Surface characteristics and wetting mechanism of respirable coal dust

In this study,FTIR and XPS spectroscopy,specific surface area and pore size analyses,wetting and other experimental means have been applied to investigate respirable coal dust surface properties and wetting mechanism.The research shows that coal dust surface structures,chemical and element compositions are changed in the refining process of coal dust.Compared with large particle coal dust,respirable coal dust is a weak hydrophilic and strong hydrophobic substance.The reason:the smaller the particle size of coal dust,the more unsaturated its surface.The absorption of air is strong and it is easy to form an air film on coal dust surfaces. Coal dust contact with water is actually a compound contact of liquid in contact with a solid and gas in contact with a solid. The smaller the particle size,the larger the pore volume and the higher the degree of surface roughness,the larger the area of gas in contact with a solid and the worse the coal dust wettability.Another reason is that the changes in the composition of atoms on the dust surface and structures affect coal dust wettability.The results of this study establish a theoretical basis for the invention of effective reduced-dust technology.

Surface characteristics of rapidly solidified nickel-based superalloy pow-ders prepared by PREP

The surface microstructure and the surface segregation of FGH 95 nickel-basedsuperalloy powders prepared through plasma rotating electrode processing (PREP) have beeninvestigated by using SEM and AES. The results indicate that the surface microstructure of powderschanges from dendrite into cellular stricture as the particle size of powders decrease, and thepredominant precipitates solidified on the particle surfaces were identified as MC' type carbidesenriched with Nb and Ti. It was also indicated that along with the depth of particle surfaces, thesegregation layer of S, C and O elements are thick, and that of Ti, Cr elements are thin for largesire powders while they are in reverse for median size particles.

Surface Characteristics of Mussel-inspired Polydopamine Coating on Titanium Substrates

Mussel adhesive proteins are non-toxic, biodegradable and have low immunogenic qualities that make them highly attractive for medical purposes compared with man-made materials. 3,4-DOPA, which is a dopamine precursor, is a critical element for achieving mussel-like adhesive properties. In present study, polydopamine was coated onto the titanium surfaces by dipping in a 2 mg/mL dopamine solution in 10 mM Tris- HCl buffer at pH 8.5. EDX element analysis and Raman spectroscopic analysis of the surface were conducted to verify the formation of polydopamine. The surface characteristics of polydopamine-coated titanium plates were observed by SEM and AFM. Hydrophilicity and corrosion-resistance were also evaluated by static contact angle measurements and potentiodynamic polarization corrosion tests. The absorption intensity for pH-induced polymerization rapidly increased for the initial four hours and thereafter smoothly increased. EDX element analyses revealed that the content of carbon and oxygen increased and the content of titanium decreased after the coating process. In the Raman spectra, polydopamine resulted in two new peaks at approximately 1 370 and 1 570 cm^-1 resulting from the stretching and deformation of catechol. Microstructural features revealed that nanometer-sized bright granules were randomly distributed after coating, and these nanoparticles grew with increased coating time. The Ra values of polydopamine-coated titanium plates were showed to increase with coating time. Compared to the pure titanium curve, the inflection point of polydopamine-coated titanium was located at a higher corrosion potential and lower corrosion current density. Findings from our research suggested that polydopamine coatings offer a versatile approach for titanium surface modification.

CHANGE OF SURFACE CHARACTERISTICS DURINGOXYGEN BLEACHING OF SULPHATE PULP

The change of surface characteristics during oxygen bleaching of sulphate pulp was analysed by using ESCA. The results show that oxygen to carbon ratios gradually increase andbinding staes of carbon markedly change during oxygen bleaching of birch sulophate pulp. ESCA is anovel and useful tool for the Study of pulp bleaching.

Comparison of Surface Characteristics of Mesoporous Titania Prepared in Matrix-Free Solutions and Using Triton X Reverse Micelles

Titania nanoparticles have been prepared from the precursor compound Ti(OiPr)4 using Triton X reverse micelles with varying surfactant tail, in a matrix-free aqueous (pH 2) and in non-aqueous phase (benzyl alcohol and glacial acetic acid, solvothermal method). The importance of this work lies in the further elucidation in the synthetic methodology of preparing well-characterized nanoporous solids. Comparison of the texture characteristics and surface properties of the samples prepared from each technique, was carried out using physicochemical techniques: pXRD, ΒΕΤ/DFT/BJH, FTIR, DRUV-Vis and SEM. The results show that the use of Triton X reverse micelles with varying surfactant size results in TiO2 solids with adjustable surface characteristics in contrast to matrix-free. Specifically, samples of the latter methods present higher surface area values at lower calcination temperatures but present reduced thermal stability and control of their surface properties.

