Carbon nanotubes(CNTs) decorated with palladium were synthesized and applied to hydrogen storage of gas phase. The results show that the amount of hydrogen storage of the decorated CNTs is up to 3.9%(mass fraction...Carbon nanotubes(CNTs) decorated with palladium were synthesized and applied to hydrogen storage of gas phase. The results show that the amount of hydrogen storage of the decorated CNTs is up to 3.9%(mass fraction), of which, almost 85% H2 can be desorbed at ambient temperature and pressure, while the non-decorated CNTs has a poor performance of hydrogen storage(only about 0.5%H2, mass fraction). These indicate that it is feasible to enhance the performance of hydrogen storage of CNTs by further decoration with hydrogen-storing metals or alloys.展开更多
As CO2 is injected into pore spaces of water-filled reservoir rocks, it displaces much of the pore fluids. In short terms (several to tens of years), the greater part of the injected CO2 is predicted to stay as free C...As CO2 is injected into pore spaces of water-filled reservoir rocks, it displaces much of the pore fluids. In short terms (several to tens of years), the greater part of the injected CO2 is predicted to stay as free CO2 , i.e. in a CO2 rich dense phase that may contain some water. This paper investigates the sorption characteristics for rocks (quartzose arenite, greywacke, shale, granite and serpentine) and minerals (quartz and albite) in the CO2 rich dense phase. The measurements were conducted at 50°C and 100°C, and pressures up to 20 MPa. Our results demonstrated that significant quantities of CO2 were sorbed with all the samples. Particularly, at 50°C and 100°C, quartzose arenite showed largest sorption capacity among the other samples in higher pressures (>10 MPa). Furthermore, comparison with model prediction based on the pore filling model, which assumed that CO2 acts as filling pore spaces of the rocks and minerals, suggested the importance of the sorption mechanism in the CO2 geological storage in addition to the pore-filling mechanism. The present results should be pointed out that the sorption characteristics may have significant and meaningful effect on the assessment of CO2 storage capacity in geological media.展开更多
The building sector accounts for more than 40% of the global energy consumption. This consumption may be lowered by reducing building energy requirements and using renewable energy in building energy supply systems. S...The building sector accounts for more than 40% of the global energy consumption. This consumption may be lowered by reducing building energy requirements and using renewable energy in building energy supply systems. Solar air-conditioning systems(SACS) are a promising solution for the reduction of conventional energy in buildings. The storage, especially the cold storage, plays an important role in SACS for unstable solar irradiation. In this paper, we took the absorption refrigerating unit as an example, and the solar air-conditioning system of an office building in Beijing was simulated. The accuracy of this model was verified by comparing with the SACS operation data. Moreover, based on the simulation data, the cold storage capacity of the solar air-conditioning system in different climatic regions was studied. The cold storage capacities of SACS in 20 cities distributed in different climate regions were studied systematically. The results simulated by our proposed model will be beneficial to the SACS design, and will enlarge the application of SACS.展开更多
文摘Carbon nanotubes(CNTs) decorated with palladium were synthesized and applied to hydrogen storage of gas phase. The results show that the amount of hydrogen storage of the decorated CNTs is up to 3.9%(mass fraction), of which, almost 85% H2 can be desorbed at ambient temperature and pressure, while the non-decorated CNTs has a poor performance of hydrogen storage(only about 0.5%H2, mass fraction). These indicate that it is feasible to enhance the performance of hydrogen storage of CNTs by further decoration with hydrogen-storing metals or alloys.
文摘As CO2 is injected into pore spaces of water-filled reservoir rocks, it displaces much of the pore fluids. In short terms (several to tens of years), the greater part of the injected CO2 is predicted to stay as free CO2 , i.e. in a CO2 rich dense phase that may contain some water. This paper investigates the sorption characteristics for rocks (quartzose arenite, greywacke, shale, granite and serpentine) and minerals (quartz and albite) in the CO2 rich dense phase. The measurements were conducted at 50°C and 100°C, and pressures up to 20 MPa. Our results demonstrated that significant quantities of CO2 were sorbed with all the samples. Particularly, at 50°C and 100°C, quartzose arenite showed largest sorption capacity among the other samples in higher pressures (>10 MPa). Furthermore, comparison with model prediction based on the pore filling model, which assumed that CO2 acts as filling pore spaces of the rocks and minerals, suggested the importance of the sorption mechanism in the CO2 geological storage in addition to the pore-filling mechanism. The present results should be pointed out that the sorption characteristics may have significant and meaningful effect on the assessment of CO2 storage capacity in geological media.
基金funded by the National Key R&D Program of China (No. 2017YFC0702600)
文摘The building sector accounts for more than 40% of the global energy consumption. This consumption may be lowered by reducing building energy requirements and using renewable energy in building energy supply systems. Solar air-conditioning systems(SACS) are a promising solution for the reduction of conventional energy in buildings. The storage, especially the cold storage, plays an important role in SACS for unstable solar irradiation. In this paper, we took the absorption refrigerating unit as an example, and the solar air-conditioning system of an office building in Beijing was simulated. The accuracy of this model was verified by comparing with the SACS operation data. Moreover, based on the simulation data, the cold storage capacity of the solar air-conditioning system in different climatic regions was studied. The cold storage capacities of SACS in 20 cities distributed in different climate regions were studied systematically. The results simulated by our proposed model will be beneficial to the SACS design, and will enlarge the application of SACS.