Surface engineering of P2-type cathode material targeting long-cycling and high-rate sodium-ion batteries

The widespread interest in layered P2-type Mn-based cathode materials for sodium-ion batteries(SIBs)stems from their cost-effectiveness and abundant resources.However,the inferior cycle stability and mediocre rate performance impede their further development in practical applications.Herein,we devised a wet chemical precipitation method to deposit an amorphous aluminum phosphate(AlPO_(4),denoted as AP)protective layer onto the surface of P2-type Na_(0.55)Ni_(0.1)Co_(0.7)Mn_(0.8)O_(2)(NCM@AP).The resulting NCM@5AP electrode,with a 5 wt%coating,exhibits extended cycle life(capacity retention of78.4%after 200 cycles at 100 mA g^(-1))and superior rate performance(98 mA h g^(-1)at 500 mA g^(-1))compared to pristine NCM.Moreover,our investigation provides comprehensive insights into the phase stability and active Na^(+)ion kinetics in the NCM@5AP composite electrode,shedding light on the underlying mechanisms responsible for the enhanced performance observed in the coated electrode.

Deghosting towed streamer data in τ/p domain based on rough sea surface reflectivity

Currently, the deghosting of towed streamer seismic data assumes a flat sea level and a sea-surface reflection coefficient of-1; this decreases the precision of deghosting. A new method that considers the rough sea surface is proposed to suppress ghost reflections. The proposed deghosting method obtains the rough sea surface reflection coefficient using Gaussian statistics, and calculates the optimized deghosting operator in the r/p domain. The proposed method is closer to the actual sea conditions, offers an improved deghosting operator, removes the ghost reflections from marine towed seismic data, widens the bandwidth and restores the low-frequency information, and finally improves the signal-to- noise ratio and resolution of the seismic data.

Cloning and Prokaryotic Expression of P23 Major Surface Protein Gene from Theileria sergenti

[Objective] The aim was to study cloning and prokaryotic expression of P23 major surface protein gene of Theileria sergenti. [Method] A pair of specific primers was designed according to the sequence of P23 major surface protein of T. sergenti (D84447).The P23 gene was amplified by PCR from genomic DNA of T. sergenti and cloned into pMD18-T vector to construct recombinant clonal vector pMD18-P23. Positive clones were identified by PCR screening and restriction digestion. A recombinant expression plasmid pGEX-4T-P23 was constructed by subcloning the cloned P23 gene into the linearized pGEX-4T-1 vector and transformed into E. coli BL21. After introduction by IPTG,the expressed fusion protein was identified by SDS-PAGE and Western-blotting. [Result] The cloned gene has a total length of 507 bp. Sequencing result showed that the nucleotide sequence of the cloned P23 gene shared 99.4% identity with that of P23 published in GenBank (D84447). The expressed fusion protein was 46 ku in molecular mass. Induction opportunity of zhours after culture inoculation was the best,the induction time of 6 h was the best,and induction temperature of 34 ℃ was the best as well,IPTG of 1 mmol/L had little effect on the expression. Western-blotting indicated that recombinant protein was recognized by specific antibody. [Conclusion] This study would lay a foundation for further research on the prevention and diagnose of T. sergenti.

TWIP钢表面Ni-P化学镀层组织结构及性能研究

目的在孪生诱发塑性钢(TWIP)表面制备Ni-P镀层,提高TWIP钢的耐腐蚀性能。方法通过化学镀工艺在TWIP钢表面制备了高磷Ni-P镀层,并进行不同温度的热处理,利用扫描电镜及能谱仪、X射线衍射仪及原子力显微镜等探究了热处理温度和时间对Ni-P镀层形貌和组织结构的影响。通过电化学方法研究了TWIP钢表面镀层的耐蚀性能。结果随着热处理温度的升高,镍磷原子发生迁移,胞状组织边界模糊,粗糙度降低,其中600℃热处理镀层表面最为致密平整。随着热处理温度的升高,镀层组织结构演变过程如下:非晶态(普通镀层)→非晶态部分晶化,Ni12P5、Ni5P2等亚稳态镍磷化合物析出(300℃)→非晶态完全晶化、稳态Ni3P相长大(400℃)→晶粒长大(500℃、600℃)。Ni-P镀层能够明显提升TWIP钢的耐腐蚀性能。随着热处理温度的升高,镀层的耐蚀性能先降低后升高。600℃热处理1h镀层的腐蚀电流密度为0.25μA/cm^(2),与普通Ni-P镀层相比降低了80.9%,与TWIP钢基体相比降低了99.6%。600℃热处理镀层光滑致密无缺陷的表面促进了保护性氧化膜的产生,使镀层的耐蚀性能提高。结论合适的热处理工艺提高了Ni-P镀层的致密性和保护能力,光滑致密无缺陷的镀层能够为TWIP钢提供良好的防护。