Role of biochar surface characteristics in the adsorption of aromatic compounds:Pore structure and functional groups

Biochar(BC)are widely used as highly efficient adsorbents to alleviate aromatics-based contaminants due to their ease of preparation,wide availability,and high sustainability.The surface properties of BCs usually vary greatly due to their complex chemical constituents and different preparation processes and are reflected in the values of parameters such as the specific surface area(SSA),pore volume/size,and surface functional groups(SFGs).The effects of SSA and pore volume/size on the adsorption of aromatics have been widely reported.However,the corresponding mechanisms of BC SFGs towards aromatics adsorption remains unclear as the compositions of the SFGs are usually complex and hard to determine.To address in this gap in the literature,this review introduces a new perspective on the adsorption mechanisms of aromatics.Through collecting previously-reported results,the parameters log P(logarithm of the Kow),polar surface area,and the positive/negative charges were carefully calculated using Chem Draw3D,which allowed the hydrophobicity/hydrophilicity properties,electron donor-acceptor interactions,Hbonding,and electrostatic interactions between SFGs and aromatics-based contaminates to be inferred intuitively.These predictions were consistent with the reported results and showed that tailor-made BCs can be designed according to the molecular weights,chemical structures,and polarities of the target aromatics.Overall,this review provides new insight into predicting the physicochemical properties of BCs through revealing the relationship between SFGs and adsorbates,which may provide useful guidance for the preparing of highly-efficient,functional BCs for the adsorption of aromatics.

Surface characteristics of microalgae and their effects on harvesting performance by air flotation

Flotation is considered as an effective and energy efficient method for harvesting microalgae.However,the interaction mechanism between bubble-algae cell and cell-cell interfacial boundaries in microalgae flotation is not completely clear.To better understand the effects of surface characteristics on microalgae flotation performance,the hydrophobicity and the zeta potential of two different microalgae species were quantified based on experimental measurements and the extended DLVO(Derjagin–Landau–Verwey–Overbeek)theory.Flotation experiments were then carried out and the effects of surface characteristics on microalgae flotation performance were analyzed.Algae Chlorella vulgaris and Anabaena vasriabilis show naturally hydrophilic and hydrophobic properties,respectively.The addition of a cationic surfactant(C16TAB)can modify hydrophilic microalgae cells into hydrophobic and further Chlorella hydrophobicity is enhanced with increased C16TAB concentrations.The zeta potentials of both algae strains are negative in the tested pH range.Compared with Chlorella vulgaris,the magnitude of zeta potential of Anabaena vasriabilis is found larger at the same pH,resulting in a more dispersed distribution in the suspension.In addition,flotation experiments demonstrated that microalgae hydrophobicity and zeta potential have significant impacts on the harvesting efficiency and concentration factor.The hydrophobic attraction is found to play a more important role in determining the harvesting performance than electrostatic repulsion between the interacting surfaces,especially for hydrophobicity algae in the present study.Finally,the highest flotation efficiency and the highest concentration factor could not be concurrently obtained for both algae strains,suggesting that optimized flotation conditions should be selected as a compromise.

Recognition of abnormal body surface characteristics of oplegnathus punctatus

To identify the abnormal characteristics of the oplegnathus punctatus is great importance to the detection of iridovirus disease in the breeding environment.In this paper,an advanced neural network model to identify the characteristics of the oplegnathus puncta-tus and predict its different periods of suffering from iridovirus disease is proposed based on the establishment of a data set.First of all,a standard format data set of oplegnathus punctatus and an abnormal format date set are established in order to verify the effective-ness of the method in this paper.And then,the feature extraction fusion method is used for preprocessing in terms of the abnormal format data set,which combines the edge fea-tures extracted by the improved multi-template Sobel operator and the color features extracted by the HSV model.Finally,an improved VGG-GoogleNet network recognition model comes into being through the fusion and improvement of the VGG and GoogleNet neural network structure.The experiments results show that the prediction accuracy rate for oplegnathus punctatus suffering from iridovirus disease in the the abnormal format data set and the standard format data set are improved,which reach 98.55%and 69.18%.

