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Structure Parameters and Physiological Indices Research of High-quality and High-yield Apple Orchards 被引量:1
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作者 薛晓敏 王翠玲 +2 位作者 王金政 孟海凤 聂佩显 《Agricultural Science & Technology》 CAS 2014年第11期1953-1956,1959,共5页
In order to research environment parameters and physiological indices of high-quality and high-yield apple trees, two orchards with young and mature apples trees were investigated to explore structural parameter of ap... In order to research environment parameters and physiological indices of high-quality and high-yield apple trees, two orchards with young and mature apples trees were investigated to explore structural parameter of apple tree and community, and some physiological indices in fields and by room measurements. The results showed that tree height of high-quality orchard was in the range of 260 to 290 cm, branch angle in 70°-75°, and orchard coverage rate in 75%-94%, and the connec-tion rates between rows and trees were lower. Furthermore, the total branches of mature orchard reached 1.04 ×106 per hm2, while the young orchard was 8.79 ×105 per hm2; the leaves were thick and chlorophyl content was high, with SPAD value at 58.22. Additional y, the photosynthesis of the orchard was strong, and net photo-synthetic rate was 17.48-21.8 μmolCO2/(m2·s). The proportions of lateral shoot of bearing part were 81% and 75% respectively. 展开更多
关键词 High-quality and high-yield Apple orchard structure parameters Physio-logical index
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3D structure parameterization design and modeling for irregular structure of stope bottom 被引量:3
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作者 曾庆田 Wang Liguan 《High Technology Letters》 EI CAS 2016年第1期55-62,共8页
Stope mining design is a very important and complicated task in daily production design and technical management of an underground mine.Based on workface technology and human-computer interaction technology,this study... Stope mining design is a very important and complicated task in daily production design and technical management of an underground mine.Based on workface technology and human-computer interaction technology,this study introduces a method of 3D parametric design for the irregular structure of stope bottoms,and focuses on solving technical problems in surface modeling of stope bottom structure.Optimization of the minimum span length algorithm(MSLA) and the shortest path search algorithm(SPSA) is conducted to solve the problem of contour-line based instant modeling of stope bottom structures,which makes possible the 3D parametric design for irregular structure of stope bottom.Implementation process and relevant methods of the proposed algorithms are also presented.Feasibility and reliability of the proposed modeling method are testified in a case study.In practice,the proposed 3 D parameterization design method for irregular structure stope bottom proves to be very helpful to precise 3D parametric design.This method is capable of contributing to improved efficiency and precision of stope design,and is worthy of promotion. 展开更多
关键词 irregular stope bottom structure STOPE structure parameterization design surface reconstruction modeling
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STRUCTURE PARAMETERS DESIGN AND PERFORMANCE TEST OF FUEL INJECTION SYSTEM 被引量:4
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作者 WU Changshui YU Jinxia YANG Lin ZHUO Bin 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2006年第3期407-411,共5页
Based on the numerical simulation analysis, structure parameters of the high pressure fuel pump and common rail as well as flow limiter are designed and the GD-1 high pressure common rail fuel injection system is self... Based on the numerical simulation analysis, structure parameters of the high pressure fuel pump and common rail as well as flow limiter are designed and the GD-1 high pressure common rail fuel injection system is self-developed. Fuel injection characteristics experiment is performed on the GD-1 system. And double-factor variance analysis is applied to investigate the influence of the rail pressure and injection pulse width on the consistency of fuel injection quantity, thus to test whether the design of structure parameters is sound accordingly. The results of experiment and test show that rail pressure and injection pulse width as well as their mutual-effect have no influence on the injection quantity consistency, which proves that the structure parameters design is successful and performance of GD-1 system is sound. 展开更多
关键词 High pressure common rail fuel injection system structure parameters design Variance analysis
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Relationship between initial efficiency and structure parameters of carbon anode material for Li-ion battery 被引量:1
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作者 申建斌 唐有根 +1 位作者 梁逸曾 谭欣欣 《Journal of Central South University of Technology》 EI 2008年第4期484-487,共4页
