Suppression of Co(Ⅱ)ion deposition and hazards:Regulation of SEI film composition and structure

Despite the presence of Li F components in the solid electrolyte interphase(SEI)formed on the graphite anode surface by conventional electrolyte,these Li F components primarily exist in an amorphous state,rendering them incapable of effectively inhibiting the exchange reaction between lithium ions and transition metal ions in the electrolyte.Consequently,nearly all lithium ions within the SEI film are replaced by transition metal ions,resulting in an increase in interphacial impedance and a decrease in stability.Herein,we demonstrate that the SEI film,constructed by fluoroethylene carbonate(FEC)additive rich in crystalline Li F,effectively inhibits the undesired Li^(+)/Co^(2+)ion exchange reaction,thereby suppressing the deposition of cobalt compounds and metallic cobalt.Furthermore,the deposited cobalt compounds exhibit enhanced structural stability and reduced catalytic activity with minimal impact on the interphacial stability of the graphite anode.Our findings reveal the crucial influence of SEI film composition and structure on the deposition and hazards associated with transition metal ions,providing valuable guidance for designing next-generation electrolytes.

Variability of phytoplankton absorption in the northern South China Sea:influence of the size structure and pigment composition of algal populations

Data from three cruises conducted in the Zhujiang River （ZR）, coastal waters of Guangdong （CWGD） and the northern South China Sea （NSCS） during 2003 and 2004 were examined for assessing the relative importance of pigment composition and packaging effect in modifying the specific absorption coefficients of phytoplankton. The three survey regions differ widely in their phytoplankton community with large cells dominating the ZR and CWGD waters and small cells dominating the NSCS region. Variations in the size structure and the accessory pigments have much effect on the chlorophyll a-specific absorption coefficient of phytoplankton. The size index accounted for about 42% and 33% of the variation of the specific absorption coefficient at 440 and 675 nm, respectively. Using the multiple regression analysis approach, pigment concentrations for each sample were calculated. The accessory pigments other than chlorophyll a contribute to absorption mainly in the blue - to - green region of the spectrum and their absorptions account for about 44%, 43% and 53% on the average of the total phytoplankton absorption at 440 nm for the ZR, CWGD and NSCS regions. Among the accessory pigments, the photosynthetic carotenoids （noted PSC） play a dominant role in the ZR and CWGD waters, while in the NSCS the nonphotosynthetic carotenoids （noted PPG） as well as PSC have important contributions. Because the variations of both the size structure and accessory pigments in algal populations contributed to the variability of the specific absorption coefficient in the study regions, these factors may be considered explicitly in future bio - optical algorithms to derive chlorophyll a concentration more accurately.

Floristic Composition, Structure and Soil Properties of Mixed Deciduous Forest and Deciduous Dipterocarp Forest: Case Study in Madan Watershed, Myanmar

Patterns of woody regeneration in terms of species composition and diversity were studied in mixed deciduous forest (MDF) and deciduous dipterocarp forest (DDF) in Minbyin reserved forest of Lewe Township. A total of 57 plant species of MDF belonging to 28 families and 342 individuals and 25 plant species of DDF consist of 15 families and 285 individuals were identified. Plant species diversity was quantitatively higher in the MDF (H' = 3.68) compared to the DDF (H' = 2.39). Tectona grandis showed the highest density (30), dominance (4.40 m2) and IVI (27.01) of MDF and Dipterocarpus tuberculatus also composed the highest density (109), dominance (9.02 m2) and IVI (81.87) in DDF. The smallest diameter class (10 - 20 cm) comprised with 29 species, 103 individuals in MDF and 18 species, 85 individuals in DDF. The size class distribution displayed a reverse J-shaped pattern. The largest numbers of species were concentrated in the smallest height class in both investigated forests because of height and diameter distribution is closely related. The total densities of seedlings and saplings were 1219 and 531 ha-1 in MDF and 988 and 444 ha-1 in DDF respectively. Although soil texture of (40 - 50 cm) and (90 - 100 cm) were sandy clay loam in mixed deciduous forest, the other layers of both investigated forests were sandy loam.