Simulation analysis on characteristics of land surface over western Qinghai-Xizang Plateau during freez-ing-thawing period

Using the Global Energy and Water Cycle Experiment-Asian Monsoon-Tibet Plateau Experiment (GAME-Tibet) observa-tional data-from October 2002 through September 2003-of Gaize in the western Qinghai-Xizang Plateau (QXP),the land-surface characteristics of the Qinghai-Xizang Plateau are simulated by the improved land-surface model Common Land Model (CoLM).The results show that CoLM can reproduce the land-surface characteristics of plateau areas well.In the sur-face-energy balance of the western QXP in the winter half year,the sensible heat (SH) flux constituted the dominant energy,and the latent heat (LH,here and after) flux is very small.Although the LH flux nearly equals zero in freezing season,it cannot be ig-nored during the period of freezing-thawing in QXP.In the transition season from midto late-May,the frequent phase change of soil water that is caused by the freezing-thawing process leads to the increase of LH flux and decrease of the Bowen ratio.The simulation results also indicate that the changes of surface effective heat fluxes (SH and LH flux) are associated with precipitation and the frequent change between freezing and thawing processes in soil surface.

Characteristics of Laser-Induced Surface and Bulk Damage of Large-Aperture Deuterated Potassium Dihydrogen Phosphate at 351 nm

Deuterated potassium dihydrogen phosphate damage performance at 351 nm is studied on a large-aperture laser system. Bulk and rear-surface damage are initiated under the 3ω fluences of 6.T J/cm2 and 33/cm2, and show different growth characteristics under multiple laser irradiations with the fluence of 6 J/cm2. The size and number of bulk damage keep unchanged once initiated. However, surface damage size also does not grow, while surface damage number increases linearly with laser shots. Different damage thresholds and growth behaviors suggest different formations of bulk and surface damage precursors. The cause of surface damage is supposed to be near-surface absorbing particles buried under the sol-gel coating.

Identification,Characterization,and Probiotic Potentials of Lactobacillus pentosus SF-1

In recent years probiotics have been considered as a potential substitution of antibiotics to control pathogens and treat infectious diseases in aquaculture.In the present study a strain of Lactobacillus pentosus,named as L.pentosus SF-1,was isolated from waters in aquaculture.The species identification of this strain was conducted by 16S rRNA sequence,and the physiological and biochemical characteristics of this strain were assessed.Furthermore,the virulence,antibiotic sensitivity,cell surface characteristics and acid/base-resistance of L.pentosus SF-1 were determined to evaluate the probiotic potentials of this strain.Specifically,L.pentosus SF-1 is sensitive to most common antibiotics,and no hemolysin was generated from it,indicating the safety of this strain to hosts.In addition,L.pentosus SF-1 was able to tolerate the artificial gastric juice at pH 3 for 4 h and the artificial intestinal fluid at pH 6.8 or 8.0 for 6 h.Moreover,the analysis of self-aggregation and the adhesion of L.pentosus SF-1 to organic solvents suggested a high potential of L.pentosus SF-1 to inhabit the hosts,which was confirmed by testing the colonization of L.pentosus SF-1 in germ-free zebrafish.Interestingly,L.pentosus SF-1 displayed a high bactericidal activity against several bacterial pathogens.Consistently,the incubation of L.pentosus SF-1 significantly promoted the expression of antimicrobial components in zebrafish,contributing to the protection of the fish from E.tarda infection in vivo.Taken together,the probiotic strain L.pentosus SF-1 could be applied as anti-infection reagent in aquaculture.

Surface Roughness Around a 325-m Meteorological Tower and Its Effect on Urban Turbulence

Based on slow- and fast-response measurements under neutral stratification conditions from a 325-m meteorological tower located in a built-up area of north-central Beijing as well as a descriptive survey of surface roughness elements (i.e., buildings and trees) around the tower site, urban roughness lengths, zo, with zero-plane displacement height are estimated using logarithmic wind profile and morphometric methods in eight 45° directional sectors. When comparing their results with each other, the slow-response method tends to give smaller zo values. At a given location, considerable directional variations in values are observed. The effect of surface roughness on urban turbulence characteristics in terms of non-dimensional standard deviations of three-component velocity, σi/u*1 (where i = u, v, w and u*1 is local friction velocity), is investigated.