The initial efficiency is a very important criterion for carbon anode material of Li-ion battery.The relationship between initial efficiency and structure parameters of carbon anode material of Li-ion battery was inve... The initial efficiency is a very important criterion for carbon anode material of Li-ion battery.The relationship between initial efficiency and structure parameters of carbon anode material of Li-ion battery was investigated by an artificial intelligence approach called Random Forests using D10,D50,D90,BET specific surface area and TP density as inputs,initial efficiency as output.The results give good classification performance with 91%accuracy.The variable importance analysis results show the impact of 5 variables on the initial efficiency descends in the order of D90,TP density,BET specific surface area,D50 and D10;smaller D90 and larger TP density have positive impact on initial efficiency.The contribution of BET specific surface area on classification is only 18.74%,which indicates the shortcoming of BET specific surface area as a widely used parameter for initial efficiency evaluation. 展开更多
关键词 Li-ion battery carbon anode material initial efficiency structure parameters
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Nanoscale Reciprocating Sliding Contacts of Textured Surfaces:Influence of Structure Parameters and Indentation Depth
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作者 Rui-Ting Tong Geng Liu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2018年第4期168-181,共14页
Textured surfaces are widely used in engineering components as they can improve tribological properties of sliding contacts, while the detailed behaviors of nanoscale reciprocating sliding contacts of textured surface... Textured surfaces are widely used in engineering components as they can improve tribological properties of sliding contacts, while the detailed behaviors of nanoscale reciprocating sliding contacts of textured surfaces are still lack of study. By using multiscale method, two dimensional nanoscale reciprocating sliding contacts of textured surfaces are investigated. The influence of indentation depth, texture shape, texture spacing, and tip radius on the average friction forces and the running-in stages is studied. The results show that the lowest indentation depth can make all the four textured surfaces reach steady state. Surfaces with right-angled trapezoid textures on the right side are better for reducing the running-in stage, and surfaces with right-angled trapezoid textures on the left side are better to reduce wear. Compared with other textured surfaces, the total average friction forces can be reduced by 82.94%–91.49% for the case of the contact between the tip with radius R = 60rand the isosceles trapezoid textured surface. Besides,the total average friction forces increase with the tip radii due to that bigger tip will induce higher contact areas. This research proposes a detailed study on nanoscale reciprocating sliding contacts of textured surfaces, to contribute to design textured surfaces, reduce friction and wear. 展开更多
关键词 NANOSCALE Reciprocating sliding contacts Textured surface structure parameters Indentation depth
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Effect of lateral structure parameters of SiGe HBTs on synthesized active inductors
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作者 赵彦晓 张万荣 +3 位作者 黄鑫 谢红云 金冬月 付强 《Chinese Physics B》 SCIE EI CAS CSCD 2016年第3期434-439,共6页
The effect of lateral structure parameters of transistors including emitter width, emitter length, and emitter stripe number on the performance parameters of the active inductor (AI), such as the effective inductanc... The effect of lateral structure parameters of transistors including emitter width, emitter length, and emitter stripe number on the performance parameters of the active inductor (AI), such as the effective inductance Ls, quality factor Q, and self-resonant frequency too is analyzed based on 0.35%tm SiGe BiCMOS process. The simulation results show that for AI operated under fixed current density Jc, the HBT lateral structure parameters have significant effect on Ls but little influence on Q and 090, and the larger Ls can be realized by the narrow, short emitter stripe and few emitter stripes of SiGe HBTs. On the other hand, for AI with fixed HBT size, smaller Jc is beneficial for AI to obtain larger Ls, but with a cost of smaller Q and 090. In addition, under the fixed collector current Ic, the larger the size of HBT is, the larger Ls becomes, but the smaller Q and ab become. The obtained results provide a reference for selecting geometry of transistors and operational condition in the design of active inductors. 展开更多
关键词 SiGe HBT lateral structure parameters active inductor
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PARACRYSTAL STRUCTURE PARAMETERS STUDIES IN LDPE/EPO BLENDS WITH VARIANCE-RANGE FUNCTION METHOD
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作者 Huan GAO Bao Quan YANG Zhi Shen MO Changchun Institute of Applied Chemistry,Academia Sinica,Changchun,130022Zhong Cheng HU The Center of Analysis and Measurement,Northeast Normal University,Changchun 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第4期321-322,共2页
X-ray diffraction line profiles of low density polyethylene(LDPE)/ (ethylene-propylene-octene-1)copolymer(EPO)blends have been analyzed with variance range function method.Theories for determining the microparacrystal... X-ray diffraction line profiles of low density polyethylene(LDPE)/ (ethylene-propylene-octene-1)copolymer(EPO)blends have been analyzed with variance range function method.Theories for determining the microparacrystallite size and the distortion parameter from single reflection have been described,and the value of these two parameters at (110)and(200)directions have been determined. 展开更多