A series solution for surface motion amplification due to underground group cavities:Incident P waves

A series solution for surface motion amplification due to underground group cavities for incident plane P waves is derived by Fourier-Bessel series expansion method. It is shown that underground group cavities significantly am-plify the surface ground motion nearby. It is suggested that the effect of subways on ground motion should be con-sidered when the subways are planned and designed.

Surface Acoustic Wave Device with Reduced Insertion Loss by Electrospinning P(VDF–TrFE)/ZnO Nanocomposites

Surface acoustic wave(SAW) devices have been utilized for the sensing of chemical and biological phenomena in microscale for the past few decades. In this study, SAW device was fabricated by electrospinning poly(vinylidenefluoride-co-trifluoroethylene)(P(VDF-TrFE)) incorporated with zinc oxide(ZnO) nanoparticles over the delay line area of the SAW device. The morphology, composition, and crystallinity of P(VDF-TrFE)/ZnO nanocomposites were investigated. After measurement of SAW frequency response, it was found that the insertion loss of the SAW devices incorporated with ZnO nanoparticles was much less than that of the neat polymer-deposited device. The fabricated device was expected to be used in acoustic biosensors to detect and quantify the cell proliferation in cell culture systems.

Face Grinding Surface Quality of High Volume Fraction SiC_(p)/Al Composite Materials

The existing research on SiC_(p)/Al composite machining mainly focuses on the machining parameters or surface morphology.However,the surface quality of SiC_(p)/Al composites with a high volume fraction has not been extensively studied.In this study,32 SiC_(p)/Al specimens with a high volume fraction were prepared and their machining parameters measured.The surface quality of the specimens was then tested and the effect of the grinding parameters on the surface quality was analyzed.The grinding quality of the composite specimens was comprehensively analyzed taking the grinding force,friction coefficient,and roughness parameters as the evaluation standards.The best grinding parameters were obtained by analyzing the surface morphology.The results show that,a higher spindle speed should be chosen to obtain a better surface quality.The final surface quality is related to the friction coefficient,surface roughness,and fragmentation degree as well as the quantity and distribution of the defects.Lower feeding amount,lower grinding depth and appropriately higher spindle speed should be chosen to obtain better surface quality.Lower feeding amount,higher grinding depth and spindle speed should be chosen to balance grind efficiently and surface quality.This study proposes a systematic evaluation method,which can be used to guide the machining of SiC_(p)/Al composites with a high volume fraction.

Satellite observations of the partial pressure of carbon dioxide in the surface water of the Huanghai Sea and the Bohai Sea

Based on 5831 continuous in situ measurements of the partial pressure of carbon dioxide on the sea surface p(CO2),related parameters of the sea surface temperature (SST) and chlorophyll-a (Chl a) concentration in 2010 winter,spring and summer of the Huanghai Sea and the Bohai Sea,the inherent relations among them are investigated preliminarily.This study reveals that the seasonal variability of SST and Chl a concentration has a significant influence on p(CO2).The authors have proposed a new algorithm to estimate p(CO2) from SST and Chl a concentration measurements.Compared with the vessel data,the root mean square error (RMSE) of p(CO2) retrieved by using the new model is 13.45 μatm(latm=101.325 kPa) and the relative error is less than 4％.Then,SST and Chl a concentration data observed by satellite are used to retrieve p(CO2) in the Huanghai Sea and the Bohai Sea; and a better accuracy can be obtained if the quality control for sea surface chlorophyll-a concentration observed by satellite is used.The RMSE of retrieved p(CO2) data with quality control and that without quality control are 15.82 μatm and 31.74 μatm,respectively.

