2-D Modeling and Calculations of Stratospheric Ozone and Influences of Convection, Diffusion, and Time

An engineering system approach of 2-D cylindrical model of transient mass balance calculations of ozone and other concerned chemicals along with fourteen photolysis, ozone-generating and ozone-depleting chemical reaction equations was developed, validated, and used for studying the ozone concentrations, distribution and peak of the layer, ozone depletion and total ozone abundance in the stratosphere. The calculated ozone concentrations and profile at both the Equator and a 60˚N location were found to follow closely with the measured data. The calculated average ozone concentration was within 1% of the measured average, and the deviation of ozone profiles was within 14%. The monthly evolution of stratospheric ozone concentrations and distribution above the Equator was studied with results discussed in details. The influences of slow air movement in both altitudinal and radial directions on ozone concentrations and profile in the stratosphere were explored and discussed. Parametric studies of the influences of gas diffusivities of ozone DO3 and active atomic oxygen DO on ozone concentrations and distributions were also studied and delineated. Having both influences through physical diffusion and chemical reactions, the diffusivity (and diffusion) of atomic oxygen DO was found to be more sensitive and important than that of ozone DO3 on ozone concentrations and distribution. The 2-D ozone model present in this paper for stratospheric ozone and its layer and depletion is shown to be robust, convenient, efficient, and executable for analyzing the complex ozone phenomena in the stratosphere. .

Modelling,Validation,and Calculations of Stratospheric Ozone Dynamics and Latitudinal Changes

This paper presents an engineering system approach of 2-D cylindrical model of mass balance calculations with convection,diffusion,and all potential photolysis,ozone generating and depleting chemical reactions considered.This model was developed,validated,and tested under different conditions for the stratospheric ozone.The calculated ozone concentrations and profile in the stratosphere at both the Equator and mid-latitudinal location of 40°S were found to exhibit a similar and close profile and peak value of the published measured data.The discrepancy between the calculations and measurements for the average ozone concentration was shown to be less than 1%and the variation of distributions to be less than 19%.The latitudinal changes of ozone concentrations,distribution,and peak of the layer were found to shift from 9.41 ppm at mid-altitude of z=30 km at the Equator,to 7.81 ppm at z=34.5 km at 40°S,to 5.78 ppm at higher altitude z=39 km at the South Pole.The total ozone abundances at strategic latitudes at 0°S,20°S,40°S,60°S,and 90°S,were found to remain stable and not much changed,from 305 DU to 335 DU,except a smaller value of 288 DU at the South Pole.The possible explanations of ozone profile change and peak shifting as affected by solar/UV radiation,latitudinal locations,and ozone-depleting reactions were discussed and elaborated.The 2-D ozone Model presented in this paper is a robust,efficient,executable,and validated model for studying the complex ozone phenomena in the stratosphere.

Satellite Measurements of the Madden–Julian Oscillation in Wintertime Stratospheric Ozone over the Tibetan Plateau and East Asia

We investigate the Madden-Julian Oscillation （MJO） signal in wintertime stratospheric ozone over the Tibetan Plateau and East Asia using the harmonized dataset of satellite ozone profiles. Two different MJO indices -- the all-season Real-Time multivariate MJO index （RMM） and outgoing longwave radiation-based MJO index （OMI） -- are used to compare the MJO- related ozone anomalies. The results show that there are pronounced eastward-propagating MJO-related stratospheric ozone anomalies （mainly within 20-200 hPa） over the subtropics, The negative stratospheric ozone anomalies are over the Tibetan Plateau and East Asia in MJO phases 4-7, when MJO-related tropical deep convective anomalies move from the equatorial Indian Ocean towards the western Pacific Ocean. Compared with the results based on RMM, the MJO-related stratospheric column ozone anomalies based on OM1 are stronger and one phase ahead. Further analysis suggests that different sampling errors, observation principles and retrieval algorithms may be responsible for the discrepancies among different satellite measurements. The MJO-related stratospheric ozone anomalies can be attributed to the MJO-related circulation anomalies, i.e., the uplifted tropopanse and the northward shifted westerly jet in the upper troposphere. Compared to the result based on RMM, the upper tropospheric westerly jet may play a less important role in generating the stratospheric column ozone anomalies based on OMI. Our study indicates that the circulation-based MJO index （RMM） can better characterize the MJO- related anomalies in tropopause pressure and thus the MJO influence on atmospheric trace gases in the upper troposphere and lower stratosphere, especially over subtropical East Asia.

