A process of biooxidation followed by thiosulfate leaching of gold from refractory gold concentrate was investigated.Mineralogical studies on the concentrate showed that very fine gold grains(<10μm)were encapsulat...A process of biooxidation followed by thiosulfate leaching of gold from refractory gold concentrate was investigated.Mineralogical studies on the concentrate showed that very fine gold grains(<10μm)were encapsulated in pyrite and arsenopyrite,while the proportion of monomer gold was only 21%.The gold-bearing sample was identified as a high-sulfur fine-sized wrapped-type refractory gold concentrate.The gold leaching efficiency obtained by direct cyanidation was only 59.86%.After biooxidation pretreatment,the sulfide minerals were almost completely decomposed,92 wt%of the mineral particles of the biooxidation residue were decreased to<38μm,and the proportion of monomer gold in the biooxidation residue was over 86%.Meanwhile,the gold content in the biooxidation residue was enriched to 55.60 g/t,and the S,Fe,and As contents were reduced to approximately 19.8 wt%,6.97 wt%,and 0.13 wt%,respectively.Ammoniacal thiosulfate was used for gold extraction from the biooxidation residue of the refractory gold concentrate.The results showed that the optimal reagent conditions were 0.18 M thiosulfate,0.02 M copper(II),1.0 M ammonia,and 0.24 M sulfite.Under these conditions,a maximum gold leaching efficiency of 85.05%was obtained.展开更多
A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring type pulveri...A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring type pulverizing leaching tower mill, the concentrate is ground to <35.6 μm of 95.5 % while simultaneously leached by NaOH of 12 kg/t, then carried out intensified alkaline leaching for 48 h by NaOH of 108 kg/t in enhanced agitation tanks with the pulp concentration of 40% solids at the environmental temperature of 9.5 ~ 13.5 ℃ and the environmental pressure of 10 5 Pa. The oxidation rate of As is 94.9%, and 47.6% for S. The total consumption of NaOH is only 20% of that theoretically calculated under the conditions of full oxidation at the same oxidation rates of arsenic to arsenate and sulfur to sulfate. The gold leaching rate by NaCN in 24 h is increased from 9.2% before pretreatment to 94.2%. The consumption of NaCN is 7.5 kg/t, which is one times less than that before pretreatment. The extraction cost of gold is about 422 Yuan/t.展开更多
A hydrometallurgical process for refractory gold-bearing arsenosulfide concentrates at ambient temperature and pressure was presented, including fine grinding with intensified alkali-leaching (FGIAL), enhanced agita...A hydrometallurgical process for refractory gold-bearing arsenosulfide concentrates at ambient temperature and pressure was presented, including fine grinding with intensified alkali-leaching (FGIAL), enhanced agitation alkali-leaching (EAAL), thiosulfate leaching and displacement. Experimental results on a refractory gold concentrate showed that the total consumption of NaOH in alkaline leaching is only 41% of those theoretically calculated under the conditions of full oxidization for the same amount of arse- nides and sulfides transformed into arsenates and sulfates, and 72.3% of gold is synchro-dissoluted by thiosulfate self-generated during alkaline leaching. After alkaline leaching, thiosulfate leaching was carried out for 24 h. The dissolution of gold is increased to 91.9% from 4.6% by cyanide without the pretreatment. The displacement of gold by zinc powder in the solution gets to 99.2%. Due to an amount of thiosulfate self-generated during alkaline leaching, the reagent addition in thiosulfate leaching afterwards is lower than the normal.展开更多
