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Orthogonal array design for the optimization of stripping Sr(Ⅱ) from ionic liquids using supercritical CO2
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作者 Tao Yang Jing Fu +1 位作者 Qingde Chen Xinghai Shen 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2017年第1期26-31,共6页
The strontium ions extracted from the aqueous phase into 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide(C_2mimNTf2) with dicyclohexyl-18-crown-6(DCH18C6) was stripped effectively by supercritical CO_2(s... The strontium ions extracted from the aqueous phase into 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide(C_2mimNTf2) with dicyclohexyl-18-crown-6(DCH18C6) was stripped effectively by supercritical CO_2(sc-CO_2).Hexafluoroacetylacetone(HFAA)-acetonitrile was found to be an excellent modifier of sc-CO_2 to enhance the stripping efficiency.In the orthogonal array design(OAD),OA_(25)(5~5)matrix was employed to optimize the stripping of Sr(Ⅱ) from the DCH 18C6-C_2mimNTf_2 system.Effects of five experimental factors:temperature,pressure,concentration of HFAA,static and dynamic extraction times as well as each factor at five-levels on the stripping of Sr(Ⅱ) were optimized.The effects of these parameters were treated by the analysis of variance(ANOVA).The results showed that Sr(II) could be nearly 100%extracted from the IL phase at 308 K,30 MPa,40 min of dynamic extraction and 60 mmol·L^(-1) HFAA in acetonitrile,respectively.Finally,the stripping mechanism was studied by ESI-MS. 展开更多
关键词 supercritical CO2 stripping Ionic liquid Strontium Orthogonal array design
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Leakage research on supercritical carbon dioxide fluid in rolling piston expander 被引量:3
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作者 TIAN Hua MA YiTai +2 位作者 LI MinXia LIU ShengChun WANG KaiYang 《Science China(Technological Sciences)》 SCIE EI CAS 2012年第6期1711-1718,共8页
The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon di... The leakage research on supercritical carbon dioxide fluid in rolling piston expander was investigated experimentally.Using expander instead of throttle valve is an important way to improve the efficiency of carbon dioxide refrigeration system.However,the supercritical fluid leakage in expander is serious and is the main factor affecting the expander's efficiency.This paper presented and compared four classic leakage models.The analysis indicated that laminar leakage model is suitable in leakage simulation of expander.A leakage test system,including the leakage test part which has two types of leakage specimens with different gaps ranging from 5 to 15 m,was established.The experimental results indicated that lubricant film played an important role.When the leakage clearance of cylindrical specimen was 5 m,the mass flow rate of leakage was about 0.88 g s-1.The data was 3.638 g s-1 with leakage clearance being 10 m and 7.11g s-1 with leakage clearance being 15 m.A modified leakage model was developed,whose average deviation was within 10% compared with the experimental data.At last,this paper simulated the leakage in rolling piston expander presented by Tian et al.(2010).The leakage between rolling piston and cylinder was the most serious part with the value up to 0.04 kg s-1. 展开更多
关键词 LEAKAGE supercritical carbon dioxide liquid rolling piston expander leakage model
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