国内外LNG船再液化系统及其关键设备发展现状

为了实现LNG船再液化系统及其关键设备的国产化和自主可控发展,调研了国内外再液化系统厂家。根据处理对象将系统分为Reliquefaction和Subcooler,分析不同厂家的工艺特点、设备组成,并对比不同厂家的市场、成本优劣。

提高蒸汽驱后期开发效果技术对策研究

针对辽河油田杜229块兴隆台油藏实施的20个蒸汽驱井组,部分井组进入蒸汽驱开发后期,出现蒸汽突破现象严重、油层纵向动用不均、平面上受效程度不同导致井组生产效果变差的问题,为进一步提高井组开发效果,利用数值模拟及动态监测手段精细描述蒸汽腔发育形态,开展了剩余油分布规律研究。创新提出四项技术对策改善井组开发效果,一是引入SUBCOOL指导动态调控防止蒸汽突破;二是实施分层汽驱提高油层纵向动用程度;三是实施热水驱提高层内动用程度;四是降低操作压力,提高蒸汽腔平面上的波及体积。通过上述方法的实施,井组综合递减率由18.4%降至2.4%,井组实现持续稳产,油汽比由0.15提高到0.20,提高开发效果,保证了杜229块油藏汽驱开发的经济性。该研究对改善同类油藏蒸汽驱开发效果及经济性提供了技术参考。

Methane hydrate formation and dissociation in synthetic seawater

The formation and dissociation of methane gas hydrate at an interface between synthetic seawater （SSW） and methane gas have been experimentally investigated in the present work. The amount of gas consumed during hydrate formation has been calculated using the real gas equation. Induction time for the formation of hydrate is found to depend on the degree of subcooling. All the experiments were conducted in quiescent system with initial cell pressure of 11.14 MPa. Salinity effects on the onset pressure and temperature of hydrate formation are also observed. The dissociation enthalpies of methane hydrate in synthetic seawater were determined by Clausius-Clapeyron equation based on the measured phase equilibrium data. The dissociation data have been analyzed by existing models and compared with the reported data.

Mechanism of Calcium Carbonate Scale Deposition under Subcooled Flow Boiling Conditions

Fouling of heat transfer surfaces during subcooled flow boiling is a frequent engineering problem in process industries. It has been generally observed that the deposits in such industrial systems consist mainly of calcium carbonate （CaCO3）, which has inverse solubility characteristics. This investigation focused on the mechanism to control deposition and the morphology of crystalline deposits. A series of experiments were carried out at different surface and bulk temperatures, fluid velocities and salt ion concentrations. It is shown that the deposition rate is controlled by different mechanism in the range of experimental parameters, depending on salt ion concentration. At higher ion concentration, the fouling rate increases linearly with surface temperature and the effect of flow velocity on deposition rate is quite strong, suggesting that mass diffusion controls the fouling process. On the contrary, at lower ion concentration, the fouling rate increases exponentially with surface temperature and is independent of the velocity, illustrating that surface reaction controls the fouling process. By analysis of the morphology of scale, two types of crystal （calcite and aragonite） are formed. The lower the temperature and ion concentration, the longer the induction period and the higher the percentage of calcite nreciDitated.

Numerical Prediction for Subcooled Boiling Flow of Liquid Nitrogen in a Vertical Tube with MUSIG Model

Multiple size group （MUSIG） model combined with a threedimensional twofluid model were em ployed to predict subcooled boiling flow of liquid nitrogen in a vertical upward tube. Based on the mechanism of boiling heat transfer, some important bubble model parameters were amended to be applicable to the modeling of liquid nitrogen. The distribution of different discrete bubble classes was demonstrated numerically and the distribu tion patterns of void fraction in the wallheated tube were analyzed. It was found that the average void fraction in creases nonlinearly along the axial direction with wall heat flux and it decreases with inlet mass flow rate and sub cooled temperature. The local void fraction exhibited a Ushape distribution in the radial direction. The partition of the wall heat flux along the tube was obtained. The results showed that heat flux consumed on evaporation is the leading part of surface heat transfer at the rear region of subcooled boiling. The turning point in the pressure drop curve reflects the instability of bubbly flow. Good agreement was achieved on the local heat transfer coefficient aalnst experimental measurements, which demonstrated the accuracy of the numerical model.

