with an intact atrial septum(aortic and mitral valves stenosis variant),that led to the cardiogenic shock and acute pulmonary edema.The procedure included bilateral banding of the pulmonary artery branches and atrioseptostomy with stenting of the interatrial septum.The surgery was performed through a median sternotomy.展开更多
With the new development trend of multi-resource coordinated Earth observation and the new goal of Earth observation application of“short response time,high observation accuracy,and wide coverage”,space-aeronautics ...With the new development trend of multi-resource coordinated Earth observation and the new goal of Earth observation application of“short response time,high observation accuracy,and wide coverage”,space-aeronautics cooperative complex task planning problem has become an urgent problem to be solved.The focus of this problem is to use multiple resources to perform collaborative observations on complex tasks.By analyzing the process from task assignment to receiving task observation results,we propose a multi-layer interactive task planning framework which is composed of a preprocessing method for complex tasks,a task allocation layer,a task planning layer,and a task coordination layer.According to the characteristics of the framework,a hybrid genetic parallel tabu(HGPT)algorithm is proposed on this basis.The algorithm uses genetic annealing algorithm(GAA),parallel tabu(PT)algorithm,and heuristic rules to achieve task allocation,task planning,and task coordination.At the same time,coding improvements,operator design,annealing operations,and parallel calculations are added to the algorithm.In order to verify the effectiveness of the algorithm,simulation experiments under complex task scenarios of different scales are carried out.Experimental results show that this method can effectively solve the problems of observing complex tasks.Meanwhile,the optimization effect and convergence speed of the HGPT is better than that of the related algorithms.展开更多
基金supported by NSFC (No. 61571055)fund of SKL of MMW (No. K201815) Important National Science & Technology Specific Projects (2017ZX03001028)
文摘In millimeter wave(mmWave) multiple-input multiple-output(MIMO) systems, hybrid precoding has been widely used to overcome the severe propagation loss. In order to improve the spectrum efficiency with low complexity, we propose a joint hybrid precoding algorithm for single-user mmWave MIMO systems in this paper. By using the concept of equivalent channel, the proposed algorithm skillfully utilizes the idea of alternating optimization to complete the design of RF precoder and combiner. Then, the baseband precoder and combiner are computed by calculating the singular value decomposition of the equivalent channel. Simulation results demonstrate that the proposed algorithm can achieve satisfactory performance with quite low complexity. Moreover, we investigate the effects of quantization on the analog components and find that the proposed scheme is effective even with coarse quantization.
文摘Ethyl methacrylate (EMA) doped with luminescent ternary terbium complex (Tb(acac) 3·dam) with acetylacetone (Hacac) and diantipylmethane (dam) was incorporated into the microporous silica gel. With the polymerization of EMA, the hybrid material containing Tb(acac) 3·dam was obtained. The hybrid material exhibited good toughness and transparency and higher thermal stability than that of the pure complex and pure polymer matrix. In the range of doping concentration of Tb(acac) 3·dam (0.05%, 0.1%, 0.2%, 0.5%, 1.0%, 2.0% and 5.0%), emission intensity increases with the increasing of corresponding doping concentration and concentration quenching effect has not taken place.
基金supported by the Foundation of Education Department of Fujian Province(Nos.JB12199 and JA11245)the National Natural Science Foundation of China(Nos.21233004 and 40972035)
文摘Polyoxometalates(POMs) with Cd-coordination complexes acting as supporting units are rarely reported. The linkage of the supporting units with inorganic building block(polyanion) is generally established on terminal O-atoms, but scarcely via bridging O-atoms. By introducing liquid small organic molecule(pyridine, C5NH5) as assistant "structure-directing agent", we obtained a novel organic-inorganic hybrid polytungstate,(Hpy)4[Cd(phen)2(P2W18O62)]·nH2O(1, n ≈ 3, py = pyridine, phen = 1,10-phenanthroline), under hydrothermal conditions. The single-crystal X-ray diffraction analysis shows that 1 is the first compound containing an asymmetric heteropolyanion, [Cd(phen)2(P2W18O62)]4–, a Wells-Dawson-type polyanion monosupported by Cd-coordination complex via di-bridging O-atoms.