Numerical investigation of the mechanical behavior of the backfill–rock composite structure under triaxial compression

To ensure safe and economical backfill mining,the mechanical response of the backfill–rock interaction system needs to be understood.The numerical investigation of the mechanical behavior of backfill–rock composite structure(BRCS)under triaxial compression,which includes deformation,failure patterns,strength characteristics,and acoustic emission(AE)evolution,was proposed.The models used in the tests have one rough interface,two cement–iron tailings ratios(CTRs),four interface angles(IAs),and three confining pressures(CPs).Results showed that the deformation,strength characteristics,and failure patterns of BRCS under triaxial compression depend on IA,CP,and CTR.The stress–strain curves of BRCS under triaxial compression could be divided into five stages,namely,compaction,elasticity,yield,strain softening,and residual stress.The relevant AE counts have corresponding relationships with different stages.The triaxial compressive strengths of composites increase linearly with the increase of the CP.Furthermore,the CP stress strengthening effect occurs.When the IAs are45°and 60°,the failure areas of composites appear in the interface and backfill.When the IAs are 75°and 90°,the failure areas of composites appear in the backfill,interface,and rock.Moreover,the corresponding failure modes yield the combined shear failure.The research results provide the basis for further understanding of the stability of the BRCS.

Failure characteristics and the damage evolution of a composite bearing structure in pillar-side cemented paste backfilling

A backfilling body-coal pillar-backfilling body(BPB)structure formed by pillar-side cemented paste backfilling can bear overburden stress and ensure safe mining.However,the failure response of BPB composite samples must be investigated.This paper examines the deformation characteristics and damage evolution of six types of BPB composite samples using a digital speckle correlation method under uniaxial compression conditions.A new damage evolution equation was established on the basis of the input strain energy and dissipated strain energy at the peak stress.The prevention and control mechanisms of the backfilling body on the coal pillar instability were discussed.The results show that the deformation localization and macroscopic cracks of the BPB composite samples first appeared at the coal-backfilling interface,and then expanded to the backfilling elements,ultimately appearing in the coal elements.The elastic strain energy in the BPB composite samples reached a maximum at the peak stress,whereas the dissipated energy continued to accumulate and increase.The damage evolution curve and equation agree well with the test results,providing further understanding of instability prevention and the control mechanisms of the BPB composite samples.The restraining effect on the coal pillar was gradually reduced with decreasing backfilling body element's volume ratio,and the BPB composite structure became more vulnerable to failure.This research is expected to guide the design,stability monitoring,instability prevention,and control of BPB structures in pillar-side cemented paste backfilling mining.

The Key Influence of Fluid in Metamorphic Rock Preserves, Mineral Assemblages, Compositions and Structures: Study from High-Pressure Eclogite and Its Amphibolization in the Western Dabie Mountains,Central China

The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should

Composition and Structure of Ti-6Al-4V Alloy Plasma-based Ion Implanted with Nitrogen

The composition and structure of Ti 6Al 4V alloy plasma based ion implanted with nitrogen was investigated.The nitrogen depth distribution shows more antiballistic with distribution peak heightened with increased implantation time(dose),and more like a parabola at the low implantation pulse voltage.When implantation pulse voltage is increased,the implantation depth increased with the nitrogen distribution peak being deepened,widened and lowered somewhat.TiN,TiN+Ti 2N,or Ti 2N second phases were formed in the implanted layer.The relative percentage of nitrogen content in the form of TiN increases when going deeper into the implanted(TiN formed) layer.The increase of implantation pulse width and/or time is favourable for the formation of TiN rather than Ti 2N.It is unfavourable for formation of any nitrides when implantation pulse voltage is decreased to 30kV or less.Tiny crystalline particles (made mainly of Ti 2N and a smaller percentage of TiO 2 phases) of regular shapes such as triangle and tetragon, etc .(about 20 nm) are found distrbuted dispersively in the near surface region of samples implanted at the high implantation pulse voltage (75kV).

Composite wave-absorbing structure combining thin plasma and metasurface

In order to solve the thickness dependence of plasma absorption of electromagnetic waves and further reduce the backward radar scattering cross section(RCS)of the target,we designed a novel composite structure of a metasurface and plasma.A metasurface with three absorption peaks is designed by means of an equivalent circuit based on an electromagnetic resonance type metamaterial absorber.The reflection and absorption of the composite structure are numerically and experimentally verified.The finite integration method was used to simulate a composite structure of finite size to obtain the RCS.The experimental measurements of electromagnetic wave reflection were conducted by a vector network analyzer(Keysight N5234A)and horn antennas,etc.The research showed that the absorption capacity of this composite structure was substantially improved compared to either the plasma or the metasurface,and it is more convenient for application due to its low plasma thickness requirement and easy fabrication.