A new hydrometallurgical process for a carbonaceous refractory gold concentrate at ambient temperature and pressure was presented, including grinding-leaching, intensified alkaline leaching(IAL), thiosulfate leaching ...A new hydrometallurgical process for a carbonaceous refractory gold concentrate at ambient temperature and pressure was presented, including grinding-leaching, intensified alkaline leaching(IAL), thiosulfate leaching and cementation by zinc powder. The experimental results show that the grinding-leaching and intensified alkaline leaching process result in the selective oxidation of arsenopyrite and pyrite. The oxidation ratio of As is 96.6%, and 46.7% for S. The total consumption of NaOH in alkaline leaching is only 28% of that theoretically calculated under the conditions of full oxidization for the same amount of arsenopyrite and pyrite transforming into arsenates and sulfates, and 83.6% of gold is synchro-dissoluted by thiosulfate self-generated during pretreatment. Since the carbonaceous matter in concentrate possesses a strong capability of preg robbing, the cyanidation process is not suitable for the extraction of gold after pretreatment. However, the gold leaching rate by thiosulfate leaching for 24h is increased to 91.7% from 03.2% by ultra-fine grinding without the pretreatment. The recovery of gold by zinc cementation gets to 99.6%. Due to the thiosulfate self-generated during alkaline leaching, the reagent addition in thiosulfate leaching afterwards is lower than the normal one.展开更多
高盐矿区往往缺乏淡水资源供生产使用。针对矿区盐水现状,进行高砷难处理金精矿生物氧化-氰化提金试验,考查不同氯离子浓度对硫化物氧化率、金浸出率等技术指标的影响。结果表明,氯离子浓度对金精矿生物氧化的不利影响随着浓度的升高而...高盐矿区往往缺乏淡水资源供生产使用。针对矿区盐水现状,进行高砷难处理金精矿生物氧化-氰化提金试验,考查不同氯离子浓度对硫化物氧化率、金浸出率等技术指标的影响。结果表明,氯离子浓度对金精矿生物氧化的不利影响随着浓度的升高而增强,氯离子浓度1.5 g L以上时,硫化物的氧化率显著降低,10 g L氯离子盐水生物氧化延长至18 d,砷浸出率88.4%,硫氧化率仅为35.3%。相同生物氧化渣在相同氰化条件下采用清水和10 g L氯离子盐水进行氰化浸出时,盐水将降低金的浸出率。1.5 g L、5 g L氯离子盐水生物氧化10 d后的氧化渣采用10 g L氯离子盐水氰化,金的浸出率分别比清水氰化时的分别低2.8、3.4个百分点。难处理金精矿生物氧化砷浸出率均高于硫氧化率,表明毒砂氧化率高于黄铁矿,金浸出率与毒砂氧化率的相关性较黄铁矿氧化率更加密切。展开更多
基金financially supported by the Special Funds for the National Natural Science Foundation of China(No.U1608254)the Open Fund of State Key Laboratory of Comprehensive Utilization of Low-Grade Refractory Gold Ores(No.ZJKY2017(B)KFJJ01 and ZJKY2017(B)KFJJ02)。
文摘A process of biooxidation followed by thiosulfate leaching of gold from refractory gold concentrate was investigated.Mineralogical studies on the concentrate showed that very fine gold grains(<10μm)were encapsulated in pyrite and arsenopyrite,while the proportion of monomer gold was only 21%.The gold-bearing sample was identified as a high-sulfur fine-sized wrapped-type refractory gold concentrate.The gold leaching efficiency obtained by direct cyanidation was only 59.86%.After biooxidation pretreatment,the sulfide minerals were almost completely decomposed,92 wt%of the mineral particles of the biooxidation residue were decreased to<38μm,and the proportion of monomer gold in the biooxidation residue was over 86%.Meanwhile,the gold content in the biooxidation residue was enriched to 55.60 g/t,and the S,Fe,and As contents were reduced to approximately 19.8 wt%,6.97 wt%,and 0.13 wt%,respectively.Ammoniacal thiosulfate was used for gold extraction from the biooxidation residue of the refractory gold concentrate.The results showed that the optimal reagent conditions were 0.18 M thiosulfate,0.02 M copper(II),1.0 M ammonia,and 0.24 M sulfite.Under these conditions,a maximum gold leaching efficiency of 85.05%was obtained.