Role of Stratospheric Processes in Climate Change: Advances and Challenges

In this review,instead of summarizing all the advances and progress achieved in stratospheric research,the main advances and new developments in stratosphere-troposphere coupling and stratospheric chemistry-climate interactions are summarized,and some outstanding issues and grand challenges are discussed.A consensus has been reached that the stratospheric state is an important source of improving the predictability of the troposphere on sub-seasonal to seasonal(S2S)time scales and beyond.However,applying stratospheric signals in operational S2S forecast models remains a challenge because of model deficiencies and the complexities of the underlying mechanisms of stratosphere-troposphere coupling.Stratospheric chemistry,which controls the magnitude and distribution of many important climate-forcing agents,plays a critical role in global climate change.Convincing evidence has been found that stratospheric ozone depletion and recovery have caused significant tropospheric climate changes,and more recent studies have revealed that stratospheric ozone variations can even exert an impact on SSTs and sea ice.The climatic impacts of stratospheric aerosols and water vapor are also important.Although their quantitative contributions to radiative forcing have been reasonably well quantified,there still exist large uncertainties in their long-term impacts on climate.The advances and new levels of understanding presented in this review suggest that whole-atmosphere interactions need to be considered in future for a better and more thorough understanding of stratosphere-troposphere coupling and its role in climate change.

Increasing Surface UV Radiation in the Tropics and Northern Mid-Latitudes due to Ozone Depletion after 2010

Excessive exposure to ultraviolet(UV)radiation harms humans and ecosystems.The level of surface UV radiation had increased due to declines in stratospheric ozone in the late 1970s in response to emissions of chlorofluorocarbons.Following the implementation of the Montreal Protocol,the stratospheric loading of chlorine/bromine peaked in the late 1990s and then decreased;subsequently,stratospheric ozone and surface UV radiation would be expected to recover and decrease,respectively.Here,we show,based on multiple data sources,that the May–September surface UV radiation in the tropics and Northern Hemisphere mid-latitudes has undergone a statistically significant increasing trend[about 60.0 J m^(–2)(10 yr)^(–1)]at the 2σlevel for the period 2010–20,due to the onset of total column ozone(TCO)depletion[about−3.5 DU(10 yr)^(–1)].Further analysis shows that the declines in stratospheric ozone after 2010 could be related to an increase in stratospheric nitrogen oxides due to increasing emissions of the source gas nitrous oxide(N_(2)O).

Impact of Tropical Indian Ocean Temperature on the Ozone Layer in East Asia

Based on the reanalysis data of monthly mean sea surface temperature (SST) from British Hadley Center and ozone mass mixing ratio from National Aeronautics and Space Administration (NASA) during 1980-2015, two indexes IOBI and IODI of the main modes characterizing SST changes in the tropical Indian Ocean——Indian Ocean Basin (IOB) and Indian Ocean Dipole (IOD) were calculated firstly, and then the correlation of SST anomaly (SSTA) in the tropical Indian Ocean and ozone mass mixing ratio in the stratosphere over East Asia from 1980 to 2015 was analyzed. Besides, the impact of SST changes in the tropical Indian Ocean on the distribution of ozone layer in East Asia was discussed. The results show that SST changes in the tropical Indian Ocean had significant effects on stratospheric ozone distribution in East Asia, and it was consistent with the temporal changes of IOB and IOD. IOBI and IODI had a certain correlation with stratospheric ozone changes in East Asia, with a particularly significant correlation in the lower stratosphere (70 hPa) and middle stratosphere (40 hPa) especially during spring and autumn.

Ozone during Stratospheric Warmings at Uccle

The day-to-day variations in ozone content at Uccle (51°N) during some stratospheric warming events are examined. In particular, the attention is focused on the timing of commencement of ozone enhancement prior to peak day of warming and on the relationship in the ozone content between the upper and lower stratosphere. These two features are compared with the predictions of ozone transport models. There seems to be an agreement between model predictions and observed features in some cases.

从中国首台紫外-可见光高光谱卫星仪器反演得到的高空间分辨率臭氧廓线

Understanding the vertical distribution of ozone is crucial when assessing both its horizontal and vertical transport,as well as when analyzing the physical and chemical properties of the atmosphere.One of the most effective ways to obtain high spatial resolution ozone profiles is through satellite observations.The Environmental Trace Gases Monitoring Instrument(EMI)deployed on the Gaofen-5 satellite is the first Chinese ultraviolet-visible hyperspectral spectrometer.However,retrieving ozone profiles using backscattered radiance values measured by the EMI is challenging due to unavailable measurement errors and a low signal-to-noise ratio.The algorithm developed for the Tropospheric Monitoring Instrument did not allow us to retrieve 87%of the EMI pixels.Therefore,we developed an algorithm specific to the characteristics of the EMI.The fitting residuals are smaller than 0.3%in most regions.The retrieved ozone profiles were in good agreement with ozonesonde data,with maximum mean biases of 20%at five latitude bands.By applying EMI averaging kernels to the ozonesonde profiles,the integrated stratospheric column ozone and tropospheric column ozone also showed excellent agreement with ozonesonde data,The lower layers(0-7.5 km)of the EMI ozone profiles reflected the seasonal variation in surface ozone derived from the China National Environmental Monitoring Center(CNEMC).However,the upper layers(9.7-16.7 km)of the ozone profiles show different trends,with the ozone peak occurring at an altitude of 9.7-16.7 km in March,2019.A stratospheric intrusion event in central China from August 11 to 15,2019,is captured using the EMI ozone profiles,potential vorticity data,and relative humidity data.The increase in the CNEMC ozone co ncentration showed that downward transport enhanced surface ozone pollution.