关键词 EPO PARACRYSTAL structure parameterS STUDIES IN LDPE/EPO BLENDS WITH VARIANCE-RANGE FUNCTION METHOD LDPE
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Effect of die structure parameters on deformation behavior of bent tube in free bending process
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作者 Wei Wang Cheng Cheng +3 位作者 Li Wan Jie Tao Xun-zhong Guo Chun-mei Liu 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2023年第3期487-503,共17页
The bending section of tube between the bending die and the guider is in a less constrained state during the free bending process.The free bending dies have the important impact on the plastic deformation behavior and... The bending section of tube between the bending die and the guider is in a less constrained state during the free bending process.The free bending dies have the important impact on the plastic deformation behavior and the forming quality of tube.To study the evolution law of the deformation behavior of tube with the die structure parameters and optimize the free bending die parameters,the free bending experiments and the corresponding numerical simulations were carried out.The design principle of free bending die was illustrated.The free bending experiment was conducted to verify the reliability of the numerical simulation method.Based on the numerical simulation results,the influence of the distance between the center point of bending die and the front end of guider on the forming quality of bent tube is more obvious than that of the fillet of guider.However,the fillet of bending die hardly affects the stress and strain distribution and the evolution of the wall thickness.Finally,the free bending experiments with the newly determined free bending dies were conducted.The ultimate bending radius of bent tube is reduced and the forming quality is improved. 展开更多
关键词 Free bending Die structure parameter Forming quality Numerical simulation TUBE
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Structure Optimization of a Tesla Turbine Using an Organic Rankine Cycle Technology
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作者 Yongguo Li Caiyin Xu +1 位作者 Can Qin Dingjian Zheng 《Fluid Dynamics & Materials Processing》 EI 2024年第6期1251-1263,共13页
The so-called ORC(Organic Rankine Cycle)heat recovery technology has attracted much attention with regard to medium and low temperature waste heat recovery.In the present study,it is applied to a Tesla turbine.At the ... The so-called ORC(Organic Rankine Cycle)heat recovery technology has attracted much attention with regard to medium and low temperature waste heat recovery.In the present study,it is applied to a Tesla turbine.At the same time,the effects of the disc speed,diameter and inter-disc gap on the internal flow field and output power of the turbine are also investigated by means of CFD(Computational Fluid Dynamics)numerical simulation,by which the pressure,velocity,and output efficiency of the internal flow field are obtained under different internal and external conditions.The highest efficiency(66.4%)is obtained for a number of nozzles equal to 4,a disk thickness of 1 mm,and a gap of 1 mm between the disks.The results of the study serve as a theoretical basis for the structural design and optimization of Tesla turbines. 展开更多
关键词 ORC Tesla turbine CFD numerical simulation structural parameters
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Effect of Structure Parameters on Power and Magnetic Field in Electromagnetic Soft-Contact Continuous Casting System 被引量:5
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作者 DENG An-yuan WANG En-gang HE Ji-cheng 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2008年第1期19-24,共6页
To design a power source system and mold for electromagnetic soft-contact continuous casting process and to theoretically estimate the heat losses from the charges and the system power, the effect of structure paramet... To design a power source system and mold for electromagnetic soft-contact continuous casting process and to theoretically estimate the heat losses from the charges and the system power, the effect of structure parameters on system power and magnetic flux density distribution was calculated using finite element method. The results show that as for electromagnetic soft-contact continuous casting system with partial-segment type mold, the power consumption is much more than that with a full-segment type mold; about 62% of electric power is dissipated in the mold, and the effective acting range of magnetic field is relatively narrow. Optimizing mold structure is a crucial measure of remarkably reducing mold power consumption and saving electric energy. Increasing slit number, width, and length can remarkably increase the magnetic flux density in the mold and can reduce the electric energy consumption. Among structure parameters, slit number and slit width are relatively more effective to reduce energy consumption. For a round billet electromagnetic continuous casting system with diameter of 178 ram, the reasonable slit number, width, and length are about 24--32, 0. 5--1.0 mm, and 160 mm, respectively. 展开更多
