Fabrication and characterization of multi-scale coated boron powders with improved combustion performance:A brief review

Boron has high mass and volume calorific values,but it is difficult to ignite and has low combustion efficiency.This literature review summarizes the strategies that are used to solve the above-mentioned problems,which include coatings of boron by using fluoride compounds,energetic composites,metal fuels,and metal oxides.Coating techniques include recrystallization,dual-solvent,phase transfer,electrospinning,etc.As one of the effective coating agents,the fluorine compounds can react with the oxide shell of boron powder.In comparison,the energetic composites can effectively improve the flame temperature of boron powder and enhance the evaporation efficiency of oxide film as a condensed product.Metals and metal oxides would react with boron powder to form metal borides with a lower ignition point,which could reduce its ignition temperature.

Optimization and Characterization of Combined Degumming Process of Typha angustata L. Stem Fibers

Plant derived natural fibers have been widely investigated as alternatives to synthetic fibers in reinforcing polymers.Researchers over the years have explored many plant fibers using different extraction processes to study their physical,chemical,and mechanical properties.In this context,the present study relates to the extraction,characterization,and optimization of Typha angustata L.stem fibers.For this purpose,desirability functions and response surface methodology were applied to simultaneously optimize the diameter(D),linear density(LD);yield(Y),lignin fraction(L),and tenacity(T)of Typha stem fibers.Typha stems have been subjected to both alkali(NaOH)and enzymatic(pectinex ultra-SPL)treatments.Three levels of process variables including enzyme concentration(10,15,and 20 ml/L)and treatment duration(10,15,and 20 days)were used to design the experiments according to the factorial design.Experimental results were examined by analysis of variance and fitted to second order polynomial model using multiple regression analysis.The Derringer’s desirability function released that the values of process variables generating optimized diameter,linear density,yield,lignin ratio and tenacity are 20 ml/L and 20 days for concentration of pectinex ultra-SPL enzyme and treatment duration,respectively.Confirmation was performed and high degree of correlation was found between the experimental and statistical values.Moreover,the morphological structure has been investigated by the scanning electron microscope,showing a crenelated structure of ultimate fiber bundles of cellulose composing the Typha fiber.Compared to Typha stem non-treated fibers(TSNTF),Typha stem combined treated fibers(TSCTF),brings to improve mechanical properties.This change in mechanical properties is affected by modifying the fiber structure showing alpha cellulose of(66.86%)and lignin ratio of(10.83%)with a crystallinity index of(58.47%).

MORPHOLOGY AND STRUCTURE OF TRANSFORMATION PRODUCTS FORMED AT INTERMEDIATE TEMPERATURE IN A Cu-Zn-Al ALLOY

A TTT diagram for th ie precipitation formed at some intermediate temperatures through cooling from high lemperalure parenl phase in a Cu-27 27Zn-3.73Al allay is established by means of dilatormetric measurement.The morphology and structure of transformation products formed at some intermediate tem peratures isothermally through cooling from high temperature parent phase and up-quenching from DO_(3) parent phase are studied by metallographic.X-ray and electron microscopy analyses.Three regions in the two separate C curves are obtained according to different morphology of precipitate:rod-like a,plate-like bainite and a rods,and bainite plates.Prolonged aging makes bainite plate change gradually into a whose lattice parameters are no different from that of a formed equilibriumly from parent phase.The structure is almost orthorhombic long period structure for bainites formed from B_(2) and DO_(3) parent phase,but monoclinic for martensite from DO_(3).They correspond to the overlapping and separating of(1210)and(2010)diffraction peaks respectively,showing the lower degree of ordering in bainite.

Study on urban spatial structure and morphology of Guangzhou-Foshan metropolitan coordinating region compared with Randstad,Netherlands