The Impacts of Two Types of El Nińo on Global Ozone Variations in the Last Three Decades

The effects of E1Nifio Modoki events on global ozone concentrations are investigated from 1980 to 2010 E1 Nifio Modoki events cause a stronger Brewer-Dobson （BD） circulation which can transports more ozone-poor air from the troposphere to stratosphere, leading to a decrease of ozone inthe lower-middle stratosphere from 90~S to 90~N. These changes in ozone concentrations reduce stratospheric column ozone. The reduction in stratospheric column ozone during E1 Nifio Modoki events is more pronounced over the tropical eastern Pacific than over other tropical areas because transport of ozone-poor air from middle-high latitudes in both hemispheres to low latitudes is the strongest between 60°W and 120°W. Because of the decrease in stratospheric column ozone during E1 Nifio Modoki events more UV radiation reaches the tropical troposphere leading to significant increases in tropospheric column ozone An empirical orthogonal function （EOF） analysis of the time series from 1980 to 2010 of stratospheric and tropospheric ozone monthly anomalies reveals that： E1 Nifio Modoki events are associated with the primary EOF modes of both time series. We also found that E1 Nifio Modoki events can affect global ozone more significantly than canonical E1 Nifio events. These results imply that E1 Nifio Modoki is a key contributor to variations in global ozone from 1980 to 2010.

Evaluating the Ozone Valley over the Tibetan Plateau in CMIP6 Models

Total column ozone(TCO)over the Tibetan Plateau(TP)is lower than that over other regions at the same latitude,particularly in summer.This feature is known as the“TP ozone valley”.This study evaluates long-term changes in TCO and the ozone valley over the TP from 1984 to 2100 using Coupled Model Intercomparison Project Phase 6(CMIP6).The TP ozone valley consists of two low centers,one is located in the upper troposphere and lower stratosphere(UTLS),and the other is in the middle and upper stratosphere.Overall,the CMIP6 models simulate the low ozone center in the UTLS well and capture the spatial characteristics and seasonal cycle of the TP ozone valley,with spatial correlation coefficients between the modeled TCO and the Multi Sensor Reanalysis version 2(MSR2)TCO observations greater than 0.8 for all CMIP6 models.Further analysis reveals that models which use fully coupled and online stratospheric chemistry schemes simulate the anticorrelation between the 150 hPa geopotential height and zonal anomaly of TCO over the TP better than models without interactive chemistry schemes.This suggests that coupled chemical-radiative-dynamical processes play a key role in the simulation of the TP ozone valley.Most CMIP6 models underestimate the low center in the middle and upper stratosphere when compared with the Microwave Limb Sounder(MLS)observations.However,the bias in the middle and upper stratospheric ozone simulations has a marginal effect on the simulation of the TP ozone valley.Most CMIP6 models predict the TP ozone valley in summer will deepen in the future.

Advances in Studies of the Middle and Upper Atmosphere and Their Coupling with the Lower Atmosphere

Recent advances in studies of the middle and upper atmosphere and their coupling with the lower atmosphere in China are briefly reviewed. This review emphasizes four aspects: (1) Development of instrumentation for middle and upper atmosphere observation; (2) Analyses and observation of middle and upper atmosphere; (3) Theoretical and modeling studies of planetary wave and gravity wave activities in the middle atmosphere and their relation to lower atmospheric processes; (4) Study on the coupling between the stratosphere and the troposphere.

Comparison of trends in the Hadley circulation between CMIP6 and CMIP5

There have been extensive studies on poleward expansion of the Hadley cells and the associated poleward shift of subtropical dry zones in the past decade.In the present study,we study the trends in the width and strength of the Hadley cells,using currently available simulation results of the Coupled Model Intercomparison Project Phase-6(CMIP6),and compare the trends with that in CMIP5 simulations.Our results show that the total annual-mean trend in the width of the Hadley cells is 0.13°±0.02°per decade over 1970–2014 in CMIP6 historical All-forcing simulations.It is almost the same as that in CMIP5.The trend in the strength of the Northern-Hemisphere(NH)cell shows much greater weakening in CMIP6 than in CMIP5,while the strength trend in the Southern-Hemisphere(SH)cell shows slight strengthening.Single-forcing simulations demonstrate that increasing greenhouse gases cause widening and weakening of both the NH and SH Hadley cells,while anthropogenic aerosols and stratospheric ozone changes cause weak strengthening trends in the SH cell.CMIP6 projection simulation results show that both the widening and weakening trends increase with radiative forcing.