Swelling-induced morpholine functionalized adamantane-containing poly(aryl ether ketone) (MAPEK) membranes were prepared for vanadium flow batteries. MAPEK membranes were prepared from chloromethylated polymer and mor...Swelling-induced morpholine functionalized adamantane-containing poly(aryl ether ketone) (MAPEK) membranes were prepared for vanadium flow batteries. MAPEK membranes were prepared from chloromethylated polymer and morpholine and further swelling-induced with hot phosphoric acid to obtain membranes with enhanced ionic conductivity. The swelling, selectivity, and ionic conductivity of MAPEK membranes were regulated by varying the swelling temperature. Selective swelling-induced microphase separation in MAPEK membranes, forming wider ion transport pathways and resulting in low area resistance. The unique rigid adamantane-containing backbone limited the swelling of membranes. Consequently, MAPEK membranes showed excellent selectivity and conductivity (vanadium ion permeability coefficient of MAPEK membranes was lower than 3.82 × 0−7 cm2min−1) (Nafion212 membrane, 42.5 × 0−7 cm2min−1), and MAPEK-150 membrane exhibited low area resistance (0.17 Ωcm2). The vanadium flow batteries (VFB) with MAPEK-150 membrane exhibited high energy efficiency (91.1% at 80 mAcm−2, 81.4% at 200 mAcm−2). Furthermore, MAPEK membranes showed good stability in VFB and oxidative electrolytes. The swelling-induced method utilized in this work is a versatile and facile method to enhance the conductivity of ion-exchange membranes.展开更多
The present work investigates the thermally controlled deformation characteristics in temperature-sensitive hydrogels bilayers.The free energy density for temperature-sensitive hydrogels is modified,upon which the fin...The present work investigates the thermally controlled deformation characteristics in temperature-sensitive hydrogels bilayers.The free energy density for temperature-sensitive hydrogels is modified,upon which the finite element model is developed and implemented through user-defined material subroutine UHYPER in the commercial software ABAQUS.The modified UHYPER implementation allows for more vividly depicting the continuous deformation in phase temperature region for temperature-sensitive hydrogels.Several thermally controlled cases of temperature-sensitive hydrogel including grippers,self-folding boxes,thermally driven origami are presented to illustrate a wide array of complex interesting applications or phenomena.Furthermore,we develop a simple model to theoretically calculate the bending angle of the temperature-sensitive hydrogel bilayers,which has been validated by the finite element simulation results.Our study can provide more insights for optimal design in thermally controlled hydrogels structures.展开更多
基金supports from the National Natural Science Foundation of China(21444006,21706164)the State Key Laboratory of Fine Chemicals,Dalian University of Technology(KF2106)+3 种基金Liaoning Provincial Education Department(LJ2019005)Natural Science Foundation of Liaoning Province(2021-NLTS-12-01)Liaoning Revitalization Talents Program(XLYC1907029)Liaoning Provincial Science and Technology Department(2019-MS-261)is greatly appreciated.
文摘Swelling-induced morpholine functionalized adamantane-containing poly(aryl ether ketone) (MAPEK) membranes were prepared for vanadium flow batteries. MAPEK membranes were prepared from chloromethylated polymer and morpholine and further swelling-induced with hot phosphoric acid to obtain membranes with enhanced ionic conductivity. The swelling, selectivity, and ionic conductivity of MAPEK membranes were regulated by varying the swelling temperature. Selective swelling-induced microphase separation in MAPEK membranes, forming wider ion transport pathways and resulting in low area resistance. The unique rigid adamantane-containing backbone limited the swelling of membranes. Consequently, MAPEK membranes showed excellent selectivity and conductivity (vanadium ion permeability coefficient of MAPEK membranes was lower than 3.82 × 0−7 cm2min−1) (Nafion212 membrane, 42.5 × 0−7 cm2min−1), and MAPEK-150 membrane exhibited low area resistance (0.17 Ωcm2). The vanadium flow batteries (VFB) with MAPEK-150 membrane exhibited high energy efficiency (91.1% at 80 mAcm−2, 81.4% at 200 mAcm−2). Furthermore, MAPEK membranes showed good stability in VFB and oxidative electrolytes. The swelling-induced method utilized in this work is a versatile and facile method to enhance the conductivity of ion-exchange membranes.
基金The authors are grateful for the support by National Natural Science Foundation of China under Grant Nos.11902167 and 12072167the special research funding from the Marine Biotechnology and Marine Engineering Discipline Group in Ningbo University。
文摘The present work investigates the thermally controlled deformation characteristics in temperature-sensitive hydrogels bilayers.The free energy density for temperature-sensitive hydrogels is modified,upon which the finite element model is developed and implemented through user-defined material subroutine UHYPER in the commercial software ABAQUS.The modified UHYPER implementation allows for more vividly depicting the continuous deformation in phase temperature region for temperature-sensitive hydrogels.Several thermally controlled cases of temperature-sensitive hydrogel including grippers,self-folding boxes,thermally driven origami are presented to illustrate a wide array of complex interesting applications or phenomena.Furthermore,we develop a simple model to theoretically calculate the bending angle of the temperature-sensitive hydrogel bilayers,which has been validated by the finite element simulation results.Our study can provide more insights for optimal design in thermally controlled hydrogels structures.
