The novel sulfonated polybenzimidazole(sPBI)/amine functionalized titanium dioxide(AFT) composite membrane is devised and studied for its capability of the application of high temperature proton exchange membrane fuel...The novel sulfonated polybenzimidazole(sPBI)/amine functionalized titanium dioxide(AFT) composite membrane is devised and studied for its capability of the application of high temperature proton exchange membrane fuel cells(HT-PEMFCs),unlike the prior low temperature AFT endeavors.The high temperature compatibility was actualized because of the filling of free volumes in the rigid aromatic matrix of the composite with AFT nanoparticles which inhibited segmental motions of the chains and improved its thermal stability.Besides,amine functionalization of TiO2 enhanced their dispersion character in the sPBI matrix and shortened the interparticle separation gap which finally improved the proton transfer after establishing interconnected pathways and breeding more phosphoric acid(PA) doping.In addition,the appeared assembled clusters of AFT flourished a superior mechanical stability.Thus,the optimized sPBI/AFT(10 wt%) showed 65.3 MPa tensile strength;0.084 S·cm^-1 proton conductivity(at 160℃;in anhydrous conditions),28.6% water uptake and PA doping level of 23 mol per sPBI repeat unit.The maximum power density peak for sPBI/AFT-10 met the figure of0.42 W·cm^-2 at 160℃(in dry conditions) under atmospheric pressure with 1.5 and 2.5 stoichiometric flow rates of H2/air.These results affirmed the probable fitting of sPBI/AFT composite for HT-PEMFC applications.展开更多
通过磺化反应在壳聚糖(CS)上引入磺酸基团制得具备良好质子传导能力的磺化壳聚糖(SPCS)。以含氟聚苯并咪唑(FPBI)为基体材料,通过掺杂磺化壳聚糖制备得到FPBI-SPCS复合质子交换膜。研究了SPCS的质量分数对复合膜的机械性能、热稳定性、...通过磺化反应在壳聚糖(CS)上引入磺酸基团制得具备良好质子传导能力的磺化壳聚糖(SPCS)。以含氟聚苯并咪唑(FPBI)为基体材料,通过掺杂磺化壳聚糖制备得到FPBI-SPCS复合质子交换膜。研究了SPCS的质量分数对复合膜的机械性能、热稳定性、吸水率、溶胀度、质子电导率等性能影响。结果表明,复合膜的质子电导率随着SPCS质量分数的增加而增加,但是吸水率、溶胀度却随着SPCS质量分数的增加而下降,复合膜依然能够保持良好的机械性能和热稳定性。FPBI-SPCS复合膜在80℃下最高电导率达18.52 m S/cm,有望在质子交换膜燃料电池中得到应用。展开更多
基金supported by the National Natural Science Foundation of China(Nos.21776034,21476044 and 21406031)Joint Funds of the National Natural Science Foundation of China(U1663223)+1 种基金National Key Research and Development Program of China(2016YFB0101203)Changjiang Scholars Program(T2012049)。
文摘The novel sulfonated polybenzimidazole(sPBI)/amine functionalized titanium dioxide(AFT) composite membrane is devised and studied for its capability of the application of high temperature proton exchange membrane fuel cells(HT-PEMFCs),unlike the prior low temperature AFT endeavors.The high temperature compatibility was actualized because of the filling of free volumes in the rigid aromatic matrix of the composite with AFT nanoparticles which inhibited segmental motions of the chains and improved its thermal stability.Besides,amine functionalization of TiO2 enhanced their dispersion character in the sPBI matrix and shortened the interparticle separation gap which finally improved the proton transfer after establishing interconnected pathways and breeding more phosphoric acid(PA) doping.In addition,the appeared assembled clusters of AFT flourished a superior mechanical stability.Thus,the optimized sPBI/AFT(10 wt%) showed 65.3 MPa tensile strength;0.084 S·cm^-1 proton conductivity(at 160℃;in anhydrous conditions),28.6% water uptake and PA doping level of 23 mol per sPBI repeat unit.The maximum power density peak for sPBI/AFT-10 met the figure of0.42 W·cm^-2 at 160℃(in dry conditions) under atmospheric pressure with 1.5 and 2.5 stoichiometric flow rates of H2/air.These results affirmed the probable fitting of sPBI/AFT composite for HT-PEMFC applications.
文摘通过磺化反应在壳聚糖(CS)上引入磺酸基团制得具备良好质子传导能力的磺化壳聚糖(SPCS)。以含氟聚苯并咪唑(FPBI)为基体材料,通过掺杂磺化壳聚糖制备得到FPBI-SPCS复合质子交换膜。研究了SPCS的质量分数对复合膜的机械性能、热稳定性、吸水率、溶胀度、质子电导率等性能影响。结果表明,复合膜的质子电导率随着SPCS质量分数的增加而增加,但是吸水率、溶胀度却随着SPCS质量分数的增加而下降,复合膜依然能够保持良好的机械性能和热稳定性。FPBI-SPCS复合膜在80℃下最高电导率达18.52 m S/cm,有望在质子交换膜燃料电池中得到应用。