关键词 continuous casting soft-contact mold electromagnetic field electric power structure parameter
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Mode analysis and structure parameter optimization of a novel SiGe-OI rib optical waveguide 被引量:4
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作者 冯松 高勇 +1 位作者 杨媛 冯玉春 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2009年第8期90-94,共5页
The mode of a novel SiGe-OI optical waveguide is analyzed, and its single-mode conditions are derived. The Ge content and structure parameters of SiGe-OI optical waveguides are respectively optimized. Under an operati... The mode of a novel SiGe-OI optical waveguide is analyzed, and its single-mode conditions are derived. The Ge content and structure parameters of SiGe-OI optical waveguides are respectively optimized. Under an operation wavelength of 1300 nm, the structures of SiGe-OI rib optical waveguides are built and analyzed with Optiwave software, and the optical field and transmission losses of the SiGe-OI rib optical waveguides are analyzed. The optimization results show that when the structure parameters H, h, W are respectively 500 nm, 250 nm, 500 nm and the Ge content is 5%, the total power loss of SiGe-OI rib waveguides is 0.3683 dB/cm considering the loss of radiation outside the waveguides and materials, which is less than the traditional value of 0.5 dB/cm. The analytical technique for SiGe-OI optical waveguides and structure parameters computed by this paper are proved to be accurate and computationally efficient compared with the beam propagation method (BPM) and the experimental results. 展开更多
关键词 SiGe-OI rib optical waveguides mode analysis Ge content structure parameters
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Effects of molecular structure parameters on ring-opening reaction of benzoxazines 被引量:4
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作者 刘欣 顾宜 《Science China Chemistry》 SCIE EI CAS 2001年第5期552-560,共9页
A colorless monoclinic crystal of dichloro-benzoxazine was obtained and examined by single crystal X-ray diffraction analysis. At the same time, molecular modeling analysis of nine benzoxazine compounds with different... A colorless monoclinic crystal of dichloro-benzoxazine was obtained and examined by single crystal X-ray diffraction analysis. At the same time, molecular modeling analysis of nine benzoxazine compounds with different substituting groups was performed. Both single crystal X-ray diffraction analysis and molecular modeling analysis provide a detailed picture of molecular structure on molecular level and show good consistence with each other. On the basis of structural analysis, the effects of molecular structure parameters on ring-opening polymerization of ben-zoxazines have been explored. 展开更多
关键词 BENZOXAZINES single crystal structure parameters
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Influence of structure parameters on aeroelastic stability for labyrinth seal based on energy method 被引量:3
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作者 Nengmao Wang Yanrong Wang Aimei Tian 《Propulsion and Power Research》 SCIE 2018年第4期288-295,共8页
Numerical analysis of turbomachinery based on energy method is used to predict the aeroelastic stability of the straight-through labyrinth seal by solving aerodynamic work and vibration modes has been compared.It'... Numerical analysis of turbomachinery based on energy method is used to predict the aeroelastic stability of the straight-through labyrinth seal by solving aerodynamic work and vibration modes has been compared.It's found that the increase of pressure ratio leads to the in the circumferential direction of the labyrinth seal corresponds to the number of vibrating nodal diameters.In order to investigate the influence of structure parameters,the effect of relative thickness of the tooth tip,the width of the seal cavity and the eccentricity of the rotor on the aeroelastic stability of the labyrinth seal has been studied.The result of numerical calculation shows that the change of the structural parameters can affect the aeroelastic stability of the labyrinth seal to a certain extent,and can be applied in the structural optimization. 展开更多
关键词 Labyrinth seal Aeroelastic stability Energy method Nodal diameters structure parameters
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Integrated Optimization of Structure and Control Parameters for the Height Control System of a Vertical Spindle Cotton Picker 被引量:1
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作者 Xingzheng Chen Congbo Li +2 位作者 Rui Hu Ning Liu Chi Zhang 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2021年第6期405-416,共12页