文摘A new process for the hydrometallurgy of refractory gold concentrates was presented. The process comprises grinding leaching, intensified alkaline leaching (IAL), cyanidation and adsorption. In a stirring type pulverizing leaching tower mill, the concentrate is ground to <35.6 μm of 95.5 % while simultaneously leached by NaOH of 12 kg/t, then carried out intensified alkaline leaching for 48 h by NaOH of 108 kg/t in enhanced agitation tanks with the pulp concentration of 40% solids at the environmental temperature of 9.5 ~ 13.5 ℃ and the environmental pressure of 10 5 Pa. The oxidation rate of As is 94.9%, and 47.6% for S. The total consumption of NaOH is only 20% of that theoretically calculated under the conditions of full oxidation at the same oxidation rates of arsenic to arsenate and sulfur to sulfate. The gold leaching rate by NaCN in 24 h is increased from 9.2% before pretreatment to 94.2%. The consumption of NaCN is 7.5 kg/t, which is one times less than that before pretreatment. The extraction cost of gold is about 422 Yuan/t.
基金This project was financially supported by the Natural Science Foundation of Liaoning Province of China (No.2001101015) and theFree Study Item of the Institute of Metal Research, Chinese Academy of Sciences (No.AM05-0866)
文摘A hydrometallurgical process for refractory gold-bearing arsenosulfide concentrates at ambient temperature and pressure was presented, including fine grinding with intensified alkali-leaching (FGIAL), enhanced agitation alkali-leaching (EAAL), thiosulfate leaching and displacement. Experimental results on a refractory gold concentrate showed that the total consumption of NaOH in alkaline leaching is only 41% of those theoretically calculated under the conditions of full oxidization for the same amount of arse- nides and sulfides transformed into arsenates and sulfates, and 72.3% of gold is synchro-dissoluted by thiosulfate self-generated during alkaline leaching. After alkaline leaching, thiosulfate leaching was carried out for 24 h. The dissolution of gold is increased to 91.9% from 4.6% by cyanide without the pretreatment. The displacement of gold by zinc powder in the solution gets to 99.2%. Due to an amount of thiosulfate self-generated during alkaline leaching, the reagent addition in thiosulfate leaching afterwards is lower than the normal.
文摘A new hydrometallurgical process for a carbonaceous refractory gold concentrate at ambient temperature and pressure was presented, including grinding-leaching, intensified alkaline leaching(IAL), thiosulfate leaching and cementation by zinc powder. The experimental results show that the grinding-leaching and intensified alkaline leaching process result in the selective oxidation of arsenopyrite and pyrite. The oxidation ratio of As is 96.6%, and 46.7% for S. The total consumption of NaOH in alkaline leaching is only 28% of that theoretically calculated under the conditions of full oxidization for the same amount of arsenopyrite and pyrite transforming into arsenates and sulfates, and 83.6% of gold is synchro-dissoluted by thiosulfate self-generated during pretreatment. Since the carbonaceous matter in concentrate possesses a strong capability of preg robbing, the cyanidation process is not suitable for the extraction of gold after pretreatment. However, the gold leaching rate by thiosulfate leaching for 24h is increased to 91.7% from 03.2% by ultra-fine grinding without the pretreatment. The recovery of gold by zinc cementation gets to 99.6%. Due to the thiosulfate self-generated during alkaline leaching, the reagent addition in thiosulfate leaching afterwards is lower than the normal one.
文摘高盐矿区往往缺乏淡水资源供生产使用。针对矿区盐水现状,进行高砷难处理金精矿生物氧化-氰化提金试验,考查不同氯离子浓度对硫化物氧化率、金浸出率等技术指标的影响。结果表明,氯离子浓度对金精矿生物氧化的不利影响随着浓度的升高而增强,氯离子浓度1.5 g L以上时,硫化物的氧化率显著降低,10 g L氯离子盐水生物氧化延长至18 d,砷浸出率88.4%,硫氧化率仅为35.3%。相同生物氧化渣在相同氰化条件下采用清水和10 g L氯离子盐水进行氰化浸出时,盐水将降低金的浸出率。1.5 g L、5 g L氯离子盐水生物氧化10 d后的氧化渣采用10 g L氯离子盐水氰化,金的浸出率分别比清水氰化时的分别低2.8、3.4个百分点。难处理金精矿生物氧化砷浸出率均高于硫氧化率,表明毒砂氧化率高于黄铁矿,金浸出率与毒砂氧化率的相关性较黄铁矿氧化率更加密切。