In recent years,regional integration of Chinese cities has gradually developed.Meanwhile,metropolitan areas and urban agglomerations have taken shape.On the one hand,the development of the metropolitan area has brought about urban spatial expansion,as well as population and economic growth.On the other hand,it has led to problems such as the urban sprawl and suburbanization,increasing pressure on environmental resources,and the decline of urban central areas.Under this background,the Guangdong-Hong Kong-Macao Greater Bay Area Development Plan Outline proposes to accelerate the integration of Guangzhou-Foshan(Guang Fo)Metropolitan Coordinating Region(MCR),and to construct a networked space pattern driven by urban poles and shafts.Based on the academic research of Metropolitan Coordinating Region(MCR),as well as the theory of urban spatial structure and morphology,this study focus on urban spatial patterns and elements in different scales,from two individual cites(Guangzhou and Foshan),Guang Fo MCR,to Guangdong-Hong Kong-Macao(GHM)Greater Bay Area.With GIS and the mapping method,the spatial elements such as green space,water system,built-up area,road network,rail transit network and main pivot points of the Guang Fo MCR are classified,laid out individually and again overlaid in order to figure out the relationship of these elements.At the same time,through the comparative case study of the Randstad MCR in the Netherlands,the enlightenment of solving the development problem of MCR is hopefully to be obtained.As delta cities,the Guang Fo MCR is cut by the multi-channel water network,while the urban built-up area is concentrated in the middle of the MCR and spread out along the traffic corridor to the suburban district.The traffic structure of the Guang Fo MCR is characterized by the outward radiation of the central area of Guangzhou and Foshan.Simultaneously,the traffic connection between Guangzhou and Foshan is relatively weak.Compared with the polycentric spatial structure,which is called Decentralized Compact pattern of Randstad MCR,the Guang Fo MCR presents a city form with little hierarchy but homogeneity,and its urban space is disorderly spread.The bluegreen system of water and vegetation is fragmented because of the urban invasion in Guang Fo MCR,while the green heart in central Randstad is well preserved.As a result,it is well advised to explore a more resilient and ecological urban development in Guang Fo MCR.

Effect of nickel oxide morphology on the nitrogen electrochemical reduction reaction

In order to study the effect of catalysts’morphology on the electrochemical reduction of nitrogen gas,sample catalysts of NiO with four different morphologies(hollow spherical,sea urchin-shape,cubic block,and rod-like)were prepared.Characterization of the NiO catalysts was carried out using SEM,BET,XRD and electrochemical investigation techniques.The results indicated that the nitrogen reduction reaction(NRR)is strictly dependent on the morphology of the NiO catalysts,as the hollow spherical NiO showed the best electrochemical NRR performance of NH3 yield rate(3.21μg h^-1 mg^-1 cat.,4.1910^-11 mol cm^-2 s^-1)and Faradaic efficiency(1.37%),which was higher than the yields and efficiencies of the rod-NiO(1.8μg h^-1 mg^-1 cat.,3.2410^-11 mol cm^-2 s^-1,1.17%),sea urchin-NiO(1.66μg h^-1 mg^-1 cat.,2.4410^-11 mol cm^-2 s^-1,1.08%)and cubic block-NiO(1.32μg h^-1 mg^-1 cat.,2.1410^-11 mol cm^-2 s^-1,0.81%),respectively.These results match the order of the specific surface area of the NiO samples,with hollow spherical(113.91 m^2 g^-1)>rod-NiO(55.12 m^2 g^-1)sea urchin-NiO(55.29 m^2 g^-1)>cubic block-NiO(38.57 m^2 g^-1).This correlation can be attributed to the fact that large specific surface areas can provide more active sites for electrocatalysis.This work demonstrates the effect of the morphology of the NiO catalysts on its electrochemical NRR properties,which could offer some opportunity for the preparation of new electrode materials with improved electrocatalytic properties.

Copper Ion Beam Irradiation-Induced Effects on Structural,Morphological and Optical Properties of Tin Dioxide Nanowires

The 0.8 Me V copper （ Cu） ion beam irradiation-induced effects on structural, morphological and optical properties of tin dioxide nanowires （Sn02 NWs） are investigated. The samples are irradiated at three different doses 5 × 10^12 ions/cm2, 1 ×10^13 ions/cm2 and 5 × 10^13 ions/em2 at room temperature. The XRD analysis shows that the tetragonal phase of Sn02 NWs remains stable after Cu ion irradiation, but with increasing irradiation dose level the crystal size increases due to ion beam induced coalescence of NWs. The FTIR spectra of pristine Sn02 NWs exhibit the chemical composition of SnO2 while the Cn-O bond is also observed in the FTIR spectra after Cu ion beam irradiation. The presence of Cu impurity in SnO2 is further confirmed by calculating the stopping range of Cu ions by using TRM/SRIM code. Optical properties of SnO2 NWs are studied before and after Cu ion irradiation. Band gap analysis reveMs that the band gap of irradiated samples is found to decrease compared with the pristine sample. Therefore, ion beam irradiation is a promising technology for nanoengineering and band gap tailoring.

