The importance of energy has been rooted in every aspect of human life. If we have no access to electricity and depend on traditional biomass fuels to meet household energy demands, it will mean we cannot enjoy the mo...The importance of energy has been rooted in every aspect of human life. If we have no access to electricity and depend on traditional biomass fuels to meet household energy demands, it will mean we cannot enjoy the modern energy service. With the deepening international understanding of the issue, many countries have been promoting the practice of eliminating energy poverty, and the "universal access to affordable, clean and sustainable energy" has become one of the post 2015 UN development goals.展开更多
An iron(Ⅲ)-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for...An iron(Ⅲ)-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.展开更多
The growing up of green chemistry has now a history of more than twenty years,with a blooming development demonstrated by its great contribution to sustainable development and economical benefit to our society.It is w...The growing up of green chemistry has now a history of more than twenty years,with a blooming development demonstrated by its great contribution to sustainable development and economical benefit to our society.It is well accepted that green chemistry is the development and utilization of a展开更多
文摘The importance of energy has been rooted in every aspect of human life. If we have no access to electricity and depend on traditional biomass fuels to meet household energy demands, it will mean we cannot enjoy the modern energy service. With the deepening international understanding of the issue, many countries have been promoting the practice of eliminating energy poverty, and the "universal access to affordable, clean and sustainable energy" has become one of the post 2015 UN development goals.
基金the National Basic Research Program of China (Nos. 2013CB228103, 2012CB215306)NNSFC (Nos. 21472033, 21325208, 21172209)+3 种基金FRFCU (No. WK2060190025)SRFDP (No. 20123402130008)CAS (No. KJCX2-EW-J02)Fok Ying Tung Education Foundation for the financial support
文摘An iron(Ⅲ)-catalyzed selective oxidation of 5-HMF to 2,5-DFF in air at room temperature was developed.This approach gives 2,5-DFF with good selectivity and yields. Additionally, a two-step process was developed for the oxidation of 2,5-DFF to 2,5-FDCA at remarkably high substrate concentrations. This work demonstrates unequivocally the great potential of iron as a cheap and earth-abundant catalyst for the development of new protocols for the conversion of biomass to value-added chemicals.
文摘The growing up of green chemistry has now a history of more than twenty years,with a blooming development demonstrated by its great contribution to sustainable development and economical benefit to our society.It is well accepted that green chemistry is the development and utilization of a