The self-assembly of polyalcohol ligand 1,1,1-tris(hydroxymethyl)ethane with Dy(NO3)3· 6H2 O and Cr3O-Bzo-t-Bu precursor in the presence of triethylamine step-by-step generated a heterometallic 3d–4f chain. ...The self-assembly of polyalcohol ligand 1,1,1-tris(hydroxymethyl)ethane with Dy(NO3)3· 6H2 O and Cr3O-Bzo-t-Bu precursor in the presence of triethylamine step-by-step generated a heterometallic 3d–4f chain. Magnetic investigation of the complex indicates typical slow relaxation of the magnetization at low temperature.展开更多
基金supported by the NSF of China(Nos.21031002,21421001)Natural Science Fund of Tianjin,China(No.15JCZDJC38800)
文摘The self-assembly of polyalcohol ligand 1,1,1-tris(hydroxymethyl)ethane with Dy(NO3)3· 6H2 O and Cr3O-Bzo-t-Bu precursor in the presence of triethylamine step-by-step generated a heterometallic 3d–4f chain. Magnetic investigation of the complex indicates typical slow relaxation of the magnetization at low temperature.