SPHERULITIC STRUCTURE AND MORPHOLOGY OF POLY(ETHYLENE SUCCINATE)/POLY(ETHYLENE OXIDE) (PES/PEO) BLENDS WITH ONE-STEP CRYSTALLIZATION

The spherulitic structure and morphology development of poly(ethylene succinate)/poly(ethylene oxide) (PES/PEO) blends with one-step crystallization behavior were observed by means of polarizing optical microscope.It was found that the pure PES spherulite in which the adequate quantity of PEO melt existed in the interlamellar regions,and the blending spherulite formed by both PES and PEO lamellae could form simultaneously.When the two types of spherulites contacted with each other the front of the blending ...

Structural,Morphological and Electrical Properties of In-Doped Zinc Oxide Nanostructure Thin Films Grown on p-Type Gallium Nitride by Simultaneous Radio-Frequency Direct-Current Magnetron Co-Sputtering

Zinc oxide （ZnO） is one of the most promising and frequently used semiconductor materials. In-doped nanos- tructure ZnO thin films are grown on p-type gallium nitride substrates by employing the simultaneous rf and dc magnetron co-sputtering technique. The effect of In-doping on structural, morphological and electrical properties is studied. The different dopant concentrations are accomplished by varying the direct current power of the In target while keeping the fixed radio frequency power of the ZnO target through the co-sputtering deposition technique by using argon as the sputtering gas at ambient temperature. The structural analysis confirms that all the grown thin films preferentially orientate along the c-axis with the wurtzite hexagonal crystal structure without having any kind of In oxide phases. The presenting Zn, 0 and In elements＇ chemical compositions are identified with EDX mapping analysis of the deposited thin films and the calculated M ratio has been found to decrease with the increasing In power. The surface topographies of the grown thin films are examined with the atomic force microscope technique. The obtained results reveal that the grown film roughness increases with the In power. The Hall measurements ascertain that all the grown films have n-type conductivity and also the other electrical parameters such as resistivity,mobility and carrier concentration are analyzed.

MORPHOLOGICAL STUDIES ON THERMOTROPIC LIQUID CRYSTALLINE POLYESTER——MORPHOLOGY OF SHEAR ORIENTED FILMS

The morphology of shear-oriented films of a thermotropic liquid crystalline polyester containing a triad ester mesogenic unit and a flexible spacer has been investigated in details. The formation conditions and process, the fine structures and the relaxation process of mat structure in the oriented films have been observed and discussed.

Influence of Konjac Glucomannan on the Crystallization Morphology and Structure of Calcium Oxalate

The influence of additive Konjac Glucomannan （KGM） in a variety of con- centrations on the crystallization morphology and structure of calcium oxalate （CaOxa） has been investigated by infrared spectroscopy, scanning electron microscope, X-ray diffraction and so on. The results showed KGM can complex with the Ca^2＋ ions; low concentration KGM prevents CaOxa from aggregating, raises the concentration of ions in the solution, reduces the quantity of crystals and inhibits their growth, and the crystals are round and blunt; while high concentration KGM promotes the growth of crystal, which appears in sheet-like or irregular shape. Only CaOxa monohydrate was observed in a certain system with or without the presence of KGM.

Morphology and Structure of SiO_2 Film Using Thermal Oxidation Process on(111)Silicon Crystals in Dry Oxygen Atmosphere

By means of scanning electron microscope(SEM)and high voltage electron microscope(HVEM)we have observed and analysed morphology and micro-structure of silicon oxide film with different thickness formed on(111)silicon monocrystal under dry oxygen atmosphere at 1100℃.Compared with their oxidation kinetic curves consisted of three stages,we suggested a mechanism on forming silicon oxide film.According to electron and X-ray diffraction analyses the silicon oxide films consisted of silica with different crystal structure.We also have discussed a stacking fault and a dislocation formed in the Si-Sio_2 interface region simulaneously forming silicon oxide film.

THE MORPHOLOGY AND STRUCTURE OF ETHYLCYANOETHYL CELLULOSE IN STYRENE AND POLYSTYRENE

Ethyl-cyanoethyl cellulose ((E-CE)C)/styrene solution could form anisotropic system when the concentration was high enough. The (E-CE)C/polystyrene(PS)multiphase polymer could be obtained by radical polymerization of the styrene in the solution. The (E-CE)C/PS multiphase polymer maintained both the crystalline structure of the (E-CE)C and the amorphous structure of the PS. In the multiphase polymer produced from the isotropic solution, however, the (E-CE)C formed spherulites and spread in the PS amorphous phase. While, in the multiphase polymer produced from the anisotropic solution, the (E-CE)formed cylinderic crystalline aggregates. Moreover, the ordered lamellar texture was also observed in the multiphase polymer produced from the anisotropic solution.