Analysis of Bubble Behavior in a Horizontal Rectangular Channel under Subcooled Flow Boiling Conditions

Experiments on subcooled flow boiling have been conducted using water in a rectangular flow channel.Similar to the coolant channel in internal combustion engines(IC engines),the flow channel in this experiment was asymmetrically heated.Bubble images were captured using a high speed camera from the side view of the channel.The experimental conditions in terms of bulk temperature,bulk velocity,pressure and heat flux ranged from 65°C–75°C,0.25 m/s–0.75 m/s,1–1.7 bar and 490 kW/m2–700 kW/m2,respectively.On the basis of these tests,a statistical analysis of the bubble size has been conducted considering a population of 1400 samples.It has been found that the mean Sauter bubble diameter increases with the decrease of subcooling,bulk velocity,pressure and increased heat flux.A modified correlation has been finally proposed to predict the mean Sauter bubble diameter under subcooled flow boiling conditions upstream of the onset of significant void,which shows good accuracy with the experimental results.

SAGD生产井合理井下Subcool分析研究

新疆风城油田稠油资源丰富，已探明储量3．6×10^8t，部分特超稠油油藏用常规蒸汽吞吐方法难以有效开采。为此，风城油田于2008年开始开展SAGD先导试验，由于油藏物性及国外存在一定差异，因此，各项配套工艺技术均需要试验研究。根据理论研究和国内外操作经验，Subcool控制是SAGD生产阶段的关键之一，它代表SAGD井下液面控制的合理性。通过数值模拟及现场应用情况分析，初步掌握了适合风城油田不同生产方式的Subcool值。

Experimental study on geochemical characteristic of methane hydrate formed in porous media

The natural occurrence of methane hydrates in marine sediments has been intensively studied over the past decades, and geochemical charac-teristic of hydrate is one of the most attractive research fields. In this paper, we discussed the geochemical anomaly during hydrate formation in porous media. By doing so, we also investigated the temperature influence on hydrate formation under isobaric condition. It turns out that sub-cooling is an important factor to dominate hydrate formation. Larger subcooling provides more powerful driving force for hydrate formation. During the geochemical anomaly research, six kinds of ions and the total dissolved salt （TDS） were measured before and after the experiment in different porous media. The result is that all kinds of ionic concentration increased after hydrate formation which can be defined as salting out effect mainly affected by gas consumption. But the variation ratio of different ions is not equal. Ca^2＋ seems to be the most significantly influenced one, and its variation ratio is up to 80%. Finally, we theoretically made a model to calculate the TDS variation, the result is in good accordance with measured one, especially when gas consumption is large.

Subcooled pool boiling heat transfer in fractal nanofluids:A novel analytical model

A novel analytical model to determine the heat flux of subcooled pool boiling in fractal nanofluids is developed. The model considers the fractal character of nanofluids in terms of the fractal dimension of nanoparticles and the fractal dimen- sion of active cavities on the heated surfaces; it also takes into account the effect of the Brownian motion of nanoparticles, which has no empirical constant but has parameters with physical meanings. The proposed model is expressed as a function of the subcooling of fluids and the wall superheat. The fractal analytical model is verified by a reasonable agreement with the experimental data and the results obtained from existing models.

Assessment of the Application of Subcooled Fluid Boiling to Diesel Engines for Heat Transfer Enhancement

The increasing demand of cooling in internal combustion engines(ICE)due to engine downsizing may require a shift in the heat removal method from the traditional single phase liquid convection to the application of new technologies based on subcooled fluid boiling.Accordingly,in the present study,experiments based on subcooled flow boiling of 50/50 by volume mixture of ethylene glycol and water coolant(EG/W)in a rectangular channel heated by a cast iron block are presented.Different degrees of subcooling,velocity and pressure conditions are examined.Comparison of three empirical reference models shows that noticeable deviations occur especially when low bulk subcooling and velocity conditions are considered.On the basis of the experimental data,a modified power-type wall heat flux model is developed and its ability to represent adequately reality is tested through numerical simulations against a reference rig case and a practical diesel engine.Computational results show that this modified model can effectively be used for practical engine cooling system design.

