Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive u...Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive utilization of vanadium slag was proposed,wherein zeolite A and a V2O5/TiO2 system were synthesized.The structural properties of the as-synthesized zeolite A and the V2O5/TiO2system were characterized using various experimental techniques,including X-ray diffraction,X-ray fluorescence,scanning electron microscopy,and infrared spectroscopy.The results reveal that zeolite A and the V2O5/TiO2 system are successfully obtained with high purity.The results of gas adsorption measurements indicate that the prepared zeolite A exhibits high selectivity for CO2 over N2 and is a candidate material for CO2 capture from flue-gas streams.展开更多
An alternating mesophilic and thermophilic two stage anaerobic digestion (AD) process was conducted. The temperature of the acidogenic (A) and methanogenic (M) reactors was controlled as follows: System 1 (S1...An alternating mesophilic and thermophilic two stage anaerobic digestion (AD) process was conducted. The temperature of the acidogenic (A) and methanogenic (M) reactors was controlled as follows: System 1 (S1) mesophilic A-mesophilic M; (S2) mesophilic A-thermophilic M; and (S3) thermophilic A-mesophilic M. Initially, the AD reactor was acclimatized and inoculated with digester sludge. Food waste was added with the soluble chemical oxygen demand (SCOD) concentrations of 41.4-47.0 g/L and volatile fatty acids of 2.0-3.2 g/L. Based on the results, the highest total chemical oxygen demand removal (86.6%) was recorded in S2 while S3 exhibited the highest SCOD removal (96.6%). Comparing S1 with S2, total solids removal increased by 0.5%;S3 on the other hand decreased by 0.1% as compared to S1. However, volatile solids (VS) removal in S1, S2, and S3 was 78.5%, 81.7%, and 79.2%, respectively. S2 also exhibited the highest CH4 content, yield, and production rate of 70.7%, 0.44 L CH4/g VSadded, and 1.23 L CH4/(L.day), respectively. Bacterial community structure revealed that the richness, diversity, evenness, and dominance of S2 were high except for the archaeal community. The terminal restriction fragments dendrogram also revealed that the microbial community of the acidogenic and methanogenic reactors in S2 was distinct. Therefore, S2 was the best among the systems for the operation of two-stage AD of food waste in terms of CH4 production, nutrient removal, and microbial community structure.展开更多
基金supported by the Natural Science Foundation of China (Nos. 51406029 and 51474067)the Key Laboratory Project of Liaoning Province of Education (No.LZ2015032)
文摘Traditional processes for treating vanadium slag generate a huge volume of solid residue and a large amount of harmful gas,which cause serious environmental problems.In this study,a new process for the comprehensive utilization of vanadium slag was proposed,wherein zeolite A and a V2O5/TiO2 system were synthesized.The structural properties of the as-synthesized zeolite A and the V2O5/TiO2system were characterized using various experimental techniques,including X-ray diffraction,X-ray fluorescence,scanning electron microscopy,and infrared spectroscopy.The results reveal that zeolite A and the V2O5/TiO2 system are successfully obtained with high purity.The results of gas adsorption measurements indicate that the prepared zeolite A exhibits high selectivity for CO2 over N2 and is a candidate material for CO2 capture from flue-gas streams.
基金supported by the Korean Ministry of Agriculture, Food and Rural Affairs (313007-03-1-HD020)
文摘An alternating mesophilic and thermophilic two stage anaerobic digestion (AD) process was conducted. The temperature of the acidogenic (A) and methanogenic (M) reactors was controlled as follows: System 1 (S1) mesophilic A-mesophilic M; (S2) mesophilic A-thermophilic M; and (S3) thermophilic A-mesophilic M. Initially, the AD reactor was acclimatized and inoculated with digester sludge. Food waste was added with the soluble chemical oxygen demand (SCOD) concentrations of 41.4-47.0 g/L and volatile fatty acids of 2.0-3.2 g/L. Based on the results, the highest total chemical oxygen demand removal (86.6%) was recorded in S2 while S3 exhibited the highest SCOD removal (96.6%). Comparing S1 with S2, total solids removal increased by 0.5%;S3 on the other hand decreased by 0.1% as compared to S1. However, volatile solids (VS) removal in S1, S2, and S3 was 78.5%, 81.7%, and 79.2%, respectively. S2 also exhibited the highest CH4 content, yield, and production rate of 70.7%, 0.44 L CH4/g VSadded, and 1.23 L CH4/(L.day), respectively. Bacterial community structure revealed that the richness, diversity, evenness, and dominance of S2 were high except for the archaeal community. The terminal restriction fragments dendrogram also revealed that the microbial community of the acidogenic and methanogenic reactors in S2 was distinct. Therefore, S2 was the best among the systems for the operation of two-stage AD of food waste in terms of CH4 production, nutrient removal, and microbial community structure.