Influence of Repetitive Impulse Waveforms on Surface Discharge Characteristics and Insulation Life for Polyimide Film

Accelerated insulation aging problems under high frequency repetitive impulses in power electronic transformers are drawing more and more attention in modern power systems. Partial discharge (PD) characteristics including discharge inception voltage, phase distribution and statistical characteristics on polyimide (PI) surface under different impulse waveforms and the insulation life of PI films are studied in this paper. We carry out experiments based on PD and insulation lifetime test systems, using five different types of repetitive impulses, including three bipolar waves and two unipolar waves. The experimental results show that there is little variation in discharge inception voltage under different waveforms, but great variation in phase distribution and statistical characteristics of PD. In addition, insulation life is approximately the same under different waveforms with the same polarity, and the aging rate under bipolar waveforms is larger than that under unipolar waveforms. We explain the differences between the bipolar and unipolar waveforms on insulation life, which can be concluded that the surface charge under unipolar waveform accumulates more significnatly compared with bipolar waveform and decreases the electric filed strength in discharging the air gap and inhibits surface discharge from occurring.

Thornthwaite moisture index and depth of suction change under current and future climate‒An Australian study

Climate change is one of the major global challenges and it can have a significant influence on the behaviour and resilience of geotechnical structures.The changes in moisture content in soil lead to effective stress changes and can be accompanied by significant volume changes in reactive/expansive soils.The volume change leads to ground movement and can exert additional stresses on structures founded on or within a shallow depth of such soils.Climate change is likely to amplify the ground movement potential and the associated problems are likely to worsen.The effect of atmospheric boundary interaction on soil behaviour has often been correlated to Thornthwaite moisture index(TMI).In this study,the long-term weather data and anticipated future projections for various emission scenarios were used to generate a series of TMI maps for Australia.The changes in TMI were then correlated to the depth of suction change(H s),an important input in ground movement calculation.Under all climate scenarios considered,reductions in TMI and increases in H s values were observed.A hypothetical design scenario of a footing on expansive soil under current and future climate is discussed.It is observed that a design that might be considered adequate under the current climate scenario,may fail under future scenarios and accommodations should be made in the design for such events.

Surface properties of Al-doped ZnO thin film before and after CF_4/Ar plasma etching

Al-doped ZnO(AZO) is considered as an alternative to transparent conductive oxide materials.Patterning and achieving a stable surface are important challenges in the development and optimization of dry etching processes, which must be overcome for the application of AZO in various devices. Therefore, in this study, the etch rate and surface properties of an AZO thin film after plasma etching using the adaptive coupled plasma system were investigated. The fastest etch rate was achieved with a CF_(4)/Ar ratio of 50:50 sccm. Regardless of the ratio of CF_(4) to Ar,the transmittance of the film in the visible region exceeded 80%. X-ray photoelectron spectroscopy analysis of the AZO thin film confirmed that metal-F bonding persists on the surface after plasma etching. It was also shown that F eliminates O vacancies. Consequently, the work function and bandgap energy increased as the ratio of CF-4 increased. This study not only provides information on the effect of plasma on AZO thin film, but identifies the cause of changes in the device characteristics during device fabrication.

Estimations of Land Surface Characteristic Parameters and Turbulent Heat Fluxes over the Tibetan Plateau Based on FY-4A/AGRI Data

Accurate estimates of land surface characteristic parameters and turbulent heat fluxes play an important role in the understanding of land-atmosphere interaction. In this study, Fengyun-4A (FY-4A) Advanced Geostationary Radiation Imager (AGRI) satellite data and the China Land Data Assimilation System (CLDAS) meteorological forcing dataset CLDAS-V2.0 were applied for the retrieval of broadband albedo, land surface temperature (LST), radiation flux components, and turbulent heat fluxes over the Tibetan Plateau (TP). The FY-4A/AGRI and CLDAS-V2.0 data from 12 March 2018 to 30 April 2018 were first used to estimate the hourly turbulent heat fluxes over the TP. The time series data of in-situ measurements from the Tibetan Observation and Research Platform were divided into two halves-one for developing retrieval algorithms for broadband albedo and LST based on FY-4A, and the other for the cross validation. Results show the root-mean-square errors (RMSEs) of the FY-4A retrieved broadband albedo and LST were 0.0309 and 3.85 K, respectively, which verifies the applicability of the retrieval method. The RMSEs of the downwelling/upwelling shortwave radiation flux and downwelling/upwelling longwave radiation flux were 138.87/32.78 W m^(−2) and 51.55/17.92 W m^(−2), respectively, and the RMSEs of net radiation flux, sensible heat flux, and latent heat flux were 58.88 W m^(−2), 82.56 W m^(−2) and 72.46 W m^(−2), respectively. The spatial distributions and diurnal variations of LST and turbulent heat fluxes were further analyzed in detail.