FINITE ELEMENT ANALYSIS ABOUT STRESS AND STRAIN OF SURFACE PEELING IN Cu-Fe-P SHEET

The microstructure of surface peeling in finish rolled Cu-0.1Fe-0.03P sheetis analyzed by scanning electron microscope and energy dispersive spectroscope. Fe-rich areas ofdifferent contents are observed in the matrix. The stress distributions and strain characteristicsat the interface between Cu matrix and Fe particle are studied by elastic-plastic finite elementplane strain model. Larger Fe particles and higher deforming extent of finish rolling are attributedto the intense stress gradient and significant non-homogeneity equivalent strain at the interfaceand accelerate surface peeling of Cu-0.1Fe-0.03P lead frame sheet.

PBO纤维表面改性处理的研究进展

聚对苯撑苯并二噁唑(PBO)纤维因其比强度高、比模量高、耐热性好、阻燃性好以及优异的介电性能,现已在安全防护、建筑汽车等领域得到广泛应用。由于PBO纤维表面光滑、化学惰性,导致其与基体树脂界面结合差,进一步影响复合材料的整体性能,这大大限制了PBO纤维优异综合性能的发挥,所以对PBO纤维表面进行改性处理显得尤为重要。介绍了近年来国内外针对PBO纤维不同表面改性方法及对应复合材料性能改善程度的研究进展,从PBO纤维改性方法的分类入手,阐述了各种方法的基本原理。通过对这些处理方法的比较,阐述了国内PBO纤维表面改性的研究进展,指出了国内外在PBO纤维表面改性处理上的差距,为未来的发展方向提供了参考。PBO纤维表面改性方法包括化学刻蚀法、等离子体处理、表面涂层法、化学接枝法、紫外刻蚀法、上浆剂处理等。各种改性技术各有利弊,在选择改性方法时,理应考虑达到工艺快捷有效、经济环保和无损纤维性能等指标。未来,在PBO纤维表面改性的处理方法领域,将逐步向绿色环保的上浆剂处理方向发展。

v_p/v_s ESTIMATION IN TIBETAN CRUST FROM INVERSION OF SURFACE WAVE DISPERSIONS

We estimated crustal v p/ v s ratio of Tibetan Plateau by combined inversion of Love and Rayleigh wave dispersion data. It is developed by us that the joint inversion methods using both Love and Rayleigh wave dispersion data. Thickness and S\|wave velocity of each sub layer are taken from Love wave dispersion data, then P\|wave velocity structure was deduced using Rayleigh wave dispersion data. Densities of sub layers were estimated by the empirical relationships between seismic velocity and rock density. Having S\| and P\|wave velocities, v p/ v s ratio is calculated for each sub layer. Six sub layers in crust of Tibetan Plateau has been identified, which are 0～8km, 8～30km, 30～40km, 40～62km, 62～68km and 68～75km respectively. The S\|wave velocity structure of the Plateau is 3 13, 3 32, 3 15, 3 92, 3 45 and 3 87 km/s for each sub layer; and P\|wave velocities are 6 00, 6 10, 5 72, 6 35, 6 78 and 6 64km/s respectively v p/ v s ratios in sub layers are 1 92, 1 84, 1 82, 1 62, 1 96 and 1 72; and corresponding Poisson ratios are 0 31, 0 29, 0 28, 0 19, 0 32 and 0 24. Our result on Poisson ratios of Tibetan crust was supported by seismic waveform modelling by Rodgers and Schwartz (1998).

Research on the Surface Micro-configuration in Vibration Cutting Particle Reinforced Metallic Matrix Composites SiC_p/Al

The cutting performance of particulate reinforced me tallic matrix composites(PRMMCs) SiC p/Al in ultrasonic vibration cutting and c ommon cutting with carbide tools and PCD tools was researched in the paper. Mic rostructure of machined surface was described, the relation between cutting para meters and surface roughness was presented, and characteristic of the surface re mained stress was also presented. Furthermore, wear regularity and abrasion resi stance ability of tools in ultrasonic vibration cutting and common cutting o f PRMMCs were discussed in detail. The test results show: (1) The surface config urations are obviously different when using different tools to machine such PRMM Cs. The surface machined with carbide tools looks luminous and orderly and there are seldom surface defects on it. The reason is that the soft basal body is apt to flow during cutting, therefore a layer of Al matrix film covers machined sur face. On the contrary, the surface machined with PCD tools looks lackluster. But the profile of machined surface is very clear. Superfine grooves, pits and blac k reinforce particulates can be seen easily without obvious Al film. (2) Because of unstable cutting process in common cutting, the surface is easy to produce s ome defects such as burrs, built-up edges and so on so that the quality of surf ace becomes very poor. Vibration cutting can reduce the influence of tearing, pl astic deformation and built-up edge in cutting and can restrain flutter so as t o make cutting process more stable. Therefore, surface roughness of vibration cu tting is better than that of common cutting. (3) There is an optimum value of fe ed rate in vibration cutting of PRMMCs due to the influence of material characte ristics. Whether feed rate is more than or less than this optimum value, surface roughness will increase. (4) According to analyzing the wear rate of tools in v ibration cutting PRMMCs, it can be concluded that abrasion resistance of tools w ill be improved remarkably when vibration cutting composites have a lower pe rcentage of reinforce particulate. If the percentage of reinforce particulate is higher, the influence on abrasion resistance of carbide tool in vibration cut ting will not be obvious. The research result indicates that vibration cutting effect has a close relation with material characteristics.