文摘Ternary europium complex with dibenzoylmethane(DBM)and 1,10phenanthroline(phen)was insitu synthesized in thin SiO2/polyvinyl butyral(PVB)hybrid films by a twostep solgel process and characterized by means of fluorescence spectroscopy.The luminescence spectra,fluorescence lifetimes and photostability were all investigated.The results showed that the hybrid films exhibited the characteristic emission bands of the central rare earth Eu3+.In addition,Eu3+presented longer fluorescence lifetime than in an ethanol solution and the complex had a higher photostability in the hybrid film than in the PVB film containing the corresponding pure complex.
基金supported by the National Natural Science Foundation of China(71702072 71811540414+2 种基金 71573115)the Natural Science Foundation for Jiangsu Institutions(BK20170810)the Ministry of Education of Humanities and Social Science Planning Fund(18YJA630008)
文摘Minimizing the impact of the mixed uncertainties(i.e.,the aleatory uncertainty and the epistemic uncertainty) for a complex product of compliant mechanism(CPCM) quality improvement signifies a fascinating research topic to enhance the robustness.However, most of the existing works in the CPCM robust design optimization neglect the mixed uncertainties, which might result in an unstable design or even an infeasible design. To solve this issue, a response surface methodology-based hybrid robust design optimization(RSM-based HRDO) approach is proposed to improve the robustness of the quality characteristic for the CPCM via considering the mixed uncertainties in the robust design optimization. A bridge-type amplification mechanism is used to manifest the effectiveness of the proposed approach. The comparison results prove that the proposed approach can not only keep its superiority in the robustness, but also provide a robust scheme for optimizing the design parameters.
基金Supported by the Opening Project of Key Laboratory of Comprehensive Utilization of Advantage Plants Resources in Hunan South(XNZW14C08)the NSF of Hunan Province(2015JJ2072)+2 种基金the Construct Program of the Key Discipline in Hunan Provincethe Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Provincethe Project for Undergraduate Research Study and Innovative Experiment of Hunan Provincial(2016-283)
文摘The reactions of the four-coordinated macrocyclic copper complex [CuL](ClO4)2(L = 1,4,8,11-tetraazacyclotetradecane) with NH4VO3 under different conditions gave three inorganic-organic hybrid materials of [CuL][VO3]2·2.33H2O(1), [CuL]3[V(10)O(28)]·8H2O(2) and [Cu L]3[V6O(18)]·8H2O(3). Single-crystal X-ray diffraction analyses reveal that three diverse vanadium polyoxoanions, [V6O(18)]6- ring, [V(10)O(28)]6- cluster, and [V(12)O(35)]^10- ring, were isolated from the same reactant NH4VO3 under different conditions. The [CuL]^2+ bridges the [V10O28]6- clusters to form a two-dimensional sheet in 2, and link the [V6O(18)]^6- rings in 1 and [V(12)O(35)]^10- rings in 3 into three-dimensional frameworks, respectively.
基金Supported by the National Basic Research Program of China(No2007CB80800)
文摘A novel pyridine-phenol boron complex[(dppy)BF] was encapsulated into polymer/silica composite matrix by sol-gel process. UV-Vis absorption spectra show that this process can control the aggregation structure of complex (dppy)BF. The results of photoluminescence of (dppy)BF in sol-gel composite film indicate that both fluorescence intensity and photostability are markedly increased using this method compared with other methods, which increases the practical significance of such composite film.
文摘We investigate the dynamic event-triggered state estimation for uncertain complex networks with hybrid delays suffering from both deception attacks and denial-of-service attacks.Firstly,the effects of time-varying delays and finitedistributed delays are considered during data transmission between nodes.Secondly,a dynamic event-triggered scheme(ETS)is introduced to reduce the frequency of data transmission between sensors and estimators.Thirdly,by considering the discussed plant,dynamic ETS,state estimator,and hybrid attacks into a unified framework,this framework is transferred into a novel dynamical model.Furthermore,with the help of Lyapunov stability theory and linear matrix inequality techniques,sufficient condition to ensure that the system is exponentially stable and satisfies H∞performance constraints is obtained,and the design algorithm for estimator gains is given.Finally,two numerical examples verify the effectiveness of the proposed method.
基金Sponsored by the National Natural Science Foundation of China(Grant No.61201227)the Funding of China Scholarship Council,the Natural Science Foundation of Anhui Province(Grant No.1208085MF93)the 211 Innovation Team of Anhui University(Grant Nos.KJTD007A and KJTD001B)
文摘For the purpose of investigating two complex networks' hybrid synchronization,a controller with fractional-order is provided.Regarding hybrid synchronization which includes the outer synchronization and inner synchronization,some hybrid synchronization's sufficient conditions according to the Lyapunov stability theorem and the LaSalle invariance principle are proposed.Theoretical analysis suggests that,only when the state of driving-response networks is outer synchronization and each network is in inner synchronization,two coupled networks' hybrid synchronization under some suitable conditions could be reached.Finally,theoretical results are illustrated and validated with the given numerical simulations.