Numerical Simulation on Subcooled Boiling Heat Transfer Characteristics of Water-Cooled W/Cu Divertors

In order to realize safe and stable operation of a water-cooled W/Cu divertor under high heating condition,the exact knowledge of its subcooled boiling heat transfer characteristics under different design parameters is crucial.In this paper,subcooled boiling heat transfer in a water-cooled W/Cu divertor was numerically investigated based on computational fluid dynamic（CFD）.The boiling heat transfer was simulated based on the Euler homogeneous phase model,and local differences of liquid physical properties were considered under one-sided high heating conditions.The calculated wall temperature was in good agreement with experimental results,with the maximum error of 5%only.On this basis,the void fraction distribution,flow field and heat transfer coefficient（HTC）distribution were obtained.The effects of heat flux,inlet velocity and inlet temperature on temperature distribution and pressure drop of a water-cooled W/Cu divertor were also investigated.These results provide a valuable reference for the thermal-hydraulic design of a water-cooled W/Cu divertor.

Determination of the subcooled liquid solubilities of PAHs in partitioning batch experiments

Subcooled liquid solubility is the water solubility for a hypothetical state of liquid. It is an important parameter for multicomponent nonaqueous phase liquids （NAPLs） containing polycyclic aromatic hydrocarbons （PAHs）, which can exist as liquids even though most of the solutes are solid in their pure form at ambient temperature. So far, subcooled liquid solubilities were estimated from the solid water solubility and fugacity ratio of the solid and （subcooled） liquid phase, but rarely derived from experi- mental data. In our study, partitioning batch experiments were performed to determine the subcooled liquid solubility of PAHs in NAPL-water system. For selected PAH, a series of batch experiments were carried out at increased mole fractions of the target component in the NAPL and at a constant NAPL/ water volume ratio. The equilibrium aqueous PAH concentrations were measured with HPLC and/or GC- MS. The suhcooled liquid solubility was derived by extrapolation of the experimental equilibrium aqueous concentration to a mole fraction of unity. With the derived subcooled liquid solubility, the fugacity ratio and enthalpy of fusion of the solute were also estimated. Our results show a good agreement between the experimentally determined and published data.

Critical Heat Flux with Subcooled Flowing Water in Tubes for Pressures from Atmosphere to Near-Critical Point

During last 45 years, two groups of the experimental data on critical heat flux were obtained in bare tubes, covering the pressures from atmosphere to near-critical point. One group of the data were obtained in the inner diameter of 2.32, 5.16, 8.05, 10.0 and 16.0 mm, respectively, with the ranges of pressure of 0.1-1.92 MPa, velocity of 1.47-23.3 m/s, local subcooling of 3.7-108.7 ℃ and heat flux of up to 38.3 MW/m2. Another group of the data were obtained in the inner diameter of 4.62, 7.98 and 10.89 mm, respectively, with the ranges of pressure of 1.7-20.6 MPa, mass flux of 454-4,055 kg/（m2.s） and inlet subcooling of 53-361 ℃. The results showed complicated effects of the pressure, mass flux, subcooling and diameter on the critical heat flux. They were formulated by two empirical correlations. A mechanistic model on the limit of heat transfer capability from the bubbly layer to the subcooled core was also proposed for all the results.

SUBCOOLED BOILING REGIME RECOGNITION BASED ON FRACTAL CHARACTERISTIC QUANTITIES OF SOUND PRES-SURE

Based on acquisition of sound pressure in subcooled boiling twophase system and through dynamic data processing methods, the dynamical behavior of the system is discussed. With the introduction of fractal concept, an analysis to the fractal feature of sound pressure signal is carried out. Moreover, the pseudo phase diagrams of typical time series of sound pressure are given. Finally, through dynamic clustering and on the basis of calculating correlation dimension and Hurst exponent of sound time series on different subcooling conditions, the recognition of developing regime of the twophase system is delivered, which provides a new practical approach of recognition and diagnosis for vaporliquid boiling system.

Numerical simulation on boiling heat transfer of evaporation cooling in a billet reheating furnace

The boiling heat transfer of evaporation cooling in a billet reheating furnace was simulated.The results indicate that the bubbles easily aggregate inside of the elbow and upper side of the horizontal regions in theπshaped support tubes.The circulation velocity increasing helps to improve the uniformity of vapor distribution and decrease the difference of vapor volume fraction between upper and down at end of the horizontal sections.With the increase of circulation velocity,the resistance loss and the circulation ratio both increase,but the former will decrease with the increase of work pressure.