Effect of Fe Particle on the Surface Peeling in Cu-Fe-P Lead Frame

Under the surface peeling of Cu- Fe- P lead frame alloy larger Fe particles were observed by energy dispersive spectroscopy. By using the large strain two-dinension plane strain model and elastic plastic finite element method, the cause for peeling damage of Cu-Fe-P lead frame aUoy was investigated. The results show that when the content of Fe particles is more than 30% at local Fe-rich area the intense stress coacentration in the Fe particle would make the Fe particle broken up. The high equivalent stress mutation and the mismatch of equivalent strain 10% at the two sides of intefrace make it easy to develop the crack and peeling damage on finish rolling. The larger Fe particles in the Cu-Fe-P alloy should be avoided.

Analysis of Response Surface in the Study of RE(NO_3)_3-HNO_3-P507-Kerosene Extraction System

RE(NO_3)_3-HNO_3-P507-kerosene extraction system(RE=La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er, Tm,Yb,Lu,Y)was studied by the response surface technique.14 models for extracting single rare earth ele- ment in a broad range of acidity and initial rare earth concentration were obtained by using the stepwise regression method.Three-dimensional display of the response surface of the model of extracting Er^(3+)was showed as an example,which reveals clearly the dependence of distribution ratio upon both initial acidity and ini- tial rare earth concentration.

Cell Surface Display of Red-Grouper Nervous Necrosis Virus Capsid Protein on <i>Pichia pastoris</i>

Nervous necrosis virus (NNV), the etiological agent of viral nervous necrosis, has a high mortality rate of 100% in hatchery-reared larvae and juveniles. At present, there are still no effective vaccines available for NNV. Pichia pastoris surface display of viral capsid proteins was generated in hopes of developing an oral vaccine against red-grouper-nervous-necrosis virus (RGNNV) in fish. Fingerlings or juveniles that showed clinical signs of NNV infection were proved by RT-PCR for the appearance of expected length of 198 bpcDNA and further analysis by DNA sequencing. The DNA fragment containing AGα1 linked to RG-NNVRNA2, 2100 bp in length, was inserted into pPIC9K vector. Linearlized plasmids were electroporated into P. pastoris GS115 (mut+His?) and yeast isolates that had Muts?His+ and resistance phenotype at 4 mg/mL geniticin were selected to determine the integration of the target gene by PCR reaction. The extracted cell walls from the yeasts cultured in buffered-methanol-complex medium (BMMY) through an induction of 0.5% methanol for 6 days, were investigated for the fusion proteins by western blot. A protein band of 73 kDa predicted to be the fusion protein and a non-specific one of 56 kDa were detected. Staining of the fusion proteins expressing cells with corresponding antibodies revealed their presence of NNVRNA2, but varied the intensity of detected signals from cell to cell by confocal laser scanning fluorescence microscopy. The predicted fusion proteins tertiary structure also confirmed exposed conformation of the fusion protein on the cell wall. In this study, the capsid proteins from the red-spotted grouper nervous necrosis virus were successfully expressed on the cell surface of P. pastoris but still low levels of fusion protein expression. Further studies are required to optimize fully surface protein expression prior to evaluate the possible use of the constructed recombinant yeast as an oral vaccine against RG-NNV infection.