基金Supported by the National Natural Science Foundation of China(No.20871022)Natural Science Foundation of Liaoning Province,China(No.20061073)
文摘A novel inorganic-organic hybrid based on isopolyanion,{[Cu2(phen)2(μ-ox)][H2Mo8O26]}·4EtOH·Et2O(1) (phen=phenanthroline,ox=oxalate),was synthesized under open-air mild reaction conditions,and characterized by elemental analysis,IR,ICP,TG and single crystal X-ray diffraction analysis.The crystal structure belongs to triclinic system with space group Pī and cell parameters:a=1.1075(5) nm,b=1.1608(5) nm,c=1.3333(5) nm,α=91.683(5)o,β=113.996(5)o,γ=112.170(5)o,V=1.4159(10) nm3,Mr=2017.44,Z=1,Dc=2.366 g/cm3 and F(000)=980.0.The structure of hybrid 1 is a 1D chain constructed of alternating octamolybdate isopolyanions [β-(Mo8O26)4-] and oxalato-bridged dinuclear copper complex cations [Cu2(phen)2(μ-ox)]2+.Ultimately,a 3D supramolecular network was formed by hydrogen bond interactions among the adjacent chains.The result shows that hybrid 1 is the first example of inorganic-organic hybrid constructed from isopolyanion and oxalato-bridged dinuclear copper complex fragment (CCDC No.665101).
文摘For a successful selection of citrus plants when mating with cultural forms through the method of distant hybridization it is necessary to choose a promising father component such as: a) a complex hybrid of inchangensis "Caucasus" obtained using hybrid citrange of American origin _ C. Kinokuni X C.ichanglemon, which gives an eatable lemon with a chemical composition similar to the normal lemon fruit and without any damage it can resist frost at -16 ℃ temperature and b) spontaneous mutations of trifoliata: #1 and #2 which are distinguished among trifoliata species. Their fruits don't contain or contain a small amount of the substances that deteriorate the taste: naringin, porcine and so on. They are characterized by high index of frost resistance. In the experiment when obtaining sexual hybrids of the Washington naval orange the above mentioned components were used and hybrid seedlings were obtained, which are distinguished according to their phenotypic hereditary features. Selected seedlings represent the best initial material for a successful future work.
文摘Critical aortic valve stenosis in newborns is the cause of a severe clinical condition with the onset of symptoms during first hours after birth.We present a clinical case of a successful surgical correction of a critical aortic stenosis using a hybrid method applied in a newborn during the first day of life.The infant was diagnosed with a hypoplastic left heart complex with an intact atrial septum(aortic and mitral valves stenosis variant),that led to the cardiogenic shock and acute pulmonary edema.The procedure included bilateral banding of the pulmonary artery branches and atrioseptostomy with stenting of the interatrial septum.The surgery was performed through a median sternotomy.
基金the National Natural Science Foundation of China(72001212).
文摘With the new development trend of multi-resource coordinated Earth observation and the new goal of Earth observation application of“short response time,high observation accuracy,and wide coverage”,space-aeronautics cooperative complex task planning problem has become an urgent problem to be solved.The focus of this problem is to use multiple resources to perform collaborative observations on complex tasks.By analyzing the process from task assignment to receiving task observation results,we propose a multi-layer interactive task planning framework which is composed of a preprocessing method for complex tasks,a task allocation layer,a task planning layer,and a task coordination layer.According to the characteristics of the framework,a hybrid genetic parallel tabu(HGPT)algorithm is proposed on this basis.The algorithm uses genetic annealing algorithm(GAA),parallel tabu(PT)algorithm,and heuristic rules to achieve task allocation,task planning,and task coordination.At the same time,coding improvements,operator design,annealing operations,and parallel calculations are added to the algorithm.In order to verify the effectiveness of the algorithm,simulation experiments under complex task scenarios of different scales are carried out.Experimental results show that this method can effectively solve the problems of observing complex tasks.Meanwhile,the optimization effect and convergence speed of the HGPT is better than that of the related algorithms.