Characteristics of surface and subsurface of formed thread parts by axial-infeed thread rolling process

The thread rolling process has been widely applied to manufacture high-performance thread parts.In this process,the evolutions of surface and subsurface are frequently introduced,which affect the working performance of manufactured parts.In this study,an axial-infeed thread rolling process(ATRP)is employed,and the macro-meso surface characteristics under different lubrications and operating conditions are investigated.Moreover,the distributions of microstructure and hardness on the subsurface of formed tooth are analyzed in detail,along with the study of stress state and yield strength change.It is found that the MoS_(2)grease is more effective in reducing the surface roughness and defects than the lubrication oil and water-base graphite during the ATRP process.Increasing rolling speed improves the quality of surface morphology and can reduce the surface roughness.On the subsurface of bottom and flank,intensive shear stress occurs in a narrow region,resulting in the elongation and refinement of the grains and increasing the low angle grain boundary fraction.Based on the grain size and plastic strain,the yield strength is predicted.The maximum yield strength and hardness on the bottom of formed tooth are improved by 41.2% and 39.4%,respectively.

放牧对古尔班通古特沙漠南部半固定沙垄地表性质的影响(英文)

Intensive grazing in spring-summer has been responsible for environmental degradation of the Gurbantunggut Desert in recent years. The coverage of plants and biological crusts, sand surface stability and physicochemical characteristics of soil on the dune surface were conducted in 2002 （winter grazing） and 2005 （spring-summer grazing）. The results showed that over 80% of the total area of the dune surface was covered by well-developed biological crusts and plants in 2002, when the interdune and middle to lower part of dune slopes were stabilized and only the crest had 10-40 m wide mobile belt. Affected by spring-summer grazing in 2005, over 80% of the total cover of biological crust was destructed and the plant coverage only reached 1/5 of that in 2002, especially the ephemeral plant cover had a great change. The value of sand transport potential in 2005 only reached 1/3 of that in 2002, but the total surface activity in 2005 was 1.6 times stronger than that in 2002. Meanwhile the mobile area began to expand from the dune top to the whole dune surface following spring-summer grazing. Compared with 2002, medium sand content of the dune surface soil increased by 13.9%, while that of fine and very fine sands decreased by 7.4% and 8.0% respectively in 2005 and the soil organic matter in 2005 was only about 1/2 of that in 2002. It is obvious that the presence of snow cover and frozen soil in winter could avoid the surface structure destruction in winter, while spring-summer grazing made excessive damage to biologic crusts and ephemeral plants. Spring is the main windy season in Gurbantunggut Desert and therefore intensive activity of dune surface occurred following spring-summer grazing, which led to a great loss of fine sand and organic matter. It can be seen that grazing season have a significant influence on the sustainable development of the desert ecosystem in Northwest China.

Influence of substrate process tolerances on transmission characteristics of frequency-selective surface

Frequency-selective surface （FSS） is a two-dimensional periodic structure consisting of a dielectric substrate and the metal units （or apertures） arranged periodically on it. When manufacturing the substrate, its thickness and dielectric constant suffer process tolerances. This may induce the center frequency of the FSS to shift, and consequently influence its characteristics. In this paper, a bandpass FSS structure is designed. The units are the Jerusalem crosses arranged squarely. The mode-matching technique is used for simulation. The influence of the tolerances of the substrate＇s thickness and dielectric constant on the center frequency is analyzed. Results show that the tolerances of thickness and dielectric constant have different influences on the center frequency of the FSS. It is necessary to ensure the process tolerance of the dielectric constant in the design and manufacturing of the substrate in order to stabilize the center frequency.

Evolution of surface morphology and photoluminescence characteristics of 1.3-μm In_(0.5)Ga_(0.5)As/GaAs quantum dots grown by molecular beam epitaxy

Evolution of surface morphology and optical characteristics of 1.3-μm In0.5Ga0.5As/GaAs quantum dots （QDs） grown by molecular beam epitaxy （MBE） are investigated by atomic force microscopy （AFM） and photoluminescence （PL）. After deposition of 16 monolayers （ML） of In0.5Ga0.5As, QDs are formed and elongated along the [120] direction when using sub-ML depositions, while large size InGaAs QDs with better uniformity are formed when using ML or super-ML depositions. It is also found that the larger size QDs show enhanced PL efficiency without optical nonlinearity, which is in contrast to the elongated QDs.