Morphology of Barium Hydrogen Phosphate Formation Induced by Phosphate-Mineralization Microbe

Phosphate-mineralization microbe was chosen to study the influences of bacterial mixture,filtrate,bacteria solution,bacterial body and bacterial secretion on barium hydrogen phosphate crystal formation.The chemical compositions and structures of samples were characterized with scanning electron microscopy（SEM）,transmission electron microscopy（TEM）,and X-ray diffraction techniques（XRD）,revealing that the crystal morphology of barium hydrogen phosphate was dumbbell-shaped pattern,nanoparticles via aggregate clusters,irregular sphere with different sizes.The results indicated that bacterial body and bacterial secretion could induce the formation of irregular quadrilateral and spheres,respectively.But the effect of bacterial secretion was stronger than that of bacterial body when induced barium hydrogen phosphate crystal in bacteria solution.However,the crystals form could be affected only in bacterial mixture,but filtrate could induce the formation of nanoparticles.As a result,the bacteria and metabolites play an important role in the process of crystal nucleation,growth,and accumulation of barium hydrogen phosphate.

The Impact of Microscopic Fungi on the Morphological and Structural Properties of Carbon Steel

The growth of the microscopic fungi on the solid surface has a great influence on technical materials destruction. The aim of this study was to determine the influence of two strains of micromycetesPenicillium palitansstrain6 andArthrinium phaeospermumstrain 10 on morphological and structural properties of carbon steel surfaces in the nutrient medium. The difference in consumption of chlorine byP. palitans6(0.07 wt%) andA. phaeospermum10(0.04 wt%) and the difference in accumulation of a newly formed elementmanganese forP. palitans6(0.01 wt%) andA. phaeospermum10(0.03 wt%) has been observed. A relation between the surface and interface fungal stimulated processes, the biotic oxidation of steel surface as well as formation of the mixed oxides on the biomodified steel surface has been determined. The morphology of surfaces was characterized by scanning electron microscopy, the structure—by the X-ray diffraction method, Fourier transformation infrared and X-ray fluorescence spectroscopy.

Migration of paleo-uplift in southwestern Tarim Basin and its implications for orogenesis and reservoir development, NW China

Based on well horizon calibration,the typical seismic profiles in southwestern Tarim Basin were interpreted systematically,regional geological sections were established,and the regional denudation thickness of each tectonic period was restored.On this basis,the plane morphology maps of ancient structures of the Cambrian pre-salt dolomites in different periods were compiled,and the spatial distribution,development,evolution and migration of paleo-uplift in the late Early Paleozoic were analyzed.In the late Early Paleozoic,there existed a unified regional paleo-uplift widely distributed in southwestern Tarim Basin,which is called the southwestern Tarim plaeo-uplift.The“Tarim SW paleo-uplift”and“Hetian paleo-uplift”proposed in previous literatures are not independent,but the result of the spatio-temporal migration and evolution of the southwestern Tarim paleo-uplift identified in this paper.The southwestern Tarim paleo-uplift emerged at the end of Middle Ordovician,and took its initial shape with increased amplitude in the Late Ordovician.During the Silurian,the southwestern Tarim paleo-uplift rose steadily and expanded rapidly to the east,incorporating Pishan-Hetian and other areas,with the structural high locating in the Pishan-Hetian area.During the Devonian,the southwestern Tarim paleo-uplift began to shrink gradually,to a limited range in the Pishan-Hetian area in the southern part of the basin.During the Carboniferous,the southwestern Tarim paleo-uplift became an underwater uplift,that is,the paleo-uplift gradually died out.The southwestern Tarim paleo-uplift belongs to the forebulge of the southwestern Tarim foreland basin in the late Early Paleozoic,and its formation and evolution are related to the early Paleozoic orogeny of the West Kunlun orogenic belt in the south of the Tarim Basin.The migration of the southwestern Tarim paleo-uplift from the northwestern part of the southwestern Tarim Basin to the Pishan-Hetian area indicates the early Paleozoic orogenic process of the West Kunlun orogenic belt,which started in the western section at the end of Middle Ordovician and extended from west to east in a“scissor”style.The migration and evolution of the southwestern Tarim paleo-uplift controlled the development of unconformities at the end of Middle Ordovician,the end of Late Ordovician,and the end of Middle Devonian,and the spatial distribution of dissolved fracture-cave reservoirs in weathered crust below the unconformities in the southwest of Tarim Basin.The migration of the structural high of the southwestern Tarim paleo-uplift also played an important role in controlling the development of dissolved fracture-cave reservoirs in weathered crust.