Vertical picking method is a predominate method used to harvest cotton crop.However,a vertical picking method may cause spindle bending of the cotton picker if spindles collide with stones on the cotton field.Thus,how... Vertical picking method is a predominate method used to harvest cotton crop.However,a vertical picking method may cause spindle bending of the cotton picker if spindles collide with stones on the cotton field.Thus,how to realize a precise height control of the cotton picker is a crucial issue to be solved.The objective of this study is to design a height control system to avoid the collision.To design it,the mathematical models are established first.Then a multi-objective optimization model represented by structure parameters and control parameters is proposed to take the pressure of chamber without piston,response time and displacement error of the height control system as the opti-mization objectives.An integrated optimization approach that combines optimization via simulation,particle swarm optimization and simulated annealing is proposed to solve the model.Simulation and experimental test results show that the proposed integrated optimization approach can not only reduce the pressure of chamber without piston,but also decrease the response time and displacement error of the height control system. 展开更多
关键词 Cotton picker Height control system structure parameters Control parameters Integrated optimization
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Extracting Structure Parameters of Dimers for Molecular Tunneling Ionization Model
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作者 赵松峰 黄方 +1 位作者 王国利 周效信 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第3期366-374,共9页
We determine structure parameters of the highest occupied molecular orbital(HOMO)of 27 dimers for the molecular tunneling ionization(so called MO-ADK)model of Tong et al.[Phys.Rev.A 66(2002)033402].The molecular wave ... We determine structure parameters of the highest occupied molecular orbital(HOMO)of 27 dimers for the molecular tunneling ionization(so called MO-ADK)model of Tong et al.[Phys.Rev.A 66(2002)033402].The molecular wave functions with correct asymptotic behavior are obtained by solving the time-independent Schr(o|¨)dinger equation with B-spline functions and molecular potentials which are numerically created using the density functional theory.We examine the alignment-dependent tunneling ionization probabilities from MO-ADK model for several molecules by comparing with the molecular strong-field approximation(MO-SFA)calculations.We show the molecular PerelomovPopov-Terent'ev(MO-PPT)can successfully give the laser wavelength dependence of ionization rates(or probabilities).Based on the MO-PPT model,two diatomic molecules having valence orbital with antibonding systems(i.e.,Cl_2,Ne_2)show strong ionization suppression when compared with their corresponding closest companion atoms. 展开更多
关键词 molecular structure parameters molecular ADK model molecular PPT model ionization suppression
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A STUDY ON THE ESTIMATION OF TEMPERATURE STRUCTURE PARAMETER IN ABL WITH ELEVATED INVERSION
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作者 B.Roy U.K.De B.Pal 《Acta meteorologica Sinica》 SCIE 1995年第3期349-359,共11页
Temperature structure parameter in the vertical is estimated once by using the turbulence outer scale approximation and another by using the Obukhov similarity relationship during the formation of an elevated inversio... Temperature structure parameter in the vertical is estimated once by using the turbulence outer scale approximation and another by using the Obukhov similarity relationship during the formation of an elevated inversion.A comparison of the profiles drawn using both the methods is done for the pur- pose of assessing the accuracy of the similarity method when applied to levels above the surface-based layer.The profiles obtained by both the methods are also compared with a similar profile obtained af- ter considering a bulk shear between the ground and top of the elevated layer. 展开更多
关键词 kytoon Doppler sodar temperature structure parameter Obukhov similarity method elevated inversion
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Accurate Structure Parameters for Tunneling Ionization Rates of Gas-Phase Linear Molecules
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作者 赵松峰 栗建科 +2 位作者 王国利 李鹏程 周效信 《Communications in Theoretical Physics》 SCIE CAS CSCD 2017年第3期289-300,共12页
In the molecular Ammosov–Delone–Krainov(MO-ADK) model of Tong et al. [Phys. Rev. A 66(2002)033402], the ionization rate depends on the structure parameters of the molecular orbital from which the electron is removed... In the molecular Ammosov–Delone–Krainov(MO-ADK) model of Tong et al. [Phys. Rev. A 66(2002)033402], the ionization rate depends on the structure parameters of the molecular orbital from which the electron is removed. We determine systematically and tabulate accurate structure parameters of the highest occupied molecular orbital(HOMO) for 123 gas-phase linear molecules by solving time-independent Schr¨odinger equation with B-spline functions and molecular potentials which are constructed numerically using the modified Leeuwen–Baerends(LBα)model. 展开更多
关键词 molecular structure parameters one-electron potentials molecular ADK model
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Determination of structure parameters in strong-field ionization models of atoms
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作者 Xuan-Hong Gao Lei Zhang +2 位作者 Zhi-Hong Jiao Guo-Li Wang Song-Feng Zhao 《Communications in Theoretical Physics》 SCIE CAS CSCD 2020年第9期118-126,共9页