Numerical Simulation of Subcooled Boiling Inside High-Heat-Flux Component with Swirl Tube in Neutral Beam Injection System

In order to realize steady-state operation of the neutral beam injection（NBI） system with high beam energy,an accurate thermal analysis and a prediction about working conditions of heat-removal structures inside high-heat-flux（HHF） components in the system are key issues.In this paper,taking the HHF ion dump with swirl tubes in NBI system as an example,an accurate thermal dynamic simulation method based on computational fluid dynamics（CFD） and the finite volume method is presented to predict performance of the HHF component.In this simulation method,the Eulerian multiphase method together with some empirical corrections about the inter-phase transfer model and the wall heat flux partitioning model are considered to describe the subcooled boiling.The reliability of the proposed method is validated by an experimental example with subcooled boiling inside swirl tube.The proposed method provides an important tool for the refined thermal and flow dynamic analysis of HHF components,and can be extended to study the thermal design of other complex HHF engineering structures in a straightforward way.The simulation results also verify that the swirl tube is a promising heat removing structure for the HHF components of the NBI system.

Experimental study of the onset of nucleate boiling in vertical helically-coiled tubes

The experiments of the onset of nucleate boiling using R134a as working fluid were conducted in vertical helically-coiled tubes. The experiments were carried out with a range of pressure from 450 to 850 kPa, inlet subcooling from 4.7 to 15.0℃, heat flux from 0.11 to 8.9 kW/m2 and mass flux from 218. 2 to 443. 7 kg/（ m2 · s ）. The heat flux, superheat and temperature undershoot at the ONB are analyzed in vertical helically-coiled tubes. Also, the effects of mass flux, system pressure, inlet subcooling and geometric parameters on the ONB are studied. The results demonstrate that the inception heat flux and superheat increase with increasing mass flux and inlet subcooling, but decrease with increasing system pressure and helix diameter. The pitch of the helical coil has a slight effect on the wall superheat and heat flux at the ONB. The correlation of heat flux at the ONB of subcooled flow boiling in helical coil is developed based on the experimental data, and it shows a good agreement with the experimental data.

Critical Heat Flux in Forced Convective Boiling with a Wall Jet

The critical heat flux (CHF) in the forced convective boiling with a wall jet has been investigated.The experiments of CHF with a wall jet have been performed over a wide range of ρ l/ρ g=6.6-1 603 and ΔT sub =0-60 K. The mechanism on CHF is discussed and a CHF model based on heat balance in sublayer can provide a good clue for analyzing and deriving CHF.Finally,a generalized correlation is presented, which can predict CHF for saturated and subcooled conditions.

PIV Measurement of Velocity Distribution in the Moderator Circulation Test (MCT)

Korea Atomic Energy Research Institute (KAERI) has been carrying out a scaled-down moderator test program to simulate the CANDU-6 moderator circulation phenomena during steady state operation and accident conditions. The Moderator Circulation Test (MCT) facility was designed and constructed as 1/4 scale of the prototype of CANDU-6 reactor. In the present work spatial distribution of two-dimensional velocity in the MCT facility under isothermal condition was measured using planar Particle Image Velocimetry (PIV) system which consists of double pulsed laser, synchronizer, and high speed camera. TSI’s Insight TM 4G software was used to perform PIV image capturing, PIV calculation and post processing. 10 μm sized silver-coated hollow sphere particles were used as flow tracer particles. Multiple experiments were conducted to cover large area of the MCT facility with limited field of view of a single camera. Instantaneous and averaged velocity field were analyzed for each spatial position and flow rate. This research is capable of offering validation data for self-reliant CFD tools to predict moderator subcooling margin in CANDU-6 reactor.

Modeling of Subcooled Boiling Heat Transfer to Cool Electronic Components in a Micro-Channel

This paper aims to model a subcooled flow boiling in a vertical stainless-steel micro-channel with an upward flow in 1 mm diameter, 40 mm length and 0.325 mm thickness tube. Water has been considered as a working fluid. The heat flux varies from 600 - 750 kW·m-2, input velocity from 1 - 2 m·s-1, and the subcooled temperature varies from 59.6 - 79.6 K. The working pressure and saturation temperature are 1 atm and 372.75 K, respectively. The results show that, the flow boiling keeps the temperature of the channel wall lower and more uniform than a single-phase flow, as long as the flow boiling does not reach the dry-out point. The onset point of dry-out depends on three factors, heat flux, inlet velocity, and subcooled temperature. In addition, the dry-out occurs at a point near the channel inlet with increased heat flux and subcooled temperature. Decreasing the inlet velocity would also cause the dry-out point to shift closer to the inlet of the channel.