A {NIT] cluster-substituted sandwich-type phosphotungstate Na10（NH4）4[{（B-a-PW9034）Ni3 （OH）（H20）2（HAle））2Ni].22H20 （1） was synthesized using the conventional aqueous solution method. Compound 1 represents...A {NIT] cluster-substituted sandwich-type phosphotungstate Na10（NH4）4[{（B-a-PW9034）Ni3 （OH）（H20）2（HAle））2Ni].22H20 （1） was synthesized using the conventional aqueous solution method. Compound 1 represents the first nickel-containing sandwich-type polyoxometalate functionalized by bisphosphonate ligands. Further, the sandwich-type polyoxoanions aggregated via the H-bonding interactions into a two-dimensional （2D） suoramolecular framewnrk.展开更多
基金supported by the National Natural Science Foundation of China(No.21101022)Fundamental Research Funds for the Central Universities(No.10QNJJ009)
文摘A {NIT] cluster-substituted sandwich-type phosphotungstate Na10（NH4）4[{（B-a-PW9034）Ni3 （OH）（H20）2（HAle））2Ni].22H20 （1） was synthesized using the conventional aqueous solution method. Compound 1 represents the first nickel-containing sandwich-type polyoxometalate functionalized by bisphosphonate ligands. Further, the sandwich-type polyoxoanions aggregated via the H-bonding interactions into a two-dimensional （2D） suoramolecular framewnrk.