Preparation of Flower-like Copper Foam Supported Co_(3)O_(4) Electrocatalyst and Its Hydrogen Evolution Performance

Flower-like copper foam Co_(3)O_(4) catalysts(Co_(3)O_(4)/CF) were prepared by hydrothermal method.The crystalline structure and microscopic morphology of the prepared samples were characterized by using X-ray diffractometer(XRD) and scanning electron microscope(SEM),and the electrochemical properties were investigated by an electrochemical workstation.The experimental results show that the Co_(3)O_(4) catalysts are successfully prepared on the foamed copper support by hydrothermal method,and the material’s morphology is mainly flower cluster.When the current density is 10 mA·cm^(-2),the overpotential value of the Co_(3)O_(4)/CF catalyst is 141 mV,lower than that of blank support.The electrochemical impedance(EIS) spectrum shows that the R_(ct )value of the Co_(3)O_(4)/CF catalyst decreases,and the Coulomb curves of double-layer show that the electrochemically active area of the Co_(3)O_(4)/CF catalyst efficiently increases compared with that of the blank support.Therefore,the as-obtained Co_(3)O_(4)/CF catalyst exhibits a good hydrogen evolution rate,showing great applicability potential in the catalytic electrolysis of water for hydrogen production.

Parametric study on contact sensors for MASW measurement-based interfacial debonding detection for SCCS

Steel-concrete composite structures(SCCS)have been widely used as primary load-bearing components in large-scale civil infrastructures.As the basis of the co-working ability of steel plate and concrete,the bonding status plays an essential role in guaranteeing the structural performance of SCCS.Accordingly,efficient non-destructive testing(NDT)on interfacial debondings in SCCS has become a prominent research area.Multi-channel analysis of surface waves(MASW)has been validated as an effective NDT technique for interfacial debonding detection for SCCS.However,the feasibility of MASW must be validated using experimental measurements.This study establishes a high-frequency data synchronous acquisition system with 32 channels to perform comparative verification experiments in depth.First,the current sensing approaches for high-frequency vibration and stress waves are summarized.Secondly,three types of contact sensors,namely,piezoelectric lead-zirconate-titanate(PZT)patches,accelerometers,and ultrasonic transducers,are selected for MASW measurement.Then,the selection and optimization of the force hammer head are performed.Comparative experiments are carried out for the optimal selection of ultrasonic transducers,PZT patches,and accelerometers for MASW measurement.In addition,the influence of different pasting methods on the output signal of the sensor array is discussed.Experimental results indicate that optimized PZT patches,acceleration sensors,and ultrasonic transducers can provide efficient data acquisition for MASW-based non-destructive experiments.The research findings in this study lay a solid foundation for analyzing the recognition accuracy of contact MASW measurement using different sensor arrays.

Diversity and structural composition of species in dipterocarp forests:a study from Fasiakhali Wildlife Sanctuary, Bangladesh

Fasiakhali Wildlife Sanctuary is a protected area composed of tropical remnant rainforest that harbor substantial number of large,old Garjan（Dipterocarpus spp.）trees.The present study assessed composition,structure and diversity of the species in this protected area.A total of 32 trees species were recorded with DBH ≥ 11 cm belonging to 24 genera and 19 families.The forest is low in plant diversity as represented by Shannon–Wiener diversity and Simpson Dominance indices.Dipterocarpus turbinatus was the most dominant species with maximum relative density,frequency,dominance,and importance value index.Syzygium firmum and Tectona grandis followed in terms of dominance.The structural composition indicated higher number of individuals in the medium growth classes（41 to 〈 511 cm DBH and 16–20 m height ranges）,whereas D.turbinatus was the only species that dominated most of the growth classes.Poor stem density in lower growth classes indicated meager recruitment of regeneration which may be due to lower annual precipitation,increased grazing and encroachments.This study will help to understand the patterns of tree species composition and diversity in the remnant dipterocarp forests of Bangladesh.It will also contribute to identifying threatened plants to undertake D.turbinatus based conservation and sustainable management of the Fasiakhali Wildlife Sanctuary.