利用远震P波和瑞雷面波偏振评估ChinArray一期地震计方位偏差

利用远震P波和瑞雷面波偏振特征的两种独立分析方法,对2011—2013年间在南北地震带南段布设的中国地震科学探测台阵一期台站的方位偏差进行了评估。研究使用了震中距30°-90°范围内696次远震的P波数据和震中距10°-170°范围内1928次地震的瑞雷面波数据。结果显示:两种偏振分析方法所得台站的水平方位角偏差具有较好的一致性。在全部352个台站中,除4个台站由于可用数据较少而未进行评估外,281个台站的南北向分量与地理北向偏差小于10°,21个台站的方位偏差在10°-20°之间,其余台站则出现故障或偏差较大。所获结果与前人基于远震P波的结果类似,但存在7个台站的方位偏差与其结果差异超过5°,进一步的分析表明这些台站在不同时段水平方位角偏差发生过改变,需要分时段进行评估。同时,研究发现仪器不同分量的增益故障会影响仪器水平方位角的偏差估计,可与噪声功率谱结合开展协同评估。

刃口钝圆半径对SiC_(p)/Al复合材料铣削表面质量和切屑形貌影响研究

碳化硅颗粒增强铝基复合材料(SiC_(p)/Al)具有卓越的物理力学性能,广泛应用于航空航天、电子、军事等高端领域。本文以体积分数为20%的SiC_(p)/Al复合材料为研究对象,采用单因素试验方法进行干式铣削,分析刀具刃口钝圆半径和切削速度对切削力、表面形貌、表面粗糙度(Ra)和切屑形貌的影响。结果表明:切削力随着刃口钝圆半径的增加而降低,随着切削速度的增加先降低后增加;随着刃口钝圆半径的增加,加工表面的凹坑和犁沟缺陷减少,表面Ra呈降低趋势。随着切削速度的增加,加工表面的划痕缺陷增多,表面Ra呈现先增加后降低的趋势;在不同刃口钝圆半径和不同切削速度下,切屑形状均呈不规则锯齿状。切屑非自由表面微观形貌随着刃口钝圆半径的增加逐渐变得光滑,随着切削速度的增加出现更严重的裂纹。

原位SERS研究Au纳米结构表面SPR催化对硝基碘苯偶联反应

表面增强拉曼光谱(SERS)因其极高灵敏度和表面特异性,可用于表面等离激元共振(SPR)催化反应过程的原位监测。利用SERS技术原位研究对硝基碘苯(PNIB)在贵金属纳米粒子表面的催化偶联反应过程。研究了激光功率、波长及基底对催化偶联的影响,初步研究了该偶联反应的机理。研究表明,PNIB在金纳米粒子单层膜(Au MLF)表面发生SPR催化偶联反应生成1,2-双(4-碘苯基)二氮烯,增大激光功率可使反应达到平衡时间明显缩短。Au@Ag纳米膜表面偶联效率提高了约10倍,不同基底表面的偶联反应活性为Au@Ag(532nm)>Au@Ag(638nm)>Au(638nm)。该反应为热电子诱导的还原反应。

Some Inequalities for L_p-mixed Affine Surface Area

In this paper, the concepts of the ith L;-mixed affine surface area and Lp-polar curvature images are introduced, some new inequalities connecting these new notions with Lρ-centroid bodies and ρ-Blaschke bodies are showed. Moreover, a Blaschke-Santalo type inequality for Lρ-mixed affine surface area is established. Our results also imply the similar to the inequalities for Marcus-Lopes, Bergstrom and Ky Fan.

Electrochemical behavior of Cu-Zn-Al shape memory alloy after surface modification by electroless plated Ni-P

The electrochemical behavior of Cu-Zn-Al shape memory alloy (SMA) with andwithout electroless plated Ni-P was investigated by electrochemical methods, in artificial Tyrode'ssolution. The results showed that Cu-Zn-Al SMA engendered dezincification corrosion in Tyrode'ssolution. The anodic active current densities as well as electrochemical dissolution sensitivity ofthe electroless plated Ni-P Cu-Zn-Al SMA increased with NaCl concentration rising, pH of solutiondecreasing and environmental temperature uprising. X-ray diffraction analysis indicated that aftersurface modification by electroless plated Ni-P, an amorphous plated film formed on the surface ofCu-Zn-Al SMA. This film can effectively isolate matrix metal from corrosion media and significantlyimprove the electrochemical property of Cu-Zn-Al SMA in artificial Tyrode's solution.