The Ammosov–Delone–Krainov(ADK) and Perelomov–Popov–Terent'ev(PPT) ionization models were widely used in strong-field physics and attosecond science due to their many attractive advantages such as simpler anal... The Ammosov–Delone–Krainov(ADK) and Perelomov–Popov–Terent'ev(PPT) ionization models were widely used in strong-field physics and attosecond science due to their many attractive advantages such as simpler analytical formula, less computational demands, and satisfied accuracy of ionization rate. Based on the density-functional theory, we systematically determine accurate structure parameters of 25 atoms, 24 positive ions and 13 negative ions and tabulate for future applications. The wave function with correct asymptotic behavior is obtained by solving the time-independent Schr?dinger equation with B-spline basis sets and the accurate structure parameters are extracted from this wave function in the asymptotic region. The accuracies of structure parameters are carefully examined by comparing the ionization probabilities(or yields) calculated by PPT and ADK models with those of solving the threedimensional time-dependent Schr?dinger equation and the experimental data. 展开更多
关键词 strong-field ionization models structure parameters density-functional theory
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Time-shift effect of spontaneous combustion characteristics and microstructure difference of dry-soaked coal
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作者 Yikang Liu Haiyan Wang +4 位作者 Huiyong Niu Tao Wang Zhiwen Chen Yuqi Chen Qingjie Qi 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第4期171-185,共15页
The physical and chemical properties of the air-dried residual coal after soaking in the goaf will change,resulting in an increase in its spontaneous combustion tendency.This study aimed to look into the features and ... The physical and chemical properties of the air-dried residual coal after soaking in the goaf will change,resulting in an increase in its spontaneous combustion tendency.This study aimed to look into the features and mechanism of soaked-dried coal's spontaneous combustion.Five samples of coal were dried to various degrees,and the weight loss features during thermal processing were examined.Based on this,the pore structure and chemical structure characteristics of the coal samples with the highest tendency to spontaneous combustion were quantitatively examined,and the mechanism by which soaking-drying afected the spontaneous combustion heating process of the remaining coal in goaf was investigated in turn.The results show that T1 decreases with the increase of drying time,T2–T6 shows a fuctuating change,and the ignition activation energy of 36-S-Coal is smaller than that of other coal samples.The pore type of 36-S-Coal changes from a oneend closed impermeable pore to an open pore,and the pore group area is large.During the 36 h drying process,the internal channels of the coal were dredged,and a large number of gravels and minerals were precipitated from the pores with the air fow.A large number of gravels were around the pores to form a surface structure that was easy to adsorb various gases.Furthermore,infrared spectroscopy was used to analyze the two coal samples.It was found that soaking and drying did not change the functional group types of coal samples,but the fatty chain degree of 36-S-Coal was reduced to 1.56.It shows that the aliphatic chain structure of coal is changed after 36 h of drying after 30 days of soaking,which leads to the continuous shedding of aliphatic chain branches of residual coal,and the skeleton of coal is looser,which makes the low-temperature oxidation reaction of 36-S-Coal easier.Based on the above results,the coal-oxygen composite mechanism of water-immerseddried coal is obtained,and it is considered that the key to the spontaneous combustion oxidation process of coal is to provide oxygen atoms and accelerate the formation of peroxides. 展开更多
关键词 Water-soaked coal Coal spontaneous combustion FTIR TG-DTG Pore structure Chemical structure parameters
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The correlation between molecular structure parameters of O-ethyl N-isopropyl phosphoro(thioureido)thioates and their retention data in RP-HPLC
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作者 WANG,Qin-Sun GAO,Ru-Yu YANG,Hua-Zheng YAN,Bing-Wen National Laboratory.of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第1期76-80,共8页
A retention prediction system(RPS)of seven O-ethyl N-isopropyl phosphoro(thioureido)- thioates in reversed phase HPLC was investigated.The system is based on the solvent selectivity triangle concept.Three molecular st... A retention prediction system(RPS)of seven O-ethyl N-isopropyl phosphoro(thioureido)- thioates in reversed phase HPLC was investigated.The system is based on the solvent selectivity triangle concept.Three molecular structure parameters(hydrophobicity Ⅱ,substituent length L, and substituent maximum width B_5)were used to describe the quantitative structure-retention relation- ships.With these quantitative relationships,the retention behaviours of other eight homologs for different mobile phase composition were predicted.The predicted values were consistent with the measured values within relative error of 10%,which means that it is possible to apply the reported method to predict retention values for qualitative purposes for different mobile phase compositions. 展开更多
关键词 The correlation between molecular structure parameters of O-ethyl N-isopropyl phosphoro thioureido)thioates and their retention data in RP-HPLC data
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