STRUCTURE AND MAGNETIC PROPERTIES OF YFe_(12-x)Ti_x COMPOUNDS

The structure and magnetic properties of the YFe12-xTix compounds (x=0.85, 1.00, 1.10, 1.20 and 1.30) have been investigated. Both the thermomagnetic analysis and X-ray diffraction patterns show that all compounds studied are almost single phase and crystallize in the ThMn12-type structure. The lattice parameters a, c and unit cell volume V increase monotonously with the increase of Ti content. Curie temperature Tc is almost independent on the Ti content while the spontaneous magnetization M0, the anisotropy field Ba and the anisotropy constant K1 decrease monotonously with the increase of Ti content and the temperature increases from 1.5 K to 293 K.

Experimental study on anti-penetration mechanism of bolted composite protective structure with limited span under impact of low-velocity projectile

In order to study the influence of the bolt joint mode on low-velocity projectiles penetrating the composite protective structure,two bolt joint models which connect the composite target to the fixed frame were designed,the ballistic test of the bolted composite protective structure with limited span was carried out,and the bearing and failure characteristics of the bolted region,as well as the energy dissipation of each part of the structure,were analyzed.The results show that in the condition of lowvelocity impact,there are three failure modes for the bolted composite protective structure subjected to projectile penetration,including failure of the impact point of the composite target,failure of protective structure connecting components and failure of the holes in the bolted region of the composite target;the failure mode of bolt holes in the bolted region has a great influence on the protection performance,and the allowable value of the bearing capacity of the bolted region depends on the sum of the minimum failure load in the failure modes and the friction force;shear-out failure occurring in the bolt holes in the bolted region exerts the greatest effect on ballistic performance,which should be avoided;When simultaneous failure occurs in the bolted region and the free deformation region of the composite protective structure,the energy absorption per unit surface density of the composite protective structure reaches the maximum,which can give full play to its anti-penetration efficiency.

Damage to aircraft composite structures caused by directed energy system: A literature review

This paper presents a comprehensive review of the research studies on direct energy system effect on aircraft composite structures to develop a good understanding of state-of-the-art research and development in this area.The review begins with the application of composite materials in the aircraft structures and highlights their particular areas of application and limitations.An overview of directed energy system is given.Some of the commonly used systems in this category are discussed and the working principles of laser energy systems are described.The experimental and numerical studies reported regarding the aircraft composite structures subject to the effect of directed energy systems,especially the laser systems are reviewed in detail.In particularly,the general effects of laser systems and the relevant damage mechanisms against the composite structures are reported.The review draws attention to the recent research and findings in this field and is expected to guide engineers/researchers in future theoretical,numerical,and experimental studies.

Magneto-rheological elastomer (MRE) based composite structures for micro-vibration control

Magneto-rheological elastomers （MILEs） are used to construct composite structures for micro-vibration control of equipment under stochastic support-motion excitations. The dynamic behavior of MREs as a smart viscoelastic material is characterized by a complex modulus dependent on vibration frequency and controllable by external magnetic fields. Frequency-domain solution methods for stochastic micro-vibration response analysis of the MRE-based structural systems are developed to derive the system frequency-response function matrices and the expressions of the velocity response spectrum. With these equations, the root-mean-square （RMS） velocity responses in terms of the one-third octave frequency band spectrum can be calculated. Further, the optimization problem of the complex moduli of the MRE cores is defined by minimizing the velocity response spectra and the RMS velocity responses through altering the applied magnetic fields. Simulation results illustrate the influences of MRE parameters on the RMS velocity responses and the high response reduction capacities of the MRE-based structures. In addition, the developed frequency-domain analysis methods are applicable to sandwich beam structures with arbitrary cores characterized by complex shear moduli under stochastic excitations described by power spectral density functions, and are valid for a wide frequency range.