双角螺旋线虫扫描电镜观察(英文)

[ Objective] The paper was to observe Helicotylenchus digonicus by scanning electron microscope （SEM）. [ Method ] H. digonicus collected from Changxing of Zhejiang Province was observed under scanning electron microscope, and its morphological structure was confmned under optical microscope. [ Resuit]The nematode specimens fixed by glutaraldehyde and osmium tetroxide and prepared by critical point drying were unmodified and unshrinkable with clear mor- phological structure, which could be scanned very well by scanning electron microscope. [ Conclusion ] The study provided reference for study and control of H. digonicus.

Morphological Structure and Genetic Mapping of New Leaf-Color Mutant Gene in Rice (Oryza sativa)

Leaf-color mutations are a widely-observed class of mutations, playing an important role in the study of chlorophyll biosynthesis and plant chloroplast structure, function, genetics and development. A naturally-occurring leaf-color rice mutant, Baihuaidao 7, was analyzed. Mutant plants typically exhibited a green-white-green leaf-color progression, but this phenotype was only expressed in the presence of a stress signal induced by mechanical scarification such as transplantation. Prior to the appearance of white ~eaves, mutant plant growth, leaf color, chlorophyll content, and chloroplast ultrastructure appeared to be identical to those of the wild type. After the changeover to white leaf color, an examination of the mutated leaves revealed a decrease in total chlorophyll, chlorophyll a, chlorophyll b, and carotenoid content, a reduction in the number of chloroplast grana lamella and grana, and a gradual degradation of the thylakoid lamellas. At maturity, the mutant plant was etiolated and dwarfed compared with wild-type plants. Genetic analysis indicated that the leaf mutant character is controlled by a recessive nuclear gene. Genetic mapping of the mutant gene was performed using an F2 population derived from a Baihuaidao 7 ~ Jiangxi 1587 cross. The mutant gene was mapped to rice chromosome 11, positioned between InDel markers L59.2-7 and L64.8-11, which are separated by approximately 740.5 kb. The mutant gene is believed to be a new leaf-color mutant gene in rice, and is tentatively designated as gwgl.

INVESTIGATION OF STRUCTURE AND PROPERTIES FOR POLYMER SYSTEMS BASED ON DYNAMIC RHEOLOGICAL APPROACHES

The dynamic rheological measurements have been a preferred approach to the characterization of the structure and properties for multi-component or multi-phase polymer systems,due to its sensitive response to changes of structure for these heterogeneous polymers.In the present article,recent progresses in the studies on dynamic rheology for heterogeneous polymer systems including polymeric composites filled with inorganic particles,thermo-oxidized polyolefins,phase- separated polymeric blends and functional polymers with the scaling and percolation behavior are reviewed,mainly depending on the results by the authors' group.By means of rheological measurements,not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained,the corresponding results are also significant for the design and preparation of novel polymer-based composites and functional materials.

RECENT DEVELOPMENTS IN PHOTOINITIATED CROSSLINKING OF POLYETHYLENE AND ITS INDUSTRIAL APPLICATIONS

The recent developments in the photoinitiated cross-linking of polyethylene and the significant breakthrough of its industrial application are reviewed. The enhanced photo-initiation system, the dynamics of photoinitiated crosslinking, the optimum conditions, the crystal morphological structures and related properties, and the photo- and thermo-oxidation stability of photocrosslinked polyethylene (XLPE) materials have been elucidated systematically. A new technique for producing photocrosslinked XLPE-insulated wire and cable is described in detail. It can be expected that the future applications of photocrosslinking technique of polyolefins will be very promising.

STUDIES ON STRUCTURE AND PHASE BEHAVIOR OF MULTICOMPONENT POLYMERS THROUGH RHEOLOGICAL TESTS

Rheological measurement has been a preferred approach to the characterization of the structure and phase behaviors for multi-component/multi-phase polymer systems, due to its sensitive response to the changes of structure for these heterogeneous polymers. In the present article, recent progresses in the studies on rheology for heterogeneous polymer systems including phase-separated polymeric blends and block copolymers are reviewed, mainly depending on the results by the authors＇ research group. By means of rheological measurements, not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained, also the corresponding results are significant for design and preparation of novel polymeric structural materials and functional materials.