Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomer...Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomers and polycyclic aromatic hydrocarbons, and measure their mole fraction profiles versus temperature. A low-pressure pyrolysis model of benzene was developed and validated by the experimental results. Rate of production analysis was performed to reveal the major reaction networks in both fuel decomposition and aromatic growth processes. It is concluded that benzene is mainly decomposed via H-abstraction reaction to produce phenyl and partly decomposed via unimolecular decomposition reac- tions to produce propargyl or phenyl. The decomposition process stops at the formation of acetylene and polyyne species like diacetylene and 1,3,5-hexatriyne due to their high thermal stabilities. Besides, the aromatic growth process in the low-pressure pyrolysis of benzene is concluded to initiate from benzene and phenyl, and is controlled by the even carbon growth mechanism due to the inhibited formation of C5 and C7 species which play important roles in the odd carbon growth mechanism.展开更多
A newly developed low-pressure expendable pattern casting (LP-EPC) process was introduced and its basic principles or effect factors were further analyzed. According to theoretical calculation and experimental results...A newly developed low-pressure expendable pattern casting (LP-EPC) process was introduced and its basic principles or effect factors were further analyzed. According to theoretical calculation and experimental results, the major casting parameters that are of great and critical importance on the process include pressure and flux of filling gas, decomposition characteristic and density of foam pattern, thickness and permeability of coating, pouring temperature, vacuum degree and their combination. Most of casting defects can be effectively avoided by choosing the suitable parameters. The success achieved in pouring motor housing and exhaust manifold castings demonstrates the advantages of LP-EPC process in the production of high-complicated castings with high dimension accuracy.展开更多
基金This work is supported by the National Natu- ral Science Foundation of China （No.51106146 and No.51036007）, China Postdoctoral Science Foundation （No.20100480047 and No.201104326）, Chinese Univer- sities Scientific Fund （No.WK2310000010）, and Chinese Academy of Sciences.
文摘Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomers and polycyclic aromatic hydrocarbons, and measure their mole fraction profiles versus temperature. A low-pressure pyrolysis model of benzene was developed and validated by the experimental results. Rate of production analysis was performed to reveal the major reaction networks in both fuel decomposition and aromatic growth processes. It is concluded that benzene is mainly decomposed via H-abstraction reaction to produce phenyl and partly decomposed via unimolecular decomposition reac- tions to produce propargyl or phenyl. The decomposition process stops at the formation of acetylene and polyyne species like diacetylene and 1,3,5-hexatriyne due to their high thermal stabilities. Besides, the aromatic growth process in the low-pressure pyrolysis of benzene is concluded to initiate from benzene and phenyl, and is controlled by the even carbon growth mechanism due to the inhibited formation of C5 and C7 species which play important roles in the odd carbon growth mechanism.
基金This research work is sponsored and supported by the NationalNatural Science Foundation of China. The item number is50275058
文摘A newly developed low-pressure expendable pattern casting (LP-EPC) process was introduced and its basic principles or effect factors were further analyzed. According to theoretical calculation and experimental results, the major casting parameters that are of great and critical importance on the process include pressure and flux of filling gas, decomposition characteristic and density of foam pattern, thickness and permeability of coating, pouring temperature, vacuum degree and their combination. Most of casting defects can be effectively avoided by choosing the suitable parameters. The success achieved in pouring motor housing and exhaust manifold castings demonstrates the advantages of LP-EPC process in the production of high-complicated castings with high dimension accuracy.