Internal Force Distribution in Steel-Concrete Composite Structure for Pylon of Cable-Stayed Bridge

Adopting a steel-anchor beam and steel corbel composite structure in the anchor zone on pylon is one of the key techniques for the design of Jintang bridge, a cable-stayed bridge in Zhoushan, China. In order to ensure the safety of the steel-concrete composite structure, a stud connector model for the joint section was put forward. Experiments were conducted to obtain the relation between load and slip of specimen, the failure pattern of stud connector, the yield bearing capacity and ultimate bearing capacity of a single stud, etc. The whole process of the structural behavior of the specimen was comprehensively analyzed. The features of the internal force distribution in the steel-concrete composite structure and the strain distribution of stud connector under different loads were emphatically studied. The test results show that the stud connector is applicable for the steel-concrete composite structure for pylon of Jintang bridge. The stud has a good ductility performance and a obvious yield process before its destruction. The stud connector basically works in a state of elasticity under a load less than the yield load.

A Study on the Tensile Properties of the MWK Structures for Composite Reinforcement

In this paper, the tensile properties of the MWK structures produced with different basic stitches for composite reinforcement were experimentally studied. The results show that the MWK structures with the double loop pillar stitches have better mechanical properties.

Synthesis of carbon-coated cobalt ferrite core-shell structure composite:A method for enhancing electromagnetic wave absorption properties by adjusting impedance matching

Cobalt ferrite has problems such as poor impedance matching and high density,which results in unsatisfactory electromagnetic wave(EMW)absorption performance.In this study,the CoFe_(2)O_(4)@C core-shell structure composite was synthesized by a two-step hydrothermal method.X-ray diffraction,transmission electron microscopy,Fourier transform infrared spectroscopy,thermogravimetric analysis,and vector network analysis et al.were used to test the structure and EMW absorption properties of CoFe_(2)O_(4)@C composite.The results show that the reflection loss(RL)of the CoFe_(2)O_(4)@C composite reaches the maximum value of25.66 dB at 13.92 GHz,and the effective absorbing band(EAB)is 4.59 GHz(11.20-15.79 GHz)when the carbon mass content is 6.01%.The RL and EAB of CoFe_(2)O_(4)@C composite are increased by 219.55%and 4.59 GHz respectively,and the density is decreased by 20.78%compared with the cobalt ferrite.Such enhanced EMW absorption properties of CoFe_(2)O_(4)@C composite are attributed to the attenuation caused by the strong natural resonance of the cobalt ferrite,moreover,the carbon coating layer adjusts the impedance matching of the composite,and the introduced dipole polarization and interface polarization can cause multiple Debye relaxation processes.

Basic Physical Characteristics of the Water-permeable Brick with Composite Structure

The resin-sand mixture was proposed to be used as the surface course,and cement permeable concrete was used as the base course;such two kinds of materials were combined to prepare water-permeable brick with a composite structure.The compressive strength,flexural strength,and permeability were studied by using adjusting the contents of carbon fiber,quartz powder,cement,sand,and surfactant.The study shows that the hydrophilicity of the resin-sand mixture can be improved after any amount of resin is replaced by quartz powder;by using the surfactant,the interface energy of the particles can be reduced so that the water permeability of the surface course can be promoted effectively.However,the mechanical properties of the surface course were negatively affected by the surfactant.With the optimal process consideration in the experiments,the properties about compressive strength,flexural strength,and permeability of the composite permeable brick can meet the requirements of the specifications of resin-sand based water permeable brick JGT 376-2012(compressive strength was higher than 35 MPa,the flexural strength exceeded 5.19 MPa,and the average permeability coefficient was higher than 2.3×10^(-2)cm/s).There are no obvious pores on the surface course and only water molecules can pass through it,therefore,the surface of the permeable brick cannot be blocked up by solid substances,and the permeability of such permeable brick can be improved effectively in this way.

Polarization-Insensitive Magnetic Quadrupole-Shaped and Electric Quadrupole-Shaped Fano Resonances Based on a Plasmonic Composite Structure

A combined structure with the unit cell consisting of four sub-units with 90° rotation in turn is designed. Each of sub-units is composed of two gold rods in transverse arrangement and one gold rod in longitudinal arrangement. Simulating electromagnetic responses of the structure, we verify that the structure exhibits the double Fano resonances, which originate from the coupling between magnetic quadrupoles and electric dipoles and the coupling between electric quadrupoles and electric dipoles. Simulation results also demonstrate that the structure is polarization-insensitive and shows an analogue of electromagnetically induced transparency at the two Fano resonances. Such a plasmonic structure has potential applications in photoelectric elements.